Chapter 7 Sec. 1-4 Ionic Compounds and Metals NOTES Sec. 1 Ion Formation o Chemical Bond: 3 Types of Chemical Bonds (1) Ionic (2) Covalent o Nonpolar o Polar (3) Metallic o Valence Electrons Determine the chemical properties of an element Electrons in the outermost energy level (s & p orbitals) Involved in the formation of chemical bonds GOAL OF BONDING: o Positive Ion (Cation) Formation o Negative Ion (Anion) Formation Sec. 2 Ionic Bonds and Ionic Compounds o Ionic Compound: Examples of Ionic Compounds: Formula Unit – simplest formula for an ionic compound o Ionic Bond: o Properties of Ionic Compounds Ions are packed into a regular repeating pattern called a crystal lattice (3D geometric arrangement of ions) Balances the forces of attraction and repulsion Minimizes potential energy (PE) Soluble in water but NOT in a nonpolar liquid Conduct electricity when melted or in solution Able to form electrolytes Electrolyte: an ionic compound whose aqueous solution conducts an electric current because of its free ions Properties linked to the strong nature of the ionic bond: Hard crystalline solid High melting points (MP) o WHY? High boiling points (BP) o WHY? o Energy in an Ionic Bond In every chemical reaction energy is either absorbed (endothermic – when bonds are broken) or released (exothermic – when bonds are formed) Formation of ionic compounds is always exothermic o WHY? Lattice Energy: Characteristics of Lattice Energy o Released when an ionic bond forms (negative value) o Directly related to the (1) size of the ions bonded and the (2) charges of the ions bonded o The greater the lattice energy the stronger the attraction between the ions Lattice Energy Trends: o (1) The smaller the size of the ion the ____________________ the lattice energy. o (2) The greater an ion’s charge the _______________________ its lattice energy. Sec. 4 Metallic Bonds and the Properties of Metals o Metallic Bond: “Sea of Electrons” bond Delocalized electrons: the outermost electrons (valence electrons) in metals which are free to move around o Properties of Metals High Melting Points (MP) High Boiling Points (BP) Malleable Ductile Good conductors of heat and electricity As the number of delocalized electrons increases the hardness and strength of the metal increases (alkali metals are the softest and the weakest) Form alloys Alloys: Why alloys? 2 Types of Alloys: o (1) Interstitial Characteristics: Examples: o (2) Substituted/Substitutional Characteristics: Property Review o IONIC COMPOUNDS o METALLIC COMPOUNDS Examples:
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