Dr. Grandinetti Chemistry 121 Autumn Quarter 1998 FIRST EXAMINATION Name Thursday October 22, 1998 7:30 - 8:48 PM Rec. Instr. Two-Digit Section No. Lab. Instr. -------------------------------------------------------------------------INSTRUCTIONS 1. First fill out the answer sheet as follows, using #2 pencil only. (Ink will not record). a) Print your name (Last, First, Middle Initial), starting at the far left. Fill in the corresponding circles below. b) Place your signature on the line above your printed name. c) Print your Social Security Number (without dashes) as the IDENTIFICATION NUMBER, starting at the far left. Fill in the corresponding circles below. d) Print your two-digit section above your printed name and in the columns “K” and “L” of SPECIAL CODES. Fill in the corresponding circles below. Two digit section numbers for lab day, time, and TA. Monday, 8:30 - 11:30 Lab Instructor Section No. Yang, Hsueh-Hui 39 Bullinger, Pat 40 Kahane, Alexandra 41 Pee, Gim-Yang 42 Friday, 8:30 - 11:30 Lab Instructor Section No. Yang, Hsueh-Hui 43 Al Taweel, Amany 44 Hudson, Jeffry 45 Cho, Il-Hwan 46 Beegan, Julie 47 Larson, Ben 48 2. After the proctor gives the signal, make certain you have 4 pages with 25 multiple choice questions and a periodic table. 3. The time allowed is 1 hour and 18 minutes. 4. Only marks on the answer sheet will be graded. 5. When finished hand in only the answer sheet. Useful Information Prefix MegaKiloDeciCentiMilliMicroNanoPicoFemto- Abbreviation M k d c m µ n p f Meaning 106 103 10−1 10−2 10−3 10−6 10−9 10−12 10−15 1. [7 points] A sample of matter, found in Australia, was identified as X and was found to consist of 98% silicon and 2% aluminum. Another sample of matter, also identified as X, was found in Texas and was determined to consist of 90% silicon and 10% aluminum. X is a(n) a. pure substance b. element c. mixture d. none of these 2. [7 points] Which one of the following is the smallest mass? a. 25 kg b. 2.5 × 10−2 Mg c. 2.5 × 1015 pg d. 2.5 × 103 fg e. 2.5 × 1010 ng 3. [7 points] Which one of the following is true about the liter? a. b. c. d. e. it is the SI base unit for volume it is equivalent to a cubic decimeter it is slightly smaller than a quart it contains 106 cubic centimeters all are true. 4. [7 points] Which one of the following objects is the most dense? a. b. c. d. e. an object with a volume of 2.5 L and a mass of 12.5 kg an object with a volume of 139 mL and a mass of 93 g an object with a volume of 0.00212 m3 and a mass of 4.22 × 104 mg an object with a volume of 3.91 × 10−24 nm3 and a mass of 7.93 × 10−14 ng an object with a volume of 13 dm3 and a mass of 1.29 × 103 µg. 5. [7 points] In which one of the following numbers are all of the zeros significant? a. 100.090090 b. 143.29 c. 0.05843 d. 0.1000 1 e. 00.0030020 6. [7 points] The volume of a regular cylinder, a function of its radius (r) and its height (h), is given by the formula V = πr2 h. Using the value 3.1416 for the constant π, the volume, in cm3 , of a cylinder of radius 2.34 cm and height 19.91 cm expressed to the correct number of significant figures in cm3 is a. 342.49471 cm3 b. 342.495 cm3 c. 342.49 cm3 d. 343 cm3 e. 342 cm3 7. [7 points] How many significant figures should there be in the answer to the following problem? (29.2 − 20.0)(1.79 × 105 ) =? 1.39 a. 1 b. 2 c. 3 d. 4 e. None of these 8. [7 points] The output of a plant is 4335 pounds of ball bearings per week (5 days). If each ball bearing weighs 0.0113 g, how many ball bearings does the plant make in a single day? (Use 2.2 lbs = 1 kg). a. 3.84 × 105 9. [7 a. b. c. d. e. b. 7.67 × 104 d. 3.48 × 107 c. 867 e. 2.91 × 106 points] How many electrons, protons, and neutrons are contained in an atom 116 electrons, 116 protons, 92 neutrons 92 electrons, 92 protons, 116 neutrons 24 electrons, 42 protons, 92 neutrons 92 electrons, 92 protons, 24 neutrons none of the above 10. [7 points] Isotopes are atoms that have the same number of but differing number of a. protons, electrons b. neutrons, protons c. protons, neutrons 2 d. electrons, protons 116 92 X? . 11. [7 points] In the modern periodic table the elements are arranged in a. b. c. d. e. alphabetical order order of increasing atomic number order of increasing metallic properties order of increasing neutron content None of the above 12. [7 points] Which group in the periodic table contains only nonmetals? a. 1A b. 6A c. 2B d. 2A e. 8A 13. [7 points] Which one of the following should be the most similar to strontium in chemical and physical properties? a. Li b. At c. Rb d. Ba e. Cs 14. [7 points] Which one of the following molecular formulas is also an empirical formula? a. C6 H6 O2 b. C2 H6 SO c. H2 O2 d. H2 P4 O6 15. [7 points] When a metal and a nonmetal react, the to gain electrons. a. b. c. d. e. e. C6 H6 tends to lose electrons and the metal, metal nonmetal, nonmetal metal, nonmetal nonmetal, metal none of these, these elements share electrons 16. [7 points] Which one of the following contains the greatest number of electrons? a. P3+ b. P c. P2− d. P3− 3 e. P2+ tends 17. [7 points] Of the choices below, which one is not an ionic compound? a. PCl5 b. MoCl6 c. RbCl d. PbCl2 e. all are ionic compounds 18. [7 points] What is the formula of the compound formed between strontium ions and nitrogen ions? a. SrN b. Sr3 N2 c. Sr2 N3 d. SrN2 e. SrN3 19. [7 points] The correct formula for molybdenum(IV) hypochlorite is a. Mo(ClO3 )4 b. Mo(ClO)4 c. Mo(ClO2 )4 d. Mo(ClO4 )4 e. None are correct 20. [7 points] The correct name for CrCl3 is a. b. c. d. e. chromium chlorine chromium(III) chloride monochromium trichloride chromium(III) trichloride none of these 21. [7 points] The atomic masses in the periodic table are not exact numbers. For example, carbon is listed as 12.01115 instead of 12.00000. Why? a. b. c. d. e. our technology does not allow for exact measurement of such a small quantity atoms gain and lose electrons easily and that changes their masses significantly atomic masses listed in the periodic table are weighted averages of isotopic masses atomic masses are measured in real samples that are always contaminated with other elements none of these are the correct reason 22. [7 points] The average atomic weight of copper is 63.5. Copper has two naturally occurring isotopes. One of the isotopes has an atomic weight of 62.9 and an abundance of 69.1%. The other isotope has an abundance of 30.9%. What is the atomic weight of this isotope? a. 63.2 amu b. 63.8 amu c. 64.1 amu 4 d. 64.8 amu e. none of these 23. [7 points] The mass percentage of Al in aluminum sulfate is a. 7.886% b. 15.77% c. 21.93% d. 45.70% e. 35.94% 24. [7 points] A compound with a molecular weight of 110.1 that contained only C, H, and O was analyzed by combustion. The combustion of a 5.19 g sample of the compound resulted in the formation of 12.4 g of carbon dioxide and 2.55 g of water. What is the molecular formula of this compound? a. C6 H6 O2 b. C3 H3 O c. CH3 O d. C2 H6 O5 e. none of these 25. [7 points] C2 H2 burns in O2 to produce CO2 and H2 O according to the following equation. C 2 H2 + O2 → CO2 + H2 O Balance the equation above and calculate how many grams of CO2 will be formed when 3.0 g of C2 H2 reacts with 3.0 g of O2 ? a. 2.8 b. 4.1 c. 6.2 d. 9.4 5 e. none of these 7 6 5 4 3 2 1 H Y La Ac Actinium 89 227.03 Lanthanum 57 138.91 Yttrium 39 88.91 Actinide Series Zr Hf V 24 Cr 52.00 VIB Nb Ta W 231.0359 Pa 232.04 Th Thorium 90 91 Protactinium Nd Praseodymium Ce Cerium U Uranium 92 238.03 60 Neodymium 144.24 Tungsten 74 183.85 Mo Re Np Os Sm Pu 94 (244) Samarium 62 150.36 Osmium 76 190.2 Ru 101.1 Iron Fe Co Rh Ir Eu Ni Pd Pt Gd 64 157.25 Platinium 78 195.08 Palladium 46 106.4 Nickel 28 58.69 95 Am (243) Curium Cm 96 (247) Europium Gadolinium 63 151.96 Iridium 77 192.2 Rhodium 45 102.91 Cobalt 27 58.93 VIIIB Neptunium Plutonium Americium 93 237.05 Pm 61 Promethium (145) Rhenium 75 186.2 Tc (98) 26 55.85 42 43 44 Molybdenum Technetium Ruthenium 95.94 59Pr Tantalum 73 180.95 Niobium 41 92.91 140.9077 58 Mn 25 54.94 VIIB Vanadium Chromium Manganese 23 50.94 VB 140.12 Hafnium 72 178.49 Zirconium 40 91.22 Ti Titanium Sc 22 47.88 IVB Scandium 21 44.96 IIIB Lanthanide Series Rd Radium Fr Francium 88 226.03 (223) 87 Ba Barium Cs Cesium 56 137.33 132.91 55 Sr 38 Strontium Rubidium 87.62 37Rb 85.47 Ca Calcium 20 Potassium K 40.08 39.098 19 Mg Magnesium Na Sodium 12 24.305 22.990 11 Be Berylium Li 4 9.012 IIA Lithium 3 6.941 Hydrogen 1 1.008 IA } Cu Ag Tb Cd Hg 66 Dy 162.50 Mercury 80 200.59 Cadmium 48 112.41 Zinc Zn 30 65.38 IIB Si Ga In Tl Ho 67 164.93 Thallium 81 204.38 Indium 49 114.82 Gallium 31 69.72 Bk 98 Cf (251) 99 Es (254) Pb Er 100 Fm (257) Erbium 68 167.26 Lead 82 207.2 Tin Sn 50 118.69 P As Sb Bi Tm 101 Md (258) Thullium 69 168.93 Bismuth 83 208.98 Antimony 51 121.75 Arsenic 33 74.92 Phosphorus 15 30.974 O S Se Te Po Yb 102 No (259) Ytterbium 70 173.04 Polonium 84 (244) Tellurium 52 127.60 Selenium 34 78.96 Sulfur 16 32.06 Oxygen 8 15.999 VIA F Cl Br I At Lu 103 Lr (260) Lutetium 71 174.97 Astatine 85 (210) Iodine 53 126.90 Bromine 35 79.904 Chlorine 17 35.453 Fluorine 9 18.998 VIIA Berkelium Californium Einsteinium Fermium Mendelevium Nobellium Lawrencium 97 (247) Ge Germanium 32 72.59 14 Silicon Al 13 Aluminum Terbium Dysprosium Holmium 65 158.93 Gold Au 79 196.97 Silver 47 107.87 Copper 29 63.546 IB 28.09 26.98 Nitrogen 7 N C 6 Carbon B Boron 5 14.007 12.011 10.81 VA IVA IIIA He Ne Ar Kr Xe Rn Radon 86 (222) Xenon 54 131.29 Krypton 36 83.80 Argon 18 39.948 Neon 10 20.179 Helium 2 4.003 VIIIA
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