Printed Circuit Board manufacturing PCB (Printed Circuit Board Board), ), NYÁK PWB (Printed (Printed Wiring Board Board), ), NYHL Wire network + mechanical support + base of assembly Benefits:: Benefits • Higher load load,, better dissipation dissipation,, better surface/ surface /cross section ratio • Automatic assembly, control, control, and rework • Better reliability 2 1 PCB types • Laminates (substrates substrates): ): rigid - flex • Number of layers layers:: • Single layer • Double layers, through-hole plated, • Multilayer • Feature size size:: width of conductiv and insulating stripes • normal: 0,4 – 0,6 mm • Fine : 0,3 – 0,4 mm • Very fine: 0,1 – 0,2 mm (1 raster = 2,54mm, >16mil ~12 – 16 mil ~ 4 – 8 mil 1 mil = 0,01raster) 3 Main steps of manufacturing • • • • • Materials selection (laminate laminate,, copper foil) foil) Mechanical forming (drilling, cutting cutting)) Making hole conductiv Galvanic plating Patterning – Photolithographie Photolithographie,, screen printing – Etching • Soldermask • Surface finishing finishing:: metal plating (galvanic galvanic,, immersion and electroless)) electroless 4 2 Laminate materials Insulating substrate Requirements: Requirements: • Electrical Electrical:: – Bulk resistance (specific ~: ρ) – Surface resistance – Dielectric konstans (ε (ε, DK), loss factor (D (D,, tg tgδδ) – High frequency behavior Dissipated power: power: Pv = U 2 ω C0 ε tgδ • Thermal resistance – Under joining joining,, and joule heat – Thermal expansion coefficient coefficient,, CTE (x,y,z (x,y,z axis) axis) • Water absorption • Mechanical Mechanical:: – Strength – Machinable (drilling, cutting)) cutting – Shouldn’t get buckled The big CTE in z axis cause damage of the plated copper layer: Depends on: number of layers, thickness of the copper layer and thickness of the 5 laminate 6 3 Laminate materials • Polymer resin – Without reinforcements: reinforcements: Flex PCB, – With reinforcements: reinforcements: rigid PCB • Ceramics (special applications only) only) • 7 Reinforcements:: Reinforcements • Responsible for strength,, stretch strength • Increase the heat resistance and electrical parameters.. parameters – Paper Paper,, – Fiberglass Fiberglass,, – Wowen glass – Ceramic fiber Matrix,, resin Matrix • Responsible for the surface surface,, electrical and thermal properties.. properties – Phenolic resin (bakelit): thermal resistance↓ resistance↓, water↑ water ↑ absorption – Epoxi resins: resins: adhesion↑ adhesion↑, electrical resistance ↑ – R&D: poliimid, poliimid, teflon (PTFE), liquid crystal polymers (LCP) 8 4 Laminate types FR series (flame (flame retardant) retardant) • FRFR-2: paper reinforced phenolic – Dark yellow, yellow, stable size • FRFR-3: paper reinforced epoxy – Light beige, beige, good electrical properties, properties, suitable for hole plating • FRFR-4: wowen glass reinforced epoxi – Transparent yellwish yellwish--green, green, good machinable, machinable, plateale, plateale, minimal water absorption • FRFR-5: similar to FRFR-4, better heat resistance, resistance, higher Tg • CEM 1: paper and glass reinforced epoxy epoxy:: cheaper 9 The transformation temperature at different laminate materials The CTE also changes at Tg 10 5 Properties FRFR-3 FRFR-4 FRFR-5 Rbulk, Ωcm (40oC) 4 1012 8.1014 8.1014 R , Ω (40oC) 4 1012 3 1012 3 1015 εrel, (1 MHz) 4,9 4,7 4,6 tg tgδδ (1 MHz) (GHz) 0,04 0,02 0,015 Tolerance of the solder baath (sec) 25 >120 >120 Water absorption (mg) na 15 na Tg, glass transition temperature 150 >165 Thermal expansion coefficient (z axis %) 2525-275° 275°C 5.5 11 12 6 13 Rogers laminates Copper foil • Thickness Thickness:: 17,5µ 17,5µm, 35µ 35µm, (70µ (70µm, 105µ 105µm) – Semi Semi-additiv additiv:: 5 5µ µm Cu + protectiv coating – special (eg eg.. Car electronic 400 µm) • Manufacturing Manufacturing:: galvanoplastic – Electroplating to a rotate steel cilinder, detach after half round • Mounting Mounting:: – Adhesiv foil or a dissolved thermosetting resin 14 7 Maximal load of copper stripes: • marked temperature mains the rising •-the outer layers tolerate double load than inners 15 16 8 Preparations of the laminates •Cutting •Drilling •Degreasing •Micro Micro-etching and dissolve the oxid layer Mechanical processes Cutting:: usual size is 500 – 800m • Cutting Free border Back end: routing • Drilling: single side side:: end of line, not critical Double side, side, multilayer: multilayer: key process, process, one of the first steps steps.. Need a smooth inner surface for metallization Aspect ratio: hole lenght/ lenght/hole diameter 18 9 Drill tools • • • • Material: TungstenMaterial: Tungsten-carbide (Slope Slope): ): 30 – 40o (Top angle): angle): ~140o Speed (rev): rev): 1010-90000/min smaller diameter, diameter, higher speed • Min. d =0,2 – 0,15 mm 19 Suface cleaning • Mechanical: Mechanical: abrasiv cilinder, pumice pumice,, ((wet wet)) • Degreasing Degreasing:: goal is the uniform adhesion of the new coatings (photoresists photoresists,, masks, masks, metals) metals) – Water base materials: materials: • Lúgos: NaOH, Na2CO3, Na3PO4 • Detegents, surfactans Dip or spray methods 20 10 • Organic solvents – Good degreasing efficiency but toxic toxic,, flameable – Chlorinated paraffins (carbon tetrachlorid tetrachlorid,, trichlorotrichloro -ethylene ethylene)) – toxic – Freons – cause ozon depletion • Vapor phase cleaning: cleaning: in a closed room, room, saturated vapor of iso iso-propil propil-alcohole alcohole.. The clear solvent condensed on the cold surface. surface. 21 Ultrahangos tisztítás • A hang longitudinális hullám nyomásváltozás • Kavitációs üreg keletkezik - összeomlik, • p = 108–109Pa, (folyadék – szilárd határfelületen) • Fellazítja, „letépi” a szennyeződést a felületről • Hatása függ: az oldószer – Hőmérsékletétől, – Gőznyomásától, – Felületi feszültségétől – Viszkozitásától 22 11 Ultrahangos tisztítás • • • • f = 20 – 40kHz Idő: 2 – 3 perc, (max. 10perc) Forgatni kell Oldószer: tiszta víz (meleg), – lúgos zsírtalanító oldat, – szerves oldószer, pl. aceton 23 Removing oxide layer • Oxidized surface contains contains:: Cu2O, Cu Cu(OH) (OH)2·CuCO3, • Decrease adhesion of the new films eg eg.. photoresist,, metal photoresist • Usualy acid solvents solvents:: sulfuric or hydrochloride acids (10 – 20 % w/ w/W W) • Curing time time:: 0,5 - 1 min at room temperature 24 12 Printed Circuit Imaging Photomask Photolithographie Sreen printing Photomask preparation Its role role:: transfer the pattern Master artwork: artwork: the first, first, original drawing,, the copies are the drawing teghnological photos • Manual methods: tint drawing, peelable patterns (chartpack, alfaset) → contact photo • Computer aided methods: Circuit design programs PCB design programs: include: artworks (all layers), holes, soldermasks, final controll driver software 26 13 •x;y coordinates Gerber fájl: •Light on/off •aperture size Laser photoplotter •Matrix printer system •Plotter system •Very high resolution 27 Basics of phototechnics Black and white film Photosensitive layer layer:: SilverSilver -halogenide particles disperged in gelatine emulsion Emulzió + fényérzékeny anyag Hordozó Emulsion + photosensitive crystals Fényvédő réteg Subsrate (transparent) Protectiv layer Structure of a film 28 14 Exposition - developing • Exposition: Exposition: AgBr + hν → Ag + Br latent picture • Developing Developing:: complete the reduction in the light affected particles 29 AgBr crystals crystals,, SEM image Exposed and partially developed AgBr particles 30 15 Fixing: Dissolve the unexposed AgBr Hypo bath: Na2S2O3 ⇒ water soluble Ag compound 31 Properties of photos • Negative • Sensitivity Sensitivity:: – ISO/DIN 100/21, 200/24, 400/27 • Density Density:: ((blackness blackness,, opacity) opacity) D = I0/I – Contrast Contrast,, tranprency • Resolution Resolution:: – Above 10000 dpi – Resolution is in inverse ratio to the sensitivity (bigger AgBr particle – higher sensitivity - lower resolution)) resolution 32 16 Masking methodes Goal: protect certain areas of the surface Goal: agains some physical or chemical attact – In contact masks – Out of contact contact,, eg eg:: screen mask 33 Photolithographie • Photoresist Photoresist,, photoimaigeable materials • polimer layer • Usable in PCB, hybrid IC and semiconductor industry • Resolution Resolution,, ~ minimal line width → 20 nm • types types:: – positive negative – liquid solid (film) 34 17 Photochemical background • The absorbed photon give the energy quantum to the reaction (bonding or activation energy energy). ). • W = hc hc/ /λ ⇒ to the succesful reaction need a given energy (λ is lower than a given value value). ). 35 Types of photoresists Positive:: Depolimerisation Positive caused by exposition, exposition, the molecular weight decreased, decreased, the solubility increased increased.. Negative:: polimerisation Negative polimerisation,, cross-linked bonds crossformation influence influence of light light.. The photoresist get nearly insoluble.. insoluble Liquid Solid 36 18 Polymer structures Linear Elágazó (branch?) Cros-linked 37 Positive Positiv e resists • Sensitive for UV, but hardly for visible light • Exposition Exposition:: UV • Developer Developer:: diluted NaOH (5 – 7 g/l) • Stripper Stripper:: organic solvent Negative Negativ e resists • Sensitive for light under 540 nm (yellow light needs in the workplace!) Exposition:: UV Exposition • Developer: weak alkaline solvent (1 – 2% Na2CO3) • Stripper: stronger alkaline solvent (5% NaOH) 38 19 Solid resists • „+” , „„-” the negative is more frequenty used • Thicker → important at the galvanisation • Fewer mnufacturing steps • Uniform layer thickness Mylar (poliészter) Reziszt film PE 39 Manufacturing steps (liquid resists resists)) 1. Clear Clear,, degreased surface 2. Coating methods: methods: – Spin coating (d ~ vk ~ r ) – Screen printing – Liquid carpet 3. Drying - 60…80oC – The solvent is volatilized – Film formation 40 20 41 Manufacturing steps 2 4. Exposition – – – Emulsion side stacked to the resist UV - high high-pressure Hg Hg-vapor lamp (365nm) -distance distance,, time can count, count, then experimental adjusting (dose) dose) 5. Developing – – There is a difference only in solubility solubility,, not soluble and insoluble areas The developer is spayed usually 6. Burning (positive only only)) 7. Etching 42 21 Manufacturing steps 3 - solid resists • Du Pont – Riston film • Laminating 100oC, (panel is preheated), preheated ), surface is roughed • Exposition Exposition:: booth side together,, precise positioning together • Develop Develop:: – Remove mylar film, – Develper is a weak alkaline solution (1 – 2%2%-os Na2CO3), – Spraying, need a mechanical impact 43 Exposition methodes • • • • Contact Imaging Laser Projection Imaging Imaging,, LPI Laser Direct Imaging Imaging,, LDI Step and Repeat Imaging 44 22 Contact Imaging • • • • • • • • Current, trouble trouble--free processes, Cheap instruments, Good productivity, productivity, Low yield, yield, Manual positioning is inaccurate inaccurate,, Low resoution (~100 µm), m), Mas Mask k wearing, wearing, Granular waste waste,, dust causes troubles 45 Laser projection system 46 23 • • • • Good resolution on bigger area, Precise positioning, Good productivity with traditional resists resists,, No contact betwen mask and panel, high yield,, yield • It can make hole into the polymer layer 47 Developed resist patterns, after laser imaging. 48 24 Laser direct imaging 49 • • • • Don’t need photomask photomask,, Very precise positioning positioning,, Suitable for prototyping or small series, Fexible software, adapt to deformations, deformations, psition of the panel, • Good yield • Need a new, new, very sensitive resist resist,, • The working time depends on the complexicity of the circuit. circuit. 50 25 Step and repeat Diminutive projection, mainly for semiconductor industry 51 IC fotoresist technology • Resolution: ~ 20 nm • Exposition: deep UV, 93nm, monochromatic, excimer laser • Step ad repeat • New optical materials (transparent in this wavelength eg eg.. CaF2, • New photoresist materials:: sensitive in materials this wavelength 52 26 Masking methodes Screen printing Applications: Medim or large volume production Medium feature size •Eatch-resist mask •Solder paste •Legend •Uniform layers of photoimigeable liquids (solder mask) 54 27 Properties Fiber properties: Screen properties: •Tensile strenght •Flexibility • Mesh number: holes/inch ~ dpi •Wear resistance • Free area % •Chemical resistance Materials: • Polyester • Metal (stainless 55 steel) Parts of the screen • Frame • Emulsion mask • Filler 56 28 Types and preparation • Direct (emulsion emulsion)) • Liquid Liquid,, fhotosensitive emulsion:: emulsion – dip coating coating,, – drying , – exposition • Good adhesion , ~ 20000 copies • Special illuminating box 57 Indirect photostecil photostecil)) • Negativ photoimigeable film (PVA, PVOH poly poly--vinyl acetate,, ~ alcohole) acetate • Exposition from the direction of substrate side!! side • Developer Developer:: warm water (40° (40°C) • Roll the soft mask into the sreen 58 29 Micrscopic pictures indirect direct 59 Metal stencil • Steel film, apertures cut by: – Laser – (Electrocemical Electrocemical)) etching – Plasma etching • Benefits: – More precise, – Better resolution (127 – 65 µm fine pitc IC IC--s) – Longer lifespan (50 – 100 000 prints prints)) – Good hardness and wear resistant Suitable for solder paste printing 60 30 Electrochemically etched apertures Photolithographie – then etching or galvanizing (the stencil is anode) Laser cut apertures No photo, and chemicals, Better reliability 61 Printing • Table Table:: fixing, rögzítés, positioning,, positioning quick change of panels • Squeegee Squeegee:: – sharp sharp,, chemically proof,, wearproof wearproof – Squeegi angle angle:: 45 – 60o, printing speed 62 31 Paste properties Viscosity: what is the Viscosity: optimum? • Low Low:: easy printing, the printed dots will fuse (overlap) • High High:: the printed pattern will not flow away ⇒ tixotrop Low Low,, when the liquid flow, high,, when it stay at rest high Surface tension Paste types • • • • Etch resist, resist, soldermask soldermask,, Solder paste paste,, Thick film HIC functional materials (conductiv conductiv,, resistor resistor,, dielectric pastes pastes), ), • Inks for legende 63 Etchig • Goal: Goal: removig copper from the uncovered areas.. areas • Etchant Etchant:: – Oxidativ Oxidativ:: Cu → Cu2+ + 2e– acid acid/ /alkaline pH: keep Cu2+ solved 64 32 Etchant types: types: • Acid Acid:: sulfuric Sulfuric acid – hydrogen hydrogen-peroxide H2SO4 ammónium--perszulfát (NH4)2S2O8 ammónium chlorides ferric chloride FeCl3 Copper(II) Copper (II)--chloride CuCl2 Copper--tetrammin complex Copper • Alkalic Alkalic:: [Cu Cu(NH (NH4)4]2+ 65 Etchant properties • Rate of etching (µm/min) – Depends on the temperature and the solvent concentration • Capacity (m2PCB/kg etchant) etchant) • Undercut Undercut,, etch factor: factor: ((vv ⊥/v ) • Selectivity (Sn mask on double layer PCB) • Methode of regeneration • Environmental and health impact 66 33 Etching methodes • Dipping • Spray • Jet stream – Always fresh etchant on the surface – Dissolved copper washed by heavy flow – Possibility of continuous regeneration (Copper recovery, redox potential and pH correction) • Rinse – Minimal dropping out (air knife, rubber cylinder) – The first rinse water is dangerous waste – Cascade rinsing 67 34
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