Chemistry Practice Problems Compounds: Nomenclature of Ionic Compounds Solutions: 1. Provide the missing name or formula for each ionic compound. a. TiCl4 titanium(IV) chloride The charge on titanium is 4+ and it is a transition metal so the Roman numeral must be included in the name to represent the charge on the metal. The end of chlorine is changed to –ide because it is a monatomic ion. b. magnesium nitrate Mg(NO3)2 Magnesium has 2+ charge while nitrate has a 1− charge so one Mg2+ ion will combine with two NO3− ions to form a neutral compound with the name magnesium nitrate. c. potassium carbonate K2CO3 Potassium has a 1+ charge while carbonate has a 2− charge so two K+ ions combine with one CO32− ion to form a neutral compound. d. ammonium nitrite NH4NO2 Ammonium has a 1+ charge and nitrite has a 1− charge so one of each ion will combine to form a neutral compound. e. AgNO3 silver nitrate There is no Roman numeral because silver, a transition metal, only has one possible charge. The anion is a polyatomic ion so the end of the name is not changed. f. ZnCl2 zinc chloride There is no Roman numeral because zinc only has one possible charge. Chlorine forms a monatomic ion so the ending of the name is changed to –ide. g. Fe2O3 iron(III) oxide Iron is a transition metal so the Roman numeral should be included in the name to represent the charge on the iron. Its charge is 3+ which is determined from looking at the three oxygen atoms which each have a 2− charge. Oxygen forms a monatomic ion so the end of the name is changed to –ide. Chemistry Practice Problems h. FeO iron(II) oxide In FeO, iron has a 2+ charge because there is only one of each atom and oxygen has a 2− charge. It is a transition metal so the Roman numeral should be included in the name to represent the charge on the iron. i. MnO2 manganese(IV) oxide Manganese has a charge of 4+ which is determined by looking at the two oxygen atoms which each have a charge of 2−. Oxygen forms a monatomic ion so the end of the name is changed to –ide. j. strontium phosphate Sr3(PO4)2 Strontium ion has a 2+ charge and phosphate has a 3− charge so three Sr3+ ions and two PO43− ions are combined to form a neutral compound. Parentheses are included around the phosphate ion because there are two of the ions in the formula. The subscript belongs to the ion not to just one atom in the ion. k. copper(I) oxide Cu2O The Roman numeral shows the charge on the copper ion is +1 while oxide has a 2− charge. Two Cu+ ions combine with one O2− ion to form a neutral compound. l. copper(II) nitride Cu3N2 The Roman numeral shows the charge on the copper ion is +2 while nitride has a 3− charge so two Cu2+ ions combine with two N3− ions to form a neutral compound. m. aluminum phosphate AlPO4 Aluminum has a 3+ charge and phosphate is a polyatomic ion with a 3− charge so one of each ion combine to form a neutral compound. n. iron(II) carbonate FeCO3 Iron has a 2+ charge indicated by the Roman numeral. Since carbonate has a 2− charge, one of each ion combine to form a neutral compound. o. barium bromide BaBr2 Barium ion has a 2+ charge and bromide has a 1− charge so one Ba2+ ion and two Br− ions combine to form a neutral compound. Chemistry Practice Problems p. LiOH lithium hydroxide Lithium has a 1+ charge and hydroxide has a 1− charge so one of each ion combine to form a neutral compound. q. MgSO4 magnesium sulfate The name of the metal atom is unchanged in ionic compounds and sulfate is a polyatomic ion so it is included in the name without any changes. A Roman numeral is not needed because magnesium is an alkaline earth metal with only one possible charge. r. scandium chloride ScCl3 Scandium only has one possible charge so no Roman numeral is included in the name. Chlorine forms a monatomic ion so the ending is changed to –ide.
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