..MlVfcRbli .U.INOIS URBA 1 or. «W8» iAMPWGN AGRICULTURE NOTICE: Return or renew each Lost Book is all Library Materials! The Minimum Fee for $50.00. The person charging this material is responsible for return to the library from which it was withdrawn on or before the Latest Date stamped below. its and underlining of books are reasons for disciplinary action and may result in dismissal from the University. To renew call Telephone Center, 333-8400 Theft, mutilation, UNIVERSITY OF ILLINOIS LIBRARY AT URBANA-CHAMPAIGN L161— O-I096 JUN t 1 1938 AGRICULTURE LIBR Digitized by the Internet Archive in 2011 with funding from University of Illinois Urbana-Champaign http://www.archive.org/details/reusingfoodpacka1320brew Reusing Food Packaging Is It . . . Safe? DHT 2 AG 8 Library M. Susan Brewer University of Illinois at Urbana-Champaign College of Agriculture Cooperative Extension Service Circular 1320A Helping You Put Knowledge to Cooperative Extension Service University of at Work Illinois Urbana-Champaign College of Agriculture This publication was prepared by M. Susan Brewer, Extension Specialist, Foods and Nutrition, Division of Foods and Nutrition, University of Illinois at Urbana-Champaign. Edited by Francine Weinbaum Designed by Joan R. Zagorski Urbana, July 1992 Illinois Issued in futherance of Cooperative Extension Work, Acts of May 6 and June 30, 1914, in cooperation with the U.S. Department of Agriculture. DONALD L. UCHTMANN, Director, Cooperative Extension Service, University of Illinois at Urbana-Champaign. opportunities in programs and employment. .5M— 7-92— 1320A— fw The Illinois Cooperative Extension Service provides equal Introduction How does our food get on the Many consumers an essential component in the complex distri- aging because they are concerned with protecting the environment. bution system which moves agri- Recent years have brought table? Packaging cultural products is from their point of origin to their point of con- sumption. Along with our culture, our packaging of food has become increasingly specialized and complex. Sterile boxes of fruit juice, plastic that food pouches can tolerate pressure canning, reuse food pack- in- creased environmental pollution and decreasing natural resources and landfill space. But improper reuse of food packaging can threat- en health. So it is important to follow certain guidelines (see page four). For example it is gen- erally safe to reuse glass that has and microwave-safe containers are but a few examples of specialized food packaging which did not exist twenty years ago. Food been used packaging has several functions ing materials used for protecting other than tection. its primary one of pro- Packaging protects food from microbial and other environ- for food, but not to re- use plastic or paper. Understanding the uses, specialized functions, and limitations of packag- consumer foods can help consumers make safe decisions regarding the reuse of packaging materials. mental contaminants, and from damage during distribution. It also offers the consumer nutrition and ingredient information, cooking instructions, product This circular discusses the following topics: 1. commercial sterilization tech- niques that keep microbes out; weight, brand identification, and pricing. 2. glass, plastic, and paperboard packaging of food; and includes 3. easy-to-follow guidelines for reusing food-packaging materials; 4. a glossary of food-packaging terms for the consumer to take the edgeable. who wants time to become knowl- Keeping Microbes Out Establishing microbiological stability is of primary importance for most food products. Early food packaging had to be able to tolerate heat so that the product could be canned (terminally sterilized in the container). Glass and tin (which uses high temperatures very short times), and irradiation. rials used for gamma ray The packaging mate- for these new processes must be sterilized before they are used; methods used to sterilize packaging include hydrogen per- cans were the original processed- oxide or steam treatments, expo- food packages because they could sure to ultraviolet light, or tolerate sterilization temperatures. ray irradiation. Because food flavors are apt are "hot-filled" at 170°F, so the to gamma A variety of foods change during heating, a variety chemically sterilized packaging of sterilization techniques have been designed to kill or remove microbes from food products us- must be able ing little no heat processing. or These techniques include the use of hydrogen peroxide treatments, to tolerate tempera- tures slightly above 170°F. Pack- aging materials that tolerate these processes will not always tolerate temperatures over 180°F without substantial breakdown. aseptic packaging (packaging in a sterile environment), ultra-high temperature (UHT) sterilization Glass Versus Plastic and Paperboard Most packaging materials are designed for one use. With the ex- board are designed to be recycled ceptions of glass containers re- not quiring user deposit and limited- into new packaging forms that do come into contact with food. that consumers These recycled forms can be used in outer layers of a food package or as containers for foods encased will take the product home, then in other materials. use polycarbonate facturers assume bottles, manu- discard or recycle the packaging. Packaging ingly. When manufacturers designed accord- is Packages are designed to tolerate the type of food system design a packaging system, they consider the type of food (high-acid versus (acid, base, alcohol, or fat) that low-acid), the susceptibility of the will be contained within them. food to light and oxygen (milk, No fruit juice), safety is systems or implied for for other food reuse of that pack- age in ways not suggested for the the cal protection the amount amount needed of physi- (eggs), and of product visibility They original food product. In general, desired (fresh meats). glass is the only packaging mate- consider the amount of heat to be rial designed for reuse that uses the packaging over again in original form. Plastic its and paper- also sterilization, the con- ally layers of different polymers. and the type of "home Each layer makes a contribution used during tainer size, processing" to which the product to total package performance. will be subjected (for example, microwaveable pizza). Other con- siderations include the cost availability of the and packaging mate- the food product, a problem that can be aggravated by heat and by the presence of a food into which the plasticizing chemical will dis- Flexible plastics small amounts may contain (1 to 2 percent) of solve (for example, oil, acid, or alcohol). Migration of the other substances that perform pound com- increases with length of and temperature, specialized functions. These "ad- contact time finished product (plastic versus ditives" include catalysts to aid in and glass soda bottles), recyclability the polymer formation reaction, est antioxidants to prevent oxidation between film and foods with high of the packaging material, stabiliz- fat rial, the cost of transporting the (plastic versus paper), sumer and con- attitudes about packaging. levels of migration are high- when there content at is direct contact the surface. ers to prevent degradation of the Most packaging material plastics are considered "high-barrier" packaging materials. They exclude moisture and when it is heated or exposed to ultraviolet radiation, and plasticizers. Plasti- most gases (including oxygen), and they can be either optically clear or opaque. Because of their unique characteristics, plastics are becoming the most important cizers increase the flexibility of packaging material for food prod- rigid substance. Plasticizers plastics. They intersperse around the polymer molecules and pre- made of plastics. may and many have relatively low melting points themselves. There has been some concern about the migration of plasticizers produced from base polymers called "resins." Most Plastics are actual packaging applications in- volve several types of resins. Structural polymers such as poly- ethylene (PE) and polypropylene (PP) provide mechanical properties (strength, rigidity, resistance) at low abrasion cost. Barrier polymers such as polyvinylidene chloride (PVDC) and ethylene vi- nyl alcohol (EVOH) provide pro- tection against transfer of gases, and odors. Tie resins (adhesive resins) bond the structural and barrier resins together. Heatflavors, seal resins provide package clo- sures in flexible packages. In fact, many "plastic" packages are actu- If substances are shown to migrate from the packaging into the food, they are treated as "incidental food additives" and toxico- plastic, is tact. logical studies are the aging packaging materials for food con- other so tightly that they form a ucts. than 90 percent of flexible pack- tion assesses the initial safety of vent them from bonding to each lower the melting point of the The packaging industry is largest user of plastics; more The Food and Drug Administra- out of the packaging material into conducted in order to establish safety standards. The safe reuse of packag- ing materials has been studied much less, but some generaliza- tions can be made. Guidelines for Reusing Food-Packaging Materials 1. Packages from products other 4. Do not reuse porous packag- than food should never be used ing materials such as paper, as food containers. They have paperboard, and expanded foams not been tested for safety with (for may food systems, and they con- amounts of nonfood residues. (For example, do not example, styrofoam cups and foam meat trays). They have air spaces that will harbor food par- tain small ticles and microorganisms. use plastic laundry detergent buckets for storing dry cereal.) 5. Do not reuse microwave pack- ages that contain "heat suscep2. Glass can be reused foods and for is all originally what food There is should not be used The material is more grate into the food likely to mi- if it is used again. for howrecommendadiscussed below (number 3). The may home pressure processing in the canner. hold the be damaged by the original use. an ex- ception to this rule: single-use glass jars that crisping. susceptor to the package packaged in the glass container. browning or The adhesives processes. This true regardless of was tors" for for all lid or cover, 6. It is better not to store foods ever, is subject to with strong odors or flavors in tions used food packages; the packag- re- ing material might absorb the Reuse packaging materials only with the following: chemicals that produce the odor 3. • foods similar in in sugar, fat, acidity or flavor and or alcohol content to the food originally in the material. Do packaged not use a salad dressing containing a substantial amount of vinegar. • foods that will be exposed same types of processes. to the Do not melt butter in the microwave oven using a plastic margarine container. In general, do not subject food packages to heat unless the instructions on the original package give heat ing information. Many food products are "hot-filled" into containers at low temperatures. These packages will not ate heating. release them into a ditionally, rials some packaging mate- allow certain chemicals to pass through them, transferring plastic shortening container to make and subsequently stored product. Ad- toler- odors or flavors to other foods stored in the same area. 7. When materials are safe for use microwave oven, they are usually labeled for such use. If you do not know whether the in the material is safe for use in the microwave, don't use it. Soft plastics are especially likely to flake, blister, deform, and melt. This allows plastic polymer or you 9. If bag are using a flexible film 11. Use only "food-grade paper" bread wrapper for food in direct contact with food prod- like a storage, always use it with the materials can contain residues if they with come into direct contact the film over the food with toothpicks. There should be no direct contact between the film and the food. Do not seal the contact edge between the film and the container. If you do, you may be burned by the steam that builds up during heating. This steam can escape rapidly move the film. when you re- which would be unacceptable for contact with food are manu- minimize residues, If you store a container for food storage. Many up small amounts of the substances stored in them and release them later. Motor oil plastics pick stored in plastic milk jugs will later you be present in lemonade store in foods. Paper products destined which and the fin- factured by processes it. nonfood item in a food container, do not reuse the Suppose you are using a flexible plastic wrap to cover a container of food you are heating in the microwave. Be sure to "tent" and the raw may contain materials that are not meant for human consumption. These inks may migrate into food 10. 8. Paper processing uses a va- riety of chemicals, additives to penetrate into the food. ucts. printed side out. Printing inks lemonade container. in the if same ished product is routinely tested. 6 A Glossary of Food-Packaging Terms Food-grade plastics often have AN information embossed into the Acrylonitrile bottom of the container. The type of plastic material may be to by an acronym such or EVOH. as referred HDPE the term refers to acrylonitrile that is polymerized with styrene AN films, or methyl aery late. coatings, and semirigid containers are cleared for use only for single- ABS use food-contact surfaces. They Poly(acrylonitrile-butadiene-styrene) copolymer. Heat distorts it Maximum continuous service temperature is 165°F. ABS at 200°F. is monomer. Usually, have not been tested 120°F. for use above AN films are used prima- rily in the pharmaceutical indus- try. resistant to acids, bases, fats, and oils. It does not vents and yellows sunlight. for if resist sol- exposed to ABS has been cleared food use with all foods except those containing alcohol and those subjected to thermal processing. It can be used with foods and stored at room temperature, and stored refrigerthat are filled ated or frozen. Acetyl tributyl citrate, a deriva- ATBC is used in flexible packaging films and has been cleared for use as a plasfood contact surfaces of resinous and polymeric coatings and paperboard for use with fatty foods. It has been sanctioned by the FDA and falls in paper into the "relatively harmless" toxicity category as a consumable chemical. Estimated daily human intake from current uses of plastic film is around 0.0008 milligrams per kilogram of body weight. ATBC is considered safe at this level. manufactured there is like cellophane, is but an additional reaction that includes acetic anhydride. It deformed by heat, acids, and bases, some solvents but is resistant to fats and oils. It builds up static. Maximum continuous is easily CA is 175°F. tive of citric acid. and Cellulose acetate. This material service temperature for ATBC ticizer for CA Cellophane Regenerated cellulose-based ible is flex- packaging material. Cellulose dissolved in sodium hydroxide, then extruded into an acid-salt bath to produce filaments of regenerated cellulose. It can be coated with Saran for use with oily or greasy products. Cello- phane was introduced in the 1920s as a bread wrap. It is semi- moisture-proof and heat-sealable. The heat-sealing range 300°F. Cellophane is is 200 to flammable. HDPE EVA 2. Ethylene-vinyl acetate copolymer. percent to 15 percent vinyl High-density polyethylene (see EVA is a alcohol can be used with aque- PE). ous acid and nonacid foods tinuous service temperature of rial flexible packaging mate- formed from low-density poly- ethylene (PE) and vinyl acetate. more is flexible permeable EVAs to It than PE but more are unstable at high temper- EVA is tures. low tempera- cleared for use with foods and for treatment with fatty irradiation as a sterilant (up to 8.0 megarads total), heat-sterilized. so so It is oil; dairy oil in water emulsions; beverages; and fats oils; solids with free surface oil; and foods that are refrigerated or treatment. very stretchy, to at 140°F. It is It will build and used for up milk fats static. and oils. HDPE is jugs, cleaning sup- ply bottles, and trash bags. High-oxygen-barrier An ethylene content of 20 40 percent, to 60 cent vinyl alcohol for 160°F but distorts resistant to moisture, gases, acids, no thermal frozen-stored with 3. HDPE has a maximum con- bases, solvents, moist bakery products and dry need not be it can be used as a shrink wrap. it with free surface low-moisture water and gases. atures but stable at An ethylene content of 55 food use with 80 per approved to is all foods ex- polymers Polymers used to prevent almost all oxygen als include vinyl alcohol, vinyli- transfer. These materi- EVOH cept those containing alcohol Ethylene vinyl alcohol, a copoly- and those which mer water-sterilized, hot-filled, or are not melt-processable, so they pasteurized above 150°F. are with another organic polymeric This material can be used on such as PVDC, EVOH, or AN. phase (polystyrene or nylon). refrigerated or frozen ready- EVOH can be formed into films, prepared foods to be reheated It and ethylene. may be modified by blending it of vinyl acetate sheets, and rigid containers. in the container at the time of It and gases (such dioxide). as has been tested and has been shown not EVOH has excellent it to release substances exceeding 0.15 milligrams per can be used with a wide variety of square inch of food-contact foods. There are three types of surface at 212°F. into copolymer forms HP polyester High-performance PET. This material carbon chemical barrier properties, so made use, provided the specific film provides an excellent barrier to flavors are boiling- dene chloride, and acrylonitrile. Pure polymers of these substances has a melt point of 275°F and can be melt-blown and hotfilled. The final container is yellow but has excellent barrier properties. For instance, it retains carbon dioxide in soda. EVOH: 1. An ethylene content of 55 FSL percent to 30 percent vinyl Food-simulating liquids. These alcohol can be used with acid are substances aqueous and nonacid aqueous foods with no free surface oil; simulate the possible reactions dairy oil in water emulsions; oil-free beverages; bakery prod- and dry solids with no free surface oil; and foods that are ucts hot-filled or pasteurized at 150°F or less, and room-temper- which are used to between food and materials with which they come into contact. The chemical characteristics of FSLs are specific, so a particular food may be simulated with sev- eral food-simulating liquids in- cluding distilled water, 3 percent ature-, refrigerator-, or frozen- acetic acids (acid foods), 8 percent stored. or 50 percent ethanol (alcohol- containing foods), and n-heptane (fat- or oil-containing foods). Hydrogen peroxide An oxidizing agent used for cold packaging such as sterilization of films and bottles before filling them with hot or sterilized food. Residual hydrogen peroxide limited by the FDA to is 0.1 parts per million (ppm) after packaging (FDA 21CFR 178.1005). Hydro- gen peroxide is permitted as a sterilant for PET, olefins, and EVA. LDPE PE Low-density polyethylene (see PE). Maximum continuous vice temperature is distorts at 104°F. LDPE to 140°F; Polyethylene. Polyethylene ser- it heat- is resistant moisture vapor, acids, bases, and fats and oils. It sistance to solvent static. LDPE is has poor re- and builds up used primarily packaging films and PET for for bread- wrapping bags. Polyethylene terephthalate, a is cleared for food contact surfaces polyester resin used for high-im- an "olefin polymer." The structure of this polymer is relatively pact resistant containers. loose, so barrier for both flavors as rier than it is a less effective bar- PVDC or PVC. It was carbons introduced in the food industry in PET is PE can be produced by two processes: low pressure pro- some the 1950s. duces high-density PE, while high pressure produces low-density OPP PE. Low-density Oriented polypropylene. OPP has and oxygen barrier characteristics and protects against good light moisture. It is clear but will ac- OPP can be cept printing ink. manufactured flexible. It to be semirigid to can be overlaid with metalized polyester or colored). trolled It is (silver, gold, used for con- atmosphere snack foods in melt-blown, clear. It is a PE is strong good moisture and barrier but a poor oxygen barrier, and will heat-seal to up static self. 250 Its itself. and tends it PE builds to cling to heat-sealing range to 350°F. In general is PE it- from is It is poor resistance It to bases fats but has and solvents. will not tolerate continuous boil- ing in water. Maximum continuous service temperature and heat used for tion in foods containing free These containers are more expen- oil that are if the material is less than 0.02-inch thick, or hot-filled if the ma- between 0.004- and 0.02- baby bottles. Recent 100 times) of polycarbonate bottles for school to a total of 6.0 megarads. Certain polymers have restricted uses, legisla- plastic milk programs and to 275°F. products such as juice-based distortion occurs at 180°F; maxi- mum continuous service temperature is is used used es- and beverages and tomato sauce. Heat 212°F. High-melting PET for rigid trays of the type for items. It TV dinners or entree can be heated in a micro- pecially with respect to tempera- wave ture. 350°F for 30 minutes. There has or in a conventional oven at been a moderate amount of concern that additives from these may ticularly a half-gallon milk containers for retail use. up At boiling temperatures, but they can be used for hot- trays New York allows refill (up to bottles, boil- deform badly. Modified PETs distor- tion occur at 275°F. This material is soda have melt points of 253 for irradiation sterilization and liners, been tested and approved for use with aqueous acid and nonacid inch thick. PE has been cleared stable to acids box bottles will shrink 30 percent terial is very clear and break-resistant. PET is used boiling. and It is fats. not for cooking. Copolymers have food are chips in "bubble packs" It is mold. and cleared for use for packaging but or pasteurized at 150°F PC is a rigid plastic. oils and microwave food trays. The melting point of unmodified PET is below vent development of rancid Polycarbonate. and in-the-bag pouches, filled PC not transparent. resistant to acids, bases, solvents, cereal sive, airline peanuts. and hydro- mouthwash, pourable dressings, edible oils, and peanut butter. Monolayer films will hold a crease, and are heat-sealable and transparent. The film is used for over 212°F Examples of these snack It is difficult to heat-sterilized at temperatures vor. provides a good it for soda, which air has been flushed out and replaced with nitrogen to prefla- (fat). When migrate into foods, par- if the trays are reused in microwave oven. Plasticizers PP acid or nonacid foods and bever- Substances used to increase the Polypropylene. Polypropylene ages containing no was introduced foams are used flexibility of polymeric (plastic) They prevent formation of some of the bonds between polymer molecules and make the films. Common plasti- films less rigid. cizers include dioctyl adipate (DOA), which used with PVC; butylated hydroxyanisol (BHA), is which is used with polystyrene and styrene; low-density polyeth- in the 1950s. It is PS beverage very transparent but cracks and cups, egg cartons, meat trays, and low temperatures (15°F). It was used successfully in the mid-1960s as a copolymer with PE but was eventually replaced by plain PE for bags. It is more rigid, stronger, and lighter than preparation cups for instant foods breaks PE. at It is resistant to water vapor, ylene (LDPE); high-density poly- and solvents, some polypropylenes and are re- ethylene (HDPE); and high-mo- sistant to hindered phenols, or oils. fat for hot grease, acids, bases, high temperature. Heat such as noodles and soups. PVC Polyvinyl chloride. manufac- It is tured by polymerizing vinyl chlo- monomer. Plasticizers must be added to give it flexibility. The structure of this polymer is relatively tight, but some air will ride PVC has distortion occurs at 113°F; maxi- pass through used with ethylenevinyl acetate (EVA). Other ap- mum continuous service tempera- distortion temperature of 165°F proved plasticizers are irradiation sterilization lecular- weight which are listed in The Food Chemical News Guide (pp. 328.1-328.4). Polyamide ture is 100°F. PP is cleared for up to 1 megarad total. Polypropylene is used for yogurt containers, margarine tubs, and bottles for some pourable foods such as syrup. (Nylon-6, Nylon-12) A flexible packaging material made from amino ized vegetable acids or dimer- oils. Polyamides good oxygen and water barriers, but they have low melting points. Polyamides are approved for use as food contact coating on materials not to exceed room temperatures, as a component of paperare board, as sealing gaskets for food containers, and as film coatings. Certain polyamides are approved for higher tions. temperature applica- Nylon-66 has a very high melting point but heat-seal. at 400°F; is difficult to Heat distortion occurs maximum service temperature continuous is 175°F. and a it. maximum continuous cause its shrink and melt points are so low, PVC can be used to shrink wrap foods which tolerate very little heat. It is PS fats, Polystyrene, a rigid or flexible for packaging material. PS red meats because It heat distorts at 170°F. It is resis- tant to water, oxygen (but not bon and weak dioxide), car- acids, bases, damaged by solvents and alcohol. PS films are approved for irradiation sterilization up to a total of 1 megarad. PS can be formed into a foam that is less brittle than solid PS film. PS can be foamed using fats and oils, but it is n-pentane, isopentane, or toluene as the "blowing agent"; the use of chlorfluorocarbons (CFCs) has been discontinued in the manufacture of items used by the food service industry. PS foam is approved for food use with aqueous ser- vice temperature of 150°F. Be- water, acid, bases, is brittle. a heat- and oils. resistant to some solvents, PVC is approved use as the film to wrap fresh enough air to it allows pass through the package to make the meat pig- ments "bloom" bright red. PVC is Prior Sanctioned for use in general food contact applications. The heat-sealing range 200 to 350°F. megarad. from PVC is approved for irradiation sterilization 1 is up to 10 PVDC Susceptor Polyvinylidene chloride, a co- A thin metalized film joined to a For more information contact the polymer of vinylidene chloride and vinyl chloride or methyl ac- container (often paperboard) with Society of the Plastics Industry, an adhesive. 1275 PVDC was rylate. to protect Plastics Industry). PVDC to pizza or to help generate enough heat to cause popcorn to pop. Susceptors attain temperatures of 450 is to 500°F in surfaces of materials that con- and direct contact food package come and aqueous fatty a The heat distortion temperature of the polymer is 113°F, at 160°F. is PVDC films soften 250°F, so they can be used with food that sarily is boiling, but not neces- with high-sugar or high-fat may get much hotter than 212°F. PVDC and PVC can foods that be copolymerized material, causing them to migrate generation susceptors used susceptors are currently being de- veloped; they will use nickel, cobalt, iron, and stainless steel to improve the susceptor's heating capacities. and the maxi- mum continuous service temperature plasticizers in the packaging or paperboard. Second-generation tightly together that very little gas or water can get through. volatilizing the adhesives aluminum-coated polyester film foods. The copolymerization results in film with molecules bound so and have the poten- into the food product. First- in with dry foods, and paperboard coating in contact with to microwaveable foods such as tial for gaskets, coverings that is cause browning or crisping of cleared for use as a base polymer tact food, including purpose "heat up" in the microwave oven invented in equipment from outdoor elements. After World War II, it was approved for food packaging, and it was Prior Sanctioned in 1956 (Society of the 1941 Its to produce a VCM Vinyl chloride monomer. PVC can have residues of vinyl chloride monomer (VCM) in the fin- ished plastic film. These levels have been reduced to insignifi- cant amounts since the late 1970s. family of flexible "Sarans." The Codex Committee on Food Additives and Contaminants has Sarans are clear and have excel- proposed guideline levels of lent barrier properties. Their lppm heat-sealing range 400°F. is from 280 to PVDC is resistant to gen, water, acids, bases, vents. oxy- and sol- for and 0.01 food. VCM in PVC packages ppm for the monomer in K Street N.W., Suite 400, Washington, D.C. 20005; (202)371-5200.
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