F O C U S ON P RO JECTS – B IOLOGIC AL GHG MANAGEMENT PROGRAM F UND I NG: CCEMC Funding: $500,000 Proponent Funds: $800,000 Total Project Value: $1,300,000 P RO JE CT TE AM: FEATURED PROJECT Artificial photosynthesis for managing industrially produced CO2 emissions through carbon capture and value creation Dr. Carlo Montemagno, University of Alberta Dr. Paolo Mussone, University of Alberta Kyle Minor, University of Alberta Gordon Nish, University of Alberta Generating high-value chemicals from industrial carbon dioxide emissions Geological carbon capture and storage technology involves capturing carbon dioxide (CO2) emissions at industrial facilities and sequestering the CO2 in underground formations. An alternative approach is to capture the CO2, and convert it into value-added products – generating both economic value and a “double-win” in reducing greenhouse gas (GHG) emissions. We have developed a natural process that allows us to replicate processes found in living systems to create value from emissions deemed to be environmentally damaging, and convert these emissions into value-added products that will contribute to the economy. D R . C A R LO M O NTE M AGNO Lead Principal Investigator Led by Dr. Carlo Montemagno, one of the world’s leading experts in nanotechnology, Ingenuity Lab at the University of Alberta has developed an artificial photosynthesis process that uses targeted natural enzymes and proteins, nano-scale molecular assembly and light to convert CO2 emissions into chemical energy for generating valuable organic chemicals. Inspired by photosynthesis – the process by which plants convert light into chemical energy and fuel to grow – Ingenuity Lab’s biochemical process replicates the metabolic cycle that captures CO2 from the atmosphere and converts it to hydrocarbons or sugars. The process is carbon negative and energy efficient, and results in no unwanted byproducts or toxic waste. This two-year project aims to optimize a scalable engineering system that uses industrial GHG emissions to generate high-value chemicals compatible with Alberta’s petrochemical infrastructure. At an industrial scale, solar energy and inexpensive (intermittent and off-peak) electricity would be used to power the chemical reactions that turn CO2 into valuable chemicals. The process offers a truly green solution for sustainably reducing industrial GHG emissions, while further reducing GHGs by generating high-demand, value-added chemicals that otherwise would be produced through energy-intensive petrochemical manufacturing. SEPTEMBER 2014 Project goals • Develop a novel process that reduces carbon dioxide emissions and adds additional revenue streams to Alberta’s industrial sector by generating high-value chemicals; • Mature the technology to facilitate the transition to pilot plant scale to demonstrate the potential for significant and sustainable greenhouse gas reductions; and • Conduct a commercial assessment of high-value chemicals that can be synthesized through biochemical transformation of process intermediates. Project activities The project’s main objectives and activities (all work will be done at Ingenuity Lab at the University of Alberta) are: 1. Generate extensive homogenous kinetic data for process enzymes – This activity involves determining the kinetics for all steps involved in the artificial photosynthesis process, in order to engineer a complete continuous system. The research team will determine the most economical source for all enzymes (e.g. contracted manufacturing or in-house production) and create a database of comprehensive kinetic rate equations for each enzyme involved, including each immobilized enzyme. 2. Demonstrate the continuous regeneration and net increase of RuBP – RuBP, a small sugar involved in photosynthesis, is a key component of the system. For an economically viable system, the team must show that RuBP can be continuously regenerated and used. The work involves designing and building a bench-top scale prototype with all components integrated, including electrochemical reactor, ATP regeneration reactor (ATP is adenosine triphosphate which provides energy in the system), and a continuous molecular assembly process that mimics natural ATP synthesis and regeneration. 3. Optimize foam “bubble architecture” formulation – For the system to work, a small number of molecules needs to be put into confined spaces in a reactor to enable sufficiently fast chemical reactions. The foam bubble structure (which looks rather like the foamy head on a glass of beer) provides these spaces; all the chemical reactions occur within the tiny channels in between the bubbles. Researchers will optimize the chemical composition of the foam so it has the best properties possible for the most efficient and long-term operation of a reactor in a commercial environment. 4. Do process scale-up demonstration – This activity involves scaling up and optimizing the process from laboratory bench-top to a pilot scale that is 10 times larger – a unit that would fit in the back of a pickup truck, for example. 5. Conduct commercial assessment – Ingenuity Lab has identified more than 60 chemicals that could be made from its process, from polymer precursors to liquid transportation fuels to diabetic sweeteners. A consultant will determine the most economically attractive high-value chemicals for manufacture, based on cost-efficiency of production, market assessment and the competitive landscape. For more information about the project: Dr. Carlo Montemagno, Lead Principal Investigator University of Alberta 780-641-1617 [email protected] CCEMC Celia Sollows 780-239-4150 [email protected] ALBERTA INNOVATES BIO SOLUTIONS Marie Cusack 780-918-4620 [email protected] BIOLOGICAL GHG MANAGEMENT PROGRAM Dr. Susan Wood-Bohm 613-920-0516 [email protected] About CCEMC The CCEMC is a not-for-profit, independent organization with a mandate to establish or participate in funding initiatives to reduce GHG emissions and improve our ability to adapt to climate change. Every year the CCEMC provides millions of dollars in funding for projects that reduce GHG emissions. ccemc.ca About AI Bio Solutions Alberta Innovates Bio Solutions is a Government of Alberta corporation dedicated to investing in research and innovation for the benefit of the province’s agriculture, food and forestry sectors. bio.albertainnovates.ca
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