Geochronology: Science of determining within a specified uncertainty the absolute age of a geological process • Provides the temporal framework for geological interpretations • Major ore forming systems related to specific temporally brief events during a favourable period in earth evolution (metallogenic epoch) • Erects a stratigraphy in complex and polydeformed unfossiliferous rocks • Key in placing mineralization within geodyamic context • Provides a vector to mineralization – if age of host rock, deposit or other datable event known (e.g. fluid flow), then this signature can be searched for • Reduces exploration risk “Greenland U-Pb” c. 300 documents = conservative estimate of c. 150,000 analyses With 10 – 20 new papers per year HUGE RESOURCE! 1968 1993 2013 Australia UK Geochronology database – why Different nomenclatures for (essentially) the same Different formats 238U/206Pb ± % error (2 sigma) 206Pb/238U ± abs. error (1 sigma) Migmitization vs. High grade metamorphism Inheritance vs. Xenocryst interpretation Missing information e.g. no sample location information Geographic coordinates non-standard Captured Extracted from Source Geochronology database – why Interpretation and presentation of data in useful formats by transforming raw data into information. • Distribution of data and information to the right people at the right time. • Data preservation. Different formats Reduced accessibility of data Different nomenclatures for the same interpretation Requiring a specialist for rudimentary interpretation Missing information Lack of use of geochronology to address questions (it maybe uniquely placed to answer) Geochronology database – why Interpretation and presentation of data in useful formats by transforming raw data into information. • Distribution of data and information to the right people at the right time. • Data preservation. Different formats Consistent format Different nomenclatures for Consistent nomenclature to enable ease of searching the same interpretation Missing information Base level of information consistently populated Geochronology database – why Systematic collation and assessment of geochronological data best achieved by means of a database which holds information within a structured and consistent framework Permits querying to extract relevant data and minimises difficulty in cross comparison of age information. Collate information scattered widely across published sources making this information vastly more accessible. Geochronology database – how Lookup tables: essential function of helping maintain data integrity by enforcing consistent nomenclature Rock Type Lithology Terrane Formation Mineral Technique U-Pb geochronology table Sample GUID (globally unique identifier) totally unique ID number impossible to replicate. ф Location (lat, long, DMS) location capture method Reference Ages Statistics Uncertainty MSWD Interpretation Approach Geochronology database – how Geographic and reference information Geochronology database – how Geological information, including a limited rock type list to enable ease of searching Geochronology database – how Mineral and the technique Geochronology database – how Pooled ages (e.g. the mean age from several analyses). Used to defined the ages of geological events. Geochronology database – how Every analysis on a single spot level is assigned an interpretation S = detrital I = magmatic M = metamorphic X = inherited D = rejected Geochronology database – where are we at? 500 U-Pb samples (70 publications) 10,000 individual analyses (each coded for interpretation) X (inherited) 4% D (rejected) 2% M (metamorphic) 17 % I (igneous) 32 % S (detrital) 45 % Geochronology database – where are we at? 500 U-Pb samples (70 publications) 10,000 individual analyses (each coded for interpretation) Baddeleyite Other Monazite Titanite Zircon Geochronology database – where are we at? Total 500 U-Pb samples (70 publications) 10,000 individual analyses (each coded for interpretation) (blank) MS (single fragment/grain) Electron microprobe ICPMS ICP MS (few fragments/grains) Other Count of Technique (few fragments/grains) IonSIMS microprobe (other than SHRIMP) (other than SHRIMP) TIMS s/grains) (multi fragments) Laser SIMS (SHRIMP) Laser ablation ICP MS Technique Electron microprobe ICP MS (few fragments/g Ion microprobe (other tha Laser ablation ICP MS SHRIMP TIMS (few fragments/grai TIMS (single fragment/gra (blank) Geochronology database – where are we at? What is this going to allow Magmatic Zircon Detrital Zircon Age (Ma) Oldest grain within analytical uncertainty of concordia 3970 Ma Geochronology database – what can we do with it? Help refine stratigraphy. Place direct temporal constraint on mineralization and fluid flow. Orogenic paleofluid flow recorded by discordant detrital zircons in the Caledonian foreland basin of northern Greenland C B A D Caledonian Orogenic Front The Neoproterozoic to Paleozoic evolution of northern Greenland records the development of a continental margin after Rodinia breakup. The sedimentary succession consists of Cambrian to Silurian deep-water slope and trough megasequences formed by major turbidite systems. Orogenic paleofluid flow recorded by discordant detrital zircons in the Caledonian foreland basin of northern Greenland • • • • Oscillatory zoned magmatic Homogeneous metamorphic Altered and strongly discordant Altered but concordant D C B A Orogenic paleofluid flow recorded by discordant detrital zircons in the Caledonian foreland basin of northern Greenland 18 16 0.38 14 12 Number 3600 Pb 8 6 0.26 4 3200 2 0.22 0 2400 2800 0.18 2600 2800 3000 3200 3400 3600 3800 A single time of Pb loss Age (Ma) Recent 2400 0.14 2000 0.10 0.5 1.5 2.5 3.5 238 206 U/ 4.5 5.5 Pb 18 16 14 Relative probability 12 Number 206 Pb/ 10 Discordant population derived from a similar geological province with similar zircon age structure to the concordant zircon population. 0.30 207 Relative probability Assumptions: 0.34 10 8 6 4 2 0 2300 2500 2700 2900 3100 Age (Ma) 3300 3500 3700 3900 Model the age of the discordant population, assuming Pb loss at different times, and statistically compare the model age spectra to that of the concordant population. Orogenic paleofluid flow recorded by discordant detrital zircons in the Caledonian foreland basin of northern Greenland Concordant Probability 380 Ma Age of Pb loss (Ma) Discordant: upper intercept Modelled Pb loss at 380 Ma Age (Ma) Statistically closest similarity between concordant and discordant populations is observed at ca. 380–390 Ma Geochronology database – what can we do with it? Answer some fundamental geochronology questions. Change in chronometric power – e.g. when one isotopic ratio is better to use over the other 500 450 238U/206Pb* age error 207Pb*/206Pb* age error Linear (207Pb*/206Pb* age error) Linear (238U/206Pb* age error) 400 Error Age Error (Ma) 350 1600-1700 Ma 300 250 200 150 100 50 0 0 500 1000 1500 2000 Age (Ma) Age (Ma) 2500 3000 3500 4000 Geochronology database A convenient source of Earth history data, normalized to a consistent standard - including expert opinion. A resource for understanding the geological history of Greenland. Able to address questions on: stratigraphy, age of rocks, deposits, thermal and fluid events (to mention just a few uses!) A work in progress! “Front end” set to be developed shortly to allow graphic querying and display of data How do we get the information? Comparison of U-Th-Pb techniques EMPA: 4 analyses per hour $25 per analysis >2% accuracy No loss of sample; high spatial resolution SIMS: 4 analyses per hour $25 per analysis 10-35 micron spot; 1 micron depth c. 1 % accuracy Excellent spatial resolution ID-TIMS: 1 analysis per hour (plus a lot of lab work!) $100-$300 per analysis 0.1-0.3% accuracy from crystal (or fragments) Best precision and accuracy LA-ICPMS: 40 analyses per hour $4-$8 per analysis 5-50 micron spot; 10 micron depth 1-2% accuracy Highest efficiency Geochronology database – where are we at? Pangea Superia/Sciavia Rodinia Gondwana Columbia Geochronology database – where are we at? 3225-2900 Ma: Akia terrane gneisses (west Greenland) c. 3800 - 3600 Ma: oldest gneissses in the Nuuk region Geochronology database – where are we at? c. 2800-2500 Ma: Archean gneisses (North Atlantic Craton & Rae Craton) 2900 - 2800 Ma: Mesoarchean granites and gneisses in west Greenland Geochronology database – where are we at? c. 1950 - 1840 Ma Paleoproterozoic orogenesis (Rae Craton & Nagssugtoqidian Orogen) c. 1900-1700 Ma: Ketilidian Orogeny c. 1700-1600 Ma: Independence Fjord Group Geochronology database – where are we at? c. 61-55 Ma: Paleogene basaltic magmatic province - central west and east Greenland c. 450-400 Ma Caledonian uplift and magmatism c. 950-900 Ma Caledonian granites
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