Period Periodic Table of the Elements 1 IA 1 1 18 VIII A atomic # → ±1 2 II A H 1s hydrogen English element name → copper 2 2s lithium beryllium 6.941 9.012 3s +1 12 sodium magnesium 22.99 4 4s 20 K Ca calcium 5s 38 6s Rb Sr strontium 7 7s +3 5 VB 6 VI B 7 VII B 8 VIII B 9 VIII B 10 VIII B 11 IB 12 II B 56 Cs Ba barium 132.9 137.3 +1 88 Fr Ra francium radium 223 226 +2,3,4,6,7 26 +3,2 27 +2,3 28 +2,3 29 +2,1 3p 30 Mn Fe Co Ni Cu Zn manganese iron cobalt nickel copper zinc 47.87 +3 50.94 40 +4 41 52.00 +5,3 42 54.94 +6,3,5 43 55.85 +7,4,6 44 +4,3,6,8 58.93 45 58.69 +3,4,6 46 63.55 +2,4 47 Y Zr Nb Mo Tc Ru Rh Pd Ag Cd zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium 91.22 92.91 72 +4 73 95.94 +5 74 98 +6,4 75 101.1 +7,4,6 76 +4,6,8 102.9 77 106.4 +4,3,6 78 107.9 +4,2 79 +3,1 carbon nitrogen oxygen fluorine neon 10.81 12.01 14.01 16.00 19.00 20.18 −3 15 −2 16 −1 17 S Cl Ar aluminum silicon phosphorus sulfur chlorine argon 28.09 +3 32 30.97 +4,2 32.07 −3 33 35.45 −2 34 39.95 −1 35 Ga Ge As Se Br Kr gallium germanium arsenic selenium bromine krypton 72.64 +3 50 74.92 +4,2 51 78.96 +3,5 79.90 −2 52 83.80 −1 53 In Sn Sb Te I Xe indium tin antimony tellurium iodine xenon 114.8 81 118.7 +1,3 82 121.8 +2,4 127.6 +3,5 84 126.9 +4,2 85 131.3 86 Hf Ta W Re Os Ir Pt Au Hg Pb Bi Po At Rn hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon 178.5 180.9 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 209 210 +3 104 105 106 107 108 109 110 111 6p 112 113 Lr Rf Db Sg Bh Hs Mt Ds Rg Cn lawrencium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgentium copernicum 262 261 262 266 264 277 268 281 272 285 +3 58 La +3,4 59 +3,4 Ce lanthanum cerium +4 91 61 +5,4 +6,3,4,5 62 63 94 +4,3,5,6 64 65 96 66 +3 97 67 +3,4 117 Fl Mc Lv Ts Og flerovium moscovium livermorium tennessine oganesson 289 288 292 293 294 68 +3 Er 70 +3,2 Yb thulium 167.3 100 +3,2 Tm erbium +3 69 ytterbium 168.9 +3 101 +3,2 173.0 102 +2,3 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium 227 232.0 231.0 238.0 237 239 243 247 247 251 252 257 258 259 Common Polyatomic Ions ammonium NH4+1 hydronium +1 H3O C2H3O2−1 −1 CH3COO −1 OH −1 cyanide CN cyanate OCN perchlorate ClO4−1 chlorate ClO3−1 ClO2−1 −1 chlorite hypochlorite nitrate nitrite −1 bromate −1 iodate SCN ClO NO3−1 −1 NO2 BrO3−1 −1 IO3 hydrogen sulfate permanganate periodate −1 HSO4 MnO4−1 −1 IO4 hydrogen carbonate HCO3 dihydrogen phosphate H2PO4−1 −1 sulfate SO4−2 oxalate C2O4−2 sulfite silicate SiO3−2 peroxide O2−2 carbonate SO3−2 C8H4O4−2 −2 CrO4 Cr2O7−2 −2 CO3 hydrogen phosphate HPO4−2 phthalate chromate dichromate 222 118 284 +3 99 116 Nh 164.9 +3 115 nihonium holmium 162.5 98 114 Ho dysprosium 158.9 +3 7p Dy terbium 157.3 +3,4,5,6 +3,4 Tb gadolinium 152.0 95 +3 Gd europium 150.4 +5,3,4,6 +3,2 Eu samarium 145 93 +3,2 Sm promethium 144.2 92 +3 Pm neodymium 140.9 90 +3 Nd praseodymium 140.1 +3 60 Pr Tl 83 Lu 138.9 thiocyanate 54 175.0 89 hydroxide 36 lutetium 57 acetate 18 P 5p +2,1 −4 14 Ne Si 112.4 80 10 boron 49 +2 −1 9 F 69.72 48 −2 8 O +3 65.41 +1 −3 7 Al 4p yttrium +3 He helium N 31 +2 Cr 103 ‡ 5f 25 chromium † 5d actinides +3,2,6 V 71 † 4f 24 vanadium 88.91 lanthanides (rare earth metals) +5,2,3,4 Ti 4d ‡ 6d 23 titanium 44.96 +2 +4,3,2 Sc 39 +2 cesium 22 scandium 87.62 +1 87 3d +2 rubidium 85.47 6 Metalloids −4 6 26.98 21 40.08 +1 55 4 IV B 17 VII A C 13 3 III B +2 potassium 39.10 5 +3 24.31 +1 37 Liquids +2 Mg 16 VI A B 2p Na 19 5 Gases 15 VA 4.003 +2 Be 11 3 4 Li 14 IV A ← atomic mass (rounded) 63.55 +1 2 13 III A Cu 1.008 3 +2,1 ← ions commonly formed 29 atomic symbol → tetraborate borate arsenate phosphate orthosilicate −2 B4O7 BO3−3 −3 AsO4 −3 PO4 −4 SiO4 Copyright © 2009–2016 Jeff Bigler. This document is licensed under a Creative Commons Attribution-Share Alike 3.0 United States License. You are free to share and/or adapt this work, with appropriate attribution, under an identical, similar, or compatible license. See http://creativecommons.org/licenses/by-sa/3.0/us/ for more information. Chemistry Reference Tables1 Table A. Standard Temperature and Pressure ...............................................................................................................2 Table B. Selected Units ................................................................................................................................................2 Table C. Selected Prefixes ............................................................................................................................................2 Table D. Physical Constants for Water ......................................................................................................................... 3 Table E. Vapor Pressure and Density of Water ............................................................................................................3 Figure F. Phase Diagram for Water .............................................................................................................................. 3 Table G. Solubility Guidelines .....................................................................................................................................4 Table H. Ksp Values for Some Insoluble Salts at 25°C .................................................................................................4 Figure I. Solubilities of Selected Compounds ..............................................................................................................4 Table J. Number Prefixes .............................................................................................................................................5 Table K. Polyatomic Ions .............................................................................................................................................5 Table L. Flame Test Colors ..........................................................................................................................................5 Table M. Aqueous Ion Colors ......................................................................................................................................5 Table N. Colors of Assorted Compounds ..................................................................................................................... 5 Table O. Common Acids ..............................................................................................................................................6 Table P. pKa Values for Common Acids ...................................................................................................................... 6 Table Q. Common Bases ..............................................................................................................................................6 Table R. Common Acid-Base Indicators ...................................................................................................................... 6 Table S. Symbols Used in Nuclear Chemistry..............................................................................................................7 Table T. Selected Radioisotopes ...................................................................................................................................7 Table U. Constants Used in Nuclear Chemistry ...........................................................................................................7 Figure V. Neutron/Proton Stability Band ..................................................................................................................... 7 Table W. Activity Series...............................................................................................................................................8 Table X. Std. Reduction Potentials ............................................................................................................................... 8 Table Y. Selected Properties of the Elements ...............................................................................................................9 Figure Z. Bonding Triangle ........................................................................................................................................ 11 Table AA. Bond Dissociation Energies & Bond Lengths .......................................................................................... 12 Table BB. Thermodymanic Data ................................................................................................................................ 13 Table CC. Some Common & Equivalent Units and Approximate Conversions......................................................... 14 Table DD. Selected Formulas and Equations ............................................................................................................. 15 Table A. Standard Temperature and Pressure Table B. Selected Units Name Values “Standard” Pressure 1 atm 760 torr 101.3 kPa Standard Temperature 0°C 32°F 273.15K atm = atmosphere Torr = millimeter of mercury (mm Hg) kPa = kilopascal °C = degree Celsius °F = degree Fahrenheit K= kelvin Name meter (SI) centimeter kilogram (SI) gram Pascal (SI derived) atmosphere mm of mercury Torr Kelvin (SI) degree Celsius amt of substance (SI) Joule (SI derived)) kilocalorie second (SI) liter part per million Symbol m cm kg g Pa atm mm Hg Torr K °C mol J kcal s L, ℓ ppm molarity M, Table C. Selected Prefixes Factor 6 10 3 10 −1 10 −2 10 −3 10 −6 10 1 Number of Units 1,000,000 1,000 0.1 0.01 0.001 0.000 001 Prefix megakilodecicentimillimicro- Symbol M k d c m (or u) mol Quantity length mass pressure temperature mole energy time volume concentration concentration adapted from: The University of the State of New York. The State Education Department. Albany, NY. 12234. 2002 Edition. Reference Tables for Physical Setting/Chemistry. http://www.nysedregents.org/testing/reftable/chemref2002.pdf Chemistry Reference Tables p. 3 Table D. Physical Constants for Water Freezing Point @ 1 atm Boiling Point @ 1 atm Heat of Fusion Heat of Vaporization Specific Heat Capacity (Cp) Freezing Point Depression Constant (Kf) Boiling Point Elevation Constant (Kb) Table E. Vapor Pressure and Density of Water Temp (°C) Pvap (kPa) density (g/cm3) 0.01 0.61173 0.99978 1 0.65716 0.99985 4 0.81359 0.99995 5 0.87260 0.99994 10 1.2281 0.99969 15 1.7056 0.99909 20 2.3388 0.99819 25 3.1691 0.99702 30 4.2455 0.99561 35 5.6267 0.99399 40 7.3814 0.99217 45 9.5898 0.99017 50 12.344 0.98799 55 15.752 0.98565 60 19.932 0.98316 65 25.022 0.98053 70 31.176 0.97775 75 38.563 0.97484 80 47.373 0.97179 85 57.815 0.96991 90 70.117 0.96533 95 84.529 0.96192 100 101.32 0.95475 105 120.79 0.95475 0°C = 273.15 K 100°C = 373.15 K 333.6 J/g 2270 J/g 4.184 J/g∙°C 0.52°C/m 1.86°C/m Figure F. Phase Diagram for Water Chemistry Reference Tables p. 4 Table G. Solubility Guidelines Ions That Form SOLUBLE Compounds Group I ions (Li+, Na+, etc.) ammonium (NH4+) nitrate (NO3–) hydrogen carbonate (HCO3–) chlorate (ClO3–) perchlorate (ClO4–) acetate (C2H3O2– or CH3COO–) halides (Cl–, Br–, I–) 2 sulfates (SO4 –) EXCEPT with sulfide (S2–) Ag+ 2+ 2+ Ag+, Cu+, Pb , Hg2 2+ 2+ 2+ 2+ Ca , Sr , Ba , Ag+, Pb Table H. Ksp Values for Some Insoluble Salts at 25°C Compound MgCO3 PbCl2 BaF2 CuCl PbI2 AgOH BaCO3 CaCO3 SrCO3 AgCl BaSO4 CaF2 Mg(OH)2 Ag2CrO4 CuI AgBr PbSO4 PbCO3 Mn(OH)2 PbCrO4 Fe(OH)2 AgI Zn(OH)2 FeS HgCl ZnS PbS CdS Al(OH)3 CuS Fe(OH)3 Ag2S HgS Ksp 1.0 × 10−5 1.7 × 10−5 2.0 × 10−6 1.0 × 10−6 1.6 × 10−8 1.0 × 10−8 8.1 × 10−9 3.8 × 10−9 9.4 × 10−10 1.8 × 10−10 1.1 × 10−10 3.9 × 10−11 1.0 × 10−11 9.0 × 10−12 5.0 × 10−12 3.3 × 10−13 2.5 × 10−13 1.6 × 10−13 4.0 × 10−14 1.8 × 10−14 1.6 × 10−14 1.5 × 10−16 7.9 × 10−18 4.0 × 10−18 2.0 × 10−18 1.0 × 10−23 8.4 × 10−28 3.6 × 10−29 1.6 × 10−34 8.7 × 10−36 1.3 × 10−36 2.0 × 10−50 3.0 × 10−53 Ions That Form INSOLUBLE Compounds carbonate (CO32–) 2 chromate (CrO4 –) phosphate (PO43–) sulfite (SO32–) hydroxide (OH–) oxide (O2–) Figure I. Solubilities of Selected Compounds EXCEPT with Group I ions, + ammonium (NH4 ) Group I ions, Group II ions, NH4+ Group I ions, NH4+, Ba2+, Sr2+, Tl+ Chemistry Reference Tables p. 5 Table J. Number Prefixes Number 1 2 3 4 5 Inorganic monoditritetrapenta- Organic methethpropbutpent- Number 6 7 8 9 10 Inorganic hexaheptaoctanonadeca- formula NH4+ H3O+ IO2+ NO+ NS+ PO+ PS+ PO2+ CH3COO− NH2− NHOH− N3− N2H3− BrO3− ClO3− CN− ion cyanate thiocyanate selenocyanate tellurocyanate hydroxide iodate methanolate methanethiolate ethanolate permanganate nitrate superoxide tetraborate carbide carbonate chromate Organic hexheptoctnondec- Table K. Polyatomic Ions ion americyl carbonyl thiocarbonyl neptunyl plutoryl selinyl selenoyl thionyl / sulfinyl sulfonyl / sulfuryl uranyl vanadyl mercury (II) mercury (I) formula AmO22+ CO2+ CS2+ NpO22+ PuO22+ SeO2+ SeO22+ SO2+ SO22+ UO2+ VO2+ Hg2+ Hg22+ ion ammonium hydronium iodyl nitrosyl thionitrosyl phosphoryl thiophosphoryl phospho acetate amide hydroxylamide azide hydrazide bromate chlorate cyanide formula OCN− SCN− SeCN− TeCN− OH− IO3− CH3O− CH3S− C2H5O− MnO4− NO3− O 2− B4O72− C22− CO22− CrO42− ion dichromate imide molybdate peroxide oxalate phthalate selenate disulfide sulfate thiosulfate dithionate silicate borate arsenate phosphate orthosilicate formula Cr2O72− NH2− MoO42− O22− C2O42− C8H4O42− SeO42− S22− SO42− S2O32− S2O42− SiO32− BO33− AsO43− PO43− SiO44− Table L. Flame Test Colors Element Ba Ca Cu Fe Color yellow-green orange-red blue-green gold Element K Li Mg Na Color pink fuchsia bright white yellow Element Pb Sb Sr Zn Color blue pale green red blue-green Table M. Aqueous Ion Colors Ion Cu+ Cu2+ Fe2+ Fe3+ Cr3+ Ni2+ Mn2+ Mn7+ Pb3+ Color green blue yellow-green orange-red violet [Cr(NO3)3] to green [CrCl3] green pink purple (e.g., the MnO4− ion) blue-green (Pb2+ and Pb4+ are clear) Ion V2+ V3+ CrO42− Cr2O72− Cu(NH3)42+ FeSCN2+ Co2+ CoCl42− Ti(H2O)63+ Color violet blue-green yellow orange dark blue red-brown (wine-red to dark orange) pink blue purple Compound NO NO2 metallic sulfides metallic oxides Color colorless gas brown gas sulfides of transition metals tend to be black oxides of colored transition metals tend to be colored Table N. Colors of Assorted Compounds Compound F2 Cl2 Br2 I2 S8 PbI2 Fe2O3 Color pale yellow gas green-yellow gas red-brown liquid dark metallic solid; dark violet vapor yellow odorous solid bright yellow precipitate reddish-brown (rust) Chemistry Table O. Common Acids Formula HCl (aq) HNO3 (aq) H2SO4 (aq) H3PO4 (aq) H2CO3 (aq) HC2H3O2 (aq) or CH3COOH (aq) Table Q. Common Bases Formula NaOH (aq) KOH (aq) Ca(OH)2 (aq) NH3 (aq) Reference Tables p. 6 Table P. pKa Values for Common Acids Name hydrochloric acid nitric acid sulfuric acid phosphoric acid carbonic acid ethanoic acid (acetic acid) Name sodium hydroxide potassium hydroxide calcium hydroxide aqueous ammonia Table R. Common Acid-Base Indicators pH Range of Indicator Color Change Color Change bromophenol blue 3.0 – 4.6 yellow−purple methyl orange 3.2 – 4.4 red−yellow bromocresol green 3.8 – 5.4 yellow−blue methyl red 4.4 – 6.2 red−yellow litmus 5.5 – 8.2 red−blue bromothymol blue 6.0 – 7.6 yellow−blue phenol red 6.8 – 8.4 yellow−red thymol blue 8.0 – 9.6 yellow−blue phenolphthalein 8.2 – 10 clear−pink Acid H2O HPO42− HCO3− NH4+ HCN H2PO4− H2S pKa 15.7 12.6 10.2 9.2 9.1 7.2 7.0 Conj. Base OH− PO43− CO32− NH3 CN− HPO42− HS− H2CO3 CH3COOH HCOOH HNO2 HF C6H8O7 (citric acid) 6.4 4.8 3.7 3.3 3.2 HCO3− CH3COO− HCOO− NO2− F− 3.1 C6H7O7− H3PO4 HSO4− HNO3 H3O+ HCl HBr HI HClO4 H2SO4 2.2 2.0 −1.4 −1.7 −7.0 −9.0 −10 −10 −12 H2PO4− SO42− NO3− H 2O Cl− Br− I− ClO4− HSO4− Any acid with a pKa value less than 0 is a strong acid; any base with a pKa value greater than 14 is a strong base. Chemistry Reference Tables Table S. Symbols Used in Nuclear Chemistry Name Notation alpha particle 4 2 He beta particle (electron) 0 -1 e gamma radiation neutron proton positron Symbol or 24 or 0 0 1 0n 0 -1 1 1 H or 0 1 e or 1 1p 0 1 − n p + p. 7 Table T. Selected Radioisotopes Decay Nuclide Half-Life Mode 3 12.26 y H − 14 5730 y C − 16 7.2 s N − 19 17.2 s Ne + 24 15 h Na − 27 9.5 min Mg − 32 Table U. Constants Used in Nuclear Chemistry Constant Value mass of an electron (me) mass of a proton (mp) mass of a neutron (mn) Bequerel (Bq) Curie (Ci) 0.00055 amu 1.00728 amu 1.00867 amu 1 disintegration/second 3.7 x 1010 Bq Figure V. Neutron/Proton Stability Band 14.3 d − 36 3.01 × 105 y 1.23 s 1.26 × 109 y 12.4 h 0.175 s 27.7 d 8.51 min − + + − − − 59 Fe 46.3 d − Co 85 Kr 5.26 y 10.76 y − − 4.8 × 1010 y − Sr 28.1 y − Tc 2.13 x 105 y − I 8.07 d − Cs 30.23 y − Sm 1.93 d − 2.69 d − 3.82 d Fr 27.5 s Ra 1600 y P Cl 37 K 40 K 42 K 37 Ca 51 Cr 53 Fe 60 87 Rb 90 99 131 137 153 198 Au 222 Rn 220 226 232 Th 233 235 238 239 241 U U U 10 5 1.4 x 10 y 1.62 x 10 y 8 7.1 x 10 y 9 4 4.51 x 10 y Pu 2.44 x 10 y Am 432 y Chemistry Reference Tables Table W. Activity Series Metals p. 8 Table X. Std. Reduction Potentials Nonmet als F2 Cl2 Br2 I2 Cs Rb K Reacts with cold H2O Na and acids, replacing Li hydrogen. Reacts with O2, forming oxides. Ba Sr Ca Mg Be Reacts with steam (not Al cold H2O) and acids, Mn replacing hydrogen. Zn Reacts with O2, forming Cr oxides. Fe Cd Does not react with H2O. Co Reacts with acids, Ni replacing hydrogen. Sn Reacts with O2, forming Pb oxides. H2 Sb Reacts with O2, forming Bi oxides. Cu Ag Fairly unreactive, Hg forming oxides only Au indirectly. Pt Arrows indicate direction from LEAST to MOST active elements. An element can replace any element below itself on the activity series. Note that the order of elements in the activity series is similar to, though not quite identical with, the order of elements/ions in the table of Std. Reduction Potentials (Table X). Half-Reaction E0 (V) Li+ + e− Li(s) Cs+ + e− Cs(s) Rb+ + e− Rb(s) K+ + e− K(s) Ba2+ + 2 e− Ba(s) Sr2+ + 2 e− Sr(s) Ca2+ + 2 e− Ca(s) Na+ + e− Na(s) Mg2+ + 2 e− Mg(s) Be2+ + 2 e− Be(s) Al3+ + 3 e− Al(s) Mn2+ + 2 e− Mn(s) 2 H2O + 2 e− H2(g) + 2 OH− Zn2+ + 2 e− Zn(s) Cr3+ + 3 e− Cr(s) Fe2+ + 2 e− Fe(s) Cr3+ + e− Cr2+ Cd2+ + 2 e− Cd(s) Co2+ + 2 e− Co(s) Ni2+ + 2 e− Ni(s) Sn2+ + 2 e− Sn(s) Pb2+ + 2 e− Pb(s) 2 H+ + 2 e− H2(g) S(s) + 2 H+ + 2 e− H2S(g) Sn4+ + 2 e− Sn2+ Cu2+ + e− Cu+ Cu2+ + 2 e− Cu(s) Cu+ + e− Cu(s) I2(s) + 2 e− 2 I− Fe3+ + e− Fe2+ Ag+ + e− Ag(s) Hg22+ + 2 e− 2 Hg(l) Hg2+ + 2 e− Hg(l) −3.040 −3.026 −2.98 −2.931 −2.912 −2.899 −2.868 −2.71 −2.372 −1.85 −1.66 −1.029 −0.762 −0.74 −0.44 −0.42 −0.40 −0.28 −0.25 −0.13 −0.13 0.000 +0.14 +0.15 +0.159 +0.340 +0.520 +0.54 +0.77 +0.800 +0.80 +0.85 2 Hg2+ + 2 e− Hg22+ +0.91 −0.828 Br2(l) + 2 e− 2 Br− +1.07 Pt2+ + 2 e− Pt(s) +1.188 O2(g) + 4 H+ + 4 e− 2 H2O +1.23 Cl2(g) + 2 e− 2 Cl− +1.36 Au3+ + 3 e− Au(s) +1.52 3+ − 2+ Co + e Co +1.82 F2(g) + 2 e− 2 F− +2.87 Eo values at 1M concentration and 1 atm. Chemistry Reference Tables p. 9 Table Y. Selected Properties of the Elements electroneg 1st ionization Electron atomic common ativity potential Affinity radius oxidation (Pauling) (kJ/mol) (kJ/mol) (pm) states 1.1 499 — — +3 89 Ac actinium atomic mass Melting Boiling (IUPAC Point, °C Point, °C 2005) 227 1050 3200 13 Al aluminum 26.9815386 660 2467 2.7 1.61 578 42 143 +3 95 Am americium 243 994 2607 13.7 1.3 578 — 173 +3,4,5,6 51 Sb antimony 121.76 631 1950 6.69 2.05 834 103 140 +3,5 18 Ar argon 39.948 −189.2 −185.7 0.00178 — 1521 <0 98 0 33 As arsenic 74.9216 817 617 5.73 2.18 947 78 120 ±3,+5 85 At astatine 210 302 337 — 2.2 917 270 — — 56 Ba barium 137.327 725 1640 3.5 0.89 503 14 222 +2 97 Bk berkelium 247 986 — 14 1.3 601 — 170 +3,4 atomic atomic # symbol element name density g/mL 10.1 4 Be beryllium 9.012182 1278 2970 1.85 1.57 899 <0 112 +2 83 Bi bismuth 208.9804 271 1560 9.75 2.02 703 92 150 +3,5 107 Bh bohrium 5 B boron 264 — — — — — — — — 10.811 2079 2550 2.34 2.04 801 27 85 +3 35 Br bromine 79.904 −7.2 58.8 3.12 2.96 1140 324 114 ±1,+5 48 Cd cadmium 112.411 320.9 765 8.65 1.69 868 <0 151 +2 20 Ca calcium 40.078 839 1484 1.55 1 590 4 197 +2 98 Cf californium 251 — — — 1.3 608 — 186 +3 6 C carbon 12.0107 3367 4827 2.25 2.55 1086 122 77.2 ±4 58 Ce cerium 140.116 798 3257 6.66 1.12 534 — 182 +3,4 55 Cs cesium 132.9054519 28.4 669 1.87 0.79 376 45 265 +1 17 Cl chlorine 35.453 −101 −34.6 0.00321 3.16 1251 348 100 −1 24 Cr chromium 51.9961 1857 2672 7.19 1.66 653 65 128 +3,2,6 58.933195 1495 2870 8.9 1.88 760 64 125 +2,3 285 — — — — — — — — 27 Co cobalt 112 Cn copernicum 29 Cu copper 63.546 1083 2567 8.96 1.9 745 120 128 +2,1 96 Cm curium 247 1340 — 13.5 1.3 581 — 174 +3 110 Ds darmstadtium 281 — — — — — — — — 105 Db dubnium 66 Dy dysprosium 99 Es einsteinium 252 — — 68 Er erbium 167.259 1529 2868 262 — — — — — — — — 162.5 1412 2567 8.55 1.22 573 — 178 +3 — 1.3 619 — 186 +3 9.07 1.24 589 — 176 +3 63 Eu europium 151.964 822 1529 5.24 — 547 — 208 +3,2 100 Fm fermium 257 — — — 1.3 627 — — +3 9 F fluorine 18.9984032 −219.8 −188.1 0.0017 3.98 1681 328 72 −1 87 Fr francium 223 27 677 — 0.7 380 44 — +1 64 Gd gadolinium 157.25 1313 3273 7.9 1.2 593 — 180 +3 31 Ga gallium 69.723 29.8 2403 5.9 1.81 579 29 135 32 Ge germanium 72.64 947.4 2830 5.32 2.01 762 119 122.3 +4,2 79 Au gold 196.966569 1064 3080 19.3 2.54 890 223 144 +3,1 +3 72 Hf hafnium 178.49 2227 4600 13.3 1.3 659 0 159 +4 108 Hs hassium 277 — — — — — — — — 2 He helium 4.002602 −272.2 −268.9 0.000179 — 2372 <0 31 0 67 Ho holmium 164.93032 1474 2700 8.8 1.23 581 — 176 +3 1 H hydrogen 1.00794 −259.1 −252.9 2.2 1312 72 37.1 ±1 49 In indium 114.818 156.6 2080 7.31 1.78 558 29 167 +3 53 I iodine 126.90447 113.5 184 4.93 2.66 1008 295 133 −1,+5,7 77 Ir iridium 192.217 2410 4130 22.4 2.2 878 151 136 +4,3,6 26 Fe iron 55.845 1535 2750 7.86 1.83 762 15 126 +3,2 0.0000699 Chemistry Reference Tables atomic atomic # symbol element name 114 Fl flerovium 36 Kr krypton atomic mass Melting Boiling (IUPAC Point, °C Point, °C 2005) 289 — — p. 10 density g/mL — electroneg 1st ionization Electron atomic common ativity potential Affinity radius oxidation (Pauling) (kJ/mol) (kJ/mol) (pm) states — — — — — 83.798 −157 −152 0.00374 3 1351 <0 112 0 +3 57 La lanthanum 138.90547 920 3454 6.15 1.1 538 48 187 103 Lr lawrencium 262 — — — — — — — +3 82 Pb lead 207.2 327.5 1740 11.4 2.33 716 35 146 +2,4 116 Lv livermorium 292 — — — — — — — — 3 Li lithium 6.941 180.5 1342 0.543 0.98 520 60 152 +1 71 Lu lutetium 174.967 1663 3402 9.84 1.27 524 — 174 +3 12 Mg magnesium 24.305 649 1090 1.74 1.31 738 <0 160 +2 25 Mn manganese 54.938045 1244 1962 7.43 1.55 717 <0 127 +2,3,4,6,7 109 Mt meitnerium 268 — — — — — — — — 101 Md mendelevium 258 — — — 1.3 635 — — +3,2 80 Hg mercury 200.59 −38.9 357 13.5 2 1007 <0 151 +2,1 42 Mo molybdenum 95.94 2617 4612 10.2 2.16 684 72 139 +6,3,5 60 Nd neodymium 144.242 1016 3127 7 1.14 533 — 181 +3 20.1797 −248 −248.7 0.0009 — 2081 <0 71 0 237 640 3900 20.2 1.36 605 — 155 +5,3,4,6 10 Ne neon 93 Np neptunium 28 Ni nickel 58.6934 1453 2730 8.9 1.91 737 112 124 +2,3 41 Nb niobium 92.90638 2468 4742 8.57 1.6 652 87 146 +5,3 7 N nitrogen 14.0067 −209.9 −195.8 0.00125 3.04 1402 <0 70 −3 102 No nobelium 259 — — — 1.3 642 — — +2,3 76 Os osmium 190.23 3045 5030 22.6 2.2 839 106 135 +4,6,8 8 O oxygen 15.9994 −218.4 −183 0.00143 3.44 1314 141 73 −2 46 Pd palladium 106.42 1554 3140 12 2.2 804 54 137 +2,4 15 P phosphorus 30.973762 44.1 280 1.82 2.19 1012 72 110 −3 78 Pt platinum 195.084 1772 3827 21.4 2.28 868 206 139 +4,2 94 Pu plutonium 239 641 3232 19.8 1.28 585 — 159 +4,3,5,6 84 Po polonium 209 254 962 9.32 2 812 183 168 +4,2 19 K potassium 59 Pr praseodymium 39.0983 63.25 760 0.86 0.82 419 48 227 +1 140.90765 931 3017 6.77 1.13 527 — 182 +3,4 61 Pm 91 Pa promethium 145 1042 3000 7.26 — 535 — 183 +3 protactinium 231.03588 1570 4000 15.4 1.5 568 — 163 +5,4 88 Ra radium 226 700 86 Rn radon 222 −71 1140 5 0.9 509 — — +2 −61.8 0.00973 — 1037 <0 — 75 Re rhenium 186.207 3180 0 5600 21 1.9 760 14 137 +7,4,6 45 Rh rhodium 102.9055 1966 3727 12.4 2.28 720 110 134 +3,4,6 111 Rg roentgentium 272 — — — 37 Rb rubidium 85.4678 38.9 686 1.53 — — — — — 0.82 403 47 248 +1 101.07 2310 3900 12.4 261 — — — 2.2 710 101 134 +4,3,6,8 — — — — — 44 Ru ruthenium 104 Rf rutherfordium 62 Sm samarium 150.36 1074 1794 7.52 1.17 545 — 180 +3,2 44.955912 1541 2832 2.99 1.36 633 18 162 +3 266 — — — — — — — — 78.96 217 685 4.79 2.55 941 195 119 +4,−2,+6 28.0855 1410 2355 2.33 1.9 787 134 117.6 ±4 21 Sc scandium 106 Sg seaborgium 34 Se selenium 14 Si silicon 47 Ag silver 11 Na sodium 38 Sr strontium 107.8682 962 2212 10.5 1.93 731 125 144 +1 22.98976928 97.8 883 0.971 0.93 496 53 186 +1 87.62 769 1384 2.54 0.95 549 11 215 +2 Chemistry Reference Tables atomic atomic # symbol element name atomic mass Melting Boiling (IUPAC Point, °C Point, °C 2005) 32.065 112.8 444.7 16 S sulfur 73 Ta tantalum 43 Tc technetium 98 52 Te tellurium 127.6 65 Tb terbium 158.92535 81 Tl thallium 204.3833 90 Th thorium 69 Tm thulium 50 Sn tin 22 Ti titanium 180.94788 2996 p. 11 density g/mL 2.07 electroneg 1st ionization Electron atomic common ativity potential Affinity radius oxidation (Pauling) (kJ/mol) (kJ/mol) (pm) states 2.58 1000 201 103 −2 5425 16.6 1.5 761 31 146 2172 4877 11.5 1.9 449.5 989.8 6.24 2.1 1365 3230 8.23 303 1457 11.9 232.03806 1750 4790 11.7 168.93421 1545 1950 9.32 118.71 232 2270 7.31 47.867 1660 3287 4.54 +5 702 53 136 +7,4,6 869 190 142 +4,6,−2 — 569 — 177 +3,4 1.62 589 19 170 +1,3 1.3 587 — 179 +4 1.25 597 — 176 +3,2 1.96 709 107 140.5 1.54 659 8 147 +4,3,2 +4,2 74 W tungsten 183.84 3410 5660 19.3 2.36 770 83 139 +6,4 118 Uuo ununoctium 294 — — — — — — — — 115 Uup ununpentium 288 — — — — — — — — 113 Uut ununtrium 284 — — — — — — — — 92 U uranium 238.02891 1132 3818 19 1.38 598 — 156 +6,3,4,5 23 V vanadium 50.9415 1890 3380 6.11 1.63 651 51 134 +5,2,3,4 54 Xe xenon 131.293 −111.8 −107.1 0.00589 2.6 1170 <0 131 0 70 Yb ytterbium 173.04 819 1196 6.97 — 603 — 193 +3,2 39 Y yttrium 88.90585 1523 3337 4.47 1.22 600 30 180 +3 30 Zn zinc 65.409 419.6 906 7.13 1.65 906 <0 134 +2 40 Zr zirconium 91.224 1852 4377 6.51 1.33 640 41 160 +4 Figure Z. Bonding Triangle EN average electroneg ativity EN electroneg ativity difference Chemistry Reference Tables p. 12 Table AA. Bond Dissociation Energies & Bond Lengths Values given are homolytic bond dissociation energies, meaning that the electrons are divided equally between the two atoms. Hydrogen Compounds D r Bond (kJ/mol) (pm) H−H 432 74 H−B 389 119 H−C 411 109 H − Si 318 148 H − Ge 288 153 H − Sn 251 170 H−N 386 101 H−P 322 144 H − As 247 152 H−O 459 96 H−S 363 134 H − Se 276 146 H − Te 238 170 H−F 565 92 H − Cl 428 127 H − Br 362 141 H−I 295 161 Group VIIA Compounds D r Bond (kJ/mol) (pm) F−F 155 142 Cl − Cl 240 199 Br − Br 190 228 I−I 148 267 At − At 116 ? I−O 201 ? I−F 273 191 I − Cl 208 232 I − Br 175 ? Group IIIA Compounds D r Bond (kJ/mol) (pm) B−B 293 ? B−O 536 ? B−F 613 ? B − Cl 456 175 B − Br 377 ? Group IVA Compounds D r Bond (kJ/mol) (pm) C−C 346 154 C=C 602 134 C≡C 835 120 C − Si 318 185 C − Ge 238 195 C − Sn 192 216 C − Pb 130 230 C−N 305 147 C=N 615 129 C≡N 887 116 C−P 264 184 C−O 358 143 C=O 799 120 C≡O 1072 113 C−B 356 ? C−S 272 182 C=S 573 160 C−F 485 135 C − Cl 327 177 C − Br 285 194 C−I 213 214 Si − Si 222 233 Si − N 355 ? Si − O 452 163 Si − S 293 200 Si − F 565 160 Si − Cl 381 202 Si − Br 310 215 Si − I 234 243 Ge − Ge 188 241 Ge − N 257 ? Ge − F 470 168 Ge − Cl 349 210 Ge − Br 276 230 Ge − I 212 ? Sn − F 414 ? Sn − Cl 323 233 Sn − Br 273 250 Sn − I 205 270 Pb − F 331 ? Pb − Cl 243 242 Pb − Br 201 ? Pb − I 142 279 Group VA Compounds D r Bond (kJ/mol) (pm) N−N 167 145 N=N 418 125 N≡N 942 110 N−O 201 140 N=O 607 121 N−F 283 136 N − Cl 313 175 P−P 201 221 P−O 335 163 P=O 544 150 P=S 335 186 P−F 490 154 P − Cl 326 203 P − Br 264 ? P−I 184 ? As − As 146 243 As − O 301 178 As − F 484 171 As − Cl 322 216 As − Br 458 233 As − I 200 254 Sb − Sb 121 ? Sb − F 440 ? Sb − Cl(5) 248 ? Sb − Cl(3) 315 232 Group VIA Compounds D r Bond (kJ/mol) (pm) O−O 142 148 O=O 494 121 O−F 190 142 S=O 522 143 S − S(8) 226 205 S=S 425 149 S−F 284 156 S − Cl 255 207 Se − Se 172 ? Se = Se 272 215 Chemistry Reference Tables p. 13 Table BB. Thermodymanic Data Standard enthalpy of formation (H f ) & standard entropy ( S ) for selected compounds. Note that standard enthalpy values are in kilojoules per mole, whereas entropy values are in joules per mole∙Kelvin. Substance State Ag Ag+ AgCl AgBr AgNO3 Al Al+3 AlCl3 Al2O3 Al(OH)3 Ba BaCl2 BaCO3 Ba(NO3)2 BaO Ba(OH)2 BaSO4 Be BeO Br2 Br− C CCl4 CHCl3 CH4 C2H2 C2H4 C2H6 C3H8 CH3OH C2H5OH C6H12O6 CO CO2 CO3−2 Ca Ca+2 CaCl2 CaCO3 CaO Ca(OH)2 Ca3(PO4)2 CaSO4 Cd Cd+2 CdCl2 CdO Cd(OH)2 CdS CdSO4 Cl2 Cl− ClO4− Cr s aq s s s s aq s s s s s s s s s s s s ℓ aq s ℓ ℓ g g g g g ℓ ℓ s g g aq s aq s s s s s s s aq s s s s s g aq aq s ΔH f S kJ ( mol ) ( molJK ) 0 105.79 −127.01 −100.4 −124.4 0 −538.4 −704 −1675.7 −1277 0 −858.6 −1216.3 −992 −553.5 −998.2 −1473.2 0 −599 0 −121 0 −135.4 −134.5 −74.8 +226.7 +52.3 −84.7 −103.8 −238.7 −277.7 −1275 −110.53 −393.51 −675.23 0 −543.0 −795.8 −1206.9 −634.92 −986.1 −4126 −1434.1 0 −75.92 −391.5 −258.35 −561 −162 −935 0 −167.080 −128.10 0 42.6 72.7 96.2 107.1 140.9 28.3 −321.7 110.7 50.9 62.8 123.7 112.1 214 70.4 112 132.2 10 14 152.2 82 5.7 216.4 201.7 186.2 200.8 219.5 229.5 269.9 126.8 160.7 212 197.6 213.6 −56.9 41.4 −53.1 104.6 92.9 39.8 83.4 241 106.7 51.8 −73.2 115.3 54.8 96 65 123 223.0 56.5 182.0 23.8 Substance State Cr2O3 Cu Cu+ Cu+2 CuO Cu2O Cu(OH)2 CuS Cu2S CuSO4 F− F2 Fe Fe(OH)3 FeO Fe2O3 Fe3O4 FeSO4 H2 H+ HBr HCO3− HCl HF HI HNO3 HPO4−2 HSO4− H2O H2O H2PO4− H2S Hg Hg+2 HgO I− I2 K K+ KBr KCl KClO3 KClO4 KNO3 Mg Mg+2 MgCl2 MgCO3 MgO Mg(OH)2 MgSO4 Mn Mn+2 MnO g s aq aq s s s s s s aq g s s s s s s g aq g aq g g g aq aq aq ℓ g aq g ℓ aq cr aq s s aq s s s s s s aq s s s s s s aq s ΔH f S kJ ( mol ) ( molJK ) −1139.7 0 +71.7 +64.8 −157.3 −168.6 −450 −53.1 −79.5 −771.4 −335.35 0 0 −823.0 −272 −824.2 −1118.4 −929 0 0 −36.29 −689.93 −92.31 −273.30 26.50 −174.1 −1299.0 −886.9 −285.830 −241.826 −1302.6 −20.6 0 170.21 −90.79 −56.78 0 0 −252.14 −393.8 −436.7 −397.7 −432.8 −494.6 0 −467.0 −641.3 −1095.8 −601.60 −924.5 −1284.9 0 −220.8 −385.2 81.2 33.2 40.6 −99.6 42.6 93.1 108 66.5 120.9 107.6 −13.8 202.7 27.3 106.7 61 87.4 146.4 121 130.6 0.0 198.6 91.2 186.8 173.7 206.5 155.6 −33.5 131.8 69.9 188.7 90.4 205.7 76.0 −32.2 70.3 111.3 116.1 64.2 102.5 95.9 82.6 143.1 151.0 133.0 32.7 −138.1 89.6 65.7 26.9 63.2 91.6 32.0 −73.6 59.7 Substance State MnO2 N2 NH3 NH4+ NO2− NO3− N2H4 NH4Cl NH4NO3 NO NO2 N2O N2O4 Na Na+ Na2CO3 NaHCO3 NaCl NaF NaNO3 NaOH Ni NiCl2 NiO OH− O2 P4 PCl3 PCl5 PH3 PO4−3 Pb Pb+2 PbBr2 PbCl2 PbO PbO2 PbS PbSO4 S SO2 SO3 SO4−2 S Si SiO2 Sn Sn+2 SnO2 Zn Zn+2 ZnI2 ZnO ZnS s g g aq aq aq ℓ s s g g g g s aq s s s s s s s s s aq g s g g g aq s aq s s s s s s s g g aq s s s aq s s aq s s s ΔH f S kJ ( mol ) ( molJK ) −520.0 0 −45.94 −133.26 −104.6 −206.85 +50.6 −314.4 −365.6 +90.2 +33.2 +82 +9.2 0 −240.34 −1131 −948 −411.2 −573.6 −467 425.6 0 −316 −239.7 −230.015 0 0 −287.0 −374.9 +5 −1277.4 0 0.92 −278.7 −359.4 −219.0 −277.4 −100 −920 0 −296.81 −395.7 −909.34 2 0 −910.7 0 −8.9 −577.63 0 −153.39 −208.0 −350.46 −206.0 53.0 191.5 192.3 113.4 123.0 146.4 121.2 94.6 151.1 210.7 240.0 220 304.2 51.2 59.0 136 102 72.1 51.5 116 64.5 29.9 107 38.0 −10.8 205.0 164.4 311.7 364.5 210 −222 64.8 10.5 161.5 136.0 66.5 68.6 91 149 31.8 248.1 256.7 20.1 aq 18.8 41.8 51.6 −17.4 52.3 41.6 −112.1 161.1 43.6 57.7 Chemistry Reference Tables Table CC. Some Common & Equivalent Units and Approximate Conversions Some Common & Equivalent Units Length 1 in (inch) = 12 in = 3 ft = 5,280 ft = 2.54 cm 1 ft (foot) 1 yd (yard) 1 mi (mile) Mass 1 lb (pound) 1 ton 1 tonne = 16 oz = 2000 lb = 1000 kg Volume 1 pinch 3 teaspoons 2 tablespoons 8 oz. (ounces) 2 cups 2 pints 4 quarts = = = = = = = = 1,760 yd ~ 454 g ≤ 18 teaspoon 1 tablespoon (Tbsp) 1 ounce 1 cup 1 pint 1 quart 1 gallon Some APPROXIMATE Conversions Length 1 cm ~ width of a small paper clip 6 in ~ length of a (US) dollar bill 1 ft ~ 30 cm 1m ~ 1 yd 1 mi ~ 1.6 km 0.6 km ~ 1 mi 1 pinch 1 mL 1 teaspoon (tsp) 1 tablespoon (Tbsp) 2 Tbsp. 1 C (cup) 1 qt (quart) ~ ~ ~ = = = ~ ≤ 1 8 teaspoon 10 drops 5 mL 3 tsp 1 fl. oz. 8 fl. oz. 1L 1 small paper clip 1 nickel (5¢ coin) 1 oz 1 pound (lb) 1 ton ~ ~ ~ = = 1 gram (g) 5g 30 g 16 oz 2000 lb Speed 60 mi/h Density air water Volume Mass ~ ~ ~ ~ 60 drops 15 mL 30 mL 250 mL ~ ~ 0.5 kg 1 tonne ~ 100 km/h ~ 30 m/s ~ 1 g/L ~ 1 g/mL ~ 1 tonne/m3 ~ ~ 8 lb/gal 1 ton/yd3 p. 14 Chemistry Reference Tables p. 15 Table DD. Selected Formulas and Equations Density Mole Conversions Percent Error Percent Composition Concentration Gases D M V D = density Titration Colligative Properties mass of part *100% mass of whole moles of solute molarity ( M ) liter of solution moles of solute molality (m) kg of solvent moles of A mole fraction ( A ) total moles % composition P1 V1 P2 V2 T1 T2 Ka pOH = −log[OH ] Kw= Ka∙Kb = 1 × 10 Thermodynamics Electrochemistry Temperature Radioactive Decay parts per million (ppm) grams of solute 1,000,000 grams of solvent n = moles T = temperature (K) 1 atm = 101.3 kPa = 760 torr = 760 mm Hg = 29.92 in. Hg = 1.013 bar = 14.7 psi χ χA = mole fraction of A PA= partial pressure of A PA = APT PT = PA + PB + PC + … PT = total pressure NA = normality of H3O+ NB = normality of OH− NAVA = NBVB VA = volume of acid VB = volume of base Tf = freezing point depression (°C) Tb = boiling point elevation (°C) Tf = imKf Kf = freezing point depression constant (H2O = 0.52 °C/m) Kb = boiling point elevation constant (H2O = 1.86 °C/m) Tb = imKb i = van’t Hoff factor (dissociation factor) π = osmotic pressure m = molality M = molarity (mol/L) N = normality (mol/L) π = iM RT = N RT R = ideal gas constant T = temperature (K) pH + pOH = 14 Heat (moles of solute)(dissociation factor) liter of solution Latm L kPa L torr R 0.0821 mol 8.31 mol 62.4 mol K K K − Equilibrium normality ( N ) P = pressure V = volume (L) pH = −log[H3O+] Acid-Base V = volume 1 mol = [molar mass] g (molar mass = formula weight = gram formula mass) 1 mol = 22.4 L of gas at 0°C and 1 atm 1 mol = 6.022 × 1023 molecules, atoms, or particles measured value - accepted value % error *100% accepted value PV = nRT Pressure M = mass −14 Kb [H3O ][A ] [HA] pKa = −log(Ka) pH pK a log [H B][OH ] [B] pKb = −log(Kb) base acid Kp = gas press. Kc = molar conc. Δn = change in equil. const. equil. const. # moles q = heat q = m Cp T T = change in temperature m = mass q = m Hf Hf = heat of fusion Cp = specific heat capacity q = m Hv Hv = heat of vaporization ΔG° = ΔH° − TΔS° G° = standard free energy S° = standard entropy ΔG° = −RT ln K H° = standard enthalpy T = temperature (K) q = charge I = current (amperes) t = time (seconds) q (Coulombs) I t F = Faraday’s constant = 96,000 Coulomb per mole electrons ΔG° = −nFE° n = moles of electrons E° = standard reduction potential K = °C + 273.15 K = Kelvin °C= (°F−32) * 5/9 °C = degrees Celsius °F = degrees Fahrenheit t t t = total elapsed time A = amount left number of half-lives = A Ao 12 ½ τ½ = half-life Ao = original amount ½ Kp = Kc(RT)Δn
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