KEY Last Name ____________________________ First Name _______________ Lab Sec. # ____; TA: _____________________; Lab day/time: ___________ thelifecurve.com Dr. Toupadakis Circle one Fall 2010 CHEMISTRY 2C Section A FINAL EXAM Instructions: CLOSED BOOK EXAM! No books, notes, or additional scrap paper are permitted. All information required is contained on the exam. Place all work in the space provided. If you require additional space, use the back of the exam. A scientific calculator may be used (if it is a programmable calculator, its memory must be cleared before the exam). This exam has 19 pages total. (1) Read each question carefully. 01. a b c d e 02. a b c d e 03. a b c d e 04. a b c d e 05. a b c d e 06. a b c d e 07. a b c d e 08. a b c d e 09. a b c d e 10. a b c d e 11. a b c d e (2) For Part I, II and III there is no partial credit. There is 12. a b c d e 13. a b c d e (3) partial credit for part IV. The last three pages contain a periodic table and some useful information. You may remove them for easy access. 14. a b c d e (4) If you finish early, RECHECK YOUR ANSWERS! 15. a b c d e 16. a b c d e 17. a b c d e 18. a b c d e 19. a b c d e 20. a b c d e 21. a b c d e 22. a b c d e 23. a b c d e 24. a b c d e 25. a b c d e 26. a b c d e 27. a b c d e 28. a b c d e 29. a b c d e U.C. Davis is an Honor Institution Possible Points # # # # # # # # # # # 01–25 26-29 30 31 32 33 34 35 36 37 38 Total (2 points each) (6 points each) (10 points total) (06 points total) (10 points total) (10 points total) (08 points total) (10 points total) (10 points total) (12 points total) (14 points total) Score (164) Earned Points / 50 / 24 / 10 / 06 / 10 / 10 / 08 / 10 / 10 / 12 / 14 /164 or % Toupadakis F2010 Final Exam page Part I: Concepts (2 points each) No partial credit is available 1. The reaction: Cl2 + CH2 =CH2 ClCH2 CH2 Cl is an example of: (a) a polymerization reaction (b) a substitution reaction (c) an elimination reaction (d) an isomerization reaction (e) an addition reaction 2. A nucleus is held together by (a) an electric force (b) a gravitational force (c) a nuclear force (d) a magnetic force (e) none of the above 3. P2O5 reacts with water. The product is: (a) P4 (b) H5P3O10 (c) H3PO2 (d) H3PO3 (e) H3PO4 4. If ∆ stands for the crystal field splitting and P for the electron pairing energy, how many unpaired electrons does a d5 octahedral complex have if ∆ > P? (a) 5 (b) 1 (c) 2 (d) 3 (e) 4 5. The hybridization of the carbon atom marked with the asterisk (*) and the total # of and (a) (b) (c) (d) (e) 6. bonds for the structure below will be: sp2 5 +3 sp 11 + 3 sp2 11 + 3 2 sp 2 +3 sp 10 + 3 O C * What is the coordination number and oxidation number of the metal ion in Pd(en)Cl2? (a) CN = 3, ON = +2 (b) CN = 3, ON = +4 (c) CN = 3, ON = +2 (d) CN = 4, ON = 0 (e) CN = 4, ON = +2 Your Name 2 Toupadakis F2010 Final Exam page 3 7. What is the correct IUPAC name for [Co(NH3)5Br]SO4 ? (a) Bromopentaamminecobalt(III) sulfate (b) Pentaamminebromocobalt(II) sulfate (c) Pentaamminebromocobalt(III) sulfide (d) Pentaamminebromocobalt(III) sulfate (e) Pentaamminebromocobaltate(III) sulfate 8. As the atomic number of an element INCREASES, the ratio of neutrons to protons in stable nuclei (a) does not relate to stability. (b) increases. (c) stays the same. (d) decreases. (e) none of the above. 9. Choose the CORRECT statement: (a) Mass defect of a nucleus is the gain in mass that occurs when isolated protons and neutrons combine to form the nucleus. (b) Binding energy of a nucleus is the mass defect converted into energy that is gained during the nuclear reaction. (c) Binding energy of a nucleus is the mass of the nucleus converted to energy. (d) Mass defect of a nucleus is the loss in mass that occurs when isolated protons and neutrons combine to form the nucleus. (e) None of the above 10. Identify the species X in the following nuclear equation: 2 11H 2X (a) proton (b) neutron (c) “ ” particle (d) electron (e) none of the above 11. What is the IUPAC name for the compound? (a) (b) (c) (d) (e) Your Name 4,5-dimethylhexane 2-isopropylpentane 2-methyl-3-propylbutane 2,3,4,5,6-pentamethylheptane Octane 4 2 He Toupadakis F2010 Final Exam page 12. Choose the INCORRECT statement: (a) Both, lighter and heavier elements are less stable than midweight elements near iron-56. (b) In nuclear fission heavy elements gain stability and release energy by fragmenting to yield midweight elements. (c) In nuclear fusion light elements gain stability and release energy by fusing together. (d) In a supercritical fission process, on average, less than one neutron causes another fission event. (e) None of the above 13. Hypophosphorous acid H3PO2 is a (a) monoprotic acid (b) diprotic acid (c) triprotic acid (d) strong acid (e) None of the above 14. Assume that the mechanism of a reaction has 2 steps. The CORRECT statement is: (a) There are 2 transition states. (b) There are 2 intermediates. (c) There are 3 activation energies. (d) The overall order of the reaction is 2. (e) The reaction is bimolecular. 15. In the following electrochemical cell what is the oxidizing agent and how many electrons are transferred? Zn(s) | Zn2+(aq) || Fe3+(aq), Fe2+(aq) || Pt(s) (a) (b) (c) (d) (e) 16. Zn2+, Zn, Fe3+, Fe2+, Pt, 2e 2e 2e 2e 0e Consider the chemical equation: H2O + H2O H3O+ + OHThe number of moles of electrons transferred in the reaction represented by this chemical equation is: Your Name 4 Toupadakis (a) 0 F2010 (b) 1 (c) 2 (d) 3 Final Exam page 5 (e) 4 17. Write the formula of tetraaquadichlorochromium(III) chloride. (a) Cl[Cr(H2O)4Cl2] (b) [Cr(H2O)4Cl]Cl (c) [Cr(H2O)4Cl]Cl2 (d) [Cr(H2O)4Cl2]Cl (e) [(H2O)4Cl2Cr]Cl 18. Choose the CORRECT statement: (a) the rate constant increases energy increases. (b) the rate constant increases energy decreases. (c) the rate constant increases energy decreases. (d) the rate constant increases energy increases. (e) None of the above. as the temperature increases and the activation as the temperature decreases and the activation as the temperature increases and the activation as the temperature decreases and the activation 19. Determine the number of different isomers for the complex, M(en)F2I2. When trying to determine the number of isomers, keep the (en) group in the same position in all of your drawings. M stands for the metal ion and en for ethylenediamine. (a) 4 (b) 3 (c) 2 (d) 1 (e) 5 20. From the following elements, pick the transition metal. (a) Se (b) Re (c) Rn (d) Ra (e) Al 21. The coordination compounds [Co(NO2)(NH3)5]SO4 and [Co(ONO)(NH3)5]SO4 are: (a) Ionization isomers (b) Linkage isomers (c) Geometric isomers (d) Coordination isomers (e) The same chemical compound 22. Which of the following is FALSE? (a) A fuel cell is a closed system. (b) A sacrificial anode can be used to prevent corrosion. (c) A primary cell battery cannot be recharged. (d) As a galvanic cell operates its potential for electrical work decreases. (e) None of the above. Your Name Toupadakis F2010 Final Exam page 23. Choose the CORRECT statement: (a) A zero-order reaction is a reaction with a rate constant equal to zero. (b) The higher the value of an exponent in a rate law, the less sensitive is the reaction rate to a concentration change of that component. (c) The rate constant does not depend on the presence of a catalyst. (d) Intermediates sometimes can be isolated. (e) None of the above 24. 213 Bi decays with emission of an -particle. The resulting nuclide is unstable and emits a -particle. What is the final nuclide formed? (a) 209Pb 25. 6 (b) 8He (c)3Be (d) 4Li (e) 12C In the coordination compound [M(CN)2(en)2]Br2, the charge of the metal and its coordination number, respectively are: (a) +1, 3 (b) +2, 3 (c) +2, 6 (d) +2, 4 (e) +4, 6 Your Name Toupadakis F2010 Final Exam page 7 Part II: Short Calculations (6 points each) No partial credit is available 26. A current of 2.00 A passing for 5.00 h through a molten metal chloride MClx deposits 22.2 g of the metal. If the molar mass of the metal is 118.69 g/mol, then the value of x is: (a) 1 (b) (5.00 h) 2 3600 s 2.00 C h s (22.2 g M) 1 mol M 118 .69 g M 0.373 mol e 0.187 mol M 27. (c) 3 = (d) 4 1 mol e 96500 C (e) 5 = 0.373 mol e- = 0.187 mol M 2 mol e 1 mol M = 2e 1 metal atom x=2 The activation energy of a reaction is 53 kJ/mol. Its rate doubles when the temperature increases by 10oC? What was the temperature before it was increased? (a) (b) (c) (d) (e) ln k1 k2 ln 1 2 Your Name 280 K 298 K 33 K 290 K 640 K E 1 R T2 1 T1 53000 J/mol 1 8.314 J / mol K (x 10) K 1 x K x = 298 Toupadakis 28. F2010 Final Exam page 8 Calculate the maximum kinetic energy of the beta particle emitted in the radioactive decay of 6He. Assume that the beta particle has maximum energy when no other emission is involved. Use the conversion, 1 amu = 931.5 MeV. Isotopic mass of 6He = 6.01889 amu, Isotopic mass of 6Li = 6.01512 amu. (a) 1.67 MeV (b) 5.85 MeV (c) 7.49 MeV (d) 3.51 MeV (e) 9.51 MeV Loss of mass = (mass of 6He) - (mass of 6Li) = (6.01889 amu) - (6.01512 amu) = 0.00377 amu Energy equivalent = (931.5 MeV/amu)( 0.00377 amu) = 3.51 MeV 29. The general formula of the series of compounds whose molecule contains two double bonds, one ring and an ether group is: (a) (b) (c) (d) (e) CnH2nO CnH2n+1O CnH2n+2O CnH2n-4O CnH2n-6O Saturated hydrocarbon, CnH2n+2 Two double bonds, CnH2n+2-4 or CnH2n-2 One ring, CnH2n-2-2 or CnH2n-4 One ether group, CnH2n-4O Therefore: CnH2n-4O Your Name Toupadakis F2010 Final Exam page Part III. Short Answer Fill in the blanks with the appropriate answers 30. [10 points possible--each is worth 2 pts] Identify the following molecules as chiral or achiral. Also, designate the molecule as R, S, fac, mer, cis, trans, or none of the above. Molecule Chiral (optically active) or Achiral (optically inactive)? Designation Chiral Cis Achiral NONE Achiral Fac Chiral S Achiral NONE H2 C H2 N H2C CH2 H2N NH 2 Co H2C N H2 Br Cl B A B M A B A OH H HOOC C CH3 CH3 H3C H3C Your Name C CH3 9 Toupadakis 31. F2010 Final Exam [6 points possible--each is worth 2 pts] Draw the following: trans-1,2-dibromocyclobutane Br H H Br - CO mer-tribromotricarbonylferrate(II) ion Br CO Fe Br Br CO 3-chloro-2-hexene Cl 32. [10 points possible--each is worth 2 pts] Identify the correct functional group with the molecule listed. Molecule Functional Group Ether O NH2 Amine NH 2 CHO H C Aldehyde H CH 3 O Ketone NH O Your Name Amide page 10 Toupadakis F2010 Final Exam page 11 33. (10 pts--each is worth 1 pt) Fill in the following table. Coordination number Metal d electrons 6 [Cr(H2O)4Cl2]+ 4 2+ [Cu(NH3)4] d 3 d 9 Metal oxidation number Can it be chiral? Possible geometries +3 No octahedral no Sq. Planer or Tetrahedral +2 34. (8 pts total--each is worth 2 pts) Consider the following molecule: A B C HC C O a. (2 Pts) What is the hybridization of atom A? sp b. (2 Pts) What is the hybridization of atom B? sp3 c. (2 Pts) What is the hybridization of atom C? sp2 d. (4 Pts) What type of atomic orbitals overlap to form the C=O double bond? A. -bond. C ( ? ) and O ( ? ) B. -bond C ( ? ) and O ( ? ) A. -bond. C ( sp2 ) and O ( p ) B. -bond C ( p ) and O ( p ) Your Name Toupadakis 35. F2010 Final Exam page 12 [10 points—each formula is worth 1 pt] Fill in the blanks with the appropriate chemical formula(s). Sodium oxide + H2O Sodium peroxide + H2O Potasium superoxide + H2O P4O10 + H 2O Li + H2O Na + Cl2 Your Name NaOH NaOH + H2O2 KOH + H2O2 + O2 H3PO4 LiOH + H2 NaCl Toupadakis F2010 Final Exam page 13 Part IV. Long Answer Calculations Show your work for partial credit. Put answers in the spaces provided. 36. [10 Points] Consider a reaction that is represented by the following general chemical equation: A(g) + B(g) → 2 C(g) + 3 B(g) ©AT2010F From the following data: a) b) c) d) Determine the overall reaction order (explain or show your work). Determine the value and units of the rate constant. Determine the rate of the reaction for [A] = 3.0x10-2 M and [B] = 2.0x10-3 Μ. Could this reaction be a one-step reaction? Explain. Experiment Initial [A], M Initial [B], M Initial Rate (M/s) 1 0.10 0.10 0.0050 2 0.40 0.10 0.080 3 0.10 0.20 0.0050 a) Overall reaction order is: Experiment 1 and 2 R [A]2 Experiment 1 and 3 R 0 [B] R [A]2 R = k [A]2 Therefore: Overall reaction order = 2 b) Rate constant k is: From experiment 1: R = k [A]2 0.0050 = k(0.10)2 c) Rate of reaction is: R = k [A]2 R = (0.50)( 3.0x10-2)2 d) k = 0.50 M-1s-1 Rate = 4.5x10-4 M/s No. If this reaction was a one-step reaction then its rate law expression would be: R = [A][B]. Because it is different from the experimentally determined rate law, the reaction is a multistep reaction. Your Name Toupadakis F2010 Final Exam 37. (12 pts) Consider the reaction described by the following chemical equation: page 14 ©AT2010F 2NO + Br2 2NOBr During the reaction an intermediate is detected, and the rate law determined by experiment is: Rate = k [NO]2[Br2] 1. 2. Could this reaction be a one-step reaction? Explain why. For this reaction the following mechanism has been suggested: Step 1: NO + Br2 k1 NOBr2 Fast equilibrium k-1 Step 2: k2 NOBr2 + NO 2NOBr Slow step a. Demonstrate by showing your work that this mechanism is acceptable because it satisfies the two requirements. b. Besides the fact that this mechanism satisfies the two requirements, what other additional support is there according to the data given in this problem? Explain briefly. ……………………………………………………………………………………………………………………………………………………. 1. Even though the rate law determined by experiment agrees with a one-step reaction mechanism, the detection of an intermediate drops this possibility because by definition a one-step reaction mechanism does not involve any intermediates. 2a. First requirement The sum of the steps must give the balanced equation of the reaction. Step 1: NO + Br2 k1 NOBr2 k-1 Step 2: NOBr2 + NO NO + Br2 + NOBr2 + NO 2NOBr NOBr2 + 2NOBr Overall chemical equation: 2NO + Br2 2NOBr Your Name Toupadakis F2010 Final Exam page 15 Second requirement The mechanism has to agree with the experimentally determined rate law. Overall rate = rate of slow step = rate of 2nd step = k2 [NO][NOBr2] First step is fast equilibrium Rate (forward) = Rate (reverse) k1 [NO][Br2] = k-1[NOBr2] [NOBr2] = (k1 /k-1)[NO][Br2] Overall rate = k2[NO][NOBr2] = k2[NO](k1 /k-1)[NO][Br2] = (k1 /k-1)k2[NO]2 [Br2] = k[NO]2[Br2] Where k = (k1 /k-1)k2 2b. The detection of an intermediate. 38. (14 points) Consider the reaction represented by the following chemical equation: 2Cr(s) + 3H2O(l) + 3OCl–(aq) 2Cr3+(aq) + 3Cl–(aq) + 6OH–(aq) A. Make a drawing of a cell that uses this reaction and indicate on the diagram the following: (a) (b) (c) B. Your Name (a) (b) (c) (d) The anode and the cathode. The direction in which the anions and cations migrate through the salt bridge. The direction in which the electrons migrate through the external circuit. Write the anode half reaction. Write the cathode half reaction. Calculate Eo for the cell. Write the cell notation. Toupadakis F2010 Final Exam page 16 A. B. (a) Anode half reaction Cr (s) Cr3+(aq) + 3 e- Eo = +0.74 V (b) Cathode half reaction OCl-(aq) + H2O(l) + 2e- Cl-(aq) + 2OH-(aq) (c) Eo = +0.94V Eo for the cell 2Cr (s) 2Cr3+(aq) + 6 e- Eo = +0.74 V 3OCl-(aq) + 3H2O(l) + 6e- 3Cl-(aq) + 6OH-(aq) Eo = +0.94V 2Cr(s) + 3H2O(l) + 3OCl–(aq) 2Cr3+(aq) + 3Cl–(aq) + 6OH–(aq) Eocell = (+0.74 V) + (+0.94V) = + 1.68 V (d) Cell notation Cr(s)|Cr3+(aq)|| OH–(aq), OCl–(aq), Cl–(aq), |Pt(s) Your Name Toupadakis F2010 Final Exam page 17 Potentially Useful Information: (You may remove this page for ease of access) Constants: R = 8.3145 J / mol K NA = 6.022 x 1023 1 atm = 760 torr c = 3.00 x 108 m/s R = 0.0821 L atm / mol K h = 6.626 x 10-34 J s 1 nm = 10-9 m 1 L = 1000 cm3 F = 96,485 C/ mol e1 amu = 1.6605x10-27 kg 1 g = 6.02 x 1023 amu 1 MeV = 1.6 x 10-13 J Equations: Slope = Δy/Δx G H PV nRT rate k[ A]0 rate rate T S ln G k1 k2 [ A]t ln[ A]t 1 [ A]t k[ A] 2 o Ecell 1 A 1C 1s E 1 R T2 k k[ A] Ecell ToF – 32 = 1.8 ToC TK = ToC + 273.15 G 1 T1 1 [ A]0 2 t1 2 t1 2 0.693 k 1 k[ A]0 Ecell = Eox + Ered 0.0592 log Keq at 25oC. n o nFE cell G 1 mol e where N = # of remaining atoms 620 r 96,485 C 400 430 v o b y G ln Nt = ln No – t 800 g 580 560 Your Name Ae ΔE = Δm c2 ch arg e (C) current ( A) x time (s) N k [ A]0 2k t1 kt ln[ A]0 kt RT ln K eq c h kt [ A]0 0.0592 o log Q and Ecell n Rate of decay = G RT ln Q Ea RT 490 nFE cell Toupadakis F2010 Final Exam page 18 Potentially Useful Information: (You may remove this page for ease of access) Cr2O7 Electrode Half Reaction (aq) + 14H+(aq) + 6e- 2Cr3+(aq) + 7H2O(l) 2- O2(g) + 4H+(aq) + 4e- 2 H2O(l) Pt2+(aq) + 2 e- Pt (s) - E˚/volts +1.33 +1.23 +1.20 - Br2(l) + 2e 2Br (aq) +1.09 OCl (aq) + H2O(l) + 2e Cl-(aq) + 2OH (aq) +0.94 Ag+(aq) + e– Ag(s) +0.80 I2 (s) + 2e- 2 I- (aq) +0.54 - - 2+ - – Cu (aq) + 2e Cu(s) Fe3+(aq) + 1 e- Fe2+ (aq) +0.34 Sn4+(aq) + 2e- Sn2+(aq) 2H+(aq) + 2 e- H2 (g) +0.15 Sn2+(aq) + 2 e- Sn (s) –0.14 3+ - +0.77 0.00 2+ V (aq) + e V (aq) 3+ - -0.26 2+ Cr (aq) + e Cr (aq) Fe2+(aq) + 2 e- Fe (s) -0.424 Cr3+(aq) + 3 e- Cr (s) Zn2+(aq) + 2 e- Zn (s) –0.74 Cr 2+ –0.44 –0.76 - (aq) + 2 e Cr (s) -.90 Mn2+(aq) + 2e- Mn(s) -1.18 V2+ (aq) + 2e- V (s) -1.19 3+ - Al (aq) + 3e Al (s) -1.66 Mg2+ (aq) + 2e- Mg (s) -2.36 Li+ (aq) + 1e- Li (s) -3.040 Spectrochemical Series CN- > CO > NO2- > en > NH3 > SCN- > H2O > ONO- > ox2- > OH- > F- > SCN- > Cl- > Br- > I- Visible Region of the Electromagnetic Spectrum Violet 400 nm Your Name Blue 475 Green 510 Yellow 570 Orange 590 Red 650 nm Toupadakis F2010 Final Exam page 19 Potentially Useful Information: (You may remove this page for ease of access) Periodic Table Key 1 Atomic Number Symbol Atomic Mass Electronegativity H 2 He 1.008 2.20 3 4 5 6 7 8 9 Li Be B C N O F Ne 6.941 0.98 9.012 1.57 10.81 2.04 12.01 2.55 14.01 3.04 16.00 3.44 19.00 3.98 20.18 - 11 Na Mg Al Si 14 15 16 S Cl Ar 22.99 0.93 24.31 1.31 26.98 1.61 28.09 1.90 30.97 2.19 32.06 2.58 35.45 3.16 39.95 - 19 12 21 Ti 22 23 V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 39.10 0.82 40.08 1.00 44.96 1.36 47.90 1.54 50.94 1.63 52.00 1.66 54.94 1.55 55.85 1.83 58.93 1.88 58.70 1.91 63.55 1.90 65.38 1.65 69.72 1.81 72.59 2.01 74.92 2.18 78.96 2.55 79.90 2.96 83.80 - 36 Ru Rh Pd Ag Cd In Sn Sb Te 52 53 I Xe 85.47 0.82 87.62 0.95 88.91 1.22 91.22 1.33 92.91 1.6 95.94 2.16 (98) 1.9 101.1 2.2 102.9 2.28 106.4 2.20 107.9 1.93 112.4 1.69 114.8 1.78 118.7 1.96 121.8 2.05 127.6 2.1 126.9 2.66 131.3 - Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb 82 83 Bi Po At Rn 132.9 0.79 137.3 0.89 175.0 1.27 178.5 1.3 180.9 1.5 183.9 2.36 186.2 1.9 190.2 2.2 192.2 2.20 195.1 2.28 197.0 2.54 200.6 2.00 204.4 2.04 207.2 2.33 209.0 2.02 (209) 2.0 (210) 2.2 (222) - - 87 88 103 104 105 106 107 Ra Lr Unq Unp Unh Uns (223) 0.7 (226) 0.9 (260) - - - - - 57 59 60 61 80 81 84 85 109 Une - 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb 138.9 1.10 140.1 1.12 140.9 1.13 144.2 1.14 (145) 1.13 150.4 1.17 152.0 1.2 157.3 1.20 158.9 1.2 162.5 1.22 164.9 1.23 167.3 1.24 168.9 1.25 173.0 1.1 89 Your Name 58 79 54 Cs Fr 78 51 35 Tc 77 50 34 Mo 76 49 33 Nb 75 48 32 Zr 74 47 31 Y 73 46 30 39 72 45 29 38 71 44 28 Sr 56 43 27 Rb 55 42 26 18 Sc 41 25 17 Ca 40 24 P K 37 20 13 4.003 10 Ac Th 90 Pa 91 92 U Np 93 Pu 94 Am 95 Cm 96 Bk 97 Cf 98 Es 99 Fm 100 Md 101 No 102 (227) 1.1 232.0 1.3 (231) 1.5 238.0 1.38 (237) 1.36 (244) 1.28 (243) 1.3 (247) 1.3 (247) 1.3 (251) 1.3 (252) 1.3 (257) 1.3 (258) 1.3 (259) 1.3 86
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