Petersen Chem (practice) Quiz Chapter 13 Name______________ Pd______ 1.000 atm = 760.0 mmHg = 760.0 torr = 14.69 psi = 101.325 kPa = Standard atmospheric pressure Kelvin = Celsius + 273 STP = 0°C and 1.00 atm R = 0.08206 L•atm/(mol•K) SHOW YOUR WORK!!! UNITS!!! Use a periodic table, gas law summary and a molemap. 1. True or False. At the same temperature and pressure, 3 moles of argon (Ar) occupy more volume at STP than 3 moles of methane (CH4). 2. If the pressure on an enclosed gas is increased, and the temperature is not changed, will the volume increase or decrease? (Circle one) 3. If the volume of a gas sample does not change, and the temperature is decreased, will the pressure increase or decrease? 4. Use Boyle's Law to solve this problem. A 500. mL bicycle tire is to be filled to a pressure of 3.50 atm (about 50 psi). What volume of 1.00 atm air would be needed? 5. Use Charles' Law to solve this problem. A 1.80 L helium balloon at a temperature of 298 K inside a store is carried outside to a car where the temperature is 265 K. Assuming no pressure change, what is the volume of the balloon in the car? 6. Combined Gas Law. A 3.0 L (leakproof) flexible balloon at STP is allowed to rise in the atmosphere to an altitude where the temperature is -9.0°C and the pressure is 0.60 atm. What is its volume at this altitude? 7. Avogadro's Law 10.0 grams of CO2 gas occupy a volume of 5.09 L at STP. What volume is occupied by 6.02E24 molecules of this gas at the same conditions? 8. Ideal Gas Law 2.0 moles of C2H6 gas occupy what volume at 745 mmHg and 28°C? 9. The vapor pressure of water is 23.8 mmHg at 25°C. What is the partial pressure of oxygen if it is collected over water at 25°C if the total pressure is 0.991 atm? 10. Butane (C4H10(g)) burns in oxygen to form carbon dioxide and water. Write the equation for this, and then calculate how many liters of CO2 are produced when 1.00 g of butane burns (at STP) (practice) Quiz Chapter 13 Petersen Chem Name______________ Pd______ 1. False. No matter what the gas, the volume of 3 moles of gas at STP = 67.2 L (Avogadro) 2. decrease. Pressure and volume of a gas are inversely related. (Boyle’s Law) 3. decrease. Lowering the temperature slows down the gas molecules and they collide less frequently with the walls, lowering the pressure (Law of Gay-Lussac) 4. P1V1=P2V2 (3.50atm)(500.ml) = (1.00atm)V2 V2 = 1750mL 5. V1/T1 = V2/T2 V2 = 1.60L 6. P1V1/T1 = P2V2/T2 7. V1/n1 = V2/n2 8. PV=nRT 9. Pt = PO2 + PH2O Pt = 0.991atm x 760mmHg/1atm = 753mmHg 753mmHg = PO2 + 23.8mmHg PO2 = 729mmHg 10. C4H10 + 6.5 O2 ---> 4CO2 + 5H2O (or doubled coefficients) 1.00gC4H10 x 1mol/58.12gC4H10 x 4molCO2/1mol C4H10 x 22.4LCO2/1molCO2 = 1.54L CO2 1.80L/298K = V2/265K (1.00atm)(3.0L)/(273K) = ((0.60atm)V2/(264K) V2 = 4.8L n1 = 10.0gCO2 x 1mol/44.01gCO2 = 0.227molCO2 n2 = 6.02E24molecules x 1mol/6.02E23molecules = 10.0molCO2 5.09L/0.227mol = V2/10.0mol V2 = 224L (745/760atm)(V)=2.0mol(0.08206L•atm/mol•K) V = 50.4L
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