Safety Data Sheet Aluminum Nitrate, 9-Hydrate Section 1 Product Name: Recommended Use: Synonyms: Distributor: Chemical Information: Chemtrec: Product Description Aluminum Nitrate, 9-Hydrate Science education applications Aluminum Trinitrate: Aluminum Nitrate, Nonahydrate Carolina Biological Supply Company 2700 York Road, Burlington, NC 27215 1-800-227-1150 800-227-1150 (8am-5pm (ET) M-F) 800-424-9300 (Transportation Spill Response 24 hours) Section 2 Hazard Identification Classification of the chemical in accordance with paragraph (d) of §1910.1200; WARNING Causes skin irritation. Causes serious eye irritation. GHS Classification: Skin Corrosion/Irritation Category 2, Serious Eye Damage/Eye Irritation Category 2A, Acute Toxicity - Oral Category 5 Acute Toxicity Dermal Contains Acute Toxicity Inhalation Gas Contains Acute Toxicity Inhalation Vapor Contains Acute Toxicity Inhalation Dust/Mist Contains Section 3 Chemical Name Aluminum Nitrate, 9-Hydrate Section 4 100 % of the mixture consists of ingredient(s) of unknown toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity Composition / Information on Ingredients CAS # 7784-27-2 % 100 First Aid Measures Emergency and First Aid Procedures Inhalation: In case of accident by inhalation: remove casualty to fresh air and keep at rest. Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact: IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Ingestion: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Section 5 Extinguishing Media: Fire Fighting Methods and Protection: Fire and/or Explosion Hazards: Aluminum Nitrate, 9-Hydrate Firefighting Procedures Use dry chemical, CO2 or appropriate foam. Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. N/A Page 1 of 4 Safety Data Sheet Hazardous Combustion Products: Aluminum oxide dust,, Nitrogen oxides Section 6 Spill or Leak Procedures Steps to Take in Case Material Is Released or Spilled: Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this SDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill. Ventilate the contaminated area. Avoid the generation of dusts during clean-up. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Vacuum or sweep up material and place in a disposal container Section 7 Handling: Storage: Storage Code: Handling and Storage Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Keep container tightly closed in a cool, well-ventilated place. Keep container tightly closed in a cool, well-ventilated place. Green - general chemical storage Section 8 Protection Information ACGIH Chemical Name No data available Control Parameters Engineering Measures: Personal Protective Equipment (PPE): Respiratory Protection: Eye Protection: Skin Protection: Gloves: Section 9 Formula: Al(NO3)3•9H2O Molecular Weight: 375.13 g/mol Appearance: Solid Odor: No data available Odor Threshold: No data available pH: 2.5 - 3.5 at 50 g/l at 25 °C (77 °F) Melting Point: 73 C Boiling Point: No data available Flash Point: No data available Flammable Limits in Air: N/A N/A Section 10 Reactivity: Chemical Stability: Conditions to Avoid: Aluminum Nitrate, 9-Hydrate (TWA) N/A OSHA PEL (STEL) N/A (TWA) N/A (STEL) N/A No exposure limits exist for the constituents of this product. General room ventilation might be required to maintain operator comfort under normal conditions of use. Good general room ventilation should be sufficient to control airborne contaminates to safe levels. Lab coat, apron, eye wash, safety shower. No respiratory protection required under normal conditions of use. Respiratory protection may be required in addition to ventilation depending upon conditions of use. Wear chemical splash goggles when handling this product. Have an eye wash station available. Avoid skin contact by wearing chemically resistant gloves, an apron and other protective equipment depending upon conditions of use. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Nitrile Physical Data Vapor Pressure: N/A Evaporation Rate (BuAc=1): N/A Vapor Density (Air=1): N/A Specific Gravity: N/A Solubility in Water: Soluble Log Pow (calculated): No data available Autoignition Temperature: No data available Decomposition Temperature: No data available Viscosity: No data available Percent Volatile by Volume: N/A Reactivity Data No data available Stable under normal conditions. None known. Page 2 of 4 Safety Data Sheet Incompatible Materials: Hazardous Decomposition Products: Hazardous Polymerization: Strong reducing agents, Strong acids Nitrogen oxides, Aluminum oxide dust,, Metals (powdered) Will not occur Section 11 Routes of Entry Symptoms (Acute): Delayed Effects: Toxicity Data Inhalation, ingestion, eye or skin contact. Gastrointestinal, No data available Acute Toxicity: Chemical Name Aluminum Nitrate, 9-Hydrate CAS Number 7784-27-2 Carcinogenicity: Chemical Name Aluminum Nitrate, 9-Hydrate CAS Number 7784-27-2 Chronic Effects: Mutagenicity: Teratogenicity: Sensitization: Reproductive: Target Organ Effects: Acute: Chronic: Oral LD50 Oral LD50 Rat 3671 mg/kg IARC Listed Inhalation LC50 Not determined NTP Not listed OSHA Not listed No evidence of a mutagenic effect. No evidence of a teratogenic effect (birth defect). No evidence of a sensitization effect. No evidence of negative reproductive effects. See Section 2 Not listed as a carcinogen by IARC, NTP or OSHA. Section 12 Overview: Mobility: Persistence: Bioaccumulation: Degradability: Other Adverse Effects: Ecological Data This material is not expected to be harmful to the ecology. No data No data No data No data No data Chemical Name N/A CAS Number 7784-27-2 Section 13 Eco Toxicity Disposal Information Disposal Methods: Dispose in accordance with all applicable Federal, State and Local regulations. Always contact a permitted waste disposer (TSD) to assure compliance. Not Determined Waste Disposal Code(s): Section 14 Transport Information Ground - DOT Proper Shipping Name: Not dangerous goods Air - IATA Proper Shipping Name: Not regulated for air transport by IATA. Section 15 Regulatory Information TSCA Status: Chemical Name Dermal LD50 Not determined A component (or components) of this product is not listed on the TSCA Inventory of Existing Chemical Substances. Product is for research and development use only. CAS Number Aluminum Nitrate, 9-Hydrate § 313 Name § 304 RQ CERCLA RQ § 302 TPQ CAA 112(2) TQ Page 3 of 4 Safety Data Sheet No data available 7784-27-2 Section 16 Revised: 09/09/2015 No No No No No Additional Information Replaces: 09/03/2014 Printed: 10-29-2015 The information provided in this (Material) Safety Data Sheet represents a compilation of data drawn directly from various sources available to us. Carolina Biological Supply makes no representation or guarantee as to the suitability of this information to a particular application of the substance covered in the (Material) Safety Data Sheet. Glossary ACGIH CAS CERCLA DOT IARC N/A American Conference of Governmental Industrial Hygienists Chemical Abstract Service Number Comprehensive Environmental Response, Compensation, and Liability Act U.S. Department of Transportation International Agency for Research on Cancer Not Available Aluminum Nitrate, 9-Hydrate NTP OSHA PEL ppm RCRA SARA TLV TSCA IDLH National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million Resource Conservation and Recovery Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act Immediately dangerous to life and health Page 4 of 4
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