CHEMISTRY – 1st SEMESTER EXAM REVIEW STRATEGY: Start by reading through your notes and study guides to refresh your memory. Look over the Chapter Highlights for Chapters 1-7. Then, use this review sheet as a starting point to identify the areas on which you need to spend more study time. For those areas, go back to homework assignments, text resources, and notes to practice more problems. Prepare an index card with notes to help with difficult concepts. These questions are only samples and do not include specific examples of how vocabulary and other conceptual information might appear in a multiple-choice test. The questions will be similar to those on chapter tests. FORMAT: Questions will include no more than 100 multiple-choice questions and 1 essay from those that I give you. You will be given a periodic table. You may use 1 handwritten small (3.5”x5”) index card to prompt your memory. Chapter 1: Matter and Change 1. What is the difference between an element and a compound? 2. What is the difference between a heterogeneous and homogeneous mixture? 3. Compare and contrast a solution, colloid, and suspension. 4. Classify the following as element, compound, heterogeneous mixture, or solution. a. graphite (carbon) c. table salt (NaCl) b. grape juice d. vegetable soup 5. Classify the following as chemical or physical changes. a. cutting wire c. apple slices turning brown b. melting ice d. compressing a gas 6. Classify the following properties as physical or chemical. a. melts at 68.0C c. decomposes in air b. corrosive d. conductive Chapter 2: Measurements and Calculations 11. What is the meaning behind the Law of Conservation of Mass and the Law of Multiple Proportions? 12. What is the difference between a quantitative and a qualitative observation? 13. What is density? How is it determined experimentally and mathematically? 14. List the metric prefixes from mega to nano, the symbols for each, and list what they represent numerically. 15. What is the difference between precision and accuracy? 16. Complete the following conversions significantly: a. 340.0 mm to km c. 9.00 ns to s -3 b. 0.0320 Mg to g d. 3.05 x 10 km to cm Chapter 3: Atoms: The Building Blocks of Matter 20. List the particles that makeup an atom. Where are each of the particles located in an atom? What kind of charge do each of the particles have? What is the relative size of each particle? 21. Identify the scientists who made the following discoveries and name their experiments. a. Atoms contain negatively charged particles called electrons. b. Atoms contain a dense, positive nucleus. 22. What is the primary difference between the modern model of the atom and Bohr’s model? 23. Write the nuclear representation, which includes atomic number & mass number, for the following isotopes. a. carbon-14 c. nickel-63 b. chromium-53 d. zirconium-92 24. What are valence electrons and where are they located? 7. Classify the following characteristic as either being that of a metal or a nonmetal. a. dull c. shiny b. malleable d. brittle 8. What are the 4 states of matter and how would you distinguish between each? 9. What is a change of state? Is it physical or chemical…why? Give some examples of the change of state. 10. Determine where each of the following are on the periodic table: groups/families, noble gases, periods, alkali metals, metals, transition metals, nonmetals, halogens, metalloids, alkaline earth metals, rare earth metals, lanthanides, and actinides. 17. In a lab, the average measured density for Pre-1982 3 pennies was 7.98 g/cm . Given that the literature value 3 for the density is 8.92 g/cm , calculate the percent error. 18. Determine the number of significant figures in each of the following numbers. a. 0.000357 d. 3,004 b. 8.7010 e. 700.00 3 c. 100,000 f. 6.2030 x 10 19. Convert a and b into scientific notation and c and d into standard form. -3 a. 548,000 c. 1.200 × 10 7 b. 0.0000770 d. 9.25 × 10 25. Calculate the average atomic mass of copper if 69.17% of 63 the copper atoms occurring in nature are Cu and 30.83% 65 are Cu. 26. Complete the table for the following isotopes. Symbol Zn Atomic # 20 Mass # 65 74 40 # of protons 34 # of neutrons 21 # of electrons 18 27. Determine the mass in grams of each of the following. a. 6.50 moles of Cu 18 b. 1.05 x 10 atoms of Hg 28. How many moles are there in each of the following? 2 a. 1.50 x 10 grams ZnS 25 b. 2.25 x 10 molecules of CO2 Chapter 4: Arrangement of Electrons in Atoms 29. What is electromagnetic radiation and what are the seven types listed from lowest energy to highest energy? 30. What is wavelength? What is frequency? How are wavelength and frequency related? 31. What formulas can be used to calculate wavelength and frequency? 32. What formula is used to either calculate energy or frequency. 33. What is the meaning of the ground state of an electron and excited state of an electron? 34. What happens as an electron goes from its ground state to an excited state? 35. What occurs when an electron goes from an excited state to its ground state? 36. What is the maximum number of electrons that an orbital can contain? That the s, p, d, and f sublevels can contain? 37. Define the following: Heisenberg Uncertainty Principle, Aufbau Principle, Pauli Exclusion Principle, and Hund’s Rule? Chapter 5: The Periodic Table 40. Describe the periodic trends for atomic radius, ionic radius, ionization energy, and electron affinity. 41. Explain the trends listed above. (Think of the energy levels involved within a group and the increasing number of protons across a period.) 42. Which group on the periodic table has the largest atomic radii? 43. Which group on the periodic table has the highest first ionization energy? 44. According to trends, what elements on the periodic table st have the highest /lowest 1 ionization energy? 45. Compare the element Fe and Cu when answering the following. a. Which element has the smallest atomic radius? b. Which element has the largest first ionization energy? 46. How many valence electrons are in each of the following elements? a. Ba b. Pb c. Po d. Rn 38. Complete the orbital notation and electron configuration notation (box and spectroscopic) for the following. Circle the valence electrons. # electrons Symbol electron configuration F Ca P N Se 39. Predict the ions that will form from the following atoms, show the Noble Gas it will be like when it forms an ion, and give the Noble Gas configuration of the neutral atom. Atom Ion Noble Gas Electron Configuration K Cl O Mg 47. In each pair of elements, circle the one that has the largest atomic radius. a. Cs or Fr b. Sn or Pb c. Ag or Cd 48. In each pair of elements, circle the one that has the largest first ionization energy. a. Cs or Ba c. Au or Hg 49. How are the elements arranged in the current periodic table? 50. Circle the particle with the LARGER radius. Which is larger in each example, the neutral atom or the ion? –1 2+ a. Cl Cl b. Mg Mg 51. Circle the atom with the HIGHER electronegativity. a. C Si b. Cs W c. F Cl 52. Based on the electronegativity of each element in the following compounds, are the bonds in the compound IONIC, COVALENT or POLAR COVALENT? a. MgO c. LiCl b. H2O d. Br2 Chapter 6: Chemical Bonding and Molecular Geometry 53. Atoms that have very similar electronegativities are expected to form _________bonds. 54. Metals typically have ______________________ ionization energies. 55. Metals and non-metals form ___________ bonds. 56. Non-metals share electrons in __________ bonds. 57. The ability of an atom in a molecule to attract shared electrons to itself is called _______. 58. Compare & contrast single, double, and triple bonds. 59. Atoms having greatly differing electronegativities are expected to form _________ bonds. 60. Metallic bonds can be described as metal atoms surrounded by a __________ ___ __________ 61. According to the Octet Rule, chemical bonds form because atoms gain, lose, or share electrons to have a full outer energy level ( __ electrons in most atoms). What is the difference between an ionic compound and a covalent compound? 62. List general characteristics of ionic compounds. 63. Why is it more difficult to list general characteristics of covalent compounds. 64. Draw Lewis dot diagrams for the following compounds: a. CBr4 b. Li2S c. CO2 65. For water, a. Determine the general VSEPR form (ABxEy) b. Draw the Lewis dot diagram. c. Draw the geometric structure indicating a 3-D structure. d. Indicate the name of the molecular shape. e. Indicate the polarity of the molecule. 66. Explain what VSEPR stands for and how VSEPR theory is used to predict the shape of molecules. Chapter 7: Chemical Formulas and Chemical Compounds 67. How many atoms of each element are shown in each compound? a. CaC2O4 c. Pb(C2O4)2 b. Zn(NO3)2 d. Li3PO4 68. State the number of molecules / formula units that are represented by each of the following. How many atoms of each element are shown in each? compound? a. 4 AlBr3 c. N2O4 b. 2 Fe(NO3)2 d. 3 HBr 69. Classify the following ions as either a monatomic or polyatomic. +3 -1 a. Al d. H +2 -1 b. Hg2 e. MnO4 -2 -2 c. CO3 f. O 70. Classify the following ions as either cations or anions. +3 +1 a. Al d. NH4 -1 -2 b. MnO4 e. CO3 -2 +1 c. O f. Na 71. Write formulas for the following compounds (HINT: First determine the type of compound - ionic / covalent). a. calcium bromide f. tin (IV) oxide b. magnesium hydroxide g. silicon dioxide c. iron (III) sulfate h. dinitrogen tetroxide d. hydrogen fluoride i. hydrogen sulfide e. potassium sulfite j. ammonium acetate 72. Write the names for the following compounds (HINT: First determine the type of compound - ionic / covalent). a. P4O6 h. MgSO4 b. Cu2CO3 i. CrCl3 c. Zn(MnO4)2 j. NH4OH d. AuCl3 k. HClO3 e. Li2Cr2O7 l. Cu3(PO4)2 f. Be3P2 m. LiH g. PbSO4 n. BaCl2 73. Write the formula for copper (II) sulfate pentahydrate. 74. Name the following acids: a. HCl b. HClO3 c. HClO2 75. What is the % composition of AgNO3? 76. What is the empirical formula for a compound made up of 66.0% Ba 34.0% Cl? 77. What is the molecular formula for a molecule with empirical formula CH2O and molar mass 120.12 g/mol? POSSIBLE ESSAY QUESTIONS: The test will include 2 of these 4 questions. You will choose 1 of those 2 to answer. You will be asked to answer the question with a well-structured essay, using proper grammar. Follow every detail in the prompts of each question to earn full credit. Use sufficient detail to convey understanding, and use proper scientific terminology related to the subject. I will be looking for certain key terms that must be used to answer each question completely. Review your notes and text to figure out what these are for each topic, and build your essay around them. 1. Describe what the Hydrogen Line Emission Spectrum is and how it led to Bohr’s Model of the Atom. Use a sketch of Bohr’s model of the hydrogen atom to help explain the concepts. Use appropriate terminology to earn full credit. 2. Describe the quantum model of the atom. List the 4 quantum numbers and describe the information that is provided by each quantum number. Draw sketches of 2 types of orbitals. Use appropriate terminology to earn full credit. 3. Describe the three principles that guide the electron configuration of an atom. Demonstrate with an example using arrow or box notation and spectroscopic notation. Use appropriate terminology to earn full credit. 4. Compare and contrast the ionic, polar covalent, non-polar covalent, and metallic chemical bonds in terms of the electrons that are involved. Describe properties typical of compounds that are formed from the different types of bonds. Use appropriate terminology to earn full credit.
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