Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 Finite auxetic deformations of plane tessellations Holger Mitschke1 , Vanessa Robins2 , Klaus Mecke1 rspa.royalsocietypublishing.org and Gerd E. Schröder-Turk1 1 Theoretische Physik, Friedrich-Alexander Universität Research Cite this article: Mitschke H, Robins V, Mecke K, Schröder-Turk GE. 2013 Finite auxetic deformations of plane tessellations. Proc R Soc A 469: 20120465. http://dx.doi.org/10.1098/rspa.2012.0465 Received: 5 September 2012 Accepted: 11 October 2012 Subject Areas: structural engineering, geometry, mechanics Keywords: Poisson’s ratio, strain amplification, tilings and tessellations, isostaticity, skeletal frameworks, cellular structures Author for correspondence: Gerd E. Schröder-Turk e-mail: [email protected] Erlangen-Nürnberg, Staudtstrasse 7B, 91058 Erlangen, Germany 2 Applied Maths, Research School of Physical Sciences and Engineering, The Australian National University, Canberra, 0200 Australian Capital Territory, Australia We systematically analyse the mechanical deformation behaviour, in particular Poisson’s ratio, of floppy barand-joint frameworks based on periodic tessellations of the plane. For frameworks with more than one deformation mode, crystallographic symmetry constraints or minimization of an angular vertex energy functional are used to lift this ambiguity. Our analysis allows for systematic searches for auxetic mechanisms in archives of tessellations; applied to the class of one- or two-uniform tessellations by regular or star polygons, we find two auxetic structures of hexagonal symmetry and demonstrate that several other tessellations become auxetic when retaining symmetries during the deformation, in some cases with large negative Poisson ratios ν < −1 for a specific lattice direction. We often find a transition to negative Poisson ratios at finite deformations for several tessellations, even if the undeformed tessellation is infinitesimally non-auxetic. Our numerical scheme is based on a solution of the quadratic equations enforcing constant edge lengths by a Newton method, with periodicity enforced by boundary conditions. 1. Introduction Materials with negative Poisson ratios, termed auxetic by Evans et al. [1], were once believed a rarity but have recently been found in amazing variety. Poisson’s ratio ν can be expressed as Electronic supplementary material is available at http://dx.doi.org/10.1098/rspa.2012.0465 or via http://rspa.royalsocietypublishing.org. ν =− ⊥ , with the imposed strain in a given direction and ⊥ the resulting strain in the perpendicular direction. c 2012 The Author(s) Published by the Royal Society. All rights reserved. Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 The widespread appearance of auxetic behaviour results from generic features of complex microstructure that is common to these materials, rather than from specific interactions. The universal appearance of auxetic behaviour cannot be based on some particular homogeneous material property, but must be related to general features of a complex micro-structure below a certain length scale. To first order, that micro-structure is often approximated by a periodic bar-and-joint framework of rods (usually stiff), freely pivoting at mutual joints of two or more rods. A frequent geometric element of auxetic structures are re-entrant elements (non-convex polygons; e.g. see the inverted honeycomb pattern), but other mechanisms based on rotating or stretching motifs have also been proposed [21]. It seems timely to search in a systematic way for auxetic structures and their building principles. Here, we describe (i) the methodology for systematic numerical analyses of the deformation of symmetric structures and (ii) as results of this analysis, several novel auxetic frameworks and new (deformation) mechanisms with transitions from non-auxetic to auxetic behaviour at finite strains. We focus on bar-and-joint frameworks, henceforth referred to as frameworks, consisting of stiff rods of constant length that pivot freely at mutual joints (figure 1). Specifically, we will focus on periodic and symmetric bar-and-joint frameworks, which can be interpreted as tessellations (or tilings) of the plane by polygons with straight edges [22]. Mathematically speaking, S = (K, E) is an embedded graph consisting of a set of nodes, K, and a set of edges, E. Every node i ∈ K corresponds to a joint, with coordinates pi = {xi , yi }. Every edge e = {i, j} ∈ E (with i, j ∈ K) corresponds to a rigid bar of length l{ij} that defines the distance constraints (2.1) |pi − pj |2 − l2{ij} = 0 ∀ {i, j} ∈ E. The solutions of this system of quadratic equations are permissible configurations compatible with the bar length equations. The geometric object given by the polynomial equations is called an affine variety [23]. A deformation is a continuous one-dimensional hyperpath P(δ) = {pi (δ)} through the configuration space that fulfils equations (2.1) for all δ with P(0) the initial configuration. Our results are based on the geometric exploration of the full affine variety for finite values of δ and not only for the limit of infinitesimally small values of δ usually considered in infinitesimal rigidity theory [24]. We study the deformation of portions of the frameworks that correspond to a single unit cell or multiple translational unit cells and apply periodic boundary conditions. Because it is possible that an initially periodic infinite framework does not retain its symmetry during an imposed deformation, the restriction to one or a few translational unit cells represents a restrictive assumption. Note the discussion by Borcea & Streinu [25] on how periodic boundary conditions can induce non-genuine infinitesimal mechanisms. .................................................. 2. Periodic bar-and-joint frameworks as models for auxetic structures 2 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 If, for a given elongation along one direction, the material expands in the perpendicular direction, Poisson’s ratio becomes negative. Such auxetic behaviour has been reported in polymeric and metal foams [2], carbon ‘buckypaper’ nanotube sheets [3], coulombic crystals in ion plasmas [4], elastic strut frameworks [5], tetrahedral framework silicates [6], micro-porous polymers [1], α-cristobalites [7], cubic metals [8,9] and self-avoiding membranes [10]. Locally auxetic behaviour has been observed in semicrystalline polymer films [11]. Related phenomena are the negative normal stress in bio-polymer networks [12] and the dilatancy of granular media [13]. Inspired by these findings, technological applications, such as enhanced shock absorption [14], self-cleaning filters [15], tunable photonic crystal devices [4] and molecular-scale strain amplifiers [16], have been proposed. Complex physical behaviour beyond the mechanical properties results, e.g. phonon dispersion [17] and wave propagation or attenuation [18,19]. For a broader discussion of Poisson’s ratio in the context of modern materials, see the review article by Greaves et al. [20]. Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 (a) d=0 Figure 1. Novel auxetic frameworks: (a) triangle–square wheels and (b) hexagonal wheels, which include both rotating and re-entrant elements. For both structures, the edge equations alone ensure unique deformations that retain the hexagonal symmetry and hence yield ν(δ) = −1. Two-sided arrows (orange) represent the imposed deformation along e , here chosen to be in the direction of a0 . The one-sided, horizontal arrows (grey) are the lattice vector b0 . (Online version in colour.) 3. Methodology In general, the deformation behaviour of a framework need not be unique, that is, the affine variety of equation (2.1) can have dimensions greater than one. A continuum of deformation modes is possible, that is, multi-dimensional solutions of equations (2.1). However, Poisson’s ratio is well defined and a purely geometric property only with respect to a single unique deformation path. If the deformation mode is not unique, Poisson’s ratio can only be defined by identifying one deformation path from the continuum of solutions, and defining Poisson’s ratio with respect to that unique mode. In this article, two approaches are used to reduce multi-dimensional continua of deformations to single deformation modes, namely by constraining symmetry or by requiring minimization of an angular energy functional. (a) Deformation with symmetry constraints Most of the results of this article are obtained by enforcing that a framework retains some or all of its symmetries throughout the deformation (in addition to periodicity). A periodic bar-and-joint framework can be built from a translational unit cell by appending copies translated by all possible integer multiples of two linearly independent lattice vectors a0 and b0 (figure 2). For periodic bar-and-joint frameworks, we assume that the deformation mode retains the periodicity of the structure, i.e. an extended or infinite fraction of the structure responds to an applied strain in the same way as a single translational unit cell (with lattice vectors a0 and b0 , figure 2). .................................................. d = –0.15 3 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 (b) d = 0 d = –0.1 Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 (a) 4 b|| e^ 0 b (d) 0 l e|| l¢ e^ e|| a|| a0 a (d) a^ b^0 (b) b^ (c) e^ 0 b0 e || b0|| e^ 0 b (d ) e || a|| a0 a (d) a^ b0 e^ 0 e|| b|| 0 e|| b (d) e^ a (d) a0 b^0 b^ Figure 2. Set-up for the deformation of the translational unit cell used for the definition of Poisson’s ratio in equation (3.2). The strain δ is applied in the e direction (here the vertical direction). (a) General case: the crystal system is not retained, the unit cell may be or may become oblique, (b) sheared rectangular deformation also with loss of crystal system (rectangular to oblique), and (c) crystal system retaining deformation of a hexagonal unit cell. A symmetric bar-and-joint framework S is mapped onto itself under the action g(S) for all elements g ∈ G of the symmetry group1 G of the tessellation/framework, g(S) = S. If the solution space of a symmetric bar-and-joint framework is two- or more-dimensional, it can often be reduced to a unique deformation mode by enforcing that the deformed configurations Sδ maintain all or some of the symmetries of the original, i.e. g (Sδ ) = Sδ for elements g ∈ G of a subgroup G of G. Often, highly symmetric bar-and-joint frameworks are rigid when constraining most or all of the symmetries, have one or more subgroups with a unique deformation and have ambiguous deformation modes if too many of the symmetry constraints are relaxed [27]. Symmetry constraints may impose immediate constraints on Poisson’s ratio. For example, if the framework retains hexagonal or square symmetry during the deformation, Poisson’s ratio is ν(δ) = −1. Importantly, the existence of symmetries in the undeformed initial framework alone (without constraining the symmetries during the deformation) is not sufficient to determine the values of Poisson’s ratio; see for example, the study of a system with cubic symmetry by Norris [28]. Similarly, the limits −1 ≤ ν ≤ 0.5 only apply to isotropic and homogeneous materials, excluding the frameworks studied here. For frameworks, an isotropic Poisson ratio of ν = −1 for all directions is possible (and realized e.g. in figure 1), but values ν < −1 or ν > 1 can only be achieved for a specific direction and if the network is anisotropic (i.e. not of hexagonal or square symmetry). We note that the question of uniqueness of the deformation and of its determinacy is related to rigidity theory [29], Laman’s theorem for the rigidity of finite graphs [30], and to the 1 Symbols for the different plane groups are taken from the International tables of crystallography, volume A1 [26]. Note that for certain subgroups, non-conventional settings, e.g. c2, c11m, are used [26] with the corresponding cell transformation. .................................................. b0 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 b0|| Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 Similar to the Kirkwood–Keating model described, for example, by Sahimi & Arbabi [34], we introduce a harmonic energy functional penalizing deviations of vertex edge angles from their value in the initial undeformed configuration E[P(δ)] = [αjik (P(0)) − αjik (P(δ))]2 , (3.1) jik with P(δ) the configuration when the imposed strain is δ and P(0) the initial configuration. jik represents a pair of edges {j, i} and {i, k} that are adjacent (part of the same polygon) at node i, and jik the sum over all such edge pairs of the considered unit cell; αjik (P) is the angle formed by the edges {j, i} and {i, k} at vertex i in the configuration P. This potential is inspired by early work of Kirkwood [35] and Keating [36]. This energy functional is applied in §4a below. (c) Poisson’s ratio of periodic bar-and-joint frameworks Poisson’s ratio characterizes the contraction or extension of a material in the horizontal direction to an applied uni-axial vertical deformation.2 For a rectangular sample of size h0 × l0 , Poisson’s ratio ν is defined as the ratio of Cauchy strains ν = −((h − h0 )/h0 )/((l − l0 )/l0 ), where l0 × h0 is the size of the undeformed sample. For bar-and-joint frameworks with a rectangular translational unit cell that remains rectangular under strain δ, this definition is valid and yields the same result as the general definition given below. For general periodic bar-and-joint frameworks, we define the horizontal strain by the construction in figure 2, of relevance to this study since frameworks with hexagonal unit cells are also considered, e.g. figure 1: e is the direction of the given horizontal strain , now called δ, here chosen in the direction of the lattice vector a, i.e. e = a0 /|a0 |. Note, however, that the direction can be arbitrary and is not limited to lattice directions. Given the strain δ along e , the deformations of the translational unit cell are a(δ) = a0 (1 + δ)e + a⊥ (δ)e⊥ and b(δ) = b0 (1 + δ)e + b⊥ (δ)e⊥ , where a0 = a0 , e = |a0 | and b0 = b0 , e are the projections of the initial vectors a0 and b0 onto e ; a (δ) = (1 + δ)a0 and b (δ) = (1 + δ)b0 are the projections of the finite deformations. The projections onto the perpendicular direction are implicit functions a⊥ (δ) and b⊥ (δ) of δ that result from equations (2.1). This leads to the following definition of Poisson’s ratio: ν(δ) = − |a⊥ (δ)|+|b⊥ (δ)|−|a0⊥ |−|b0⊥ | |a0⊥ |+|b0⊥ | |a (δ)|+|b (δ)|−|a0 |−|b0 | |a0 |+|b0 | = 1− |a⊥ (δ)|+|b⊥ (δ)| |a0⊥ |+|b0⊥ | δ . (3.2) This is motivated by an experimental set-up with the structure fixed at the top and bottom layer and then stretched or compressed. Importantly, for rectangular translational unit cells, this definition constrains b (δ) = 0 (and hence prevents pure rotations), but allows for changes in 2 Note that this deformation does not necessarily correspond to a uni-axial strain. In contrast to the situation typically studied here, the term uni-axial strain means a uni-axially stressed material exhibiting no vertical strain, identical to a vanishing Poisson ratio with respect to the axial direction. .................................................. (b) Minimization of harmonic angular spring energy functionals 5 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 generalization of Maxwell’s rule [31] for the determinacy of periodic structures [32]. Note also the discussion of periodic auxetic deformations of unimode metamaterials constructed from rigid bars and pivots by Milton [33]. Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 (a) 1.0 6 0.8 .................................................. rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 n (d ) 0.6 0.4 n( 0.2 d) 0 n –0.2 inst –0.4 0 (b) –0.1 (c) d=0 d ª –0.103 (d ) –0.2 –0.3 d Poisson’s ratio (d) –0.4 d ª –0.268 –0.5 (e) d ª –0.42 Figure 3. Transition to auxetic behaviour (ν < 0) at finite strains of the two-uniform tessellation (33 .42 ; 32 .4.3.4)1 , without symmetry constraint. Both finite (grey) and instantaneous (black) Poisson ratios are given as defined in §3c. The four thick symbols in (a) correspond to the configurations (b–e) representing the compression pathway that is unique in p1. The strain δ is applied in vertical direction (along the downwards pointing lattice vector a) and the maximal compression (when √ collapse of 0 − 1 ≈ −0.482. (b) initial configuration with square unit cell; (c) δ = 3/a 0 − 1 ≈ adjacent rods occurs) is δ = 1/a√ −0.103 with νinst = 0; (d) δ = 2/a 0 − 1 ≈ −0.268 with ν = 0, i.e. horizontal extension equal to its initial value; (e) δ = −0.42 with almost collapsed edges. (Online version in colour.) the angle between a(δ) and b(δ), i.e. shear. For inhomogeneous or non-isotropic structures, ν(δ) depends on the applied strain direction e . Our method allows for arbitrary e that are not lattice vectors. Given a strain δ, Poisson’s ratio defined by equation (3.2) gives the ratio of lateral to orthogonal deformations with respect to the initial structure with δ = 0. Commonly, this definition is used for infinitesimal strains δ → 0, but it also applies to finite values δ (figures 1 and 3). We define the instantaneous Poisson ratio νinst (δ) as the Poisson ratio of the bar-and-joint framework already deformed by δ when a further infinitesimal strain dδ is applied (figures 3 and 4). (d) Numerical solution by the Newton scheme with singular value decomposition Analytic solutions of equations (2.1) are, in general, not known, but roots of these equations, i.e. the node coordinates and lattice parameters a⊥ (δ) and b⊥ (δ), can be found numerically by iterative Newton methods [37], with an affine deformation as initial, non-permissible configuration. The symmetry constraints g(S) = S are easily integrated into this scheme, and each symmetry appears as an additional linear equation. Structures that have a multi-dimensional solution space (or infinitesimal phantom mechanisms) imply an under-determined Jacobian matrix J that cannot be inverted. Such degeneracy is dealt with by a singular value decomposition method that identifies the solution with smallest displacement of the coordinate values [27]. Within tolerances, it is numerically straightforward to decide whether the structure is rigid, has a unique deformation or if the solution space is multi-dimensional. Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 (a) 7 .................................................. rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 (c) (b) (d) kites 0 νinst(d) –1 –2 inverted honeycomb –3 elongated kagome –4 –0.5 0 0.5 1.0 d Figure 4. Auxetic structures with νinst < −1 as candidates for strain amplification. Note that the deformation of the elongated kagome structure are studied in detail. (a) Kites (p1), (b) inverted honeycomb (cm), (c) elongated kagome (3.42 .6; 3.6.3.6) (cm)—the retained symmetry groups are given in parentheses, (d) instantaneous Poisson ratio. Note the anisotropy of these structures; the value of γ refers to vertical applied strain. The light grey (green) solid and dashed lines represent symmetries, the vertical arrows the direction e and the horizontal arrows the direction e⊥ . (Online version in colour.) Solutions for finite δ are obtained by computing successive intermediate permissible configurations for incremental steps that sum to δ, with random perturbations added to the initial and intermediate non-permissible configurations. It is possible that, starting from the affine deformation of the framework by a factor (1 + δ) in the strain direction, the Newton scheme does not converge to a solution of the edge equations—even if a solution exists and is unique. Bearing in mind that the goal of our study are continuous deformation paths from deformation 0 to a finite value δ, we achieve a finite strain δ by a number n of smaller increments δ. In each increment, the strain is increased by δ until δ is reached. Numerically, the deformation mode that minimizes E[P(δ)] for a given value of δ is determined by random sampling using a Monte Carlo approach. As described above, the deformation with finite δ is obtained by small increments of size δ, starting at δ = 0. A number m of possible solutions Pi (δ + δ) of the edge equations (equation (2.1)) for strain δ + δ are computed by adding small evenly distributed random numbers to all vertex coordinates of one of the n solutions Pj (δ ) with j = 1, . . . , n, before application of the Newton scheme that evolves the vertex positions to fulfil the edge equations; for the first step n = 1 with P1 equal to the initial undeformed configuration. For each solution, Pi (δ + δ), the value of E[Pi ] is computed. Out of the m solutions Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 We have applied the analysis described above to the 35 one- and two-uniform tessellations of the plane by regular or star polygons. These are tessellations with straight edges where all corners are vertices. These tessellations are enumerated by Grünbaum & Shephard [22], whose nomenclature is used below. One of the key results is that among these, there are two novel auxetic mechanisms, without enforcing any symmetry constraints (in one case, not even periodicity).3 These are the two-uniform tessellations (36 ; 32 .4.3.4), here called triangle–square wheels or TS wheels, and (36 ; 32 .62 ), here called hexagonal wheels or H wheels (figure 3). Both only allow compressions and their unique deformations to retain periodicity and hexagonal symmetry, owing to the edge equations only and without symmetry constraints, yielding ν = −1 for Poisson’s ratio in any direction. The deformation behaviour of the TS wheels, with maximal symmetry p6mm, is shown in figure 1a. We refer to it as TS wheels as it consists of a triangulated hexagonal wheel that rotates during the deformation, surrounded by a layer of alternating triangles and squares. The structure does not have any re-entrant elements. The deformation of the hexagonal wheels (H wheels) is shown in figure 1b with the name motivated by a rotating triangulated hexagon surrounded by a ring of hexagons that deform and develop re-entrant angles during the deformation. The TS wheel structure has only one degree of freedom; the corresponding deformation is a shearing deformation of all squares, with all other parts rigid. This deformation mode is unique, apparently by virtue of the edge equations only without constraining neither symmetry nor periodicity.4 In contrast to the TS wheels, the deformation of the H wheels is only unique when the primitive unit cell symmetry is retained; larger unit cells show finite mechanisms and the minimization of angular energies results in much weaker auxetic behaviour. Lakes [39] classifies auxetic materials with respect to three different features of the microstructure: rotational degrees of freedom, non-affine deformation kinematics or anisotropic structure. The two presented ones belong to the class of auxetic structures that rely on the chirality5 for the auxetic property and can be assigned to the ones with rotational degrees of freedom. The H wheels are similar to the proposed chiral honeycomb by Prall & Lakes [40], when the triangulated hexagons are replaced by circles. Also the geometry described by Milton [41] shares a feature with both the H wheels and the TS wheels, namely the universal property of this auxetic class that the lattice points are decorated by rigid objects that rotate. The 35 tessellations also contain another known auxetic mechanism in p1 (i.e. without constraint symmetry), namely the (3.6.3.6) called the trihexagonal tessellation or kagome structure, already discussed in earlier studies[42–46]. Kapko et al. [43] have noted that the number of collapse mechanisms grows with the size of the unit cell and have also considered crystallographic symmetry constraints for the deformation of this tessellation. The relevance of these results for engineered realizations made of homogeneous linear elastic material has been demonstrated by observation of ν < 0 in specimens produced by selective electron beam melting [47] of the TS wheel structure, and corroborated by finiteelement calculations [38]. The approximate agreement, in terms of Poisson’s ratio, between the 3 A preliminary account of one of these, TS wheels, has been given by Mitschke et al. [38]. We have studied the deformation behaviour for systems of N × N translational unit cells with N = 1, 3, 6, with periodic boundary conditions. From the observation that even the deformation for N = 6 maintains the internal (unconstrained) periodicity, we conclude that the edge equations alone constrain periodicity. It is noteworthy that this tiling is the only auxetic one within the 31 one- and two-uniform tilings that possess this feature. 5 In the initial state δ = 0, both the TS wheels and the H wheels are in a degenerate singular rigid position, i.e. being on a singular point in configuration space leading to rigidity that can immediately be removed by any small perturbation breaking the mirror symmetry resulting in chiral symmetry. 4 .................................................. 4. Results 8 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 Pi (δ + δ), those s solutions that have minimal energy value Emin := minm i=1 E[Pi (δ + δ)] are kept as initial configurations for the next increment. Typical values used for the parameters in this article are s/m ≈ 0.1, m ≈ 250 and δ ≈ δ/100. Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 (a) Figure 5. Unique deformations of the truncated square tessellation (4.82 ) in subgroups of the full symmetry group p4mm. Note that the deformation in subgroup p2mm in (c) is identical also to the deformation mode in subgroup pm (not shown). See the corresponding figure 5 in the electronic supplementary material for an animation of the deformation modes. Deformation mode of (4.82 ) in subgroup (a) p4, (b) c2mm and (c) p2mm. (Online version in colour.) framework with stiff rods and flexible joints on the one hand and the linear-elastic homogeneous solid structure with rigid joints is somewhat surprising, but points towards the importance of geometric principles for the deformation behaviour of auxetic structures. Published research on bending- versus stretching-dominated behaviour of cellular materials supports the idea that for bending-dominated structures, an approximation by bar-and-joint frameworks is valid [48–50]. An akin approximation of truss structures by pin-jointed frameworks has been carried out by Wicks & Guest [51], who discuss actuation of a single bar in periodic square, triangular and kagome lattices. The second principal result of our systematic exploration is the occurrence of auxetic behaviour upon finite deformations. There are a number of bar-and-joint frameworks that are not auxetic for small deformations, but become auxetic at finite values of δ. In these cases, the behaviour is clearly anisotropic as the structures are, in all cases, neither square nor hexagonal for the value of δ where ν or νinst vanish. As an example, the deformation of the two-uniform tessellation (33 .42 ; 32 .4.3.4)1 is shown in figure 3. Further uniform tessellations that are unique in p1 (i.e. without symmetry constraints) and become auxetic upon finite deformation are (32 .4.3.4) [22], called the snub square tessellation, and (33 .42 ; 32 .4.3.4)2 , discussed by Grima et al. [21]. .................................................. (c) rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 (b) 9 Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 (a) Finally, our third main result is the occurrence of large negative Poisson ratios when symmetry constraints are imposed. A collection of examples is compiled in figure 4, which includes the ‘kites’ structure [52] and the inverted honeycombs [53,54]. Among the investigated tessellations, there are two with negative Poisson ratios at δ = 0, in non-hexagonal and non-square symmetry groups. These are the two-uniform (32 .4.3.4; 3.4.6.4) tessellation, with a constant Poisson ratio of −1 in both the primitive cm and the p2 space group (interestingly, the deformation modes in these two groups are different), and the two-uniform (3.42 .6; 3.6.3.6)2 tessellation with a Poisson ratio smaller than −1 in lattice direction [01] (figure 4c); this tessellation can only be compressed but not stretched. The deformation behaviour depends strongly on the direction e of the applied strain and can change from non-auxetic to auxetic only at finite strain, and finally to ν < −1, even at δ = 0. Without the complete analysis of the algebraic variety defined by equation (2.1) presented in this study, such complex deformation behaviour is not detectable. We frequently observe that tessellations adopt a unique deformation mode and are auxetic if their symmetries are constrained to preserve glide planes, a symmetry element of plane group cm given in the International tables of crystallography [26]. If such constraints are imposed, the following tessellations become auxetic when a strain is applied in the direction of the primitive lattice vectors: (3.4.6.4), (4.82 ), (36 ; 44 .4.12), (33 .42 ; 3.4.6.4), (3.42 .6; 3.4.6.4), (3.122 ) and (63 ). Upon large enough deformations, the last one of these, (63 ), is congruent to the inverted honeycomb pattern (cf. figure 4b). Some of these constrained bar-and-joint frameworks have large negative Poisson ratios νinst < −1, making them promising candidates for applications as strain amplifiers [16]. Finally, figures 5 and 6 illustrate the obvious observation that a tessellation with ambiguous deformation modes for p1 (no constraint symmetries) may have unique deformation modes when subgroups of the full symmetry are used as constraints and that these deformation modes may be different for different subgroups. .................................................. Figure 6. Unique deformations of the great rhombitrihexagonal tessellation (4.6.12) in two different subgroup embeddings of the full symmetry group p6mm. See the corresponding figure 6 in the online supplementary material for an animation of the deformation modes: (a) subgroup p6 and (b) subgroup p31m. (Online version in colour.) rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 (b) 10 Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 (a) 60 –1.0 d) –1.5 E( 40 –2.0 20 –2.5 0 energy, E (d ) Poisson's ratio, ninst (d ) d = –0.05 d = –0.2 80 2 80 1 ninst (d) 0 60 d) E( 40 –1.0 energy, E (d ) d=0 d = –0.05 Poisson's ratio, ninst (d ) 100 (b) 20 –2.0 0 d = –0.2 100 0 ninst (d) –0.5 80 –1.0 60 –1.5 d E( –2.0 –2.5 0 ) 40 energy, E (d) Poisson's ratio, ninst (d) d = –0.05 d=0 (c) 20 0 –0.1 –0.2 –0.3 –0.4 –0.5 d Figure 7. Deformation mechanisms of the elongated kagome tiling by imposing a strain in a direction perpendicular to [01] for three different deformations (the [01] direction is the horizontal direction in this figure): (a) constraint to symmetry group c11m including a glide plane, (b) constraint to symmetry group c2 and (c) minimizing E[P] from equation (3.1) with only purely translational symmetry c1 with translation vectors (1, 0) and (1/2, 1/2). The tessellation is the same as in figure 8c, however with strain applied in the orthogonal direction to figure 8c. (Online version in colour.) (a) Symmetry constraints versus energy minimization From a physics perspective, a symmetry constraint may be expected as a secondary effect resulting from minimization of an energy functional, somewhat similar to the molecular bonds model of polyphenylacetylene described by Grima & Evans [42]. This motivates our second approach to the reduction of ambiguous deformation continua to single unique deformation .................................................. ninst (d) –0.5 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 d=0 11 100 0 Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 (d ) 100 2.0 80 1.5 60 d) E( 1.0 40 energy, E (d) Poisson's ratio, ninst (d) 0 (d ) 20 0.5 0 2.5 100 2.0 80 n inst (d ) Poisson's ratio, ninst (d) 20 2.5 1.5 60 d) E( 1.0 40 20 0.5 0 energy, E (d ) 40 inst –2.0 80 energy, E (d ) Poisson's ratio, ninst (d ) d=0 d = –0.2 d=0 n 12 60 n inst d = –0.1 –1.5 ) 0 (c) d=0 E –1.0 (d –2.5 (b) d = –0.1 –0.5 100 0 –0.1 –0.2 d –0.3 0 –0.4 Figure 8. Deformation of the same tessellation as in figure 7 for the orthogonal strain direction (i.e. strain perpendicular to [10]) (in this figure, the [10] direction is the vertical direction): (a) constraint: c11m, (b) constraint: c2 and (c) minimal energy deformation amongst all configurations with C1 periodicity. (Online version in colour.) modes, namely by picking the deformation path that minimizes a given energy functional, see also §3b. The energy functional could be the harmonic bond angle energy E[P] penalizing average deviations [α(δ) − α(δ = 0)]2 of vertex angles α from the initial value in equation (3.1), or more complicated energy functionals. A detailed study of the relationship between the deformations that minimize energy functionals such as E[P] and those that result by constraining the symmetry group is beyond the scope of this article. However, figures 7 and 8 elucidate this relationship, and its subtleties, for the deformation of the elongated kagome structure for two directions of applied strain. .................................................. d = –0.05 0 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 (a) Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 Bar-and-joint frameworks provide possibly the simplest model to study deformations of cellular materials, as applied strain causes only geometric deformations without any resulting forces. Such models are not suitable to answer questions regarding forces such as ‘How stiff is the cellular structure?’, but can be used to address the simpler question ‘Can a cellular structure be deformed?’ and, if so, ‘What is the geometric deformation mode?’. Because of the simplicity of the bar-and-joint frameworks and of the edge equations that govern their deformation, a systematic exploration of the deformations of framework geometries is possible, for example, by investigation of the large classes of periodic tessellations. A barand-joint framework can adopt one of three states: rigid (zero degrees of freedom), floppy with a unique deformation mode (one degree of freedom) or underdetermined (with two or more degrees of freedom). For the deformation modes of cellular matter, those frameworks with a single degree of freedom are most relevant. When exploring the vast class of tessellations as models for models of auxetic frameworks, we have here shown that symmetry constraints are a useful method to reduce the degrees of freedom of a framework. In many cases, a subgroup of the full symmetry group of the undeformed tessellation can be found such that the deformation becomes unique. This paper may represent the first instance where the dependence of framework deformation on symmetry is systematically investigated. However, implicit assumptions about the symmetry preserved under strain are not uncommon; even the standard inverted honeycomb structure with its re-entrant elements, often depicted as the archetypal auxetic model, does not have a unique deformation mode, unless one assumes that rectangular lattice vectors (or equivalently glide plane symmetries) are maintained during the deformation. While symmetry constraints were here largely used as a means to an end, namely to obtain structures with a single degree of freedom, it appears likely that preserved symmetries could also emerge as the result of physical forces. Figures 7 and 8 demonstrate some of the subtleties of this approach that require more in-depth investigation. Of particular interest, both theoretically and for applications such as strain amplification, would be an energy functional that, when minimized, leads to the preservation of glide plane symmetries; as has been demonstrated here, glide plane symmetries are preserved, as we have here demonstrated that glide plane symmetry constraints lead to particularly large negative values of Poisson’s ratio, below −1, evidently in anisotropic structures such as those shown in figure 4. It is an interesting question to what degree the force-less deformations of a bar-and-joint framework and those of a linear-elastic body relate to one another. Clearly, the structure of the equations underlying the two processes are very different [55,56]. Nevertheless, if the deformation mode of a bar-and-joint framework is unique, one may expect that geometry is the fundamental 6 The symmetry group p1 with lattice vectors a and b has no symmetries except for periodicity. This applies equally to the ‘centred’ group c1 with lattice vectors a and b; however, c1 is periodic under translations by (a − b)/2 and (a + b)/2. .................................................. 5. Discussion 13 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 Figure 7 shows the deformation modes and the corresponding Poisson ratio for strain perpendicular to [01]. With only translational symmetry constraints (either p1 or c1), the deformation is ambiguous, whereas for both subgroups c11m (including glide planes) and c2 (without glide planes), the deformation is unique; however, the modes for c11m and c2 are clearly different, as evidenced by the configurations as well as the Poisson ratio νinst (δ). It is then interesting to note that the deformation that minimizes E[P] without any symmetry constraints, except for pure translation c1,6 corresponds to one of these groups, namely c11m. This is an interesting observation considering that we have identified several tessellations with νinst < −1 if glide plane symmetries are constrained. Interestingly, when the strain is applied in the orthogonal direction (i.e. perpendicular to [10]; figure 8), we again observe two distinct and unique deformation modes for c11m and c2. However, for that strain direction, the unconstrained energy-minimizing mode is the same as the c2 mode, in contrast to the situation above. Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 SCHR1148/3-1 and ME1361/12-1. References 1. Evans KE, Nkansah MA, Hutchinson IJ, Rogers SC. 1991 Molecular network design. Nature 353, 124–125. (doi:10.1038/353124a0) 2. Lakes R. 1987 Foam structures with a negative Poisson’s ratio. Science 235, 1038–1040. (doi:10.1126/science.235.4792.1038) 3. Coluci VR, Hall LJ, Kozlov ME, Zhang M, Dantas SO, Galvao DS, Baughman RH. 2008 Modeling the auxetic transition for carbon nanotube sheets. Phys. Rev. B 78, 115408. (doi:10.1103/PhysRevB.78.115408) 4. Baughman R, Dantas S, Stafström S, Zakhidov A, Mitchell T, Dubin D. 2000 Negative Poisson’s ratios for extreme states of matter. Science 288, 2018–2022. (doi:10.1126/science. 288.5473.2018) 5. Sigmund O. 1994 Tailoring materials for specific needs. J. Intel. Mat. Syst. Str. 5, 736–742. (doi:10.1177/1045389X9400500602) 6. Alderson A, Evans K. 2002 Molecular origin of auxetic behavior in tetrahedral framework silicates. Phys. Rev. Lett. 89, 225503. (doi:10.1103/PhysRevLett.89.225503) .................................................. We acknowledge financial support by the German Science Foundation (DFG) through the Engineering of Advanced Materials Cluster of Excellence (EAM) at the Friedrich-Alexander University ErlangenNürnberg (FAU) and the research group Geometry and Physics of Spatial Random Systems under grant nos. 14 rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 determinant of the deformation behaviour and that the resulting deformation modes are robust to changes of the microscopic physics. One may then expect that the deformation modes of the framework are similar to those of a linear-elastic realization of the same structure (without freely jointed hinges, and with edges replaced by linear-elastic beams). The analysis by Mitschke et al. [38] of Poisson’s ratio for the TS wheel structure appears to conform to that expectation; for both a realization of this structure as a linear-elastic cellular solid by selective ion beam melting (ν ≈ −0.75) and for the bar-and-joint framework (ν = −1), negative Poisson ratios of similar magnitude were found. Note also the relationship given by Blumenfeld & Edwards [55] between local structural objects (so-called auxetons) and global auxetic deformations. Knowledge of the symmetry-constrained deformation modes, presented here for both infinitesimal and for finite strains, may be useful structural data for the development of rigidity criteria for periodic structures [32], similar to the celebrated Maxwell counting rule for an isostaticity condition [31]. Furthermore, the auxetic framework configurations identified here can be usefully applied for topological optimization algorithms that optimize a given property (here e.g. Poisson’s ratio) under given constraints [57]. The analysis described here specifically addresses planar and symmetric structures. It is however of relevance to two obvious generalizations, namely to planar disordered structures and to three-dimensional symmetric structures. Auxetic behaviour of disordered planar structures has been discussed theoretically by Blumenfeld & Edwards [55], and has also been observed experimentally, at least locally, by Franke & Magerle [11] in elastomeric polypropylene films. Franke & Magerle [11] have identified the mechanism that leads to the locally auxetic behaviour in these semi-crystalline films as an angular constraint between crystalline lamellae that, in a rough approximation, correspond to load-bearing bars of a bar-and-joint framework (but are, however, not of fixed length). The fixed angles between lamellae can be loosely interpreted as a local symmetry constraint, hence relating to the work presented in this article. The generalization to three-dimensional tessellations and networks is numerically straightforward (in particular, the complexity is polynomial in the number of joint coordinates and constraining equations). Our systematic approach of finding auxetic mechanisms by searching existing structure archives has proved fruitful in two dimensions. The identification of a large number of inherently three-dimensional auxetic mechanisms, without planar equivalent, is in our opinion more likely to be achieved by a systematic search of the large number of spatial tessellation and network structures than by conceptual generalization of planar models. Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 15 .................................................. rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 7. Yeganeh-Haeri A, Weidner D, Parise J. 1992 Elasticity of α-cristobalite: a silicon dioxide with a negative Poisson’s ratio. Science 257, 650–652. (doi:10.1126/science.257.5070.650) 8. Milstein F, Huang K. 1979 Existence of a negative Poisson ratio in FCC crystals. Phys. Rev. B 19, 2030–2033. (doi:10.1103/PhysRevB.19.2030) 9. Baughman R, Shacklette J, Zakhidov A, Stafström S. 1998 Negative Poisson’s ratio as a common feature of cubic metals. Nature 392, 362–365. (doi:10.1038/32842) 10. Bowick M, Cacciuto A, Thorleifsson G, Travesset A. 2001 Universal negative Poisson ratio of self-avoiding fixed-connectivity membranes. Phys. Rev. Lett. 87, 148103. (doi:10.1103/ PhysRevLett.87.148103) 11. Franke M, Magerle R. 2011 Locally auxetic behavior of elastomeric polypropylene on the 100 nm length scale. ACS Nano 5, 4886–4891. (doi:10.1021/nn200957g) 12. Janmey P, McCormick M, Rammensee S, Leight J, Georges P, MacKintosh F. 2007 Negative normal stress in semiflexible biopolymer gels. Nat. Mater. 6, 48–51. (doi:10.1038/nmat1810) 13. Kabla AJ, Senden TJ. 2009 Dilatancy in slow granular flows. Phys. Rev. Lett. 102, 228301. (doi:10.1103/PhysRevLett.102.228301) 14. Evans K, Alderson A. 2000 Auxetic materials: functional materials and structures from lateral thinking! Adv. Mater. 12, 617–681. (doi:10.1002/(SICI)1521-4095(200005)12:9<617::AIDADMA617>3.0.CO;2-3) 15. Alderson A, Rasburn J, Ameer-Beg S, Mullarkey P, Perrie W, Evans K. 2000 An auxetic filter: a tuneable filter displaying enhanced size selectivity or defouling properties. Ind. Eng. Chem. Res. 39, 654–665. (doi:10.1021/ie990572w) 16. Baughman R. 2003 Avoiding the shrink. Nature 425, 667. (doi:10.1038/425667a) 17. Sparavigna A. 2007 Phonons in conventional and auxetic honeycomb lattices. Phys. Rev. B 76, 134302. (doi:10.1103/PhysRevB.76.134302) 18. Ruzzene M, Scarpa F. 2005 Directional and band-gap behavior of periodic auxetic lattices. Phys. Status Solidi B 242, 665–680. (doi:10.1002/pssb.200460385) 19. Koenders MAC. 2009 Wave propagation through elastic granular and granular auxetic materials. Phys. Status Solidi B 246, 2083–2088. (doi:10.1002/pssb.200982039) 20. Greaves GN, Greer AL, Lakes RS, Rouxel T. 2011 Poisson’s ratio and modern materials. Nat. Mater. 10, 823–837. (doi:10.1038/nmat3134) 21. Grima J, Farrugia P, Caruana C, Gatt R, Attard D. 2008 Auxetic behaviour from stretching connected squares. J. Mater. Sci. 43, 5962–5971. (doi:10.1007/s10853-008-2765-0) 22. Grünbaum B, Shephard G. 1987 Tilings and patterns. New York, NY: W.H. Freeman. 23. Cox DA, Little JB, O’Shea D. 1992 Ideals, varieties, and algorithms. New York, NY: Springer. 24. Graver J. 2001 Counting on frameworks: mathematics to aid the design of rigid structures. Dolciani Mathematical Expositions. Washington, DC: Mathematical Association of America. 25. Borcea CS, Streinu I. 2010 Periodic frameworks and flexibility. Proc. R. Soc. A 466, 2633–2649. (doi:10.1098/rspa.2009.0676) 26. Wondratschek H, Müller U. (eds) 2006 International tables for crystallography volume A1: symmetry relations between space groups. Chester, UK: International Union of Crystallography. (doi:10.1107/97809553602060000101) 27. Mitschke H. 2009 Deformations of skeletal structures. Diplomarbeit, Universität ErlangenNürnberg. See http://theorie1.physik.fau.de/research/theses/2009-dipl-hmitschke.html. 28. Norris AN. 2006 Poisson’s ratio in cubic materials. Proc. R. Soc. A 462, 3385–3405. (doi:10.1098/rspa.2006.1726) 29. Thorpe MF, Duxbury PM. (eds) 1999 Rigidity theory and applications. New York, NY: Kluwer Academic Publishers. 30. Laman G. 1970 On graphs and rigidity of plane skeletal structures. J. Eng. Math. 4, 331–340. (doi:10.1007/BF01534980) 31. Maxwell JC. 1864 On the calculation of the equilibrium and stiffness of frames. Philos. Mag. J. Sci. 27, 294–299. 32. Guest S, Hutchinson J. 2003 On the determinacy of repetitive structures. J. Mech. Phys. Solids 51, 383–391. (doi:10.1016/S0022-5096(02)00107-2) 33. Milton GW. In press. Complete characterization of the macroscopic deformations of periodic unimode metamaterials of rigid bars and pivots. J. Mech. Phys. Solids. (doi:10.1016/ j.jmps.2012.08.011) 34. Sahimi M, Arbabi S. 1993 Mechanics of disordered solids. II. Percolation on elastic networks with bond-bending forces. Phys. Rev. B 47, 703–712. (doi:10.1103/PhysRevB.47.703) Downloaded from http://rspa.royalsocietypublishing.org/ on June 14, 2017 16 .................................................. rspa.royalsocietypublishing.org Proc R Soc A 469: 20120465 35. Kirkwood JG. 1939 The skeletal modes of vibration of long chain molecules. J. Chem. Phys. 7, 506–509. (doi:10.1063/1.1750479) 36. Keating PN. 1966 Effect of invariance requirements on the elastic strain energy of crystals with application to the diamond structure. Phys. Rev. 145, 637–645. (doi:10.1103/PhysRev.145.637) 37. Press W, Teukolsky S, Vetterling W, Flannery B. 2007 Numerical recipes: the art of scientific computing, 3rd edn. Cambridge, UK: Cambridge University Press. 38. Mitschke H, Schwerdtfeger J, Schury F, Stingl M, Körner C, Singer RF, Robins V, Mecke K, Schröder-Turk GE. 2011 Finding auxetic frameworks in periodic tessellations. Adv. Mater. 23, 2669–2674. (doi:10.1002/adma.201100268) 39. Lakes R. 1991 Deformation mechanisms in negative Poisson’s ratio materials: structural aspects. J. Mater. Sci. 26, 2287–2292. (doi:10.1007/BF01130170) 40. Prall D, Lakes R. 1997 Properties of a chiral honeycomb with a Poisson’s ratio of −1. Int. J. Mech. Sci. 39, 305–314. (doi:10.1016/S0020-7403(96)00025-2) 41. Milton GW. 1992 Composite materials with Poisson’s ratios close to −1. J. Mech. Phys. Solids 40, 1105–1137. (doi:10.1016/0022-5096(92)90063-8) 42. Grima JN, Evans KE. 2000 Self expanding molecular networks. Chem. Commun. 2000, 1531– 1532. (doi:10.1039/b004305m) 43. Kapko V, Treacy MMJ, Thorpe MF, Guest SD. 2009 On the collapse of locally isostatic networks. Proc. R. Soc. A 465, 3517–3530. (doi:10.1098/rspa.2009.0307) 44. Hutchinson R, Fleck N. 2006 The structural performance of the periodic truss. J. Mech. Phys. Solids 54, 756–782. (doi:10.1016/j.jmps.2005.10.008) 45. Sun K, Souslov A, Mao X, Lubensky TC. 2011 Isostaticity, auxetic response, surface modes, and conformal invariance in twisted kagome lattices. Proc. Natl Acad. Sci. USA 109, 12 369– 12 374. (doi:10.1073/pnas.1119941109) 46. Grima JN, Chetcuti E, Manicaro E, Attard D, Camilleri M, Gatt R, Evans KE. 2012 On the auxetic properties of generic rotating rigid triangles. Proc. R. Soc. A 468, 810–830. (doi:10.1098/rspa.2011.0273) 47. Schwerdtfeger J, Heinl P, Singer R, Körner C. 2010 Auxetic cellular structures through selective electron-beam melting. Phys. Stat. Sol. B 247, 269–272. (doi:10.1002/pssb.200945513) 48. Ashby MF. 2006 The properties of foams and lattices. Phil. Trans. R. Soc. A 364, 15–30. (doi:10.1098/rsta.2005.1678) 49. Deshpande VS, Ashby MF, Fleck NA. 2001 Foam topology: bending versus stretching dominated architectures. Acta Mater. 49, 1035–1040. (doi:10.1016/S1359-6454(00)00379-7) 50. Gibson LJ, Ashby MF. 1997 Cellular solids: structure and properties. Cambridge, UK: Cambridge University Press. 51. Wicks N, Guest S. 2004 Single member actuation in large repetitive truss structures. Int. J. Solids Struct. 41, 965–978. (doi:10.1016/j.ijsolstr.2003.09.029) 52. Larsen U, Signund O, Bouwsta S. 1997 Design and fabrication of compliant micromechanisms and structures with negative Poisson’s ratio. J. Microelectromech. Syst. 6, 99–106. (doi:10.1109/ 84.585787) 53. Kolpakov A. 1985 Determination of the average characteristics of elastic frameworks. J. Appl. Math. Mech. 49, 739–745. (doi:10.1016/0021-8928(85)90011-5) 54. Almgren RF. 1985 An isotropic three-dimensional structure with Poisson’s ratio = −1. J. Elasticity 15, 427–430. (doi:10.1007/BF00042531) 55. Blumenfeld R, Edwards S. 2012 Theory of strains in auxetic materials. J. Supercond. Nov. Magn. 25, 565–571. (doi:10.1007/s10948-012-1464-x) 56. Blumenfeld R. 2005 Auxetic strains: insight from iso-auxetic materials. Mol. Simul. 31, 867–871. (doi:10.1080/08927020500295044) 57. Schwerdtfeger J, Wein F, Leugering G, Singer RF, Körner C, Stingl M, Schury F. 2011 Design of auxetic structures via mathematical optimization. Adv. Mater. 23, 2650–2654. (doi:10.1002/ adma.201004090)
© Copyright 2026 Paperzz