chem_TE_ch03_FPL.fm Page 80 Monday, August 2, 2004 1:09 PM 3.3 3.3 1 Conversion Problems FOCUS Objectives Guide for Reading 3.3.1 Construct conversion factors from equivalent measurements. 3.3.2 Apply the technique of dimensional analysis to a variety of conversion problems. 3.3.3 Solve problems by breaking the solution into steps. 3.3.4 Convert complex units, using dimensional analysis. Key Concepts • What happens when a measurement is multiplied by a conversion factor? • Why is dimensional analysis useful? • What types of problems are easily solved by using dimensional analysis? Vocabulary conversion factor dimensional analysis Reading Strategy Guide for Reading Build Vocabulary L2 Paraphrase Have students write definitions of the vocabulary terms in their own words. (Acceptable answers include conversion factor: a ratio of equivalent measurements used to convert a quantity from one unit to another, and dimensional analysis: a technique of problem-solving that uses the units that are part of a measurement to solve the problem.) Reading Strategy Monitoring Your Understanding Preview the Key Concepts, the section heads, and boldfaced terms. List three things you expect to learn. After reading, state what you learned about each item listed. If you think about any number of everyday situations, you will realize that a quantity can usually be expressed in several different ways. For example, consider the monetary amount $1. These are all expressions, or measurements, of the same amount of money. The same thing is true of scientific quantities. For example, consider a distance that measures exactly 1 meter. 1 meter 10 decimeters 100 centimeters 1000 millimeters These are different ways to express the same length. Whenever two measurements are equivalent, a ratio of the two measurements will equal 1, or unity. For example, you can divide both sides of the equation 1 m 100 cm by 1 m or by 100 cm. 1 m 100 cm 1 1m 1m L2 INSTRUCT Have students examine the photograph that opens the section. Ask if any of them has ever noticed a chart or table in a bank or in the newspaper relating the values of foreign currency to the U.S. dollar. Explain that these are conversion tables that allow people to relate one currency to another. Ask, How would you decide which amount of money would be worth more—75 euros or 75 British pounds? (Convert these values to a familiar currency—U.S. dollars.) or 100 cm 1m 100 cm 100 cm 1 conversion factors Animation 3 Learn how to select the proper conversion factor and how to use it. with ChemASAP 80 Chapter 3 Conversion Factors 1 dollar 4 quarters 10 dimes 20 nickels 100 pennies Sequence As the students read the Analyze and Calculate sections of Sample Problems 3.5–3.9, have them write word sequences using the appropriate conversion factors for each problem. 2 Perhaps you have traveled abroad or are planning to do so. If so, you know—or will soon discover— that different countries have different currencies. As a tourist, exchanging money is essential to the enjoyment of your trip. After all, you must pay for your meals, hotel, transportation, gift purchases, and tickets to exhibits and events. Because each country’s currency compares differently with the U.S. dollar, knowing how to convert currency units correctly is very important. Conversion problems are readily solved by a problem-solving approach called dimensional analysis. A conversion factor is a ratio of equivalent measurements. The ratios 100 cm/1 m and 1 m/100 cm are examples of conversion factors. In a conversion factor, the measurement in the numerator (on the top) is equivalent to the measurement in the denominator (on the bottom). The conversion factors above are read “one hundred centimeters per meter” and “one meter per hundred centimeters.” Figure 3.11 illustrates another way to look at the relationships in a conversion factor. Notice that the smaller number is part of the measurement with the larger unit. That is, a meter is physically larger than a centimeter. The larger number is part of the measurement with the smaller unit. 80 Chapter 3 Section Resources Print • Guided Reading and Study Workbook, Section 3.3 • Core Teaching Resources, Section 3.3 Review • Transparencies, T31–T37 Technology • Interactive Textbook with ChemASAP, Animation 3, Problem-Solving 3.28, 3.30, 3.33, 3.35, 3.37, Assessment 3.3 chem_TE_ch03_FPL.fm Page 81 Monday, August 2, 2004 1:09 PM 1 meter 100 centimeters 1m 1 Smaller number = 10 m 100 cm Larger number 20 30 40 50 60 Conversion Factors 70 80 90 Larger unit Smaller unit A Conversion Factor Conversion factors are useful in solving problems in which a given measurement must be expressed in some other unit of measure. When a measurement is multiplied by a conversion factor, the numerical value is generally changed, but the actual size of the quantity measured remains the same. For example, even though the numbers in the measurements 1 g and 10 dg (decigrams) differ, both measurements represent the same mass. In addition, conversion factors within a system of measurement are defined quantities or exact quantities. Therefore, they have an unlimited number of significant figures, and do not affect the rounding of a calculated answer. Here are some additional examples of pairs of conversion factors written from equivalent measurements. The relationship between grams and kilograms is 1000 g 1 kg. The conversion factors are: 1000 g 1 kg and Figure 3.11 The two parts of a conversion factor, the numerator and the denominator, are equal. and and 1 kg 1000 g 1m 109 nm 106 mL 1L Based on what you know about metric prefixes, you should be able to easily write conversion factors that relate equivalent metric quantities. Checkpoint How many significant figures does a conversion factor within a system of measurement have? Dimensional Analysis Activity L2 Purpose To use dimensional analysis to convert common units Materials copies of a recipe, lists of equivalents and conversions among the following measurements: teaspoon, tablespoon, 1/4 cup, 1/2 cup, and 1 cup (These lists are found in most cookbooks.) Procedure Distribute the recipe and the conversion list to pairs of students. Explain that the students must rewrite the recipe so that it can feed six times the number of serving sizes suggested by the recipe. Point out that it would be tedious to have to measure out a particular ingredient (pick out one) in teaspoons or tablespoons six times, so students must rewrite the recipe in appropriately larger units. After students have rewritten the recipe, have student pairs exchange and compare recipes. Expected Outcome Students should use the conversion lists to write simple conversion factors, such as 3 teaspoons/1 tablespoon, and then rewrite the recipe using larger measurements. Expanding a Recipe Common volumetric units used in chemistry include the liter and the microliter. The relationship 1 L 106 µL yields the following conversion factors. 1L 106 mL Figure 3.11 Have students inspect the figure. Emphasize that a conversion factor relates two equivalent measurements. Ask, What two parts does every measurement have? (a number and a unit) Point out that if this is so, every conversion factor must contain two numbers and two units so that one number and its unit equal another number and its unit. CLASS The scale of the micrograph in Figure 3.12 is in nanometers. Using the relationship 109 nm 1 m, you can write the following conversion factors. 109 nm 1m L1 Use Visuals Figure 3.12 In this computer image of atoms, distance is marked off in nanometers (nm). Inferring What conversion factor would you use to convert nanometers to meters? Dimensional Analysis No single method is best for solving every type of problem. Several good approaches are available, and generally one of the best is dimensional analysis. Dimensional analysis is a way to analyze and solve problems using the units, or dimensions, of the measurements. The best way to explain this problem-solving technique is to use it to solve an everyday situation. Section 3.3 Conversion Problems 81 Facts and Figures Monetary Exchange Rates The conversion of chemical units is similar to the exchange of currency. Americans who travel outside the United States must exchange U.S. dollars for foreign currency at a given rate of exchange. These exchange rates vary from day to day. The daily exchange rates affect all international monetary transactions. Each time one type of money is exchanged for another, the current exchange rate serves as a conversion factor. International currency traders keep track of exchange rates 24 hours a day through a linked computer network. Answers to... Figure 3.12 1 m/109 nm Checkpoint unlimited Scientific Measurement 81 chem_TE_ch03.fm Page 82 Wednesday, April 13, 2005 1:58 PM Section 3.3 (continued) SAMPLE PROBLEM 3.5 L2 Discuss Using Dimensional Analysis How many seconds are in a workday that lasts exactly eight hours? Explain that measurements are often made using one unit and then converted into a related unit before being used in calculations. For example, students might measure volume in liters or milliliters in the laboratory, but express it as cubic centimeters in a calculation. Explain to the students that conversions are done using conversion factors. Emphasize that these conversion factors are ratios of equivalent physical quantities, such as 1 mL/1 cm3. Analyze List the knowns and the unknown. Knowns • time worked 8 h • 1 hour 60 min • 1 minute 60 s Unknown • seconds worked ? s The first conversion factor must be written with the unit hours in the denominator. The second conversion factor must be written with the unit minutes in the denominator. This will provide the desired unit (seconds) in the answer. Sample Problem 3.5 Answers 28. 1.0080 × 104 min 29. 1.44000 × 105 s Practice Problems Plus Math L2 At Earth’s farthest point from the sun, sunlight takes 8.5 minutes to reach Earth. How many weeks is this? (8.4 × 10–4 weeks) Math Handbook For help with dimensional analysis, go to page R66. 8 h 60 min 60 s 28,800 s 1 min 1h 2.8800 104 s Practice Problems Evaluate Does the result make sense? The answer has the desired unit (seconds). Since the second is a small unit of time, you should expect a large number of seconds in 8 hours. Before you do the actual arithmetic, it is a good idea to make sure that the units cancel and that the numerator and denominator of each conversion factor are equal to each other. The answer is exact since the given measurement and each of the conversion factors is exact. Handbook For a math refresher and practice, direct students to dimensional analysis, page R66. Calculate Solve for the unknown. Start with the known, 8 hours. Use the first relationship (1 hour 60 minutes) to write a conversion factor that expresses 8 hours as minutes. The unit hours must be in the denominator so that the known unit will cancel. Then use the second conversion factor to change the unit minutes into the unit seconds. This conversion factor must have the unit minutes in the denominator. The two conversion factors can be used together in a simple overall calculation. Practice Problems Problem-Solving 3.29 Solve Problem 29 with the help of an interactive guided tutorial. 28. How many minutes are there in exactly one week? 29. How many seconds are in exactly a 40-hour work week? with ChemASAP There is usually more than one way to solve a problem. When you first read Sample Problem 3.5, you may have thought about different and equally correct ways to approach and solve the problem. Some problems are easily worked with simple algebra. Dimensional analysis provides you with an alternative approach to problem solving. In either case, you should choose the problem-solving method that works best. 82 Chapter 3 82 Chapter 3 chem_TE_ch03_FPL.fm Page 83 Wednesday, August 4, 2004 6:35 PM Sample Problem 3.6 SAMPLE PROBLEM 3.6 Using Dimensional Analysis Answers Conversion Problems The directions for an experiment ask each student to measure 1.84 g of copper (Cu) wire. The only copper wire available is a spool with a mass of 50.0 g. How many students can do the experiment before the copper runs out? Analyze List the knowns and the unknown. Knowns • mass of copper available ⫽ 50.0 g Cu • each student needs 1.84 grams of copper, or 1.84 g Cu . student Unknown • number of students ⫽ ? From the known mass of copper, calculate the number of students that can do the experiment by using the appropriate conversion factor. The desired conversion is mass of copper ¡ number of students. A conversion factor is a ratio of two quantities that are equal to one another. When doing conversions, write the conversion factors so that the unit of a given measurement cancels, leaving the correct unit for your answer. Note that the equalities needed to write a particular conversion may be given in the problem. In other cases, you will need to know or look up the necessary equalities. Math Handbook For help with conversion problems, go to page R66. Calculate Solve for the unknown. Because students is the desired unit for the answer, the conversion factor should be written with students in the numerator. Multiply the mass of copper by the conversion factor. 50.0 g Cu ⫻ 1 student ⫽ 27.174 students ⫽ 27 students 1.84 g Cu Note that because students cannot be fractional, the result is shown rounded down to a whole number. Evaluate Does the result make sense? The unit of the answer (students) is the one desired. The number of students (27) seems to be a reasonable answer. You can make an approximate calculation using the following conversion factor. 1 student 2 g Cu Multiplying the above conversion factor by 50 g Cu gives the approximate answer of 25 students, which is close to the calculated answer. Practice Problems 30. An experiment requires that each student use an 8.5-cm length of magnesium ribbon. How many students can do the experiment if there is a 570-cm length of magnesium ribbon available? 31. A 1.00-degree increase on the Celsius scale is equivalent to a 1.80-degree increase on the Fahrenheit scale. If a temperature increases by 48.0°C, what is the corresponding temperature increase on the Fahrenheit scale? Problem-Solving 3.30 Solve Problem 30 with the help of an interactive guided tutorial. with ChemASAP Section 3.3 Conversion Problems 83 Practice Problems Plus L2 Chapter 3 Assessment problem 84 is related to Sample Problem 3.6. Conversion Problems Remind students that they often convert from one unit to another, both inside and outside of chemistry class. They convert money from cents to dollars and time from minutes to hours. Start out by giving them practice with everyday examples. Ask, A chicken needs to be cooked 20 minutes for each pound it weighs. How long should the chicken be cooked if it weighs 4.5 pounds? (4.5 lb × 20 min/lb = 90 min; 90 min × 1 h/60 min = 1.5 h. Most students will automatically relate 90 minutes to 1.5 hours. This may help them become comfortable with the process.) If students are having difficulty with conversion factors, you may wish to have them list several conversion factors on the chalkboard. Divide the class in half and have each group challenge the other to write the conversion factor given two related units. Remind them that each conversion factor can appear in two forms depending on which value they put in the numerator. Math Handbook For a math refresher and practice, direct students to conversion problems, page R66. Differentiated Instruction L1 Provide as much class time as possible for students to work on problem assignments in cooperative learning groups. Have students explore their own problem-solving styles. Encourage students to draw a diagram or 30. 67 students 31. 86.4°F Less Proficient Readers picture of the problem to be solved whenever possible. Some students may want to read the problem aloud or have a partner read it to them. Some may want to work with symbols and equations. Scientific Measurement 83 chem_TE_ch03_FPL.fm Page 84 Wednesday, August 4, 2004 6:37 PM Converting Between Units CLASS Converting Between Units In chemistry, as in many other subjects, you often need to express a measurement in a unit different from the one given or measured initially. Problems in which a measurement with one unit is converted to an equivalent measurement with another unit are easily solved using dimensional analysis. Suppose that a laboratory experiment requires 7.5 dg of magnesium metal, and 100 students will do the experiment. How many grams of magnesium should your teacher have on hand? Multiplying 100 students by 7.5 dg/student gives you 750 dg. But then you must convert dg to grams. Sample Problem 3.7 shows you how to do the conversion. Activity L2 Purpose To use dimensional analysis to convert between English and metric units Materials copies of media guides containing vital statistics, such as heights and weights, of players on a sports team (These guides are available from local sports franchises.) Procedure Group students. Distribute the media guides and assign each group a set of players. Ask the group to convert heights and weights into heights and masses expressed in meters and kilograms, respectively. Have students document their approach, including dimensional analysis expressions, conversion factors, and calculations. Expected Outcome Students should use conversion factors, such as 2.54 cm/1 inch and 454 g/1 lb to convert their measurements. Sports Stats SAMPLE PROBLEM 3.7 Converting Between Metric Units Express 750 dg in grams. Analyze List the knowns and the unknown. Knowns • mass ⫽ 750 dg • 1 g ⫽ 10 dg The desired conversion is decigrams ¡ grams. Using the expression relating the units, 10 dg ⫽ 1 g, multiply the given mass by the proper conversion factor. Calculate Solve for the unknown. The correct conversion factor is shown below. 1g 10 dg Note that the known unit is in the denominator and the unknown unit is in the numerator. 750 dg ⫻ Sample Problem 3.7 Because the unit gram represents a larger mass than the unit decigram, it makes sense that the number of grams is less than the given number of decigrams. The unit of the known (dg) cancels, and the answer has the correct unit (g). The answer also has the correct number of significant figures. 32. a. 44 m b. 4.6 x 10–3 g c. 10.7 cg 33. a. 1.5 × 10–2 L b. 7.38 × 10–3 kg c. 6.7 × 103 ms d. 9.45 × 107 µg Make the following conversions. a. 0.045 L to cubic centimeters (4.5 × 101 cm3) b. 14.3 mg to grams (1.43 × 10–2 g) c. 0.0056 m to micrometers (5.6 × 103 µm) d. 0.035 cm to millimeters (3.5 × 10–1 mm) 84 Chapter 3 1g ⫽ 75 g 10 dg Evaluate Does the result make sense? Answers Practice Problems Plus Unknown • mass ⫽ ? g L2 Practice Problems 32. Using tables from this chapProblem-Solving 3.33 Solve Problem 33 with the help of an interactive guided tutorial. with ChemASAP 84 Chapter 3 ter, convert the following. a. 0.044 km to meters b. 4.6 mg to grams c. 0.107 g to centigrams 33. Convert the following. a. 15 cm3 to liters b. 7.38 g to kilograms c. 6.7 s to milliseconds d. 94.5 g to micrograms chem_TE_ch03.fm Page 85 Wednesday, April 13, 2005 1:59 PM handled by breaking them down into manageable parts. For example, if you were cleaning a car, you might first vacuum the inside, then wash the exterior, then dry the exterior, and finally put on a fresh coat of wax. Similarly, many complex word problems are more easily solved by breaking the solution down into steps. When converting between units, it is often necessary to use more than one conversion factor. Sample Problem 3.8 illustrates the use of multiple conversion factors. Checkpoint What problem-solving methods can help you solve complex word problems? SAMPLE PROBLEM 3.8 Converting Between Metric Units What is 0.073 cm in micrometers? Analyze List the knowns and the unknown. Knowns • length 0.073 cm 7.3 102 cm • 102 cm 1 m • 1 m 106 µm Unknown • length ? µm Scientific Notation It is often convenient to express very large or very small numbers in scientific notation. The distance between the sun and Earth is 150,000,000 km, which can be written as 1.5 108 km. The diameter of a gold atom is 0.000 000 000 274 m, or 2.74 1010 m. When multiplying numbers written in scientific notation, add the exponents. When dividing numbers written in scientific notation, subtract the exponent in the denominator from the exponent in the numerator. Math Handbook For help with scientific notation, go to page R56. The desired conversion is from centimeters to micrometers. The problem can be solved in a two-step conversion. Calculate Solve for the unknown. First change centimeters to meters; then change meters to micrometers: centimeters ¡ meters ¡ micrometers. Each conversion factor is written so that the unit in the denominator cancels the unit in the numerator of the previous factor. 7.3 10 -2 cm 6 1 m 10 mm 7.3 102 mm 1m 102 cm L2 Discuss Multistep Problems Many complex tasks in your everyday life are best Explain that dimensional analysis is an extremely powerful problem-solving tool. Learning this method requires extra effort on the part of students. They must often use multiple conversion factors. The extra effort can be justified because the proper manipulation of the units assures accurate manipulation of the numbers. Emphasize that students should use dimensional analysis as a tool for solving all of the problems they encounter in chemistry. Their first question about any quantity should be “What are the units of this quantity?” By comparing the units of various quantities in a problem, students can discover whether they need to perform any unit conversions before proceeding. Sample Problem 3.8 Answers Problem-Solving 3.35 Solve Problem 35 with the help of an interactive guided tutorial. with ChemASAP 34. 2.27 × 10–8 cm 35. 1.3 × 108 dm Practice Problems Plus L2 Chapter 3 Assessment problem 70 is similar to Sample Problem 3.8. Evaluate Does the result make sense? Because a micrometer is a much smaller unit than a centimeter, the answer should be numerically larger than the given measurement. The units have canceled correctly, and the answer has the correct number of significant figures. Remind students that writing a number in scientific notation does not change the actual size of the number. In Sample Problem 3.8, the given measurement 0.073 cm can be written as 7.3 × 10–2 cm. Practice Problems 34. The radius of a potassium atom is 0.227 nm. Express this radius in the unit centimeters. 35. The diameter of Earth is 1.3 104 km. What is the diameter expressed in decimeters? Math Section 3.3 Conversion Problems 85 Handbook For a math refresher and practice, direct students to scientific notation, page R56. Differentiated Instruction L1 Students may benefit from a reminder that certain key words and phrases in each word problem indicate the unknown quantity and its units. Some of these phrases are: • How much • What is • How long • Determine • Find Less Proficient Readers Answers to... Checkpoint Break the solution down into steps. Use more than one conversion factor if necessary. Scientific Measurement 85 chem_TE_ch03_FPL.fm Page 86 Wednesday, August 4, 2004 6:38 PM Converting Complex Units Many common measurements are expressed Sample Problem 3.9 as a ratio of two units. For example, the results of international car races often give average lap speeds in kilometers per hour. You measure the densities of solids and liquids in grams per cubic centimeter. You measure the gas mileage in a car in miles per gallon of gasoline. If you use dimensional analysis, converting these complex units is just as easy as converting single units. It will just take multiple steps to arrive at an answer. Answers 36. 1.93 × 104 kg /m3 37. 7.0 × 1012 RBC/L Practice Problems Plus L2 1.00 L of neon gas contains 2.69 × 1022 neon atoms. How many neon atoms are in 1.00 mm3 of neon gas under the same conditions? (2.69 × 1016 atoms) Math SAMPLE PROBLEM 3.9 Converting Ratios of Units The mass per unit volume of a substance is a property called density. The density of manganese, a metallic element, is 7.21 g/cm3. What is the density of manganese expressed in units kg/m3? Analyze List the knowns and the unknown. Handbook Knowns • density of manganese ⫽ 7.21 g/cm3 • 103 g ⫽ 1 kg • 106 cm3 ⫽ 1 m3 For a math refresher and practice, direct students to dimensional analysis, page R66. Unknown • density manganese ⫽ ? kg/m3 The desired conversion is g/cm3 ¡ kg/m3. The mass unit in the numerator must be changed from grams to kilograms: g ¡ kg. In the denominator, the volume unit must be changed from cubic centimeters to cubic meters: cm3 ¡ m3. Note that the relationship between cm3 and m3 was determined from the relationship between cm and m. Cubing the relationship 102 cm ⫽ 1 m yields (102 cm)3 ⫽ (1 m)3, or 106 cm3 ⫽ 1 m3. Quick LAB L2 Objective After completing this activity, students will be able to • develop conversion factors using dimensional analysis. Dimensional Analysis Math Handbook Calculate Solve for the unknown. 1 kg 7.21 g 106 cm3 ⫻ 3 ⫻ ⫽ 7.21 ⫻ 103 kg/m3 1 cm3 10 g 1 m3 For help with dimensional analysis, go to page R66. Evaluate Does the result make sense? Students may think that because a conversion factor equals unity, it doesn’t matter whether the conversion factor or its reciprocal is used in a calculation. Remind students that a given pair of equivalent measurements yields two different conversion factors, only one of which can be used to obtain the correct conversion. Because the physical size of the volume unit m3 is so much larger than cm3 (106 times), the calculated value of the density should be larger than the given value even though the mass unit is also larger (103 times). The units cancel, the conversion factors are correct, and the answer has the correct ratio of units. Practice Problems 36. Gold has a density of Problem-Solving 3.37 Solve Problem 37 with the help of an interactive guided tutorial. 19.3 g/cm3. What is the density in kilograms per cubic meter? 37. There are 7.0 ⫻ 106 red blood cells (RBC) in 1.0 mm3 of blood. How many red blood cells are in 1.0 L of blood? with ChemASAP Skills Focus Calculating Prep Time 5 minutes Materials 3 inch × 5 inch index cards (or paper cut to approximately the same size) Class Time 15 minutes Expected Outcome Students should derive appropriate conversion factors among metric units using standard metric quantities and prefixes. 86 Chapter 3 86 Chapter 3 L3 Analyze and Conclude For Enrichment 1. If a measurement of a quantity is being converted, the unit changes. If the equivalence of a quantity is being found, the conversion factor changes the quantity itself. 2. a. 0.785 m b. 56 cm3 c. 7.7 × 107 mg d. 9.8 × 10–10 dm e. 9.6 × 103 µm f. 6.7 × 103 nm Have students express the ratio in scientific notation between the largest and smallest units listed in each table. (Table 3.3: 1 × 1012, Table 3.4: 1 × 106; Table 3.5: 1 × 109 ) chem_TE_ch03.fm Page 87 Thursday, April 14, 2005 12:49 PM Quick LAB 3 Dimensional Analysis Evaluate Understanding Purpose Procedure To apply the problemsolving technique of dimensional analysis to conversion problems. A conversion factor is a ratio of equivalent measurements. For any relationship, you can write two ratios. On a conversion factor card you can write one ratio on each side of the card. Materials • 3 inch 5 inch index • cards or paper cut to approximately the same size pen ASSESS 1. Make a conversion factor card for each metric relationship shown in Tables 3.3, 3.4, and 3.5. Show the inverse of the conversion factor on the back of each card. 2. Use the appropriate conversion factor cards to set up solutions to Sample Problems 3.7 and 3.8. Notice that in each solution, the unit in the denominator of the conversion factor cancels the unit in the numerator of the previous conversion factor. To determine students’ grasp of conversion factors, ask, What is the relationship between the numerator and the denominator of any measurement conversion factor? (They are equivalent so that the ratio of numerator to denominator equals 1.) Analyze and Conclude 1. What is the effect of multiplying a given measurement by one or more conversion factors? 2. Use your conversion factor cards to set up solutions to these problems. a. 78.5 cm ? m b. 0.056 L ? cm3 c. 77 kg ? mg d. 0.098 nm ? dm e. 0.96 cm ? µm f. 0.0067 mm ? nm 39. 40. Key Concept What happens to the numerical value of a measurement that is multiplied by a conversion factor? What happens to the actual size of the quantity? Key Concept Why is dimensional analysis useful? 44. Convert the following. Express your answers in scientific notation. a. 7.5 104 J to kilojoules b. 3.9 105 mg to decigrams c. 2.21 104 dL to microliters 45. Light travels at a speed of 3.00 1010 cm/s. Key Concept What types of problems can be solved using dimensional analysis? What is the speed of light in kilometers/hour? 41. What conversion factor would you use to convert between these pairs of units? L1 Reteach Model the conversion of 2 L to 2000 mL. Suggest that students check the answer by explaining that when using a conversion factor, such as 1 L = 1000 mL, the measurement expressed with the smaller unit (mL) should have a larger number associated with it (2000) than the measurement expressed with the larger unit (L). Connecting 3.3 Section Assessment 38. L2 Concepts Acceptable answers include (a) analyze the known and unknowns, devise a set of conversions steps that yields the desired final units, and write a conversion factor for each step; (b) calculate by multiplying (making sure that the appropriate units cancel); and (c) evaluate the magnitude and units of the calculated answer. Problem-Solving Skills Reread the passage on solving numeric problems in Section 1.4. Explain how the three-step process might apply to conversion problems that involve dimensional analysis. a. minutes to hours b. grams to milligrams c. cubic decimeters to milliliters 42. Make the following conversions. Express your answers in standard exponential form. a. 14.8 g to micrograms b. 3.72 103 kg to grams c. 66.3 L to cubic centimeters 43. An atom of gold has a mass of 3.271 1022 g. How many atoms of gold are in 5.00 g of gold? Assessment 3.3 Test yourself on the concepts in Section 3.3. with ChemASAP If your class subscribes to the Interactive Textbook, use it to review key concepts in Section 3.3. with ChemASAP Section 3.3 Conversion Problems 87 Section 3.3 Assessment 38. The numerical value (and the unit) changes; the actual size does not change. 39. Dimensional analysis provides an alternative approach to problem solving. 40. conversion problems 41. a. 1 hour / 60 min b. 103 mg / 1 g c. 103 mL / 1 dm3 42. a. 1.48 × 107 µg b. 3.72 g c. 6.63 × 104 cm3 43. 1.53 × 1022 atoms of gold 44. a. 7.5 × 101 kJ b. 3.9 × 103 dg c. 2.21 × 101 µL 45. 1.08 × 109 km/h Scientific Measurement 87
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