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SAFETY DATA SHEET
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SDS according to Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and
Restriction of Chemicals (REACH), Annex II-EU
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
Date issued
11.05.2015
1.1. Product identifier
Product name
REACH Reg. No., Comments
Exel Starter
An explosive article.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/preparation
The chemical can be used by the
general public
Exel Starter is a non electric detonator assembly consisting of a coiled
length Exel tube and Exel Connectadet SL connector 0ms.
Exel Starters are designed to provide simple connection to start a blast in
quarry, open cut and underground applications.
Usage of the product only according to existing laws and official permissions.
No
1.3. Details of the supplier of the safety data sheet
Importer
Company name
Postal address
Postcode
City
Country
Tel
E-mail
OY FORCIT AB
P.O.Box 19
10901
Hanko
Finland
+358 (0)207 440 400
[email protected]
1.4. Emergency telephone number
Emergency telephone
National poison information center / National helpdesk:countrywise telephone
number
SECTION 2: Hazards identification
2.1. Classification of substance or mixture
Classification according to
67/548/EEC or 1999/45/EC
Classification according to
Regulation (EC) No 1272/2008
[CLP/GHS]
Additional information on
classification
2.2. Label elements
Hazard Pictograms (CLP)
E; R2
Expl. 1.1;H201;
This classification describes unpacked detonators. The transport classification
can differ depending on the approved packaging.
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Signal word
Hazard statements
Precautionary statements
Other Label Information (CLP)
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Danger
H201 Explosive; mass explosion hazard.
P210 Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P250 Do not subject to grinding/shock/friction.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P370 + P380 In case of fire: Evacuate area.
P372 Explosion risk in case of fire.
P373 DO NOT fight fire when fire reaches explosives.
By using a special approved packaging a reduction of the explosive hazard is
possible. (In that case, signal word: Warning; hazard statement: H204 - Fire
or projection hazard.)
2.3. Other hazards
PBT / vPvB
Health effect
Other hazards
Not determined.
Shrapnel from detonation may cause burns and wounds.
During use of the article, a release of lead-containing reaction products
occurs.
Stythe is heavier than air and may accumulate below ground level, in pits,
channels and basements in higher concentration.
All chemicals are potentially dangerous; they should only be handled by
properly trained personnel with the necessary care.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Substance
Lead(II, IV)oxide
Identification
CAS no.: 1314-41-6
EC no.: 215-235-6
Classification
Xn; R20/22,R33
Rep 3; R62
Rep 1; R61
N; R50/53
Repr. 1A;H360Df;
Acute tox. 4;H332;
Acute tox. 4;H302;
STOT RE2;H373;
Aquatic Acute 1;H400;
Aquatic Chronic 1;H410;
Contents
1,5 %
Pentaerythritol tetranitrate
CAS no.: 78-11-5
EC no.: 201-084-3
Index no.: 603-035-00-5
Synonyms: PETN
CAS no.: 121-82-4
EC no.: 204-500-1
E; R3
Unst. expl.;H200;
6%
E; R2
T; R25
Xn; R36,R38
Expl. 1.1;H201;
Acute tox. 3;H301;
Skin Irrit. 2;H315;
Eye Irrit. 2;H319;
6,5 %
CAS no.: 13424-46-9
EC no.: 236-542-1
Index no.: 082-003-00-7
Unst. expl.; H200
Repr. 1A; H360Df
Acute tox. 4; H332
Acute tox. 4; H302
STOT RE 2; H373
Aquatic Acute 1; H400
Aquatic Chronic 1; H410
Note : E
1,5 %
Hexogen (RDX)
Lead azide
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Description of the mixture
Substance comments
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Because of the sealed assembly of the detonator, no contact to the
ingredients is to be expected under normal use.
The percentages of the ingredients relate only to the detonator (average
value).
The shock tube contains no substances presenting a health or environmental
hazard within the meaning of Directive 67/548/EEC and substances presenting
a health or environmental hazard within the meaning of Regulation (EC) No
1272/2008.
The Full Text for all R-Phrases and Hazard Statements are Displayed in
Section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General
Inhalation
Skin contact
Eye contact
Ingestion
Remove affected person from the danger area and lay down.
If unconscious, place in recovery position and seek medical advice.
Do not leave affected person unattended.
When in doubt or if symptoms are observed, get medical advice.
In case of inhalation of decomposition products, affected person should be
moved into fresh air and kept still.
Get medical attention if any discomfort continues.
In case of respiratory tract irritation, consult a physician. Cortisone spray can
be applied to open the airways. Apply spray at early stage. If breathing is
irregular or stopped, administer artificial respiration.
If skin irritation occurs: Get medical advice/attention.
Shrapnel from detonation may cause burns and wounds, possibly blood
poisoning. Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Shrapnel from detonation may cause great damage, immediately consult an
ophthalmologist.
Rinse mouth thoroughly. Get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Information for health personnel
Delayed symptoms and effects
Symptoms do not necessarily appear immediately. Patients should therefore be
kept under medical observation for at least 48 hours.
If decomposition products are inhaled pulmonary oedema can occur.
4.3. Indication of any immediate medical attention and special treatment needed
Other Information
Not determined.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
DO NOT fight fire when fire reaches explosives. Explosion risk in case of fire.
5.2. Special hazards arising from the substance or mixture
Fire and explosion hazards
May explode when heated or when exposed to flames or sparks. During
fire/explosion may be liberated: Nitrogen oxides (NOx), carbon monoxide (CO),
carbon dioxide (CO2) and lead containing reaction products.
5.3. Advice for firefighters
Fire fighting procedures
Special protective equipment for
firefighters
Other Information
Fight adjacent fire with all available means to prevent fire from reaching the
product.
DO NOT fight fire when fire reaches explosives. Leave danger zone
immediately.
Do not go near burning explosives. Use self-contained breathing protection.
Restrict the number of action force members in the hazard area.
Do not inhale explosion and combustion gases.
Collect contaminated fire extinguishing water separately. Do not allow entering
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drains or surface water.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal protection measures
Use personal protective equipment as required.
6.1.1. For non-emergency personnel
Personal precautions
Emergency procedures
Avoid contact with the product. Do not handle without protective equipment.
Act according to the rescue plan. Evacuate the area and inform manager.
Request assistance from experts.
6.1.2. For emergency responders
For emergency responders
Close the danger zone.
Request assistance from experts.
6.2. Environmental precautions
Environmental precautionary
measures
Not relevant because of the packaging.
6.3. Methods and material for containment and cleaning up
Cleaning method
Other information
Due to the composition and packaging of the substances, spillage is unlikely.
In case of any questions, please contact the supplier.
6.4. Reference to other sections
Other instructions
Fire-fighting, see Section 5.
Personal protection, see Section 8.2.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Handling
Only to be handled by authorized personnel.
The explosives must be under supervision and unavailable for unauthorized
persons.
Operating temperature range from -45 °C to +50 °C.
Handle with care - avoid bumps, friction and impact.
Keep away from sources of ignition - No smoking.
Avoid damage to the shock tube.
Never pull so hard as to stretch or break shock tubing, a premature initiation
may result. Do not use the shock tube as a lowering line.
The detonator is factory assembled into the connector block and no attempt
should be made to disassemble it.
Do not eat, drink or smoke when using the product. Wash hands before
breaks and before smoking, eating or drinking. Do not take contaminated
clothes outside the workplace.
7.2. Conditions for safe storage, including any incompatibilities
Storage
Stacks of cases should be no more than 2 meters high.
Keep in original container. National regulations must be followed with handling
and storage.
Keep cool. Store in a dry place.
Conditions for safe storage
Advice on storage compatability
Maximum storage volume should be agreed with national authorities.
The product should be used within 3 months after opening the inner bags.
Batches of detonators more than 2 years old should not be used.
7.3. Specific end use(s)
Recommendations
Specific use(s)
Obtain special instructions before use.
See Section 1.2
SECTION 8: Exposure controls/personal protection
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8.1. Control parameters
Other Information about threshold
limit values
Lead and inorganic compounds (as Pb), CAS: 7439-92-1:
0,15 mg/m3 (inhalable aerosol), EU
0,05 mg/m3 (total dust), USA
Hexogen (RDX)
CAS: 121-82-4,
Limit value Finland: 1,5 mg/m3 (8 h), 4,5 mg/m3 (15 minutes average value)
DNEL / PNEC
Method of testing
PNEC
PNEC
PNEC
PNEC
PNEC
PNEC
Other Information
Contents
Exposure route: Freshwater
Critical Component: PETN
Value: 0,3 mg/l
Exposure route: Soil
Critical Component: Lead
Value: 147 mg/kg dw
Exposure route: Saltwater sediments
Critical Component: Lead
Value: 164 mg/kg dw
Exposure route: Freshwater sediments
Critical Component: Lead
Value: 174 mg/kg dw
Exposure route: Saltwater
Critical Component: Lead
Value: 3,4 ug/l
Exposure route: Freshwater
Critical Component: Lead
Value: 6,5 ug/l
Because of the sealed assembly of detonators no contact with the ingredients
is to be expected.
In case of broken/damaged detonators, contact with the ingredients can not
be excluded.
8.2. Exposure controls
Recommended monitoring
procedures
The methods for measuring workplace atmosphere have to correspond to the
requirements of norms DIN EN 482 and DIN EN 689.
Safety signs
Precautionary measures to prevent exposure
Product-related measures to prevent
exposure
Instruction on measures to prevent
exposure
Organisational measures to prevent
exposure
Keep cases closed and store in a cool, well ventilated place.
Avoid damage of the article.
Do not eat, drink or smoke when using this product.
Wash hands before breaks and after work.
Minimize the time spent in the danger zone.
Reduce staff in the danger zone to the required level.
Separate storage facilities for street and work clothes should be available
when a risk for contamination of work clothes is to be expected.
Respiratory protection
Respiratory protection
Recommended type of equipment
Under normal conditions of use respiration protection should not be required.
In case of inadequate ventilation: Use respiratory equipment with particle filter,
type P2. /P3
DIN EN 143
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Hand protection
Hand protection
Suitable gloves type
Suitable materials
Use protective gloves.
Half-gloves. DIN EN 388
Nitrile. (NBR)
Eye / face protection
Eye protection
Suitable Eye Protection
Goggles giving complete protection to eyes.
DIN EN 166
Skin protection
Skin protection (except hands)
Work clothes made from cotton meets the requirements.
Choice and design of the work clothes to be used depends on the results of
the risk assessment for the specific working environment.
It is necessary to consider the following needs of protection:
- Protection against heat and open fire (clothing must not melt and not be
flammable).
- Protection against contact with chemicals (the fabric shall not absorb
particles of explosives as this would make the fabric more flammable).
- Protection from electrostatic charging.
- Protective clothing used to protect against further hazards (reflective clothing,
weather proof clothing) must comply with the above requirements.
Hygiene / Environmental
Specific hygiene measures
Wash hands always after work, before eating, drinking, smoking or going to
the bathroom.
Appropriate environmental exposure control
Environmental exposure controls
Use the product according to the given instructions.
Other Information
Other Information
Technical measures and the application of suitable work processes have
priority over personal protection equipment.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Odour
Comments, Odour limit
Comments, pH (as supplied)
Comments, Melting point / melting
range
Comments, Boiling point / boiling
range
Comments, Flash point
Comments, Evaporation rate
Flammability (solid, gas)
Comments, Explosion limit
Comments, Vapour pressure
Comments, Vapour density
Comments, Specific gravity
Solubility description
Comments, Partition coefficient: noctanol / water
Comments, Spontaneous
combustability
Comments, Decomposition
temperature
Solid.
Complex assembly with shock tube and detonator.
Odourless.
Not relevant.
Not relevant.
Not relevant.
Not relevant.
No data recorded.
Not relevant.
Not relevant.
Not relevant.
Not relevant.
Not relevant.
Not relevant.
Not relevant.
Not relevant.
No data recorded.
No data recorded.
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Comments, Viscosity
Explosive properties
Oxidising properties
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Not relevant.
Explosive
Not relevant.
9.2. Other information
Other physical and chemical properties
Comments
Because of the complex assembly of the article information to most of the
requested physical and chemical properties can t be given.
SECTION 10: Stability and reactivity
10.1. Reactivity
Reactivity
In case of impact or pressure influence:
- danger of explosion
- danger of bursting.
10.2. Chemical stability
Stability
The product is chemically stable under standard ambient conditions (room
temperature).
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions
Fire, heat, electrostatic or impact may cause the product to explode.
10.4. Conditions to avoid
Conditions to avoid
Mechanical influences (e.g. shock, pressure, impact, friction).
Fire, sparks or other ignition sources.
Electrostatic discharges.
10.5. Incompatible materials
Materials to avoid
Contact to acids and bases.
10.6. Hazardous decomposition products
Hazardous decomposition products
Lead containing reaction products.
Nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2).
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological Information:
LD50 oral
LD50 oral
Value: 1660 mg/kg
Animal test species: rat
Comments: PETN
Value: 100 mg/kg
Animal test species: rat
Comments: Hexogen (RDX)
Potential acute effects
Irritation
May cause skin and eye irritation.
Delayed effects / repeated exposure
Inhalation
Sensitisation
Chronic effects
STOT-single exposure
STOT-repeated exposure
Gases or fumes from an exploding or burning product may irritate airways
and lungs.
Not known.
Not known.
The substance or mixture is not classified as specific target organ toxicant,
single exposure.
Contains a substance/a group of substances which: May cause damage to
organs through prolonged or repeated exposure.
Carcinogenic, Mutagenic or Reprotoxic
Carcinogenicity
Germ Cell Mutagenicity, human
Not known.
Not known.
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Reproductive toxicity
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Contains a substance/a group of substances which: May damage the unborn
child. Suspected of damaging fertility
Symptoms of Exposure
Other Information
Comments
On the basis of the morphology of the product, no hazardous properties are
to be expected when it is handled and used with appropriate care.
Information on likely routes of exposure: Inhalation of lead fumes and dust.
The following applies to lead compounds in general:
Due to the poor absorbability via the gastrointestinal tract, only very high
doses lead to acute cases of intoxication. After a latency period of several
hours, metallic taste, nausea, vomiting, and colic s occur, in many instances
followed by shock. Chronic uptake causes peripheral muscular weakness
( drop-wrist ), anaemia, and central nervous disorders.
Women of child-bearing age should not be exposed to the substance over
longer periods of time (observe critical threshold).
Handle in accordance with good industrial hygiene and safety practice.
SECTION 12: Ecological information
12.1. Toxicity
Ecotoxicity
The product contains a substance which is very toxic to aquatic organisms.
Toxicological data for substances
Substance
Acute aquatic, fish
Acute aquatic, Daphnia
Lead(II, IV)oxide
Value: 0,1 mg/l
Method of testing: LC50
Duration: 96 h
Value: 0,98 mg/l
Method of testing: EC50
Duration: 48 h
12.2. Persistence and degradability
Persistence and degradability
Not determined.
12.3. Bioaccumulative potential
Bioaccumulative potential
Not determined.
12.4. Mobility in soil
Mobility
Not determined.
12.5. Results of PBT and vPvB assessment
PBT assessment results
Not determined.
12.6. Other adverse effects
Other adverse effects / Remarks
Prevent from entering drains and water courses.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Specify the appropriate methods of
disposal
Product classified as hazardous
waste
EWC waste code
Leave product in original containers. No mixing with other waste. Explosives
waste and explosives-tainted containers must be collected immediately and
disposed only under the supervision of experts and in accordance with given
regulations.
Uncleaned empty containers are to be handled in the same way as the ones
containing products. For any further information, please contact the seller or
manufacturer.
Yes
EWC: 160403 other waste explosives
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SECTION 14: Transport information
14.1. UN number
ADR
RID
IMDG
ICAO/IATA
Comments
0361
0361
0361
0361
Even UN number 0500 (1.4S) can be used depending on the packaging.
14.2. UN proper shipping name
ADR
RID
IMDG
ICAO/IATA
DETONATOR ASSEMBLIES, NON-ELECTRIC
DETONATOR ASSEMBLIES, NON-ELECTRIC
DETONATOR ASSEMBLIES, NON-ELECTRIC
DETONATOR ASSEMBLIES, NON-ELECTRIC
14.3. Transport hazard class(es)
ADR
RID
IMDG
ICAO/IATA
Comments
1.4B
1.4B
1.4B
1.4B
Even hazard class 1.4S (UN number 0500) can be used.
14.4. Packing group
Comments
Not determined.
14.5. Environmental hazards
14.6. Special precautions for user
EmS
Special safety precautions for user
F-B, S-X
Attention: An explosive article
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Additional information.
Additional information.
Explosives are labelled and packaged in accordance with the requirements for
explosives only.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
References (laws/regulations)
Legislation and regulations
Comments
Dangerous Substance Directive 67/548/EEC.
Dangerous Preparations Directive 1999/45/EC.
Regulation (EC) No 1907/2006 of the European Parliament and of the Council
of 18 December 2006 concerning the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency, amending Directive 1999/45/EC and repealing Council Regulation
(EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as
Council Directive 76/769/EEC and Commission Directives 91/155/EEC,
93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Regulation 1272/2008/EC (CLP)
Products should be handled only according to the specific national regulations
for handling explosives.
For professional users only.
15.2. Chemical safety assessment
Chemical safety assessment
performed
CSR required
No
No
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SECTION 16: Other information
Hazard symbol
R-phrases
S-phrases
Classification according to
Regulation (EC) No 1272/2008
[CLP/GHS]
List of relevant R-phrases (under
headings 2 and 3).
List of relevant H-phrases (Section
2 and 3).
Training advice
Important data sources used to
construct the safety data sheet
Information which has been added,
deleted or revised
Version
Responsible for safety data sheet
Comments
R2 Risk of explosion by shock, friction, fire or other sources of ignition.
S15 Keep away from heat.
S16 Keep away from sources of ignition - No smoking.
S20/21 When using do not eat, drink or smoke.
S33 Take precautionary measures against static discharges.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
Expl. 1.1; H201;
R38 Irritating to skin.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R20/22 Harmful by inhalation and if swallowed.
R33 Danger of cumulative effects.
R36 Irritating to eyes.
R2 Risk of explosion by shock, friction, fire or other sources of ignition.
R3 Extreme risk of explosion by shock, friction, fire or othersources of
ignition.
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility.
R25 Toxic if swallowed.
H302 Harmful if swallowed.
H360Df May damage the unborn child. Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life.
H315 Causes skin irritation.
H301 Toxic if swallowed.
H332 Harmful if inhaled.
H410 Very toxic to aquatic life with long lasting effects.
H201 Explosive; mass explosion hazard.
H200 Unstable explosives.
H319 Causes serious eye irritation.
Training for handling and use of explosives and detonators.
Material safety data sheet from the product manufacturer.
Directive (EC) No 1907/2006 (REACH)
Regulation (EC) No 1272/2008 (CLP)
New document format.
1
OY FORCIT AB
The information in this MSDS is based on the present state of our
knowledge. It does not represent any guarantee with regard to product
properties or their suitability for particular uses. Because the use of this
information and instructions or the conditions of use of the product is not at
our control, it is the user s duty to specify the circumstances for the safe use
of the product.