Tables for the Identification of Unknowns
Unknown & Derivative Melting and Boiling Points
April 1, 2010
ALCOHOLS (Liquid)
2‐Propen‐1‐ol (allyl alcohol)
1‐Propanol
2‐Butanol
2‐Methyl‐2‐butanol (t ‐Amyl alcohol)
2‐Methyl‐1‐propanol (isobutyl alcohol)
3‐Buthen‐1‐ol
3‐Methyl‐2‐butanol
3‐Pentanol
1‐Butanol
2‐Pentanol
3,3‐Dimethyl‐2‐butanol
2,3‐Dimethyl‐2‐butanol
3‐Methyl‐3‐pentanol
2‐Methyl‐2‐pentanol
2‐Methoxyethanol
1‐Chloro‐2‐propanol
2‐Methyl‐3‐pentanol
2‐Methyl‐1‐butanol
2‐Chloreoethanol
4‐Methyl‐2‐pentanol
3‐Methyl‐1‐butanol
2‐Ethoxyethanol
3‐Hexanol
2,2‐Dimethyl‐1‐butanol
1‐Pentanol
2‐Hexanol
2,4‐Dimethyl‐3‐pentanol
Cyclopentanol
4‐Methyl‐1‐pentanol
4‐Heptanol
1‐Hexanol
2‐Heptanol
Cyclohexanol
3‐Chloro‐1‐propanol
Furfury alcohol
1‐Heptanol
1,3‐Dichloro‐2‐propanol
2‐Octanol
2‐Ethyl‐1‐hexanol
1‐Octanol
1,2‐Ethanediol (ethylene glycol)
2‐Nonanol
1‐Linalool
1‐Phenylethanol
Benzyl alcohol
1,3‐Butanediol
1‐Nonanol
1,3‐Propanediol
Copyright University of Washington 2010
Derivatives
BP
97
97
100
102
108
113
114
116
117
120
120
120
123
123
125
127
128
129
130
132
132
135
136
137
138
139
140
141
153
156
157
159
161
161
172
177
176
179
185
195
197
198
199
202
206
207
213
215
3,5‐Dinitrobenzoate
Napthylurethane
Phenylurethane
50
74
76
116
87
59
76
101
64
62
107
111
96
72
108
80
97
72
104
70
57
64
42
86
109
95
71
75
68
48
61
77
85
70
95
65
61
75
97
51
46
39
115
72
64
60
49
112
77
81
47
129
32
62
169
43
95
113
52
178
101
84
104
113
82
101
88
68
67
72
81
68
61
99
118
58
80
62
54
129
76
130
62
115
63
60
67
56
53
106
134
184
66
164
77
65
43
31
51
143
56
65
46
95
132
48
42
38
45
65
73
33
74
di; 157
65
77
122
65
di; 137
1
ALCOHOLS (Solid)
Dodecyl alcohol
Cinnamyl alcohol
α‐Terpineol
Menthol
1‐Tetradecanol
1‐Hexadecanol
2,2‐Dimethyl‐1‐propanol
4‐Methylbenzyl alcohol
1‐Octadecanol
Benzhydrol
4‐Nitrobenzyl alcohol
Benzoin
Lanosterol
Cholesterol
ALDEHYDES (Liquid)
Heptanal
Furfural
Octanal
Benzaldehyde
Nonanal
Glutaraldehyde
Phenlethanal (phenylactaldehyde)
Salicylaldehyde
3‐Methylbenaldehyde (m ‐tolualdehyde)
2‐Methylbenzaldehyde (o ‐tolualdehyde)
4‐Methylabenzaldehyde (p ‐tolualdehyde)
Decanal
2‐Chlorobenzaldehyde
3‐Chlorobenzaldehyde
Hydrocinnamaldehyde
3‐Methoxybenzaldehyde
3‐Bromobenzaldehyde
2‐Ethoxybenzaldehyde
4‐Methoxybenzaldehyde (p ‐Anisaldehyde)
Cinnamaldehyde
ALDEHYDES (Solid)
1‐Naphthaldehyde
Phenylethanal (phenylacetaldehyde)
Piperonal
2‐Methoxybenzaldehyde
4‐Diethylaminobenzaldehyde
3,4‐Dichlorobenzaldehyde
2‐Nitrobenzaldehyde
3,4‐Dimethoxybenzaldehyde
4‐Chlorobenzaldehyde
2,3‐Dimethoxybenzaldehyde
4‐Bromobenzaldehyde
3‐Nitrobenzaldehyde
2‐Naphthaldehyde
Copyright University of Washington 2010
Derivatives
MP
25
33
36
36
39
50
52
60
60
68
93
137
140
148
3,5‐Dinitrobenzoate
Napthylurethane
Phenylurethane
60
121
79
153
67
66
80
114
152
126
82
82
100
74
91
BP
155
162
171
179
185
189
194
197
199
200
205
207
213
214
224
230
234
247
248
252
Semi‐carbazone
2,4‐DNP
Oxime
109
202
101
222
100
108
230
106
237
100
153
231
204
209
234
102
230
228
127
233
228
219
210
216
121
252
195
194
234
104
209
256
149
57
92
60
35
64
178
100
63
60
49
80
69
103
70
93
40
72
59
64
65
MP
34
34
37
39
41
44
44
45
48
54
57
58
60
Semi‐carbazone
2,4‐DNP
221
163
234
215
241
121
266
254
118
77
141
157
201
195
135
111
74
73
144
79
80
139
140
165
176
168
Derivatives
254
255
Derivatives
256
177
233
231
229
246
245
301
301
261
254
128 (257)
293
270
Oxime
98
100
146
92
93
120
102 (154)
95
110(146)
99
157 (111)
122
156
2
ALDEHYDES (Solid)…Con't
3,5‐Dichlorobenzaldehyde
2,6‐Dichlorobenzaldehyde
2,4‐Dimethoxybenzaldehyde
4‐Aminobenzaldehyde
2‐Chloro‐4‐nitrobenzaldehyde
2,4‐Dichlorobenzaldehyde
4‐(N,N‐Dimethylamino)benzaldehyde
3,4,5‐Trimethoxybenzaldehyde
2‐Chloro‐5‐nitrobenzaldehyde
4‐Hydroxy‐3‐methoxybenzaldehyde
3,5‐Dibromosalicylaldehyde
Isophthalaldehyde
3‐Hydroxybenzaldehyde
5‐Bromosalicylaldehyde
4‐Nitrobenzaldehyde
4‐Hydroxybenzaldehyde
Terephthalaldehyde
2,4,6‐Trimethoxybenzaldehyde
5‐Nitrosalicylaldehyde
AMINES (Liquid)
Diethylamine
sec ‐Butylamine
Isobutylamine
n ‐Butylamine
Diisopropylamine
Pyrrolidine
Triethylamine
2‐Aminopentane
Isopentylamine
n ‐Pentylamine
Piperidine
Di‐n ‐propylamine
Ethylenediamine
Pyridine
2‐Methylpyridine (2‐picoline)
Morpholine
n ‐Hexylamine
Cyclohexylamine
2‐Dimethylaminoethyl alcohol
1,3‐Diaminopropane
Diisobutylamine
2,6‐Dimethylpyridine (2,6‐lutidine)
3‐Methylpyridine (3‐picoline)
4‐Methylpyridine (4‐picoline)
n ‐Heptylamine
Tri‐n ‐propylamine
Di‐n ‐butylamine
1,4‐Diaminobutane
2‐Aminoethanol
2,4,6‐Trimethylpyridine (2,4,6‐collidine)
1,5‐Diaminopentane
Copyright University of Washington 2010
Derivatives
MP
65
71
71
72
74
74
74
78
79
81
85
89
104
106
106
116
116
118
126
Semi‐carbazone
BP
56
63
69
77
84
89
89
92
96
104
106
110
116
116
129
130
132
134
135
136
139
142
143
146
156
157
159
159
171
172
178
Benzamide
2,4‐DNP
Oxime
112
150
106
124
153
234
247 d
222
219
325
277
271 d
230
198
297 d
221
224
257 d
322
271
137
185
84
176
122
220
180
90
126
133
71 (112)
200
203
218
Derivatives
Acetamide
42
76
57
42
48
244
75
40
149
101
148
177
135
3
AMINES (Liquid)…con't
n ‐Octylamine
Benzyldimethylamine
Benzylmethylamine
Aniline
Benzylamine
1‐Amino‐1‐phenylethane
N,N ‐Dimethylaniline
N ‐Methylaniline
2‐Amino‐1‐phenylethane
2‐Methylaniline (o ‐toluidine)
n ‐Nonylamine
3‐Methylaniline (m ‐toluidine)
N ‐Ethylaniline
2‐Chloroaniline
4‐Methylbenzylamine
AMINES (Solid)
Indole
Diphenylamine
2‐Aminopyridine
4‐Methoxyaniline (p ‐anisidine)
4‐Iodoaniline
1,3‐Diaminobenzene (m ‐phenylenediamine)
2,4‐Dichloroaniline
4‐Bromoaniline
2‐Nitroaniline
4‐Chloroaniline
3,4‐Dichloroaniline
8‐Hydroxyquinoline
4‐Methyl‐3‐nitroaniline
2,4,6‐trichloroaniline
2,4‐Dibromoaniline
Ethyl 4‐aminobenzoate
3,4‐Diaminotoluene
Tribenzylamine
2‐Methyl‐3‐nitroaniline
2‐Methyl‐6‐nitroaniline
3‐Aminoacetophenone
2,4‐Diaminotoluene
1,2‐Diaminobenzene (o ‐phenylenediamine)
2‐Bromo‐4‐nitroaniline
4‐Aminoacetophenone
2‐Chloro‐4‐nitroaniline
2‐Methyl‐5‐nitroaniline
3‐Nitroaniline
4‐Methyl‐2‐nitroaniline
4‐Chloro‐2‐nitroaniline
2,4,6‐Tribromoaniline
Triphenylamine
2‐Nitro‐4‐methoxyaniline
2‐Methyl‐4‐nitroaniline
2‐Methoxy‐4‐nitroaniline
Copyright University of Washington 2010
Derivatives
BP
180
181
181
184
185
187
193
196
198
200
201
203
205
208
208
Benzamide
Acetamide
160
105
120
114
65
57
63
116
146
49
125
60
99
137
102
51
110
35
65
MP
52
53
57
58
62
63
63
66
71
72
72
75
78
78
79
88
89
91
92
97
97
99
102
105
106
107
107
114
115
116
122
127
129
130
139
Benzamide
Acetamide
68
180
165
154
222
125
117
204
110
192
144
240
172
174
134
148
264
157
101
71
130
109
di; 191
145
168
92
179
87
107
Derivatives
148
204
146
di; 210
168
167
118
224
301
160
205
161
186
157
148
133
158
157
128
di 244
di 185
129
167
140
117
202
153
150
151
155
99
104
232
4
AMINES (Solid)…con't
1,4‐Diaminobenzene (p ‐phenylenediamine)
4‐Nitroaniline
2‐Aminobenzoic acid (anthranilic acid)
CARBOXYLIC ACIDS (Liquid)
4‐Methylpentanoic acid (isocaproic)
2‐Bromopropanoic acid
Hexanoic acid (caproic)
2‐Bromobutanoic acid
Heptanoic acid (enanthic)
2‐Ethylhexanoic acid
Octanoic acid (caprylic)
4‐Oxopentanoic acid (levulinic)
Benzoic acid
Nonanoic acid (pelargonic)
3‐Methylbenozic acid (m ‐toluic)
Decanoic acid (capric)
3‐Phenlpropanoic acid (hydrocinnamic)
Dodecanoic acid (lauric)
CARBOXYLIC ACIDS (Solid)
Decanoic acid
2‐Oxobutanoic acid
4‐Oxopentanoic acid
Pivalic acid (trimethylacetic)
Acetoacetic acid (3‐oxobutanoic)
3‐Chloropropaoic acid
2‐Phenylbutanoic acid
Dodecanoic acid
Hydrocinnamic acid (phenylpropanoic)
Bromoacetic acid
4‐Phenylbutanic acid
Tetradecanoic acid
Trichloroacetic acid
5‐Phenylpentanoic acid
3‐Bromopropanoic acid
Hexadecanoic acid
Chloroacetic acid
cis ‐a‐Mthyl‐2‐butenoic acid
Cyanoacetic acid
Benzoylformic acid
Octadecanoic acid
Trans ‐2‐Butenoic acid (crotonic)
3‐Methoxyphenylacetic acid
Phenylacetic acid
Glycolic acid (hydroxyacetic)
Iodoacetic acid
4‐Methoxphenylacetic acid
2‐Methylphenylacetic acid
3‐Chloro‐2‐butenoic acid
2‐Chlorophenylacetic acid
Copyright University of Washington 2010
Derivatives
MP
142
147
147
Benzamide
Acetamide
di; 300
199
182
di 304
215
Derivatives
BP
199
205
205
217
223
228
239
246
249
254
263
268
279
299
Anilide
p‐Toluidide
Amide
112
99
95
98
70
63
125
75
92
81
57
102
163
57
126
70
98
78
70
108
158
84
118
78
135
87
121
123
100
112
96
102
110
108 (d )
130
99
94
108
105
100
MP / BP
29 / 284
32
34 / 245
36 / 164
37 / d
42 / 204
42 / 270
44 / 299
48 / 280
50 / 208
52 / 290
54
58 / 198
60
61
62
63 / 189
65 / 199
66
66
70
72 / 189
73
76
79
83
87
90
94
95
Anilide
p‐Toluidide
Amide
71
59
102
130
86
108
120
95
103
117
108 d
157
54
101
78
98
131
85
87
135
91
Derivatives
84
97
90
93
113
91
137
77
198
98
162
71
96
118
102
132
117
97
144
136
143
124
139
170
100
105
91
84
107
141
109
111
106
118
76
120
91
109
160
125
156
120
95
189
161
101
175
5
CARBOXYLIC ACIDS (Solid)…con't
4‐Methylphenylacetic acid
3,4‐Dimethoxyphenylacetic acid
Glutaric acid (pentanedioic acid)
3‐Phenoxypropionic acid
Phenoxyacetic acid
Citric acid hydrate
2‐Methoxybenozic acid (o ‐anisic)
Malic acid (2‐hydroxybutanedioic)
Oxalic acid dihydrate
2‐methylbenzoic (o ‐Toluic acid)
Heptanedioic acid
Nonanedioic acid
3‐Methoxybenzoic acid (m ‐anisc)
Ethylmalonic acid
m ‐Toluic acid
2‐Phenylbenzoic acid
2‐Phenoxybenzoic acid
4‐Bromophenylacetic acid
2‐Acetylbenzoic acid
Methylsuccinic acid
b ‐benzoylpropionic acid
2,6‐Dimethylbenzoic acid
4‐Isopropylbenzoic acid
Benzylmalonic acid
2‐Phenyl‐3‐hydroxy‐propanoic acid
Mandelic acid
3‐Nitrophenylacetic acid
3‐Furoic acid
Benzoic acid
Picric acid
2,4‐Dimethylbenzoic acid
2‐Benzoylbenzoic acid
Dodecanedioic acid
Maleic acid (cis ‐butenedioic)
1‐Naphtylacetic acid
2,5‐Dimethylbenzoic acid
3‐Chlorocinnamic acid
2‐Furoic acid
Trans ‐Cinnamic acid
Decanedioic acid (sebacic)
Malonic acid (propanedioic)
2‐Acetylsalicylic acid
1,3‐Acetonedicarboxylic acid
Pyridine‐2‐carboxylic acid
Phenylpropynoic acid
Methylmalonic acid
5‐Chloro‐2‐nitrobenzoic acid
3‐nitrobenzoic acid
Meso ‐Tartaric acid
4‐Chloro‐2‐nitrobenzoic acid
2‐Naphthylacetic acid
2‐Chlorobenzoic acid
Octanedioic acid (Suberic)
Copyright University of Washington 2010
Derivatives
MP / BP
95
95
98
98
99
100
101 / 200
101
101
104
105
110
110
111
112
113
113
114
115
115
116
116
117
117 d
117
118
120
121
122
123
127
127
128
130
132
132
133
133
133
134
135
135
135 d
137
137
138 d
139
140
140
142
142
142
144
Anilide
p‐Toluidide
Amide
185
224
99
192
131
197
254
125
218
189
186
207
268
144
206
201
150
126
118
200
150
164
217
152
172
160
158
141
195
191
187
155
140
135
124
153
202
230
136
155
76
126
182
164
154
118
186
165
142
142
108
168
201
253
104
142
228
162
131
218
147
176
119
102
210 d
129
157
419 d
143
175
172
136
214
95
177
131
194
116
225
146
139
133
225
169
132
110
169
130
180
165
185
260
180
186
76
143
148
210
170
138
107
100
217
154
143
187
172
200
142
217
6
CARBOXYLIC ACIDS (Solid)…con't
2,4,5‐Trimethoxybenzoic acid
2,6‐Dichlorobenzoic acid
2‐Chlorophenoxyacetic acid
2‐Nitrobenzoic acid
Diphenylacetic acid
4‐Hydroxyphenylacetic acid
2‐Bromobenzoic acid
Benzilic acid
Citric acid (anhydrous)
4‐Nitrophenylacetic acid
2,5‐Dichlorobenzoic acid
Hexanedioic acid (adipic)
3‐Bromobenzoic acid
2,4,6‐Trimethylbenzoic acid
4‐Chlorophenoxyacetic acid
Hydroxymalonic acid
3‐Chlorobenzoic acid
Salicyclic acid (2‐hydroxybenzoic)
1‐Naphthoic acid
2‐Iodobenzoic acid
4‐Nitrophtalic acid
2,4‐Dichlorobenzoic acid
3,4‐Dinitrobenzoic acid
Propene‐2,3‐dicarboxylic acid
5‐Bromosalicylic acid
2‐Chloro‐5‐nitrobenzoic acid
1,2,3‐Propanetricarboxylic acid
3,4‐Dimethylbenzoic acid
3‐Methylsalicyclic acid
3,5‐Dimethylbenzoic acid
d ‐Tartaric acid
3,4,5‐Trimethoxybenzoic acid
5‐Chlorosalicylic acid
3‐Aminobenzoic acid
3,5‐Dinitrosalicylic acid hydrate
Acetylenedicarboxylic acid
4‐methylbenzoic acid (p ‐toluic acid)
3,4‐Dimethoxybenzoic acid
4‐Chloro‐3‐nitrobenzoic acid
2,4‐Dinitrobenzoic acid
4‐Methoxybenzoic acid (p ‐anisic)
2‐Naphthoic acid
3‐Iodobenzoic acid
Coumarin‐3‐carboxylic acid
4‐Nitrophenoxyacetic acid
Succinic acid (butanedioic)
Hippuric acid
Dimethylmalonic acid
4‐Ethoxybenzoic acid
Trans ‐4‐Nitrocinnamic acid
3,4‐Dihydroxybenzoic acid
3‐Hydroxybenzoic acid
2,5‐Dihydroxybenzoic acid
Copyright University of Washington 2010
Derivatives
MP / BP
144
144
146
146
148
148
150
150
153
153
153
154
155
155
156
157 d
158
158
162
162
164
164
165
166
165
165
166
166
166
166
170
171
172
174
174
179
179 / 275
181
182
183
185
185
187
188
188
185
190
193
198
199
200 d
200
204
Anilide
p‐Toluidide
155
121
155
180
173
141
175
192
198
190
189
210
241
136
239
125
123
136
163
141
192
156
189
222
252
104
83
264 d
140
145
154
131
160
171
171
186
192
250
170
230
208
255
170
166
157
163
Amide
185
202
150
176
168
175
155
154
210 d
198
155
220
155
188
133
198
134
142
205
110
200 d
194
166
192 di
232
178
207 d
130
112
133
196 d
177
227
111
181
249 d
160
164
156
203
167
192
186
236
158
260 d
183
269 di
202
196
212
170
218
7
CARBOXYLIC ACIDS (Solid)…con't
d.l‐Tartaric acid
2,3‐Dihydroxybenzoic acid
3,5‐Dinitrobenzoic acid
3,4‐Dichlorobenzoic acid
Phthalic acid
2‐Chlorocinnamic acid
2,4‐Dihydroxybenzoic acid
4‐Hydroxybenzoic acid
3‐Nitrophthalic acid
4‐Cyanobenzoic acid
Piperonylic acid
5‐Nitrosalicylic acid
3‐Chloro‐2‐nitrobenzoic acid
Trans ‐2‐Nitrocinnamic acid
4‐Nitrobenzoic acid
4‐Chlorobenzoic acid
ESTERS (Liquid)
Methyl isovalerate
Isobutyl acetate
Ethyl pivalate (ethyl trimethylacetate)
Methyl crotonate
Ethyl butyrate
n ‐Propyl propionate
n ‐Butyl acetate
Diethyl carbonate
Methyl valerate
Methyl methoxyacetate
Methyl chloroacetate
Ethyl isovalerate
Methyl pyruvate
Methyl a‐hydroxyisobutyrate
Ethyl crotonate
3‐Methylbutyl acetate (isoamy/isopentyl)
Methyl lactate
Ethyl chloroacetate
2‐Methoxyethyl acetate
Ethyl valerate
Ethyl a‐chloropropionate
Diisopropyl carbonate
n ‐amyl acetate
Methyl hexanoate
Cyclopentyl acetate
Ethyl lactate
Ethyl pyruvate
Ethyl dichloroacatete
Ethyl a‐bromopropionate
Butyl butyrate
Ethyl hexanoate
Ethyl trichloroacetate
Hexyl acetate
Methyl acetoacetate
Copyright University of Washington 2010
Derivatives
MP / BP
204
204
207
209
210
212
213
215
218
219
229
230
235
240
241
243
Anilide
BP
117
117
118
119
122
123
126
127
127
130
131
135
137
137
138
142
145
145
145
146
146
147
149
151
153
154
155
158
162
167
168
168
168
170
3,5 Dinitrobenzoate
p‐Toluidide
236
234
147
253
176
126
197
234
179
201
204
226
224
186
211
194
204
Amide
226
175
183
168
220
168
222
162
201 d
223
169
225
185
201
179
Derivative
108
87
93
108
93
74
64
93
108
108
108
93
108
108
93
61
108
73
93
93
123
46
108
93
93
93
93
64
93
93
58
108
8
ESTERS (Liquid)…con't
Methyl heptanoate
Cyclohexyl acetate
Furfuryl acetate
Ethyl b‐bromopropionate
Ethyl acetoacetate
Methyl furoate
Dimethyl malonate
Diethyl oxalate
Ethyl d‐chlorobutyrate
Ethyl heptanoate
Ethylene glycol diacetate
n ‐Heptyl acetate
Methyl octanoate
Dimethyl succinate
Ethyl cyclohexanecarboxylate
Dimethyl methylsuccinate
Phenyl acetate
Diethyl malonate
Methyl benzoate
Dimethyl maleate
Ethyl levulinate
g‐Valerolactone
Ethyl octanoate
Octyl acetate
Ethyl benzoate
Methyl nonanoate
Benzyl acetate
Diethyl succinate
Diethyl fumarate
Methyl phenylacetate
Diethyl maleate
Methyl salicylate
Methyl decanoate
Ethyl phenylacetate
Propyl benzoate
Diethyl glutarate
Ethyl salicylate
Methyl‐b ‐phenylpropionate
ESTERS (Solid)
Ethyl mandelate
Dimethyl itaconate
Methyl stearate
Phenyl salicylate
Diethyl terephthalate
Ethyl 3‐nitrobenzoate
Dimethyl tartrate
1‐Naphthyl acetate
Methyl mandelate
Dimethyl oxalate
Ethyl 4‐nitrobenzoate
Dimethyl isophthalate
Copyright University of Washington 2010
Derivative
BP
172
175
176
179
181
181
182
185
186
187
190
192
193
196
196
196
197
199
199
204
206
207
208
210
212
215
217
217
218
220
223
224
225
228
231
234
234
238
3,5 Dinitrobenzoate
MP
37
39
39
42
44
47
49
49
53
54
56
68
3,5 Dinitrobenzoate
108
112
80
93
93
108
108
93
93
93
46
46
108
108
93
108
145
93
108
108
93
93
61
93
108
113
93
93
108
93
108
108
93
74
93
93
108
Derivative
93
108
108
146
108
93
108
217
108
108
93
108
9
ESTERS (Solid)…con't
Phenyl benzoate
Methyl 3‐hydroxybenzoate
Diphenyl phthalate
Diphenyl carbonate
Methyl 3‐nitrobenzoate
Methyl 4‐bromobenzoate
Ethyl 4‐aminobenzoate
Dimethyl d, l ‐tartarate
Methyl 4‐nitrobenzoate
Propyl 4‐hydroxybenzoate
Dimethyl fumarate
KETONES (Liquid)
3‐Buten‐2‐one (methyl vinyl ketone)
2‐Butanone
3‐Butyn‐2‐one
3‐Methyl‐2‐butanone
3‐Methyl‐3‐buten‐2‐one
Cyclobutanone
3‐Pentanone
2‐Pentanone
1‐Penten‐3‐one
3,3‐Dimethyl‐2‐butanone (pinacolone)
1‐Methoxy‐2‐propanone
4‐Methyl‐2‐pentanone
3‐Methyl‐2‐pentanone
Chloroacetone
3‐Penten‐2‐one
2,4‐Dimethyl‐3‐pentanone
3‐Hexanone
4,4‐Dimethyl‐2‐pentanone
2‐Hexanone
5‐Hexen‐2‐one
4‐Methyl‐3‐penten‐2‐one (mesityl oxide)
Cyclopentanone
5‐Methyl‐3‐hexanone
2‐Methyl‐3‐hexanone
2,4‐Pentanedione (acetylacetone)
4‐Heptanone
1‐Hydroxy‐2‐propanone
3‐Heptanone
2‐Heptanone
Cyclohexanone
2,3‐Hexanedione
3,5‐Dimethyl‐4‐heptanone
2,Methylcyclohexanone
2,6‐Dimethyl‐4‐heptanone
3‐Methylcyclohexanone
4‐Octanone
4‐Methylcyclohexanone
2‐Octanone
2,2,6‐Trimethylcyclohexanone
Copyright University of Washington 2010
Derivative
MP
69
70
74
78
78
83
90
90
96
96
102
3,5 Dinitrobenzoate
BP
81
82
86
94
98
100
102
102
103
106
115
117
118
119
122
124
125
125
128
130
130
131
136
136
139
144
146
148
151
156
158
162
165
168
169
170
171
173
179
Semi‐carbazone
146
108
146
146
108
108
93
108
108
123
Derivatives
141
136
114
173
139
112
158
135
95
150
142
160
113
125
102
164
210
152
119
209
132
196
103
123
167
84
191
126
180
96
199
123
209
2,4‐DNP
117
181
120
181
146
156
144
129
125
163
95
71
125
155
88
130
100
106
108
206
146
209
75
129
89
162
137
66
155
41
Oxime
79
49
49
56
149
91
175
43
39
58
141
10
KETONES (Liquid)…con't
Cycloheptanone
Ethyl acetoacetate
5‐Nonanone
3‐Nonanone
2,5‐Hexanedione
2‐Nonanone
Acetophenone
Ethyl levulinate
Menthone
2‐Methylacetophenone
2‐Hydroxyacetophenone
1,5,5‐Trimethylcyclohexen‐3‐one
1‐Phenyl‐2‐propanone
Propiophenone
3‐Methylacetophenone
Isobutyrophenone
1‐Phenyl‐2‐butanone
3‐Chloroacetophenone
2,4‐Dimethylacetophenone
2‐Chloroacetophenone
n ‐Butyrophenone
d ‐Carvone
4‐Chloroaetophenone
KETONES (Solid)
4‐Methylacetophenone
2,6‐Dimethyl‐2,5‐heptadien‐4‐one
2,4‐Dichloroacetophenone
4‐Chloropropiophenone
4‐Methoxyacetophenone
2‐Hydroxybenzophenone
2‐Methoxybenzophenone
3‐Bromopropiophenone
4‐Phenyl‐3‐buten‐2‐one (benzalacetone)
1‐Indanone
4‐Bromopropiophenone
Benzophenone
4‐Bromoacetophenone
3,4‐Dimethoxyacetophenone
Methyl 2‐naphthyl ketone (2‐Acetonaphthone)
4‐Methyl benzophenone
Benzalacetophenone (chalcone)
a‐Chloroacetophenone
Desoxybenzoin (benzyl phenyl ketone)
Benzoylacetone
1,1‐Diphenylacetone
4‐Methoxybenzophenone
Cinnamalacetone
2,6‐Dimethyl‐1,4‐benzoquinone
4‐Chlorobenzophenone
1,4‐Cyclohexanedione
3‐Nitroacetophenone
Copyright University of Washington 2010
Derivatives
BP
181
181
186
187
194
195
202
205
209
214
215
215
216
220
220
222
226
228
228
229
230
230
232
Semi‐carbazone
2,4‐DNP
163
133
90
112
224
119
199
148
189
205
210
200
200
174
198
181
135
232
187
160
188
163
204
148
93
MP
28
28
34
36
38
39
39
40
41
42
46
48
51
51
54
57
58
59
60
61
61
62
68
73
78
79
80
Semi‐carbazone
2,4‐DNP
Oxime
205
221
208
176
198
260
118
88
48
148
63
87
143
148
257
56
240
102
146
159
212
Oxime
137
60
156
191
207
163
59
61
118
79
70
54
55
94
190
191
231
88
63
113
50
73
95
Derivatives
223
220
251
183
187
233
171
165
208
218
235
121
170
156
148
227
258
239
230
207
262
200
245
214
204
151
170
186
180
223
231
257
185
240
228
115
146
91
143
128
140
149
154
140
89
98
165
116
153
175
105
188
132
11
KETONES (Solid)…con't
4‐Nitroacetophenone
4‐Bromobenzophenone
9‐Fluorenone
4,4’‐Dimethylbenzophenone
Benzil (Dibenzoyl)
3‐Hydroxyacetophenone
3’‐Aminoacetophenone
1,3‐Cyclohexanedione
4‐Hydroxyacetophenone
3,4‐Dihydroxyacetophenone
1,4‐Benzoquinone
1,4‐Naphthoquinone
4‐Hydroxybenzophenone
Benzoin
2,4‐Dihydroxyacetophenone
4,4‐ Dichlorobenzophenone
Camphor
Derivatives
MP
81
82
83
95
95
96
97
104
109
116
116
125
135
137
147
148
178
Semi‐carbazone
350
143
243
195
196 d
2,4‐DNP
Oxime
258
230
284
219
189
257
174
116
196
163
237
199
261
243
247
194
206 d 218
231 di
278
242
245
208
241
177
248 d
192
156
145
184 d
240
198
81
152
200 d
135
119
Derivatives
PHENOLS (Liquid)
2‐Chlorophenol
2‐Methylphenol (o ‐cresol)
2‐Bromophenol
2‐Hydroxybenzaldehyde (Salicylaldehyde)
3‐Methylphenol (m ‐cresol)
2‐Ethylphenol
2,4‐Dimethylphenol
Methyl salicylate 3‐Methoxyphenol
4‐Allyl‐2‐methoxyphenol (Eugenol)
2‐Methoxy‐4‐propenylphenol
BP / MP
176 / 7
191 / 31
195 / 5
197 / 2
202 / 12
207
212 / 27
224 / 19
243
255 / 15
268
α‐Naphthyl‐
urethane
Bromo Derivative
120
142
129
76 di
56 di
95 tri
128
84 tri
135
129
122
150
104 tri
118 tetra
Derivatives
PHENOLS (Solid)
2‐Methylphenol (o ‐cresol)
2‐Methoxyphenol
3‐Bromophenol
3‐Chlorophenol
4‐Methylphenol (p ‐cresol)
4‐Methyl‐2‐nitrophenol
2,4‐Dibromophenol
Phenol
4‐Chlorophenol
2,4‐Dichlorophenol
2‐Nitrophenol
4‐Ethylphenol
4‐Chloro‐2‐methylphenol
2,6‐Dimethylphenol
5‐Methyl‐2‐isopropylphenol (thymol)
4‐Methoxyphenol
2,5‐Dichlorophenol
3,4‐Dimethylphenol
Copyright University of Washington 2010
MP / BP
31 / 191
32 / 205
32 / 236
33 / 214
35 / 202
36
36
42 / 182
43
43
45
47
49
49
50
55
59
63
α‐Naphthyl‐
urethane
142
118
108
158
146
132
166
68 mono
113
128
Bromo Derivative
56 di
116 tri
198 tetra
95 tri
95 tri
117 di
176
160
79 mono
55 mono
142
171 tri
12
Derivatives
PHENOLS (Solid)…con't
4‐Bromophenol
4‐Chloro‐3‐methylphenol
2,6‐Dichlorophenol
3,5‐Dimethylphenol
3,5‐Dichlorophenol
2,4,5‐Trichlorophenol
2,4,6‐Trichlorophenol
2,4,6‐Trimethylphenol
2,6‐Di‐tert ‐butyl‐4‐methylphenol
2,5‐Dimethylphenol
8‐Hydroxyquinoline
4‐Hydroxy‐3‐methoxybenzaldehyde
1‐Naphthol
2,3,5‐Trimethylphenol
2‐Methyl‐4‐nitrophenol
3‐Nitrophenol
4‐tert ‐Butylphenol
1,2‐Dihydroxybenzene (catechol)
3,5‐Dihydroxytoluene
1,3‐Dihydroxybenzene (resorcinol)
2‐Chloro‐4‐nitrophenol
4‐Nitrophenol
2,4‐Dinitrophenol
4‐Hydroxybenzaldehyde
1,3,5‐Trihydroxybenzene
2,3,5,6 ‐Tetramethylphenol
2,4,6‐Trinitrophenol
2‐Naphthol
3‐Methyl‐4‐nitrophenol
1,2,3‐Trihydroxybenzene
2,4‐Dihydroxyacetophenone
Salicylic acid
Copyright University of Washington 2010
MP / BP
64
66
67
68
68
68
68
69
70
75
76
81
94
96
96
97
100
105
106
110
111
114
114
117
117
118
122
123
129
133
147
158
α‐Naphthyl‐
urethane
169
153
Bromo Derivative
95 tri
166 tri
158 di
173
178 tri
Phenylurethane 116
152
105 di
167
110
175
160
91 di
50 mono
193 tetra
104 tri
112 tri
151
145 di
118 mono
151 tri
118 mono
157
84 mono
158 di
13