Name
MW
bp °C/mm (mp)
nD20
D420
ANTIMONY
Atomic number
Crystal form
51
Sb
Oxidation states
Rhombohedral
Atomic weight
0, ±3, 5
Electrical resistivity (20˚C)
121.760
Electronegativity, Pauling
41.7 μΩ·cm
CAS number
2.05
Enthalpy of melting
74410-36-0
Specific heat (25˚C)
19.62 kJ/mol
Boiling point
0.049 cal/g K
Enthalpy of vaporization
1,950˚C
Thermal conductivity (25˚)
193.43 kJ/mol
Melting point
Ionization potential
(spectral)
630.74˚C
Specific gravity (20˚C)
6.691
(aqueous)
24.4 W/(m K)
8.641 eV (l)
16.53 eV (ll)
-0.639 V (+3)
COMPOUNDS
劇物
CXAN010
ANTIMONY ACETATE
C3H9O6Sb
O
+3
H3C C O Sb
3
298.88
Soluble: ethylene glycol
1.22
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[6923-52-0]
TSCA
EC 230-043-2
¥8,500
2kg ¥45,500
341.10
133-5 / 0.4
Flashpoint: 68°C (154°F)
Soluble: benzene, butanol, THF
Employed in conductive (static dissipation) coatings for optics and lighting
1
Component in conductive coatings.
Catalyst for polyesters.2
Employed in high voltage breakdown ZnO varistors.3
1. Yamada, K. Chem. Abstr. 111, 88785d; Jap. Patent 63 310 970, 1988.
2. Otton, J. et al. J. Polym. Sci., Part A, Polym. Chem . 1989, 27 , 3535; 1988, 26 , 2199.
3. Westin, G. et al. J. Mater. Chem . 1994, 4, 615.
1.264
AKA090
劇物
ANTIMONY(III) n-BUTOXIDE
C12H27O3Sb
nC4H 9O
(126-131)
OnC 4H 9
Sb
OnC 4H 9
HMIS: 3-1-1-X
100g
（既）2-2952
25
1.4781
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[2155-74-0]
C2H 5O
TSCA
EC 218-456-6
25g ¥21,500 100g ¥59,750
HMIS: 3-2-1-X
AKA100
劇物
ANTIMONY(III) ETHOXIDE
C6H15O3Sb
F&F: Vol. 17, p 204.
OC 2H 5
Sb
OnC 2H 5
256.93
71-3 / 0.5
1.524
1.4945
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[10433-06-4]
EC 233-914-5
2.5g ¥12,500
HMIS: 3-1-1-X
10g ¥30,500
CXAN052
H 2C
劇物
METHACRYLOXYDIPHENYLANTIMONY, 96%
C16H15O2Sb
361.03
Soluble: THF, acetone
Forms homopolymer, copolymers with styrene, methyl methacrylate using AIBN.1
1. Koton, M. Dokl. Akad. Nauk SSSR . 1968, 13 7, 1368.
O
C C O Sb
CH3
(112-4)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
HMIS: 3-2-1-X
[5613-66-1]
store <5°C
10g ¥22,500
OMAN071
劇物
p-(OCTYLOXYPHENYL)PHENYLIODONIUM 645.07
HEXAFLUOROANTIMONATE
C20H26F6IOSb
Off-white solid
Soluble; acetone, methanol, toluene
UV initiator for cationic polymerizations, e.g. cycloaliphatic epoxides
CH3(CH 2)6CH2O
-
+
I SbF 6
(57-8)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[121239-74-5]
TSCA
HMIS: 3-1-1-X
25g ¥24,000 100g ¥67,800
OMAN076
+
-+
SbF 6 S
-
S SbF 6
S
S
+
-
S SbF 6
劇物
(THIOPHENOXYPHENYL)DIPHENYLSULFONIUM 607.28/1028.28
1.40
HEXAFLUOROANTIMONATE-BIS(BIS(DIPHENYLSULFONIUM)DIPHENYLTHIOETHER HEXAFLUOROANTIMONATE BLEND
50% in propylene carbonate
C24H19F6S2Sb
Amber liquid
Flashpoint: 145°C (293°F)
UV initiator for cationic polymerizations, e.g. cycloaliphatic epoxides
1
UV sensitizer for poly(t-butoxycarbonyloxystyrene) chemically amplified photoresist.
1. Hinsberg, W. J. Vac. Sci. Technol., B 1998, 16 , 3689.
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[71449-78-0]/[89452-37-9] TSCA
HMIS: 3-1-1-X
アヅマックス株式会社
TEL 03-5543-1630
03 5543 1630
FAX 03
03-5543-0312
5543 0312
sales@azmax
[email protected]
co jp
Name
劇物
OMAN078
TRIPHENYLANTIMONY
C18H15Sb
Soluble: toluene, ether, chloroform
D420
nD20
（既）3-3436
353.07
190 / 1
(53-4)
TOXICITY: oral rat, LD50: 183 mg/kg
ΔHvap: 19.88 kcal/mole
Dipole moment: ~0.7
1.4343
COMMERCIAL
Sb
bp °C/mm (mp)
MW
Image stabilizer and fog inhibitor in photosensitive films
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[603-36-1]
TSCA
EC 210-037-6
HMIS: 2-1-0-X
25g
¥9,300 100g ¥20,000
2kg inquire
OMAN079
SbCl2
3
劇物
TRIPHENYLANTIMONY DICHLORIDE
C18H15Cl2Sb
Soluble: toluene, carbon disulfide
423.97
(143-5)
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[594-31-0]
TSCA
EC 209-834-1
5g ¥14,500
HMIS: 3-2-1-X
OMAN080
(CH 3)2N
N(CH 3)2
Sb
N(CH 3)2
劇物
TRIS(DIMETHYLAMINO)ANTIMONY
253.98
C6H18N3Sb
Vapor pressure, 30˚: 0.5 mm
Alkylated by aluminum alkyls and Grignards to form R3Sb.1
1. Thomas, C. et al. Polyhedron 1993, 12 , 89.
50-2 / 0.5
1.325
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[7289-92-1]
HMIS: 3-3-1-X
10g ¥34,500
SIT8717.7
OSi(CH 3)3
(CH 3)3SiO
Sb
OSi(CH 3)3
劇物
TRIS(TRIMETHYLSILOXY)ANTIMONY
389.32
80 / 3
1.1448
ANTIMONY TRIMETHYLSILOXIDE
C9H27O3SbSi3
Forms static-charge conductive coatings
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[194033-87-9]
HMIS: 3-2-1-X
シリコンカタログ参照
DOUBLE METAL AND POLYMERIC ALKOXIDES
PAN-040
劇物
(303.55)n
Poly(ANTIMONY ETHYLENE GLYCOXIDE)
[C6H12O6Sb2]n
Catalyst for transesterification
Antimony catalysts are utilized for
Catalyst for high clarity polyesters in combination with H3PO4/Co(OAc)2.1
the production of PET plastic used
1. Collander, D. et al. Eur. Patent 61414, 1982.
in the packaging of mineral water
and soft drinks
Solid
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[29736-75-2]
TSCA
EC 249-820-2
HMIS: 3-1-1-X
25g
¥9,000 100g ¥19,000
アヅマックス株式会社
TEL 03-5543-1630
FAX 03-5543-0312
sales@azmax
[email protected]
co jp
1.4374