Black Sea Rivers Monitoring guiding harmonization in the Black Sea Region Project: Integrated hotspots management and saving the living Black Sea ecosystem HOT BLACK SEA 2.2.1.72761.225 MIS-ETC 2303 2015 Document Control Sheet Project Full Title: Integrated hotspots management and saving the living Black Sea ecosystem Project Acronym: Hot Black Sea (HBS) Grant Agreement No. 2.2.1.72761.225 MIS-ETC 2303 Coordinator: Dr. Georgeta Alecu Project start date and duration: March 2013, 31 months Project website: http://www.bs-hotspots.eu/ Package of Activities No: PA 1 Package of Activities Title: Harmonization of Hot Spots policies Report Title: Technical Report on Black Sea Rivers Monitoring Responsible: ICPE-CA; Bourgas Municipality Partners involved: All project partners Status: Final (F) Draft (D) Revised draft (RV) Dissemination level: Public (PU) Restricted to other program participants (PP) Restricted to a group specified by the consortium (RE) Confidential, only for members of the consortium (CO) 2 ACKNOWLEDGEMENTS We sincerely thank all stakeholders who greatly contributed to the preparation of this report. Disclaimer The information contained in this report is subject to change without notice and should not be interpreted as a final commitment by any members of the HotBlackSea Consortium or the authors. This document cannot be copied, reproduced or distributed, entirely or partly, without written permission from the HotBlackSea Consortium. Acknowledgement of the authors of the document (HBS Project Consortium) shall be clearly referenced. All rights reserved to the HotBlackSea Consortium. Note: The Report is a working (living) document, it evolved during the last years in the process of stakeholders consultations and remains opened for any updates which may arrive in the Black Sea region when harmonization in rivers monitoring starts better developing. Cover page photo: Evgeni Dinev Recommended citation: HBS Project Consortium. 2015, Rivers Monitoring Report: Guiding harmonization in the Black Sea Region, HBS Project (http://bs-hotspots.eu/) publications. 129 pp. 3 CONTENT INTRODUCTION 11 STATE OF THE ART IN BLACK SEA RIVERS MONITORING 14 1. Rivers monitoring and assessments as required by EU legislation 14 2. National monitoring – country reviews 18 BULGARIA ...................................................................................................................................................... 18 GEORGIA ....................................................................................................................................................... 43 ROMANIA ....................................................................................................................................................... 52 TURKEY .......................................................................................................................................................... 73 UKRAINE ........................................................................................................................................................ 86 3. International level (Black Sea regional) 95 CONCLUSIONS AND NEEDS IN HARMONIZATION 96 1. General conclusions 96 2. Conclusions as per priorities in harmonization 101 RECOMMENDATIONS 104 ANNEX I: Rivers surveillance and operational monitoring programme in the Bulgarian Black Sea Basin, 2010-2015 113 ANNEX II. Projects in Turkey in support of surface waters management advancements 4 124 ABBREVIATIONS BG BS BSC BSIMAP BSIS BS SAP EC EcoQOs EEA EU GE HS ICPDR IPPC ISO LBS PA QA QC RO SCI TNMN TPH TR TUBITAK UA WFD WWTP Bulgaria Black Sea Black Sea Commission (Commission on the Protection of the Black Sea Against Pollution), www.blacksea-commission.org Black Sea Integrated Monitoring and Assessment Program Black Sea Information System Black Sea Strategic Action Plan European Commission, http://ec.europa.eu/ Ecosystem Quality Objectives European Environment Agency European Union Georgia Hot Spot Convention on the Protection of the Danube River, www.icpdr.org/ Integrated Pollution Prevention and Control International Organization for Standardization, http://www.iso.org Land Based Sources (of pollution) Project Activity Quality assurance Quality control Romania Sites of Community Interest (NATURE2000) Trans National Monitoring Network Total petroleum hydrocarbons Turkey The Scientific and Technological Research Council of Turkey, www.tubitak.gov.tr/ Ukraine Water Framework Directive Waste Water Treatment Plant 5 DEFINITIONS Diffuse sources – they are also named ‘non-point’ sources. Nonpoint source pollution generally results from land runoff, precipitation, atmospheric deposition, drainage, seepage or hydrologic modification. Diffuse sources are those which cannot be attributed to a specific location and their discharges/emissions are often found not in the immediate environment but in areas far away. Environmental quality standard - the concentration of a particular pollutant or group of pollutants in water, sediment or biota, which should not be exceeded in order to protect human health and the environment. Environmental target - means a qualitative or quantitative statement on the desired condition of the different components of, and pressures and impacts on, marine waters in respect of a marine region or subregion. Eutrophication - an increase in the rate of supply of organic matter to an ecosystem. Hot Spot – means a limited and definable local land area, stretch of surface water or specific aquifer that is subject to excessive pollution and necessitates priority attention in order to prevent or reduce the actual or potential adverse impacts on human health, ecosystems or natural resources and amenities of economic importance (the definition is from the revised LBSA Protocol, http://www.blackseacommission.org/_od_LBSAProtocol.asp) Hot Spots (as applied for the Concept of the HS database): (a) Point sources on the coast of the Sea which potentially affect human health, ecosystems, biodiversity, sustainability or economy in a significant manner. They are the main points where high levels of pollution loads originating from domestic or industrial sources are being discharged; (b) Defined coastal areas where the coastal marine environment is subject to pollution from one or more point or diffused sources on the coast of the Sea which potentially affect human health in a significant manner, ecosystems, biodiversity, sustainability or economy. Nutrient enrichment – a supple of inorganic forms of nitrogen, phosphorus and silica to an environment. Pressure – the mechanism through which an activity has an effect on any part of an ecosystem. Land-based sources - point and diffuse sources on land from which substances or energy reach the maritime area by water, through the air, or directly from the coast. Operational monitoring (WFD) - monitoring in areas, which are at risk of failing to meet the set environmental targets. Point sources - sources of pollution where emissions and releases are introduced into the environment from any discernable, confined and discrete conveyance, including but not limited to pipes, outfalls, channels, ditches, tunnels, conduits or wells from which pollutants are or may be discharged. Reference condition - a set of selected measurements or conditions of minimally impaired waterbodies characteristic of a waterbody type in a region. 6 Risk assessment - risk is defined as the likelihood (or probability) that a consequence (or hazard) will occur. State (governmental) monitoring – monitoring carried out in implementation of legal/policy documents (from national to global level). Surveillance monitoring – monitoring in areas, which are not at risk or a potentially/possibly at risk to not meet the set environmental targets. Surface waters – rivers, lakes and territorial waters of the Black Sea. In the WFD: Surface water means inland waters, except groundwater; transitional waters and coastal waters, except in respect of chemical status for which it shall also include territorial waters. 7 List of Figures Figure 1. Inorganic nutrient (phosphates and nitrates) loads (kt.year-1) stemming with Danube waters to the Black Sea (period 1988-2009) 11 -1 Figure 2. Total phosphorus and N-NO3 loads (kt.year ) stemming with Danube waters to the Black Sea (period 2005-2009) 12 Figure 3. N-NO3 loads stemming with Cherokhi (Choruh) River as estimated by GE and TR (period 2005-2009) 12 Figure 4. Black Sea largest rivers (see also stations at Sulina and Reni, used for calculation of Danube loads to the Black Sea) 13 Figure 5. Nitrogen loads stemming to the Black Sea from various BG rivers and WWTPs (Waste Water Treatment Plants) 19 Figure 6. Phosphorus loads stemming to the Black Sea from various BG rivers and WWTPs (Waste Water Treatment Plants) 20 Figure 7. The BG BS coast and its various sources of human pressures and areas in need for protection (SCI – Sites of Community (European Community) Interest, as designated under NATURE2000) 21 Figure 8. Monitoring stations in rivers and lakes in the Bulgarian Black Sea Basin (re-drawn from the Black Sea Basin Management Plan, 2009 for the period 2010-2015) 22 Figure 9. Locations of stations for surveillance and operational monitoring in the BG Black Sea Basin rivers in 2010-2015 (as reported to WISE). 24 Figure 10. Monitoring stations at BG rivers for calculation of loads stemming to the Black Sea 29 Figure 11. Monitoring stations in rivers and lakes (Bulgarian Black Sea Basin) for inorganic forms of nitrogen and phosphorus (sensitive areas), (re-drawn from the Black Sea Basin Management Plan, 2009) 30 Figure 12. Monitoring stations for identification of nitrates levels in surface waters in the Bulgarian Black Sea Basin (vulnerable areas), (re-drawn from the Black Sea Basin Management Plan, 2009) 31 Figure 13. BG monitoring stations for tracing environmental status in protection of valuable fish and shellfish species (re-drawn from the Black Sea Basin Management Plan, 2009) 32 Figure14. BG monitoring stations for tracing environmental conditions in protection of birds and their habitats and as defined in Art. 6 of the WFD (re-drawn from the Black Sea Basin Management Plan, 2009) 33 Figure 15. BG monitoring stations for tracing environmental conditions in protection of NATURE2000 sites under the Habitats Directive and as defined in Art. 6 of the WFD (re-drawn from the Black Sea Basin Management Plan, 2009) 34 Figure 16. BG drinking water categories 1 and 2 (re-drawn from the Black Sea Basin Management Plan, 2009) 35 Figure 17. BG monitoring stations for automated observations related to early warning of floods (Bourgas Municipality, Bulgaria) 36 Figure 18. Results of real-time observations in the Kamchia River - Poda in 2011 (Bulgaria) 37 Figure 19. Results of real-time observations in the Rezovska River in 2011 (Bulgaria) 38 Figure 20. Ecological status of water bodies in rivers and lakes of the Bulgarian Black Sea Basin in 2009 (re-drawn from the Black Sea Basin Management Plan, 2009) 40 8 Figure 21. Ecological status of Bulgarian Black Sea water bodies as per 2014 41 Figure 22. Rivers monitoring network of Georgia (Source: NEA, department of Hydrometeorology), (Legend – blue triangles – planned automated stations (posts), empty triangles – closed stations; red triangles - working stations at present) 43 Figure 23. Surface waters surveillance monitoring in Georgia (locations marked in green) 45 Figure 24. Protected areas in Georgia 50 Figure 25. Georgian drinking water monitoring: National Food Agency samples collected in 2009–2014 51 Figure 26. Rivers of the RO BS coast 54 Figure 27. The monitoring network of surface waters in the Dobrogea catchment area (Romania) 55 Figure 28. The network for monitoring of surface water quality in the Dobrogea catchment area (Romania) in 2013 56 Figure 29. Vulnerable areas to nitrates in the Dobrogea river area and the Danube Delta (Romania) 66 Figure 30. Areas intended for protection of habitats and species where water is an important factor in the Dobrogea River Area (Romania) 67 Figure 31. Protection areas of water catchments for drinking water of Dobrogea river area (Romania)68 Figure 32. Ecological status and ecological potential of surface waters in the Danube catchment area in 2013 (Romania) 72 Figure 33. Black Sea river basins of Turkey 74 Figure 34. Distribution of monitoring stations along Black Sea river basins in Turkey 79 Figure 35. Protected Areas in the Black Sea coasts of Turkey 82 Figure 36. Surface water monitoring stations – the Hydrometeorological Service under the State Emergency Service of Ukraine 88 Figure 37. Surface water monitoring stations – the State Environmental Inspection under the Ministry of Ecology and Natural Resources of Ukraine 88 Figure 38. Surface water monitoring stations – the State Agency for Water Resources (Ukraine) 89 Figure 39. Danube River monitoring stations - Danube River Basin Management Authority (Ukraine) 89 Figure 40. Surface water monitoring stations – the Sanitary-Epidemiological Service under the Ministry of Health of Ukraine 90 List of Tables Table 1. Hydromorphological quality elements (same for operational and surveillance monitoring) (Bulgaria) 25 Table 2. Physico-chemical quality elements (BNS – Bulgarian national standard; RBMP – River-basin management plan) 25 Table 3. Set of priority and specific pollutants (Bulgaria) 27 Table 4. Hydrobiological quality elements (Bulgaria) 27 Table 5. BG Rivers where loads to the Black Sea are calculated 28 Table 6. List of automated stations for monitoring of surface waters in the Black Sea basin (Bulgaria) 37 Table 7. Classification of water bodies status according to the Macrozoobenthos index (Bulgaria) 39 9 Table 8. Classes of status in assessments under EC Directives 39 Table 9. Parameters included in the Operational Monitoring Programme of surface waters in Georgia 46 Table 10. Black Sea Basin rivers and lakes monitored in Georgia 47 Table 11. Hydromorphological parameters observed in GE 48 Table 12. Physico-chemical parameters observed in GE rivers monitoring 48 Table 13. Priority substances (list I) (according to GD no. 1038/2010) (Romania) 57 Table 14. Families and groups of substances of specific pollutants (according to GD no. 1038/2010) (Romania) 58 Table 15. Indicative list (list II) of substances that correspond to the families and groups of substances enlisted in Table 14 (Romania) 59 Table 16. Hydromorphological elements in RO rivers and lakes monitoring 63 Table 17. Physico-chemical parameters monitored in Romania 63 Table 18. Hydrobiological parameters (Romania) 64 Table 19. Governmental Organizations involved in River Basin Management (Turkey) 75 Table 20. Municipality Environmental Services (Turkey) 76 Table 21. Municipality Environmental Services (Turkey) 77 Table 22. Selected sampling stations and their features (Turkey) 79 Table 23. Types of Protected Areas and Legislations (Turkey) 83 Table 24. Hydromorphological parameters (Ukraine) 91 Table 25. UA key monitored parameters for rivers 91 Table 26. List of rivers parameters reported by the BS countries to the BSC 96 Table 27. Other rivers parameters (outside of BSC reporting) monitored in the BS states rivers monitoring 98 Table 28. Frequency of sampling in rivers 99 Table 29. Common rivers parameters in the monitoring programmes of the beneficiary countries 102 10 December, 2015 Black Sea Rivers Monitoring INTRODUCTION This Report has been prepared under the HBS Project “Integrated hotspots management and saving the living Black Sea ecosystem” (www.bs-hotspots.eu), Grant Agreement No2.2.1.72761.225 MIS-ETC 2303. The Project is financed by EC as an activity under the Joint Operational Programme “Black Sea Basin 2007-2013”1. HotBlackSea is an integral part of the overall ongoing process of harmonization of policies in the Black Sea region in the field of environment protection, taking into consideration relevant European acquis. Beneficiary countries of the HBS Project are Bulgaria, Georgia, Romania, Turkey and Ukraine. The Report is part of the HBS Project activities (PA) planned within PA1 ‘Harmonization of Hot Spots policies’. Main aim of the report is to review the current rivers monitoring strategies and practices in the project beneficiary countries, find the reasons for discrepancies in data and outline needs in harmonization. The latter are many, starting from the choice of measured parameters and ending with methodologies of river loads calculation and various assessments conducted. Well known is that total riverine discharge (water and substances) to the Black Sea considerably differ in level and sometimes in trends according to various bibliographical sources (for the same years). Moreover, for a single river also there exist differing estimates, as most famous is the case of the Danube River (transboundary river, the largest one in the Black Sea catchment area), (Fig. 1 and Fig. 2). Figure 1. Inorganic nutrient (phosphates and nitrates) loads (kt.year-1) stemming with Danube waters to the Black Sea (period 1988-2009) Note: Red line (Sulina station) – data source NIMRD Grigore Antipa (Constanta, Romania); Blue line (Reni station) – data source TNMN (Trans-national monitoring network of ICPDR). Reni is located before the Danube Delta, Sulina – in the Danube Delta from the side of the Black Sea (see Fig. 4 for the exact position of these stations). Reni is used to calculate loads with the assumption that the Danube Delta does not reduce the nutrients in Danube waters, the retention is less than 10 %. 1The Programme is managed by the Romanian Ministry of Regional Development and Public Administration. 11 December, 2015 Black Sea Rivers Monitoring TP loads, kt/year N-NO3 loads, kt/year 100 500 50 0 0 2005 2006 UA data 2007 2008 2009 2005 TNMN data 2006 UA data 2007 2008 2009 TNMN data Figure 2. Total phosphorus and N-NO3 loads (kt.year-1) stemming with Danube waters to the Black Sea (period 2005-2009) Note: Blue line – Ukrainian data source (measurements in the Chilia branch of Danube); Brown line – TNMN data source (measurements at Reni) Another example is the transboundary Cherokhi2 (Choruh in Turkish) River, where GE and TR estimates do not match (Fig. 3). Unfortunately, comparison for phosphorus or orthophosphates cannot be provided as such data in GE are absent (or at least not accessible). N-NO3 loads (kt/year) 7 6 5 4 3 2 1 0 2005 2006 2007 TR data 2008 2009 GE data Figure 3. N-NO3 loads stemming with Cherokhi (Choruh) River as estimated by GE and TR (period 2005-2009) 2 In GE the River is also written Tchorokhi or Chorokhi. 12 December, 2015 Black Sea Rivers Monitoring Figure 4. Black Sea largest rivers (see also stations at Sulina and Reni, used for calculation of Danube loads to the Black Sea) Meanwhile, the BS rivers are the most serious source of pollution/eutrophication of the Sea and correct data on their contribution in nutrient enrichment and hazardous substances input is of a paramount importance. Otherwise, it is impossible to build knowledge-based nutrient- and pollution-reduction schemes with respective programmes of measures. In this report we show that harmonization of rivers monitoring for Black Sea rivers is a pending issue in the regional agenda of environmental protection, becoming more and more urgent in view of the regional disputes on the ‘share’ of each Black Sea country in the overall environmental problems and on the amount of total load of nutrients and hazardous chemicals coming to the Black Sea. The general perception is that the Danube River is the largest source of any pollution to the Black Sea. However, recent investigations showed that the loads of total petroleum hydrocarbons, originating from other rivers, might be of higher magnitude. The same may be the case for other harmful substances. However, no comparison of data is worth undertaking until river monitoring strategies and practices of the Black Sea coastal states remain non-harmonised. This Report does not discuss monitoring of land-based sources of pollution of rivers. The HBS Project LBS Monitoring Report (http://bs-hotspots.eu/Documents/Deliverables/LBS%20Monitoring%20Final%20Draft.pdf) deals in detail with this issue. 13 December, 2015 Black Sea Rivers Monitoring State of the Art in Black Sea Rivers Monitoring 1. Rivers monitoring and assessments as required by EU legislation The European Water Framework Directive (WFD, Council Directive 2000/60/EC, http://eurlex.europa.eu/legal-content/EN/TXT/HTML/?uri=CELEX:32000L0060&from=EN) is the centrepiece of European policy in the field of surface waters management, including monitoring. Full List of Guidelines under the WFD is given at: http://ec.europa.eu/environment/water/waterframework/facts_figures/guidance_docs_en.htm. The List includes a Guideline on monitoring, which inter alia explains how rivers should be monitored. Meanwhile, under the EU neighbourhood policy or other instruments, a number of EU-funded projects have taken place during the last decade, which aimed at development of a WFDcompliant monitoring in Georgia, Turkey and Ukraine with consequent preparation of river-basin management plans. The last project, EPIRB (http://blacksea-riverbasins.net/en/imprint), is still ongoing (2012-2015) and it invested a lot of effort to build capacity in rivers monitoring in Georgia and Ukraine. However, currently, WFD-compliant monitoring takes place in BG and RO only, the rest of the project beneficiary countries (GE, TR and UA) have either no specific river-monitoring strategy (TR) or the current monitoring is restricted to a few physico-chemical parameters (GE) or the list of measured parameters does not follow the WFD requirements (UA). Meanwhile, the WFD requires a long-list of physico-chemical parameters, and also a number of hydromorphological and hydrobiological elements to be included in two major types of monitoring: surveillance and operational. The purpose of surveillance monitoring is to provide the necessary data/information to: Supplement and verify results of anthropogenic pressures reviews and related risk assessments prepared under the requirements of item 1.4 of Annex II of the WFD and Art. 156 of WA; Effective planning of future monitoring programs; Assessment of long-term changes under natural conditions; Assessment of long-term changes resulting from widespread anthropogenic activities. The results of surveillance monitoring are analysed and used also in conjunction with procedure for impact assessments to develop or revise river basin management plans. Surveillance monitoring is aimed at water bodies "not at risk" or "possibly at risk" to compile or supplement the information and data necessary to determine their current condition. In control points selection for these water bodies the following criteria are used: Flowing waters with a considerable quantity of water; Standing waters with a considerable volume of water - large lakes and reservoirs; Significant water bodies that cross the state border; Places where it is necessary to evaluate the load of pollution imported to the sea; Protected areas; Predominant substrate and depth in coastal waters; The particular features of the coast and the expected pollution of transboundary origin; Shipping routes; Specifics of various elements of water quality and various impacts; Direction of propagation of pollution and the prevailing currents; 14 December, 2015 Black Sea Rivers Monitoring Locations with minimal anthropogenic impact for designation of reference sites; Stations where there exist observations in previous periods, which will increase the accuracy in evaluations and classifications. Operational monitoring covers all water bodies classified as water bodies at risk of failing to meet EcoQO (quality objectives). Operational monitoring is also applied to water bodies, where priority substances are released. The purpose of operational monitoring is: To establish the status of those bodies which are at risk in terms of achieving the objectives of the WFD; To evaluate the changes in the state of the water bodies at risk as a result of the implementation of a program of measures. Operational monitoring program could be adjusted in the period of protective measures implementation according to the information obtained on anthropogenic pressures and their impacts. This may include in particular the reduction of the frequency of monitoring, wherein the impact is found insignificant or relevant anthropogenic pressure is removed. When choosing monitoring stations the following basic requirements from Annex V to the WFD are considered: For water bodies at risk from significant point sources of pressure, control points are scheduled in each body so that to assess the magnitude and nature of the impact of the point source. When water body is under the pressure of several point sources, the stations are selected so that to determine the cumulative effect of all types of pressures. For water bodies at risk from significant diffuse sources, control points in each body are chosen so that to assess the magnitude and influence of this type of pressure; For water bodies at risk from significant hydromorphological pressure – the same as above. In choosing monitoring parameters in each water body, its most sensitive elements are considered in view of predetermined types of anthropogenic pressures to which the respective body is subjected (e.g. organic pollution, priority and specific substances, etc.) Both under surveillance and operational monitoring, the frequency of sampling is determined in line with Annex V of the WFD, taking into consideration local specifics of variability. General criteria also include: Referring to: Provision of results reliability; Provision of information on the seasonal variability of the impact of natural and / or anthropogenic pressures influencing the water bodies condition; Provision of information for understanding the structure and functioning of the ecosystem; The spatial and temporal variability of the ecosystem components; The dynamics of water in water bodies (residence time); The results of previous monitoring studies. Before building monitoring programmes, the WFD requires a number of important preparatory steps, in the case of rivers they are as follows: Identify type of river Specify type of water body Classify the water body based on risk assessment (to distinguish btw operational and surveillance monitoring) 15 December, 2015 Black Sea Rivers Monitoring Set reference conditions Set environmental targets (they are traced actually in the 6-yearly cycles of the WFD implementation) Etc. Under the WFD, a third type of monitoring is included – Investigative monitoring. The WFD states that this type of monitoring is required: 1. In cases where the reason for failure to meet environmental standards is unknown; 2. Where surveillance monitoring indicates that it is unlikely the environmental targets set in protection to be achieved, and operational monitoring has not yet started to verify the reasons of failure to achieve for a water body or water bodies the set environmental targets; 3. To clarify the magnitude and impacts of accidental pollution. The list of parameters in Investigative monitoring is dynamic and its validity in time is e limited, in order to respond to new information on the potential risks posed by emerging pollutants and any others alterations. Meanwhile, the WFD is not the only EU legal document requiring rivers monitoring. Relevant legislation includes also: Birds Directive (Council Directive 79/409/EEC of 2 April 1979 on the conservation of wild birds) Habitats Directive (Council Directive 92/43/EC of 21 May 1992 on the conservation of natural habitats and of wild fauna and flora) E91/271/EC (WWTP Directive) 91/676/EC (COUNCIL DIRECTIVE 91/676/EC OF 12 DECEMBER 1991 concerning the protection of waters against pollution caused by nitrates from agricultural sources (Nitrates Directive)) DIRECTIVE 2006/113/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 12 December 2006 (Directive for the valorisation of shellfish areas (2006/113/CE)) on the quality required of shellfish waters (codified version) /COUNCIL DIRECTIVE of 30 October 1979 on the quality required for shellfish waters (79/923/EEC)/ Directive 2008/1/EC concerning integrated pollution prevention and control (ICPP Directive) DIRECTIVE 2007/60/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 23 October 2007on the assessment and management of flood risks Common Fishery Policy (COUNCIL REGULATION (EC) No 199/2008 concerning the establishment of a Community framework for the collection, management and use of data in the fisheries sector and support for scientific advice regarding the Common Fisheries Policy) Very important Directives, which are taken into account in conducting of rivers monitoring, are: COMMISSION DIRECTIVE 2009/90/EC of 31 July 2009 laying down, pursuant to Directive 2000/60/EC of the European Parliament and of the Council, technical specifications for chemical analysis and monitoring of water status DIRECTIVE 2008/105/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 (Priority substances) on environmental quality standards in the field of water policy, amending and subsequently repealing Council Directives 82/176/EC, 83/513/EC, 84/156/EC, 84/491/EC, 86/280/EC and the supplementing Directive 2000/60/EC of the European Parliament and of the Council. The Directive 2008/105/EC is amended by Directive 2013/39/EC. 16 December, 2015 Black Sea Rivers Monitoring All the above mentioned EC Directives are transposed into the national legislation of BG and RO, also partially in TR. Transposition is planned in GE and UA with deadlines specified in their Association Agreements (AA, signed in 20143). As well understood, monitoring solely in the rivers is not enough to build programmes of measures in the so called river-basin management plans. The latter require knowledge on all pressures – natural and anthropogenic, which influence the rivers. Thus, not only LBS pressures are in need for tracing, but also pressures related to shipping, fishery, coastal zones development, rivers regulation, natural hazards4, etc. This report does not deal with ‘Pressures’ monitoring, but with ‘State/Impact’ monitoring, which is used to evaluate the natural and anthropogenic ally-driven changes in rivers, as well as to assess to the loads of nutrients and various chemicals reaching the Black Sea. The AA with its Association Agenda replaces the European Neighbourhood Policy Action Plan (ENP AP). The AA is part of a new generation of Association Agreements with Eastern Partnership countries and provides a long-term foundation for future EU-Georgia and EU-Ukraine relations without excluding any possible future developments in line with the Treaty on European Union. The AA constitutes a reform agenda for Georgia and Ukraine, based around a comprehensive programme of approximation of GE and UA national legislation to EU norms. By signing of the AA Georgia and Ukraine committed to: respecting the principles of sustainable development, protecting the environment and mitigating climate change, continuous improvement of environmental governance and meeting environmental needs, including cross- border cooperation and implementation of multilateral international agreements. In GE, actions needed for the implementation of the AA are described in its Annexes. In Annex XXVI (Environment), Georgia signed the AA in July 2014 and committed to gradually approximate its environmental legislation to the EU legislation and international instruments in the next 4 years (e.g. by 2018 for the WFD). 3 4 Climate-change adaptation programmes require most often real-time monitoring, where hazards can be in an early-warning manner predicted and preventive measures can be taken. 17 December, 2015 Black Sea Rivers Monitoring 2. National monitoring – country reviews BULGARIA In Bulgaria, rivers monitoring is regulated by the Water Act (WA), Ordinance on water quality standards, Regulation N 1 on monitoring of water, and Regulation N H-4 on characterization of surface water. 1. The Water Act has three amendments in 2014 - with State Gazette, issue 26 of 21.03.2014, 49 of 13.06.2014, and 53 of 27.06.2014; 2. Ordinance № 1 from 11.04.2011 for surface water monitoring, SG 34/29.04.2011; 3. Ordinance on standards for environmental quality for priority substances and certain other pollutants undergone amendment with Decree № 225 of 10.02.2013; 4. Ordinance № H-4 from 14.09.2012 on the characterization of surface water, amendment and suppl., SG. 79 of 23.09.2014, in force from 09.23.2014. Other relevant national documents (plans, programmes) are: 1. River Basin Management Plan – December 2009, updated in 2015 for the period 2016-2021 (Named also Black Sea Basin management Plan) 2. National allocation plan – November 2009 3. Development of programs of measures for the Nitrate Directive, the WFD and MSFD There are 33 Rivers in the Black Sea Basin on the territory of Bulgaria (those, which directly (18 in number) or indirectly inflow into the Black Sea), they are grouped in 9 river basins5. The largest is Kamchia River and it is also the most serious source of pollution among all BG Black Sea rivers. The BG Rivers are not among those, which considerably contribute to the BS eutrophication/pollution. Their loads are comparable with those discharged from BG municipal and industrial sources (Fig. 5 and Fig. 6). For detail on names of BG rivers and the 9 river basins see the Black Sea Basin Management Plan 2009 (http://www.bsbd.org/bg/BSPLAN2009.html). 5 18 December, 2015 Black Sea Rivers Monitoring Figure 5. Nitrogen loads stemming to the Black Sea from various BG rivers and WWTPs (Waste Water Treatment Plants) 19 December, 2015 Black Sea Rivers Monitoring Figure 6. Phosphorus loads stemming to the Black Sea from various BG rivers and WWTPs (Waste Water Treatment Plants) 20 December, 2015 Black Sea Rivers Monitoring However, having in mind the cumulative effects of various pressures (Fig. 7), still the BG rivers quality is of great importance for the BS well-being. Figure 7. The BG BS coast and its various sources of human pressures and areas in need for protection (SCI – Sites of Community (European Community) Interest, as designated under NATURE20006) NATURE2000 is the centrepiece of European nature and biodiversity policy, http://ec.europa.eu/environment/nature/natura2000/index_en.htm. Requirements to designating European Sites of Community Interest (SCI), Special Areas of Conservation (SAC) and Special Protection Areas (SPA) as well as related 6 21 December, 2015 Black Sea Rivers Monitoring In line with the WFD requirements, BG conducts surveillance and operational monitoring in 140 surface water bodies (Black Sea Basin), which were identified in rivers, lakes and dams. This monitoring is regular since 2008, the number of parameters vary in the range of 19-55, and the frequency 4-12 times per year. The rivers are identified according to their type (System ‘B’ in the Annex II of the WFD 2000/60/EC), and the criteria include: ecoregion, geology, average height over the sea level, substrate, character of the flow, and drying. In BG there are 5 types of rivers identified7. Investigative monitoring is also conducted in line with the WFD requirements. The Black Sea Basin Management Plan (2009, for the period 2010-2015) was developed basing it on an extensive set of observations conducted in previous years (Fig. 8). Legend Monitorng StationsinLakesand Rivers Su rve illanc e M onitoring In terna l Prog ram Ope rationa l M onitoring Monitorng StationsinMarine Waters Te rritorial Wa te rs Su rve illanc e Monitoring In terna l Prog ram Ope rationa l M onitoring 1m ile zo ne 12 m iles zo ne Figure 8. Monitoring stations in rivers and lakes in the Bulgarian Black Sea Basin (re-drawn from the Black Sea Basin Management Plan, 2009 for the period 2010-2015) criteria are given in the manuals and guidelines issued under NATURE2000 (http://bd.eionet.europa.eu/activities/Natura_2000/chapter6). Criteria fall into the following categories: ecological, social, cultural and economic, scientific and educational. Among ecological criteria most important consider uniqueness and rarity, diversity, naturalness, dependency, critical habitats, and vulnerability of the area of interest. 7 Initially they were 14 but later the number was reduced to 5. Lakes were initially grouped in 12 types, later reduced to 8. 22 December, 2015 Black Sea Rivers Monitoring The WFD chemical monitoring programmes are implemented by the Executive Environment Agency (ExEA) and its sub-divisions, and the collected data are monthly reported to the Black Sea Basin Directorate (BSBD). Hydrological monitoring is carried out by the National Institute of Meteorology and Hydrology (NIMH). For more information on the institutional framework of national monitoring of surface waters in Bulgaria see the project LBS Monitoring Report (http://www.bshotspots.eu/Documents/Deliverables/LBS%20Monitoring%20Final%20Draft.pdf). The Executive Environment Agency – Sofia (ExEA) collects, summarizes and evaluates programs to control the quality of the monitoring data in accordance with the standard BNS EN ISO/IEC 17025 - „General requirements for the competence of testing and calibration” of the Executive Agency “Bulgarian Accreditation Service(EA „BAS”). The following Guidance documents are used in monitoring and assessments: 1. Guidance No 7 - Monitoring under the Water Framework Directive; 2. Guidance No 13 - Classification of Ecological Status; 3. Guidance No 19 - Surface water chemical monitoring; 4. Guidance No 32 - Biota Monitoring. (Reference: http://ec.europa.eu/environment/water/water-framework/facts_figures/guidance_docs_en.htm) The elements, frequencies and stations in surveillance and operational monitoring of BG rivers were initially set by Order N 715/2010. Since 2013, a new Ministerial Order (182/2013) has been implemented. Surveillance monitoring Surveillance monitoring in the Black Sea Basin area covers in total 383 points (stations) for biological monitoring and 65 points8 for physico-chemical monitoring. Of these, 39 are reported to the European Commission through the system WISE (Water Information System for Europe). Operational monitoring In line with the Ministerial Order (182/2013) the following requirements are met: Total 158 points of physico-chemical monitoring in rivers and lakes are established (respectively, 120 points in rivers and 38 in lakes/dams, which means 56 additional points in rivers and 9 in lakes/dams were designated as compared with Order N 715/2010). Operational monitoring in the Black Sea Basin area covers a total of 35 points for hydromorphology. They are almost all reported to the European Commission9 through the system WISE (Water Information System for Europe). Detail information on the BG rivers monitoring is provided in Annex I to this document. The locations of stations for surveillance and operational monitoring as conducted in 2010-2015 and reported to WISE are given in Fig. 9. Initially they were 58, since 2013 the stations became 65 in rivers and lakes (Ministerial Order 182/2013) to improve the BG surveillance monitoring. 9 Only 2 points are outside of this reporting. 8 23 December, 2015 Black Sea Rivers Monitoring Figure 9. Locations of stations for surveillance and operational monitoring in the BG Black Sea Basin rivers in 2010-2015 (as reported to WISE). Note: The map contains information on: Rivers – 104 points for hydrobiological monitoring and 63 points for phyciso-chemical monitoring, as well as 3 automated stations for observation. Lakes and dams – 30 points The Tables presented below contain brief information on the three major domains of BG surface waters monitoring: hydromorphology, physico-chemistry and hydrobiology. 24 December, 2015 Black Sea Rivers Monitoring 1.1. Hydromorphology Hydromorphological quality elements are monitored once per 6 years with the exception of river flow (Table 1). Table 1. Hydromorphological quality elements (same for operational and surveillance monitoring) (Bulgaria) № Quality element Parameters Rivers Lakes 1 River continuity River continuity 6-yearly N/A Quantity and dynamics of river flow monthly monthly Connection with groundwater bodies continuously one month monthly Residence time (for lakes) N/A monthly River depth and change of the width 6-yearly N/A Structure and substratum of river bottom 6-yearly N/A Structure of river zone Variation of lake depth 6-yearly N/A N/A 6-yearly Quantity, structure and substratum of lake bottom N/A 6-yearly Structure of lake shore N/A 6-yearly 2 3 Hydrological regime Morphological conditions 1.2. Physico-chemical and hydrobiological parameters The sampling for physico-chemical parameters (Table 2) includes: basic indicators (I and II category); priority substances and specific pollutants (I category-organic substances, II category – trace metals and metalloids, III category – Others) (Annex I to this document). Table 2. Physico-chemical quality elements (BNS – Bulgarian national standard; RBMP – River-basin management plan) N Parameter 1 2 3 4 5 6 pH T 0C Conductivity, µS/cm Suspended matter (TSS), mg/dm3 BOD5, mgO2/dm3 O2 dissolved, mg/dm3 7 COD, mgO2/dm3 8 N-NH4, mg/dm3 9 10 11 N-NO2, mg/dm3 N-NO3, mg/dm3 N total, mg/dm3 Analytical Method BNS EN ISO 10523 BNS 17.1.4.01 BNS EN 27888 BNS EN 872 BNS EN 1899-1 BNS EN 25813 BNS EN ISO 5814 ISO 6060 ISO15705 BNS ISO 7150-1 BNS ISO 5664 BNS EN 26777 BNS ISO 7890-3 BNS EN 25663 25 Frequency of sampling per month/per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year December, 2015 Black Sea Rivers Monitoring N Parameter Analytical Method 12 13 14 P-PO4, mg/dm3 P total, mg/dm3 Fe, mg/dm3 (dissolved since 2010) 15 16 17 18 Mn, mg/dm3 Total hardness , mg/dm3 CaCO3 TOC, mg/dm3 Zn, µg/dm3 19 20 Cu, µg/dm3 Antracene, µg/dm3 21 Atrazine, µg/dm3 22 Benzene, µg/dm3 BNS EN 26777 BNS ISO 7890-3 BNS EN ISO 6878 BNS EN ISO 6878 BNS ISO 6332 BNS 16777 BNS EN ISO 17294 BNS ISO 6059 BNS EN 1484 ISO 8288 BNS EN ISO 17294-2 ISO 8288 internally validated laboratory methods IVLM 1016/2010 internally validated laboratory methods IVLM 1015/2010 BNS EN ISO 15680 23 Cd, µg/dm3 BNS EN ISO 17294-2 24 Chlorfenvinphos, µg/dm3 BNS EN 12918 25 Chlorpyrifos, µg/dm3 BNS EN 12918 26 1,2-dichloroethane, µg/dm3 BNS EN ISO 15680 27 Dichloromethane, µg/dm3 BNS EN ISO 15680 28 Endosulfan, µg/dm3 29 Fluoranthene, µg/dm3 30 Hexachlorobenzene, µg/dm3 31 Hexachlorobutadiene, µg/dm3 internally validated laboratory methods IVLM 1014/2010 internally validated laboratory methods IVLM 1016/2010 internally validated laboratory methods IVLM 1014/2010 BNS EN ISO 15680 32 HCH , µg/dm3 33 Pb, µg/dm3 34 Hg, µg/dm3 35 Naphthalene, µg/dm3 36 Ni, µg/dm3 37 Nonylphenols, µg/dm3 ISO 8288 BNS EN ISO 17294-2 BNS EN 188571 38 Octylphenols, µg/dm3 BNS EN 188571 39 Pentachlorbenzene, µg/dm3 40 PAH, µg/dm3 41 Simazine, µg/dm3 42 Trichlorobenzenes, µg/dm3 internally validated laboratory methods IVLM 1014/20120 internally validated laboratory methods IVLM 1016/2010 internally validated laboratory methods IVLM 1015/2010 internally validated laboratory methods IVLM 1014/20120 internally validated laboratory methods ILM 1014/2010 ISO 8288 BNS EN ISO 17294-2 internally validated laboratory methods IVLM 1012/2010 BNS EN ISO 15680 26 Frequency of sampling per month/per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 times per year 4 time per year 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) 12 times per year (for six-year cycle of the RBMP) December, 2015 Black Sea Rivers Monitoring The following set of priority substances (Table 3) is monitored at one station only – Kamchia-Poda, for the rest of the BG rivers the choice of priority substances differs depending on the known LBS discharges. The same goes for specific pollutants (Table 3), which choice in sampling depends on the expected contamination of a particular river (see Annex I to this document for details). Table 3. Set of priority and specific pollutants (Bulgaria) Group of substances Parameter Specific pollutants Priority pollutants Anthracene, µg/l Atrazine, µg/l Chlorpyrifos, µg/l 1,2-Dichloroethane, µg/l Dichloromethane, µg/l Flouranthene, µg/l Hexachlorobutadiene, µg/l (Benzo (a) pyrene), µg/l Benzo (b) floroanthene), µg/l Benzo (g,h,i) perylene, µg/l (Benzo (k) fluoroanthene), µg/l Indeno (1,2,3-cd) pyrene, µg/l Simazine, µg/l 1,2,4 – Trichlorobenzene, µg/l Trichloromethane (Chloroform), µg/l Trifluralin, µg/l Prometon, µg/l Prometryn, µg/l Propazine, µg/l Ametrin, µg/l Simetryn, µg/l Terbutryn, µg/l Hydrobiological quality elements (Table 4) include planktonic and benthic organisms, as well as fish. However, phytoplankton is monitored in the Danube River only, as the rest of the BG rivers are small and do not contain a stable plankton community. Table 4. Hydrobiological quality elements (Bulgaria) Biological element Parameter Metrics Phytoplankton (only in the Danube River) Species composition Ratio of main taxonomic groups Ratio of Cyanophyceae to other main groups Number per year Biomass Chlorophyll a Trophic index Ratio of sensitive/indicator species Surface of coverage Blooms frequency Abundance Macrophytes Species composition Abundance 27 Frequency Surveillance Operational monitoring monitoring Twice a year in one of the years of the 6-yearly cycle 6-monthly 6-monthly 6-yearly In two years of the 6- December, 2015 Black Sea Rivers Monitoring Biological element Parameter Metrics Surveillance monitoring Trophic status Macrophytes index Biotic diatoms index Macrozoobenthos (invertebrates) Species composition, abundance Bacterial maths Species composition, abundance Fish Species diversity Species composition Phytobenthos (microalgae) Abundance Health status Size structure of indicator species Presence/absence Ratio of main taxonomic groups Biotic index Diversity index (H) Share of sensitive/indicator species Density, biomass, catches Share of fishes with signs of diseases Species-specific numbers of size classes 6-yearly 6-yearly Frequency Operational monitoring yearly cycle (once per year) In two years of the 6yearly cycle (once per year) In two years of the 6yearly cycle (once per year) 6-yearly In two years of the 6yearly cycle (once per year) 1.3. Calculation of loads Until 2010, BG riverine loads stemming to the Black Sea have been calculated for 10 relatively large rivers and the positions of the stations used in such calculations, are given in Table 5 and Figure 10. Table 5. BG Rivers where loads to the Black Sea are calculated River name r. Batova - mouth r. Kamchia - "Poda" r. Dvojnitsa - mouth r. Hadjijska – v.Tankovo r. Aheloj - mouth r. Ropotamo – v.Veselie r. Diavolska – 5 km before Primorsko r. Karaach - mouth r. Veleka – v. Sinemoretz r. Rezovska - mouth Code of station BG2DO831MS001 BG2KA00119MS001 (BGRI1) BG2SE41MS003 BG2SE61MS005 BG2SE81MS008 BG2IU291MS003 BG2IU411MS001 BG2IU6915MS002 BG2VE111MS001 BG2RE855MS002 Coordinates Type of media 43,35780 28,05638 43,0198010 27,82144 42,82643 27,87675 42,70105 27,65533 42,63411 27,64047 42,31077 27,62380 42,26889 27,66492 42,19486 27,74808 42,06050 27,96669 41,98053 28,02458 river river river river river river river river river These are the coordinates for physico-chemical monitoring, while the flow is measured at Grozdevo village. With coordinates: 27.540917; 43.031557. Statistically proven is that the flow at Grozdevo village does not differ from the one measured at the Kamchia Poda station. 10 28 December, 2015 Black Sea Rivers Monitoring Figure 10. Monitoring stations at BG rivers for calculation of loads stemming to the Black Sea Currently, in line with the Ministerial Order 1/2011, there is only one station, which allows calculating riverine loads directly stemming to the Black Sea – at Kamchia River, Poda station (with the details of flow measurement specified above). There is no specific regulation, which would prescribe how to calculate river loads. The following formula is used: Ly = Qmean x Cmean x 31.536 Where: Ly = annual load (t/yr) Qmean = arithmetic mean of all daily flow data (m3/s) Cmean = arithmetic mean of all measured concentrations (mg/l) 29 December, 2015 Black Sea Rivers Monitoring Except Kamchia, all BG rivers contribute with negligible loads to the overall BS pollution/nutrient enrichment. Thus, BG reports to the BSC the Kamchia loads in separate, and for the rest of the BG rivers their cumulative load. 1.4. Other types of monitoring Apart from the WFD, there are other EC Directives, which require monitoring at rivers, as mentioned above. In sensitive areas (E91/271/EC – WWTP Directive) – the whole Black Sea Basin is identified as a sensitive area11 (Fig. 11). The monitoring includes sampling for mineral forms of nitrogen and phosphorus. Figure 11. Monitoring stations in rivers and lakes (Bulgarian Black Sea Basin) for inorganic forms of nitrogen and phosphorus (sensitive areas), (re-drawn from the Black Sea Basin Management Plan, 2009) BG Ministerial Order 970/28.07.2003 requires the identification of sensitive areas in Bulgarian water bodies, http://www3.moew.government.bg/files/file/Water/OPVodi/Kanalizacionni_sistemi/Zapoved_za_opredeliane_na_chuvstvitelni _zoni.PDF. The procedures of ‘sensitive areas’ identification is quite complicated and falls under the requirements of many BG legal and policy documents (e.g. Water Law, Ministerial Order № 6/09.11.2000, Ministerial Order №1/11.04.2011, Ministerial Order № 2/08.06.2011, and others). 11 30 December, 2015 Black Sea Rivers Monitoring In vulnerable zones (Fig. 12) - nitrates from agricultural sources (91/676/EC12 - concerning the protection of waters against pollution caused by nitrates from agricultural sources (Nitrates Directive)) Figure 12. Monitoring stations for identification of nitrates levels in surface waters in the Bulgarian Black Sea Basin (vulnerable areas), (re-drawn from the Black Sea Basin Management Plan, 2009) This Directive is transposed into the BG national legislation by Ministerial Order № 2/13.09.2007 and other related national policy documents. 12 31 December, 2015 Black Sea Rivers Monitoring Areas for protection of valuable fish and shellfish species (Freshwater Fish Directive 2006/44/ЕC and Shellfish Waters Directive 2006/113/ЕC, transposed into BG legislation by Ministerial Ord № 4/20.10.2000 and others), (Fig. 13). Figure 13. BG monitoring stations for tracing environmental status in protection of valuable fish and shellfish species (re-drawn from the Black Sea Basin Management Plan, 2009) 32 December, 2015 Black Sea Rivers Monitoring Birds Directive (Nature2000 sites; Council Directive 2009/147/EC: http://ec.europa.eu/environment/nature/legislation/birdsdirective/index_en.htm) and protected areas as defined in Art. 6 of the WFD, (Fig. 14). Figure 14. BG monitoring stations for tracing environmental conditions in protection of birds and their habitats and as defined in Art. 6 of the WFD (re-drawn from the Black Sea Basin Management Plan, 2009) 33 December, 2015 Black Sea Rivers Monitoring Habitats Directive (Council Directive 92/43/EC: http://ec.europa.eu/environment/nature/legislation/habitatsdirective/index_en.htm) and protected areas as defined in Art. 6 of the WFD, (Fig. 15). Figure 15. BG monitoring stations for tracing environmental conditions in protection of NATURE2000 sites under the Habitats Directive and as defined in Art. 6 of the WFD (re-drawn from the Black Sea Basin Management Plan, 2009) In the 2009 Black Sea Basin Management Plan (BSBMP), a separate monitoring program for surface water in surface water protected areas and areas designated for protection of water-dependent habitats and species was not planned. In the second BSBMP (2015 draft, for 2016-2021) for surface water bodies, which fall entirely or partially in water protected areas and in areas designated for protection of water-dependent habitats and species, monitoring of 34 December, 2015 Black Sea Rivers Monitoring basic physicochemical and biological quality elements for evaluation of their ecological and chemical status is planned to trace the spatial and temporal variability of certain indicators. The latter are those related to favorable conservation status of present species and habitats in the monitored areas. Drinking water (Drinking Water Directive 80/778/EEC, as amended by Directive 98/83/EC and transposed into BG legislation by Ministerial Order № 12/18.06.2002), (Fig. 16). Figure 16. BG drinking water categories 1 and 2 (re-drawn from the Black Sea Basin Management Plan, 2009) Note: the categories 1 and 2 refer to the level of treatment required to ensure surface waters are in a quality required for drinking. Relevant monitoring is organised by the BG Black Sea Basin Directorate (BSBD13) to identify these categories (A1, A2, and there is also an A3 category) and BSBD publishes reports on the result of this monitoring on its webpage (http://www.bsbd.org/bg/) on an annual basis. 13 BSBD prepares the monitoring programmes, where stations of sampling, parameters and frequencies are specified. 35 December, 2015 Black Sea Rivers Monitoring Bathing water (Directive 2006/7/EC repealing Directive 76/160/EEC) Bathing water in BG rivers is not specifically monitored. Real-time monitoring The aim of the real-time monitoring is to compliment the in situ observations, as ordered by the Minister of Environment (№715/02.08.2010) and improve the assessments of the state of the surface waters. Additionally, the collected data are used for: early warning of floods and accidental pollution; control on the minimum allowable flow of the rivers; constant tracing of the quality of transboundary rivers – e.g. Veleka and Rezovska. Real-time monitoring is a domain of the rivers monitoring, which is under fast development, and especially well it is considered in attempts to ensure early warning of floods. For instance, in the area of Bourgas Municipality, 24 new automated stations are planned for establishment in 2015-2016 (Fig. 17). Figure 17. BG monitoring stations for automated observations related to early warning of floods (Bourgas Municipality, Bulgaria) 36 December, 2015 Black Sea Rivers Monitoring Where: - river level, flow velocity and temparature; - rainfall and river level; - rainfall; Previously, automated stations for surface waters were provided by a BG-Italian project in the frames of the PHARE Programme (BG2006/018.343.06.03 “Strengthening of the surface waters monitoring in BG). Currently, there are 4 automated stations established in the Black Sea basin, as reflected in the Table below: Table 6. List of automated stations for monitoring of surface waters in the Black Sea basin (Bulgaria) N 1 2 3 4 Code VAR-02 VAR-04 VAR-03 VAR-01-S Location Obzor Sinemoretz Rezovo Poda River Dvoinica Veleka Rezovska Kamchia Coordinates N 42,49431 42,03360 41,58501 43,01182 E 27,51518 27,57595 28,01293 27,532019 Type of station Sensors Sensors Sensors Automated sampling The stations are equipped with sensors to measure the following parameters: meteorology: rain, wind velocity and direction, air temperature and humidity, atmospheric pressure and solar radiation; general physical and inorganic chemistry: water temperature, pH, conductivity, salinity, oxygen saturation and dissolved oxygen, total suspended solids, nitrites, nitrates, ammonium, phosphates; hydromorphological – water level and water quantity. A central system is established to collect the data from all stations, conduct quality control, store, manage and produce data products to visualise the obtained results. Results of observations in 2011 are presented in Figures 18 and 19. Figure 18. Results of real-time observations in the Kamchia River - Poda in 2011 (Bulgaria) 37 December, 2015 Black Sea Rivers Monitoring Figure 19. Results of real-time observations in the Rezovska River in 2011 (Bulgaria) 1.5. Data management and assessments under the WFD and others In Bulgaria, the data collected under rivers monitoring is kept in Excel files, there is no specific software to manage them. The data are not online and are not easily accessible by public. However, data are provided upon request in line with the BG Law on access to data/information as also required by the Aarhus Convention. The status of rivers is being annually assessed in line with the WFD requirements. These reports are available on the BSBD webpage in Bulgarian (http://www.bsbd.org/bg/index_bg_1668393.html). "Good chemical status" of surface water is a condition in which contaminants do not exceed the set quality standards of the environment. In assessing the ecological status, data on the main hydromorphological and basic physico-chemical parameters, specific and priority substances, as well as hydrobiological indicators are analysed. Initially, there were no quality standards for specific pollutants in evaluation of their content in inland water bodies, some appeared recently and current evaluations are carried out according to the rules set in Regulation № H-4/14.09.2012 (amended by State Gazette 79/2013) on indicators and standards for determining the quality of inland surface waters. The assessment of chemical status for priority substances follows the standards set by the EC Directive on environmental quality standards in the field of water policy (2008/105/ЕС, as amended in 2013/39/EС), and transposed in BG, State Gazette 88/2010). In ‘chemical status’ two classes are used – ‘good’ and a ‘bad’ status, where the standards set are not met. Initially, for ‘Good hydromorphological status’ there were no standards set, however, currently indicators are set in the Regulation № H-4/14.09.2012. In hydrobiology, a single index was chosen to evaluate the status of rivers – Macrozoobenthos index (for the classes identified see Table 7). The Macrozoobenthos index takes into consideration both species diversity and species abundance or biomass (for further details on the subject look in i-net for information on the indices AMBI and M-AMBI, for instance: https://www.google.co.za/search?q=Directive+2006%2F113%2F%D0%95C&rlz=1C1VASM_enZA571ZA638&oq =Directive+2006%2F113%2F%D0%95C&aqs=chrome..69i57.332j0j8&sourceid=chrome&es_sm=93&ie=UTF8#q=M-AMBI+index). 38 December, 2015 Black Sea Rivers Monitoring Table 7. Classification of water bodies status according to the Macrozoobenthos index (Bulgaria) River type Very good All types Small, plain and sub-mountain type, substrate – pebble, sand, gravel good moderate bad Very bad 5, 4-5 4, 3-4 3, 2-3 2, 1-2 1 5, 4-5, 4 3-4 3, 2-3 1-2, 2 1 ‘Ecological status’ – as mentioned above, in this assessment all findings are compiled (on hydromorphology, chemistry and biology) and each water body is assigned with one of the fifth classes of status: very good, good, moderate, bad, very bad (Table 8). Table 8. Classes of status in assessments under EC Directives EC Directive Habitats Directive Assessment of status Satisfactory status of conservation Not satisfactory Bad WFD Very good Good Moderate Bad Very bad (ecological status) WFD Good chemical status Good chemical status is not achieved (chemical status) Example of GES (ecological status) assessment under the WFD is given in Fig. 20. 39 December, 2015 Black Sea Rivers Monitoring Legend Ec ologic al status of water bodies in rivers and la kes Good Moderatelly Good Poor Bad No Data Not analyzed Areas Ec ologic al status - coastal marine waters Ba d Good Mo d e ra te Po o r 1m ile zone 12 m iles zone Figure 20. Ecological status of water bodies in rivers and lakes of the Bulgarian Black Sea Basin in 2009 (re-drawn from the Black Sea Basin Management Plan, 2009) According to the set environmental targets, most of the BG Rivers were expected to achieve good ecological status by 2015. Exceptions are the rivers: Fakiiska, Rusokastrenska, Chukarska, Kamchia, Chiradji, Madara, Provadiiska, and a few other small rivers in the Black Sea Basin. Programme of measures for BS rivers is included in the Black Sea Basin Management Plan (2009, for the period 2010-2015), which was updated in 2015 (draft prepared for public consolations). In this updated draft Black Sea Management Plan (2015), the following status of the Black Sea (Fig. 21) was taken into consideration: 40 December, 2015 Black Sea Rivers Monitoring Figure 21. Ecological status of Black Sea water bodies as per 2014 (Bulgaria) 41 December, 2015 Black Sea Rivers Monitoring The updated Black Sea Basin Management Plan (draft 2015) was preceded by a robust analysis of pressures and impacts, where all important land-based sources in Bulgaria were re-evaluated to outline priorities in Black Sea protection in the period 2016-2021. Conclusions The monitoring of BG rivers is compliant with EC legislation/policy (e.g. WFD and its Guidelines). However, there is a major shortcoming in the BG rivers monitoring and it is related to evaluation of riverine loads stemming to the Black Sea. NIMH measures river flows at 7 rivers in the BS Basin. And, among these flows, there is only one which is currently measured at the Black Sea entrance of BG rivers (or nearly). It is for the Kamchia River (Poda station for phisico-chemistry with a flow measurement at another station, which is considered eligible to calculate loads). And only this Kamchia Poda station (since 2010) allows calculating riverine loads of nutrients and pollutants discharged to the Black Sea from Bulgaria. The rest of the BG rivers cannot be evaluated for their loads stemming to the Black Sea. They are surely not large (the BG rivers are small except Kamchia), however, they have local effects, which need to be also traced. 42 December, 2015 Black Sea Rivers Monitoring GEORGIA In GE, hydrological observations started in 1930s, and in the 1950s the monitoring was already regular. In the 1960s, practically all major and medium size rivers were covered by stations. In 1980s the number of stations and monitored parameters reached their maximum – 170 stations14 and 56 parameters, including hydrological, physical, chemical and hydrobiological, were monitored at 72 rivers. The GE system at that time was an integral part of the larger Soviet System of water monitoring (the so called Hydromet system). The GE monitoring system started deteriorating in the 1990s with the collapse of the Soviet Union and economic recession of GE. The monitoring network drastically shrank (Fig. 22), stations were closed down and the capacities to undertake water quality analysis significantly reduced. Currently, the number of monitoring points increases with every year. In 2014 water quality monitoring was undertaken monthly at 69 stations - on 32 rivers at 61 river sections and at 8 lakes. In total 36 physical, chemical and 3 microbiological parameters are measured. Majority of organic substances and priority substances defined by the WFD is not measured. Hydrological observations are conducted at 29 stations. From these only 7 stations are adequately equipped. Figure 22. Rivers monitoring network of Georgia (Source: NEA, department of Hydrometeorology), (Legend – blue triangles – planned automated stations (posts), empty triangles – closed stations; red triangles - working stations at present) 14 Historical data are preserved for 145 hydrological stations. 43 December, 2015 Black Sea Rivers Monitoring The rivers monitoring is regulated by: 1. Law on Water of Georgia (1997) specifies only (Art.80) that the state water monitoring is exercised within the united state environmental monitoring system. The new “Law on Water Resources Management” was drafted during 2013-2014. It is based on the principles and approaches of the WFD and is being now under consideration. This draft Law defines that the State Monitoring System of water resources should include observations on the hydrological, hydrochemical, ecological and hydromorphological conditions of surface water and groundwater bodies. Also, data analysis of water quantitative and qualitative conditions ate mentioned - they aim to deliver information on water quality, pressures on water resources (natural and anthropogenic), water energetic potential, prediction of calamities (flood, mudflows, landslides etc.), etc. Thus, the Water Resources State Monitoring System includes the entire national set of monitoring activities, where hydrochemical, hydrobiological and hydromorphological monitoring programs are prepared and implemented. 2. Law an Environment Protection of Georgia (1996) states that state environmental monitoring is a responsibility of the Ministry of Environment and public should have access to the monitoring results In Georgia, rivers monitoring is currently under the responsibility of the National Environmental Agency (NEA). It is carried out by 3 regional divisions of NEA: in Adjara, Kutaisi (serving Western Georgia), Tbilisi (serving Eastern Georgia) and Batumi (South Georgia). These divisions are also responsible for the data management. Research and data collection at rivers are also carried out by various other organizations (e.g. Research Laboratory in Poti), however, they are neither regular nor comprehensive. There is no national rivers monitoring strategy, though “PROPOSED FRAMEWORK OF WATER MONITORING STRATEGY AND ACTION PLAN” was drafted in 2008 within the Finnish Georgian Project “Development of Environmental Monitoring and Management Systems in Georgia”. Initial draft of the Water Monitoring Strategy in Georgia has been prepared in 2015 within the frames of the EPIRB project The requirements of WFD are reflected in the new draft “Law on Water Resources Management. The draft Law will be submitted to the Parliament of Georgia for adoption in autumn 2015. Also, sub-law “Rules for planning and implementation of water resources monitoring” is under development. Initially, WFD principles and practises were introduced with the KURA-II project, continuing under the KURA-III project at pilot areas of the Alazani and Khrami-Debed River basins. In addition, a project funded by the Finish Government has also built capacity in monitoring on the Rioni River and the UNDP/GEF project – Reducing Transboundary Degradation in the Kura-Aras River Basin launched pilots as a demonstration activity on several locations of the Kura within Georgia. The EPIRB project 15continued building capacity in monitoring at GE rivers, with pilot studies in the ChorokhiAdjaristksali Basin (http://blacksea-riverbasins.net/en/pilot-basins/chorokhi-adjaristskali-basin). Prior planning the One of the main objectives of the EPIRB project is to improve availability and quality of data on the ecological, chemical, and hydro-morphological status of transboundary river basins Including groundwater. The main expected results are: Increased capacities of the respective national authority (National Environmental Agency of the Ministry of Environment and National Resources Protection of Georgia) for the WFD compliant monitoring of water quality including groundwater; quality assurance procedures in laboratories in place. 15 EPIRB Milestones: Assessment of current data and assessment tools availability Surveys to assist development of ecological monitoring status systems WFD‐compliant monitoring programmes designed for the pilot basin (the Chorokho-Ajaristskali river basin) Determination of threshold values for classifying different water body types Training programme on laboratory QA/QC Training programme on Biological and Hydro--‐morphological monitoring 44 December, 2015 Black Sea Rivers Monitoring monitoring, water bodies were identified and which of them were under risk also. Recently, this project prepared Programmes for operational and surveillance monitoring (“Surface Waters Monitoring program for the ChorokhiAjaristskali River Basin”, see http://blacksea-riverbasins.net/en/downloads-librarysearch?f[0]=field_country%3A34&f[1]=field_downloads_type%3A64&f[2]=field_downloads_type%3A59). The monitoring programme for the Chorokhi-Ajaristskali river basin was designed to meet the stated requirements of the WFD and related CIS Guidance Documents. The WFD sets out three types of monitoring programmes: surveillance, operational and investigative, as mentioned already in the Introduction of this Report. Surveillance monitoring So far, total 11 sampling locations were selected to be representative for the Surveillance monitoring programme in the Georgian Chorokhi-Ajaristskali river basin under the WFD requirements (Figure 23). Figure 23. Surface waters surveillance monitoring in Georgia (locations marked in green) Sampling methods and devices: based on European Standards and recommendations should be used in the monitoring programmes of Georgia. The biological quality elements incorporated for rivers are: Macroinvertebrates, Phytobenthos, Macrophytes and Fish; for lakes: Macroinvertebrates, Phytoplankton, Macrophytes and Fish. 45 December, 2015 Black Sea Rivers Monitoring Note: The samples have to be processed for abundance and composition of all biological quality elements up to Genus/Species level. For Ichthyofauna only migratory fish species need to be considered. The physico-chemical quality elements, for both rivers and lakes, include basic parameters, priority and specific substances as specified in EC legislation. EN ISO and other international standards should be applied for the analysis of the water samples. The hydromorphological quality elements include: Hydrological regime; River continuity; Morphological conditions. Operational monitoring Total 8 sampling locations for rivers were identified to be monitored under the Operational Monitoring for the Chorokhi-Adjaristskali River basin. The List of quality elements monitored in the Operational Monitoring Programme of the Chorokhi-Adjaristskali River basin (rivers) is presented in the Table below. Table 9. Parameters included in the Operational Monitoring Programme of surface waters in Georgia Parameter Water Temperature Dissolved Oxygen pH Conductivity Hardness Colour Ortho-Phosphates Nitrate Ammonium Chloride Sulphate Total suspended solids Biochemical oxygen demand (BOD5) Chemical oxygen demand (COD - dichromate) Oil substances Copper Zinc Macroinvertebrates River flow Unit oC mgO2/l pH units μS/cm mg/l CaCO3 visual mg P/l mg N/l mg N/l mg/l mg/l mg/l mgO2/l mgO2/l visual μg/l μg/l indices Daily Mean Flow (m3/s) Total 23 rivers and one lake are currently (as per 2015) monitored in the GE Black Sea Basin (Table 10) on a relatively regular basis, from which at 22 sites the samples are taken once a month, others – 2-4 times per year though some of them with a very limited list of parameters. 46 December, 2015 Black Sea Rivers Monitoring Table 10. Black Sea Basin rivers and lakes monitored in Georgia N 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Name of river Rioni Jojora Kvirila Ogaskura Tskhenistskali Kintrishi Korolistskali Qubastskali Bartskhana Cherokhi Adjaristskali Tkibula Lukhuni Khanistskali Lagoba Gubistskali Chkherimela Dzirula Supsa Natanebi Choloki Paliastomi (Lake) Chakvistskali Medjinistskali Number of sampling stations 6 1 4 2 5 21 1 1 1 1 2 2 3 1 1 1 1 1 1 1 1 1 1 1 The following Guidelines on standard operational procedures are recognised in GE rivers monitoring: Surface Water Quality Monitoring: Guideline Document for Decision Makers (EU project “Transboundary River Management for the Kura river basin ”(2008-2012); Good Laboratory Practice Guidelines for Sampling and Analysis (EU project “Transboundary River Management for the Kura river basin ”(2008-2012); Introduction to Biological Monitoring of Water Quality (EU project “Transboundary River Management for the Kura river basin ”(2008-2012); Field Survey Technical Guidelines (EU project “Transboundary River Management for the Kura river basin ”(2008-2012); Guidelines for Monitoring the Chemical Status of Surface Water Bodies (EPIRB project, 2012-2016); ISO and EPA methods of sampling and sample analyses. 1.1. Hydromorphology In Soviet times, hydromorphology was under monitoring at 145 hydrological stations. This monitoring is currently not widely introduced as a regular practice into GE rivers monitoring - there are only 9 river cross-sections, where water runoff, flow currents, depth and width variations are occasionally observed. Since 1990 monitoring on rivers hydromorphology was mostly exercised as a demonstration practice under the various international projects mentioned above. Collecting morphological information (Table 11): continuity of river streams, natural and artificial barriers, composition of river beds, ground cover, partial size and material, coarse wood debris, etc. is the responsibility of the NEA, formerly Hydromet. The monograph “Гидрографические описания рек и озер” (Hydrographical 47 December, 2015 Black Sea Rivers Monitoring descriptions of rivers and lakes) of the series “Water resources of USSR” contains morphological information, including longitudinal profiles of river beds and banks of many of the Georgian rivers. Table 11. Hydromorphological parameters observed in GE № Quality element Parameters Rivers Lakes 1 River continuity River continuity Yes, within 300 m of monitoring stations N/A Quantity and dynamics of river flow Yes N/A Connection with groundwater bodies No No 2 Hydrological regime Residence time (for lakes) 3 Morphological conditions No River depth and change of the width Yes N/A Structure and substratum of river bottom No N/A Structure of river zone Variation of lake depth Quantity, structure and substratum of lake bottom Structure of lake shore No N/A N/A No N/A No N/A No Note: Yes means in projects mainly, thus, not as a sustainable practice. 1.2. Physico-chemical and hydrobiological parameters Major physico-chemical parameters of the GE monitoring are enlisted in Table 12. Table 12. Physico-chemical parameters observed in GE rivers monitoring Parameter Temperature Transparency Total Suspended Solids pH Dissolved Oxygen Biological Oxygen Demand (BOD5) Nitrite Nitrogen Nitrate Nitrogen Ammonium Nitrogen Orthophosphate Sulphate Chloride Potassium Sodium Calcium Magnesium Conductivity Salinity Standard applied EPA 2130)1998 SFS-EN 872 EL. metrical (EPA 2540)1998 ISO 5815 ISO 10304-1 :2007 ISO 10304-1 :2007 ISO 7150-1 ISO 10304-1 :2007 EMEP EMEP ISO 9964 ISO 9964 ISO 7980 ISO 7980 EPA2520-1998 ISO 788-1985 EPA2520-1998 d 48 Frequency 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year 1 per month / 12 per year December, 2015 Black Sea Rivers Monitoring Parameter Iron Zn, Cu, Pb, Co, Ni, Mn Standard applied ISO 6332 ISO 8288 Frequency 1 per month / 12 per year 1 per month / 12 per year Among pollutants, regularly observed are only: Trace metals: Zinc, Copper Other metals: iron, manganese Organic micropollutants: hydrocarbons, polycyclic aromatic hydrocarbons, pesticides The laboratories apply ISO and US-EPA methods for analysis of general conditions, Annex VIII pollutants and trace metals; the methods for analysis of organic micropollutants are not yet formalised. There is no tradition in (routine) monitoring of hydrobiological parameters in fresh surface waters outside the scientific community. Initially, as mentioned above, WFD principles and practises were introduced with the KURA-II project, continuing under the KURA-III project. The project funded by the Finish Government has also dealt with hydro-biological monitoring on the Rioni River and the UNDP/GEF project – Reducing Transboundary Degradation in the Kura-Aras River Basin launched hydrobiological sampling as a demonstration activity on the Kura River (Caspian Basin). The EPIRB project included hydrobiological monitoring in its pilots (Chorokhi-Adjaristskali Basin), dealing mostly with benthos (macroalgae and invertebrates). Thus, so far hydrobiological monitoring is not introduced as a regular practice in GE. . 1.2. Calculation of loads There is no special methodology on calculation of river loads in GE. Georgia is reporting to the BSC on 4 rivers: Chorokhi, Rioni Supsa and Khobi. The loads for these rivers are calculated based on the information (annual statistic reports) submitted by the water users - discharges of different pollutants (t/year). Unfortunately, these data are rather incomplete. Currently, data on river discharges (measured flow) and selected water quality parameters, at locations close to river mouths, there exist for the Chorokhi and Rioni Rivers only. So, for these 2 rivers the formula Ly = Qmean x Cmean (as used in Bulgaria, for instance) could be applicable. 1.4. Other types of monitoring Protected areas (Fig. 24) 49 December, 2015 Black Sea Rivers Monitoring Figure 24. Protected areas in Georgia There is no special monitoring programs for the rivers located within protected areas. Biodiversity monitoring studies in protected areas are mainly conducted by university research departments and NGOs in the frameworks of international projects. Drinking water Since 2006, the National Food Agency of the Ministry of Agriculture has conducted the control on drinking water safety parameters ensuring the relevant drinking water quality monitoring (Figure 25) is being in place. The Agency undertakes its monitoring activity according to its annual plan, in which monitoring requirements are defined in national legislation. Therefore, the National Food Agency collects samples annually at the locations of drinking water treatment and checks results against the standards defined in national legislation. The frequency of sampling increases in cases of registered non-compliance and in emergency situations (e.g. floods, spills, malfunction of treatment facilities, etc.). General procedures are given in the Order of the Minister of Agriculture N2-143 on the approval of risk assessment and communication procedures in the framework of risk analysis. The procedures in case of non-compliance and emergencies are also defined. 50 December, 2015 Black Sea Rivers Monitoring Figure 25. Georgian drinking water monitoring: National Food Agency samples collected in 2009–2014 Real-time monitoring For water discharge measurements an Acoustic Doppler Current Profiler (ADCP) and old equipment (cable ways + current meters) are used. All current meters are calibrated biennially. Automatic stations for water level and water temperature monitoring are installed at 15-20 hydrological sites, but are not yet operating. 1.5. Data management and assessments under the WFD and/or others Data management is ensured in a special database (Slovenian software), which is not available online. Regular assessments are not taking place, and there is no national regulation, which would specify quality elements for rivers. There are, though, standards for 1346 chemical parameters (order of the Ministry of Labor, Health and Social Affairs, 2001), but they are inherited from Soviet times and are very much different from those specified in EC legislation (e.g. 2013//39/EС). Development of a new by-law “On Water Quality Ecological Standards” is planned for 2016. Assessments of Pressures/Impacts are problematic, thus, programmes of measures, if any, are not scientifically grounded. River-basin management plan has been drafted only for the Chorokhi-Ajaristskali River Basin (EPIRB Project) and is now submitted for public consultations (available at the www.moe.gov.ge). In accordance with AA (Association Agreement of GE with EC, 2014), Georgia has to finalize preparation of river basin management plans for other river basins in the country by 2024. Conclusions The surface waters monitoring in GE is not compliant with EC legislation, the hydrological network is critically low. Hydromorphological parameters are measured partially and rarely, and hydrobiology parameters are sampled only in pilot studies under international projects (not sustainable practice). The List of physico-chemical parameters is short as compared to the monitoring carried out in other BS countries. Sampling of sediments and biota for identification of contaminants is not carried out. 51 December, 2015 Black Sea Rivers Monitoring Riverine loads to the Black Sea are often calculated using long-term annual averages of river flows as measurements of flows on a regular basis are often missing. The used equipment in rivers monitoring is largely outdated and real-time monitoring is hardly developed. Thus, the riverine loads of Georgia to the Black Sea are poorly assessed and there is no methodology which would instruct how to calculate those loads. ROMANIA In Romania, the National System of Integrated Environmental Monitoring (SNMIMR) was established in 1990. The system functioning is under constant improvement with the support of relevant international institutions and funding. Rivers monitoring is part of the SNMIMR, and in the Black Sea Basin there is only one river under control – the Danube. "Romanian Waters" National Administration (Dobrogea Litoral) is the authority responsible for the SNMIMR in the Dobrogea-Litoral river basins area, including data management and reporting at various levels, as well as preparation of regular assessments. Acting legislation/policy documents are enlisted below: Water Law no. 107/1996 amended by GD no. 948/1999, Law no. 404/2003, Law no. 310/2004, Law no. 112/2006, Government Emergency Ordinance no. 130/2007, GEO 3/2010 approved by Law no. 146/2010, GEO 64/2011, GEO 71/2011 and GEO 69/2013 Decision no. 188 of 28 February 2002 approving the rules on the conditions for discharge of wastewater into the aquatic environment Decision no. 352 of 21 April 2005 on amending and supplementing Government Decision no. 188/2002 approving the rules on the conditions for discharge of wastewater into the aquatic environment GD no. 351/2005 regarding the approval of the phasing out of discharges, emissions and losses of priority hazardous substances Decision no. 1038 of 13 October 2010 amending and supplementing Government Decision no. 351/2005 regarding the approval of the phasing out of discharges, emissions and losses of priority hazardous substances. Order no 31/2006 for the approval of the Manual (Handbook) of the Modernization and Development of the Integrated Monitoring System of Waters in Romania (SMIAR) MO no. 245/26.03.2005 approving the methodology for risk assessment of hazardous substances in List I and II of priority/hazardous priority substances to the aquatic environment Order no. 1072 / 19.12.2003 approving the organization of national support integrated surveillance monitoring, control and decision to reduce the contribution of pollutants from agricultural sources to surface water and groundwater and approving appropriate surveillance and control program and procedures and instructions for data monitoring assessment of surface and groundwater 52 December, 2015 Black Sea Rivers Monitoring MO no. 44/2004 approving the Regulation on water quality monitoring for priority/priority hazardous substances GD no. 964/2000 on the approval of the Action Plan for water protection against pollution caused by nitrates from agricultural sources amended by Government Decision no. 1360/2005 National management plan of waters in Romania – 2004 River basin management plans in Romania – 2009 Manual (Handbook) of the Modernization and Development of the Integrated Monitoring System of Waters in Romania (SMIAR) – 2006 Order No. 161/2006 for the approval of the Normative basis for the classification of the quality of surface waters in order to establish the ecological status of water bodies The Monitoring on surface waters in Romania includes programmes of surveillance, operational (sensu WFD for water bodies at risk) and various investigations, the latter for research purposes. A distinctive feature of the RO coast is the availability of many lakes, lagoons and the large Danube Delta. The hydrografic network includes not only rivers and lakes, but also artificial channels - the Danube-Black Sea channel (64.2 km) and Poarta Alba-Midia-Navodari channel (27.5 km) and also irrigation channels from Carasu Valey (Fig. 26). 53 December, 2015 Black Sea Rivers Monitoring Figure 26. Rivers of the RO BS coast 54 December, 2015 Black Sea Rivers Monitoring The monitoring network of surface waters in the Dobrogea catchment area of RO is presented in Fig. 27. Figure 27. The monitoring network of surface waters in the Dobrogea catchment area (Romania) For rivers, the sections included in surveillance monitoring of the Danube River, Danube Delta and River Dobrogea Area are 35. For natural river water bodies 11 sections were selected, and in strongly modified river water bodies 24 monitoring sections were defined. In operational monitoring (water bodies at risk sensu the WFD) the number of monitored sections is 17: all 17 sections are located in natural water bodies. 55 December, 2015 Black Sea Rivers Monitoring Investigative monitoring program is applied where necessary to complement the data regarding water quality, and new evaluation methods for impact assessments to develop. Figure 28 presents the monitoring programs from the relevant sections as monitored in 2013. Figure 28. The network for monitoring of surface water quality in the Dobrogea catchment area (Romania) in 2013 56 December, 2015 Black Sea Rivers Monitoring The parameters for monitoring of surface waters under the Waters Integrated Monitoring System in Romania are enlisted below: a) physico-chemical parameters General (G) - temperature, conductivity/fixed residue, pH, alkalinity, suspended matter, color, turbidity Organic substances (SO) - dissolved oxygen, COD – Mn, COD-Cr, BOD5, TOC, COD Nutrients (N) - nitrates, nitrites, ammonia, Ntot, orthophosphate, Ptotal, chlorophyll "a" Heavy metals (SP-MG) - Cd, Ni, Hg, Pb and its compounds Organic micro-pollutants (SP-MO) from GD no 351/2005 GD on the approval of Program for gradually disposal of discharges, emissions and losses of priority hazardous substances, amended by Government Decision no. 783/2006, GD no. 1038/2010 (see tables below) Pollutants (AP) in list I and II of the GD 351/2005 amended by Government Decision no. 783/2006, GD no. 1038/2010 (Table 13), and other pollutants specific to river basin such as iron, manganese, chloride, sulphate, fluoride, phenols, active anionic detergent, AOX (Table 14). Table 13. Priority substances (list I) (according to GD no. 1038/2010) (Romania) No CAS number EU number Name of priority substance 1 15972-60-8 240-110-8 Alachlor 2 120-12-7 204-371-1 Anthracene 3 1912-24-9 217-617-8 Atrazine 4 71-43-2 200-753-7 Benzene 5 n.a. n.a. Brominated diphenylethers 6 7440-43-9 231-152-8 Cadmium and its compounds 7 85535-84-8 287-476-5 C10 – 13 chloralkanes 8 470-90-6 207-432-0 Chlorfenvinphos 9 2921-88-2 220-864-4 Chlorpyrifos 10 107-06-2 203-458-1 1,2-Dichloroethane 11 75-09-2 200-838-9 Dichloromethane 12 117-81-7 204-211-0 Di(2-ethylhexyl) phthalate (DEHP) 13 330-54-1 206-354-4 Diuron 14 115-29-7 204-079-4 Endosulfan 959-98-8 n.a. alpha-endosulfan 15 206-44-0 205-912-4 Flouranthene 16 118-74-1 204-273-9 Hexachlorobenzene 17 87-68-3 201-765-5 Hexachlorobutadiene 18 608-73-1 210-158-9 Hexachlorocyclohexane 58-89-9 200-401-2 (gamma-isomer,lindane) 19 34123-59-6 251-835-4 Isoproturon 20 7439-92-1 231-100-4 Lead and its compounds 21 7439-97-6 231-106-7 Mercury and its compounds 22 91-20-3 202-049-5 Naphthalene 57 December, 2015 Black Sea Rivers Monitoring No CAS number EU number Name of priority substance 23 7440-02-0 231-111-4 Nickel and its compounds 24 25154-52-3 246-672-0 Nonylphenols 104-40-5 203-199-4 (4-(para)-nonylphenol) 1806-26-4 217-302-5 Octylphenols 140-66-9 n.a. (para-tert-octylphenol) 26 608-93-5 210-172-5 Pentachlorobenzene 27 87-86-5 201-778-6 Pentachlorophenol 28 n.a. n.a. Polyaromatic hydrocarbons 50-32-8 200-028-5 (Benzo(a)pyrene) 205-99-2 205-911-9 (Benzo(b)fluoroanthene) 191-24-2 205-883-8 (Benzo(g,h,i)perylene) 207-08-9 205-916-6 (Benzo(k)fluoroanthene) 206-44-0 205-912-4 (Fluoroanthene) 193-39-5 205-893-2 (Indeno(1,2,3-cd)pyrene) 29 122-34-9 204-535-2 Simazine 30 688-73-3 211-704-4 Tributyltin compounds 36643-28-4 n.a. (Tributyltin-cation) 12002-48-1 234-413-4 Trichlorobenzenes 120-82-1 204-428-0 (1,2,4-Trichlorobenzene) 32 67-66-3 200-663-8 Trichloromethane (Chloroform) 33 1582-09-8 216-428-8 Trifluralin 25 31 * Frequency of monitoring – every month Table 14. Families and groups of substances of specific pollutants (according to GD no. 1038/2010) (Romania) No. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. Families and groups of substances of specific pollutants Organohalogen compounds and substances which may form such compounds in the aquatic environment Organophosphorus compounds Organostannic compounds Substances with carcinogenic, mutagenic or teratogenic properties Persistent mineral oils and petroleum hydrocarbons1 Cyanide2, persistent synthetic substances which may float, remain in suspension, sink or may interfere with any water use Metals and their compounds Biocides and plant protection products Substances which have a deleterious effect on the taste and / or odor of groundwater or aquatic products for human consumption (on the organoleptic properties) or can lead to the formation of this kind of substance, making them unfit for human consumption Toxic or persistent organic compounds of silicon and substances which may lead to the formation of this kind of substances in the water, except that, in terms of the biological, which are not harmful or which in water are fast converted to non-hazardous substances Inorganic compounds of phosphorus and elementary phosphorus 58 December, 2015 Black Sea Rivers Monitoring No. 12. 13. 14. 15. Families and groups of substances of specific pollutants Fluorides, mineral oils and non persistent petroleum hydrocarbons3 Substances which contribute to eutrophication (in particular, nitrates and phosphates) Suspended matter Substances that can have a negative impact on the balance of oxygen and can be measured using indicators such as chemical oxygen demand (COD) and biochemical oxygen demand (BOD5) 1For groundwater will be considered "mineral oils and hydrocarbons." 2For surface waters will be considered List II (Table 15). 3Will be considered only for surface waters. Table 15. Indicative list (list II) of substances that correspond to the families and groups of substances enlisted in Table 14 (Romania) CAS No. Substance 1 2 71-55-6 methyl chloroform; 1,1,1-trichloroethane 79-34-5 1,1,2,2-tetrachloroethane 79-00-5 1,1,2- trichloroethane 76-13-1 1,1,2-trichloro-trifluoro-ethane 75-34-3 1,1-dichloroethane 75-35-4 1,1-ethylene dichloride; vinylidene chloride 95-94-3 1,2,4,5-tetrachlorobenzene 106-93-4 1,2-dibromoethane 95-50-1 1,2-dichlorobenzene 540-59-0 1,2-ethylene dichloride 78-87-5 1,2-dichloropropane; propylene dichloride 96-23-1 1,3-dichloro -2-propanol 541-73-1 1,3-dichlorobenzene 542-75-6 1,3-dichloropropene 106-46-7 1,4-dichlorobenzene; p-dichlorobenzene 97-00-7 1-chloro-2; 4-dinitrobenzene 90-13-1 1-chloro-naphthalene 78-88-6 2,3-dichloropropene; 2,3-dichloropropilenă 93-76-5 2,4,5-T; acid 2,3,4-trichlorophenoxy-acetic acid neaplicabil 2,4-D salts and esters 120-83-2 2,4-dichlorophenol 94-75-7 2,4-D; acid 2,4-dichlorophenoxyacetic 95-85-2 2-amino-4-chlorophenol 615-65-6 2-chloro-4-methylaniline 95-51-2 2-chloroaniline 107-07-3 ethylene chlorohydrine; 2-chloroethanol 88-73-3 2-nitrozochlorobenzene 95-57-8 2-chlorophenol 95-49-8 2-chlorotoluene 59 December, 2015 Black Sea Rivers Monitoring CAS No. Substance 1 2 108-42-9 3-chloroaniline 121-73-3 3-nitroso chlorobenzene 108-43-0 3-chlorophenol 108-41-8 3-chlorotoluene 92-87-5 benzidine, 1,1 '-biphenyl-4, 4'-diamine; 4,4'-diaminobiphenyl, biphenyl-4, 4'-ilendiamin 89-63-4 4-chloro-2-nitroaniline 89-59-8 4-chloro-2-nitrotoluene 59-50-7 chlorocresol, 4-chloro-m-cresol; 4-chloro-3-methylphenol 106-47-8 4-chloroaniline 100-00-5 1-chloro-4-nitrobenzene 106-48-9 4-chlorophenol 106-43-4 4-chlorotoluene 107-05-1 3-clorpropenă; allyl chloride 98-87-3 benzylidene chloride; alpha, alpha-dichlorotoluene 7440-36-0 Antimony 7440-38-2 Arsenic and compounds 1327-53-3 diarsenic trioxide, arsenic trioxide 2642-71-9 azinphos-ethyl; dithiophosphate O, O-diethyl-4-oxobenzotriazin-3-yl-methyl 86-50-0 azinphos-methyl; dithiophosphate O, O-dimethyl 4-oxobenzotriazin-3-yl-methyl 7440-39-3 barium 25057-89-0 bentazone, 2,2-dioxide 3-isopropyl-2,1,3-benzothiadiazin-4-one 56-55-3 benzo (a) anthracene 100-44-7 benzyl chloride, alpha-chlorotoluene 7440-41-7 beryllium 92-52-4 diphenyl, biphenyl 7440-42-8 boron 57-74-9 chlordane; 1,2,4,5,6,7,8,8-octacloro-3a, 4,7,7 a-tetrahydro-4,7-metanoinden 6164-98-3 chlordimeform; N2-(4-chloro-o-tolyl)-N1, N1-dimethylformamidine 79-11-8 chloroacetic acid 108-90-7 chlorobenzene 25586-43-0 chloro-naphthalene neaplicabil chloro-nitrotoluene 126-99-8 Chloroprene; 2-chloro-1,3-butadiene; 7440-47-3 chromium 7440-48-4 cobalt 7440-50-8 copper 56-72-4 Coumafos, thiophosphate-O-3-chloro-4-methylcoumarin-7-yl and O, O-diethyl 126-75-0 demeton-S; diethyl and S-2-ethylthioethyl thiophosphate 919-86-8 demeton-S-methyl, thiophosphate of S-2-ethylthioethyl and dimethyl 301-12-2 oxydemeton-methyl; O thiophosphate, O-dimethyl and S-(2-ethyl sulfinyl-ethyl) 60 December, 2015 Black Sea Rivers Monitoring CAS No. Substance 1 2 683-18-1 Dibutyl chloride 818-08-6 Dibutyltin oxide neaplicabil dibutyl salt 27134-27-6 dichloroaniline (all isomers) neaplicabil dichloro-diamino-biphenyl 108-60-1 dichloro-di-iso-propyl ether neaplicabil dichloro-nitrobenzene (all isomers) 120-36-5 Dichlorprop; 2,4-DP; 2 - (2,4-dichlorophenoxy) propionic acid 62-73-7 dichlorvos, 2,2-dichlorovinyl phosphate, and dimethyl 109-89-7 diethylamine 60-51-5 124-40-3 dimethoate; methylcarbamoyl methyl and O dithiophosphate, O-dimethyl disulfoton; dithiophosphate O, O-diethyl 2-ethylthioethyl dimethylamine 298-04-4 disulfoton; dithiophosphate O, O-diethyl 2-ethylthioethyl 106-89-8 epichlorohydrin, 1-chloro-2,3-epoxypropane 100-41-4 ethylbenzene 122-14-5 fenitrothion; O thiophosphate, O-dimethyl and O-4-nitro-m-tolyl 55-38-9 fenthion; O thiophosphate, O-dimethyl and O-(4-methylthio-m-tolyl) 76-44-8 heptachlor; 1,4,5,6,7,8,8-heptacloro-3a, 4,7,7 a-tetrahydro-4, 7metanoinden 67-72-1 hexachloroethane 98-82-8 cumene 330-55-2 linuron, 3 - (3,4-dichlorophenyl)-1-methoxy-1-methylurea 121-75-5 malathion; dithiophosphate 1,2-bis (ethoxy-carbonyl) ethyl and O, O-dimethyl 94-74-6 MCPA, 2,4-MCPA; 4-chloro-o-toliloxiacetic 93-65-2 salts mecoprop and mecoprop; 2 - (4-chloro-2-methylphenoxy) propionic acid 10265-92-6 methamidophos; O thiophosphoramide, S-dimethyl 7786-34-7 mevinphos; 2-methoxycarbonyl-1-methylvinyl and dimethyl phosphate 7439-98-7 molybdenum 1746-81-2 Monolinuron; 3 - (4-chlorophenyl)-1-methoxy-1-methylurea 1113-02-6 omethoate; O thiophosphate, O-dimethyl and S-methylcarbamoylmethyl 56-38-2 parathion; O thiophosphate, O-diethyl and O-4-nitrophenyl 298-00-0 parathion-methyl (ISO); O thiophosphate, O-dimethyl and O-4-nitrophenyl 1336-36-3 PCB; polychlorobiphenyls; chlorinated biphenyls 85-01-8 phenanthrene 126-73-8 tributyl phosphate 14816-18-3 phoxim; alpha-(dietoxifosfinotioilimino) phenylacetonitrile 709-98-8 propanil 3 ', 4'-dichloroproprioanilide 7782-49-2 selenium 7440-22-4 silver 13494-80-9 tellurium 1461-25-2 tetrabutyl tin 61 December, 2015 Black Sea Rivers Monitoring CAS No. Substance 1 7440-28-0 2 thallium 7440-31-5 tin 7440-32-6 titanium 108-88-3 toluene 24017-47-8 triazophos; thiophosphate of O, O-diethyl O-(1-phenyl-1H,2,4-triazol-3-yl) 52-68-6 trichlorfon; 2,2,2-trichloro-1-hydroxyethyl phosphonate neaplicabil trichlorophenol 900-95-8 fentin acetate, triphenyltin acetate 639-58-7 triphenyltin chloride 76-87-9 fentin hydroxide, triphenyltin hydroxide 7440-61-1 uranium 7440-62-2 vanadium 75-01-4 vinyl chloride, chloroethylene 1330-20-7 xylene (the amount of o-, m-, p-) 7440-66-6 zinc b) biological parameters Phytoplankton (FPL) - Taxonomic composition - the list and number of species, density, saprobic index, biomass - only in case of eutrophication; Microphytobentos (MFB) - taxonomic component – the list and number of species, density, saprobic index; Macrophytes (MF) - Taxonomic composition - the list of species and number, density; Zoobenthos (ZB) - Taxonomic composition - the list and number of species, density, saprobic index, diversity index, species sensitive to human impact; Fish fauna (P) - Taxonomic composition - the list and number of species, density, species sensitive to human impact, age structure; Zooplankton (ZPL) - provides useful information in some cases: eutrophication, pollution incidents. c) microbiological parameters: total coliforms, fecal coli forms, fecal streptococci and salmonella (4-12 times per year), analysis of microbiological parameters is performed in sections for capture of surface water for drinking water (P), in sections of trans-national monitoring network (TNMN) of the International Convention for the protection of the Danube River (ICPDR) and other sectors where monitoring of these parameters is established under bilateral or international conventions and agreements. Parameter "Salmonella" is performed by decentralized units of the Ministry of Health of the territory d) parameters of toxic pollutants by natural or anthropogenic origin MG – heavy metals from list II and list of priority substances/priority hazardous substances according to GD 351/2005 (see tables above); SP-MO - organic micropollutants from GD 351/2005, relevant to the biological response, in accordance with the table above. e) ecotoxicological parameters (biota) - to highlight the effects of heavy metals and organic pollutants of anthropogenic origin by applying risk and impact assessment methodology provided in MO 245/2005 approving the methodology for risk assessment of hazardous substances in lists I and II and the priority substances/priority hazardous substances into the aquatic environment 62 December, 2015 Black Sea Rivers Monitoring In the Danube River, Danube Delta and River Dobrogea Area according to the Management Plan of River Basin, the quality elements monitored and frequency of sampling for rivers and natural lakes are presented in the tables below: 1.1. Hydromorphology Table 16. Hydromorphological elements in RO rivers and lakes monitoring № Quality element Rivers Frequency of sampling Parameters Water level and flow 1 Surveillance H = 2 times daily Q = 2-60 times per year Connection with groundwater bodies Hydrological regime River continuity 2 Morphological conditions The water level in the lake and tributary and de-fluent flows Residence time (for lakes) Connectivity of the lake with groundwater bodies River depth and change of the width Structure and substratum of river bottom Structure of river zone Variation of lake depth Volume and structure of the substratum of lake bottom Structure of lake shore Natural Lakes Frequency of sampling Surveillance Operational N/A N/A 1 time per 3 days 1 time per 6 years Operational H = 2 times daily Q = 2-60 times per year 1 time per 3 days 1 time per 6 years N/A N/A N/A N/A N/A N/A 1-30/30 days 1-30/30 days N/A N/A 1 per 6 years 1 per 6 years N/A N/A 1 per 3 days 1 per 3 days 1- yearly 1- yearly N/A N/A 1 per 6 years 1 per 6 years N/A N/A 1 per 6 years N/A 1 per 6 years N/A N/A 1 per 6 years N/A 1 per 6 years N/A N/A 1 per 6 years 1 per 6 years N/A N/A 1 per 6 years 1 per 6 years 1.2. Physico-chemical and hydrobiological parameters Table 17. Physico-chemical parameters monitored in Romania N Quality elements Parameter Frequency of sampling per month/per year Surveillance 1 Transparency 2 3 Thermal conditions Oxygen balance conditions 4 5 Salinity Acidification status Suspended matter (TSS) Turbidity Colour T 0C O2 dissolved COD-MN and/or CODCr, BOD5 and in some cases COD, TOC Conductivity/fixed residue pH Alkalinity 63 Operational 6 times per year 6 times per year 6 times per year 6 times per year 6 times per year 6-12 times per year* 6-12 times per year* 6-12 times per year* 6-12 times per year* 6-12 times per year* 6 times per year 6 times per year 6 times per year 6-12 times per year* 6-12 times per year* 6-12 times per year* December, 2015 Black Sea Rivers Monitoring N Quality elements Parameter Frequency of sampling per month/per year Surveillance 6 Nutrients 7 Nutrients (suspended matter) Priority substances water Priority substances (suspended matter) Priority substances (sediments) Priority substances (biota) Non-priority specific pollutants Non-priority specific pollutants (suspended matter) Non-priority specific pollutants (sediments) Non-priority specific pollutants (biota) Other pollutants 8 9 10 11 12 13 14 15 16 Operational N-NO2 N-NO3 Ammonium Ntotal Orthophosphates Ptotal Chlorophyll "a" Ntotal Ptotal See Table 13 6 times per year 6 times per year 6 times per year 6 times per year 6 times per year 6 times per year 6 times per year 12 times per year 6-12 times per year* 6-12 times per year* 6-12 times per year* 6-12 times per year* 6-12 times per year* 6 times per year 6 times per year 12 times per year Heavy metals: Cd, Ni, Pb, Hg 6 times per year 6 times per year Heavy metals and organic micropollutants relevant to sediments Heavy metals and organic micropollutants relevant to biota See Table 15 1 time per year 1 time per year 6 times per year 6 times per year Other heavy metals (list II) 6 times per year 6 times per year Substances from list I and II relevant to sediments Substances from list I and II relevant to biota 3) 1 time per year 1 time per year 1 time per year 1 time per year 6 times per year 6 times per year *it is monitored 12 times per year when the risk is due to the nutrients and organic matter; it is monitored 6 times per year when the risk is due to morphological alterations and priority substances 1) Priority substances (Annex X of the WFD - Decision 2455/2001 / EC) in case of pollution sources which are discharging this kind of substances 2) Non-priority specific pollutants (substances in Annex 8 and 9 of the Framework Directive) in case of sources pollution which are discharging this kind of substances 3) Other pollutants: substances not included in Annexes 8, 9 and 10 of the Framework Directive: in case of pollution sources which are discharging this kind of substances Table 18. Hydrobiological parameters (Romania) Quality elements Parameters Frequency Surveillance monitoring Operational monitoring Phytoplankton Taxonomic composition (list and no. of species) density (cells / l) Twice per year 3 times per year Microphytobenthos Taxonomic composition (list and no. of species) density (cells / m 2) Taxonomic composition (list and no. of species) density (ind / m2) Twice per year 3 times per year 1 time per 3 years 1 time per 3 years Zoobenthos Taxonomic composition (list and no. of species) density (ind / m2) Twice per year 3 times per year Fish fauna Taxonomic composition (list and no. of species) density (ind / 100m2) age structure 1 time per 3 years 1 time per 3 years Macrophytes 64 December, 2015 Black Sea Rivers Monitoring 1.3. Calculation of loads For nutrients, the MONERIS model (Modelling Nutrient Emissions in River Systems) for estimating emissions from point and diffuse sources of pollution is used. The MONERIS model calculates the emissions of nitrogen and phosphorus stemming to surface water through different pathways, as well as the instream retention in the surface water network. According to a methodology developed by the Romanian Waters National Administration, the assessment of the emission of pollutants discharged from point sources of pollution, broken down by activity branches (domestic and industrial) can be done taking into account: • flow of wastewater discharged, expressed in m3/day and thousands m3/year; • amount of pollutant contained in the wastewater, which is expressed as: For COD, BOD5, suspended matter, NT, PT as measuring unit is used tons/day, calculated as follows: Pollutant load (t/day) = = average flow (m3/day) x average concentration of pollutant (mg/l) : 1000000 Where: Average flow (m3/day) is the simple arithmetic average of the flows recorded during a year; Average concentration of the pollutant (mg/l) is the simple arithmetic average of the concentrations recorded during a year, corresponding to the above mentioned flow. For heavy metals as measuring unit is used tons/year calculated as follows: The amount of metallic ions (t/year) = = average flow (m3/year) x average concentration of metallic ions (mg/l): 1000000 Where: Average flow is the total volume of discharged wastewater registered during a year; Average concentration of metallic ions (mg/l) is the simple arithmetic average of the concentrations recorded during a year, corresponding to the above mentioned flow. For the Danube loads calculation the TNMN (https://www.icpdr.org/main/publications/tnmn-yearbooks). 65 (ICPDR) methodology is followed December, 2015 Black Sea Rivers Monitoring 1.4. Other types of monitoring Protected areas Same as in Bulgaria, in the Danube River, Danube Delta, Dobrogea River Area and coastal waters there have been identified and mapped the following categories of protected areas: protected areas for water abstraction for drinking water, areas for the protection of fish species, economically important, areas for the protection of habitats and species where the maintenance or improvement of water is an important issue, areas vulnerable to nitrate pollution from agricultural sources and bathing areas. A very important aspect regarding the distribution of protected areas is that in Romania all territory has been identified as a sensitive area to pollution with nutrients (total nitrogen and total phosphorus), on identification criteria of Annex II to Directive 91/271 / EEC concerning urban wastewater treatment and according to the position paper concluded between Romania and the European Community on the environmental chapter. Along the RO coast there are vulnerable areas and areas most threatened by pollution/eutrophication. They are demonstrated in Figure 29. In Figure 29 the vulnerability is mentioned in relation to nitrates pollution, however, the same areas are sensitive to any kind of pollution. Figure 29. Vulnerable areas to nitrates in the Dobrogea river area and the Danube Delta (Romania) 66 December, 2015 Black Sea Rivers Monitoring Besides the Danube Delta Biosphere Reserve (DDBR), for which there is a special protection and administration law concerning the economic and social development and water infrastructure, the Dobrogea region in Romania holds other 39 protected areas (Figure 30). Figure 30. Areas intended for protection of habitats and species where water is an important factor in the Dobrogea River Area (Romania) 67 December, 2015 Black Sea Rivers Monitoring Drinking water In 2007, according to the Management Plan of the Danube River, Danube Delta, Dobrogea Hydrographic area and Coastal waters in Dobrogea area, there were inventoried in total 14 water catchments surface sources out of which 2 were designated as protection areas (14.3 %). For ground water sources, in total 159 water catchments were inventoried out of which 155 were designated as protection areas (97.5%). Figure 31 presents the water catchments for drinking water from surface and groundwater sources from Dobrogea basin area. Figure 31. Protection areas of water catchments for drinking water of Dobrogea river area (Romania) 68 December, 2015 Black Sea Rivers Monitoring County Public Health Directorates (DSPJ) carry out monitoring of drinking water quality under Romanian legislation which is in line with the European Directive 98/83/EEC on the quality of water intended for human consumption. The verification of quality of drinking water is carried out in the following way: by control monitoring (water producers self-monitoring) and audit monitoring (performed by DSPJ). The frequency of sampling and parameters monitored in water supply systems for these types of monitoring are established in legislation - both audit and control monitoring programmes are carried out under Law 458/2002 and GD 974/2004 amended and supplemented. Control monitoring checks periodically organoleptic, chemical and microbiological quality of the drinking water produced and distributed, and efficiency of the treatment processes, focusing on the disinfection technology in order to determine if drinking water is adequate or not in terms of the relevant parameter values stipulated in Law no. 458/2002 on drinking water quality. Audit monitoring verifies where drinking water meets quality requirements and specifications for all parameters set out in Law 458/2002 on drinking water quality, including additional parameters imposed by sanitary authorities. Real-time monitoring The "Romanian Waters" National Administration implements the project "WATMAN - Integrated Management Information System for Water - Phase I" project which sets the foundations for application of the national strategy of water resources management, including situations resulting from extreme hydrological events (droughts and high water, pollution or accidents at the water management system) in case of disasters, drafted by the Ministry of Environment, Water and Forests. The proposed infrastructure works, equipment and endowments will be installed in different points throughout the entire Romanian territory in all 11 Hydrographic Basins: Somes-Tisa, Cris, Mures, Banat, Jiu, Olt, Arges-Vedea, Buzau-Ialomita, Siret, Prut-Bârlad and Dobrogea Litoral. The project is worth 63 million euros, of which 85% are European funds, and the remaining 15% is financed from the state budget. The project has 2 investment objectives. Investment Objective 1 - Increasing the safety of hydraulic structures Proposed investments include automatic sensors and complementary equipment for: 89 automatic stations with sensors to improve safety of dams; 233 automated stations with sensors to measure the snow level and hydrometric stations for tributary flow, sockets and derivatives; 89 dams equipped with software and hardware to control and coordinate the operation of hydrotechnical constructions; Equipment and means of intervention to flooding. Investment Objective 2 – Increasing the capacity in case of natural disasters 15 coordinating centers and 23 early intervention centers; o software and hardware endowments at the coordination centers; 69 December, 2015 Black Sea Rivers Monitoring o endowments at the early intervention centers. 51 automatic stations with sensors for monitoring water quality. Among all activities, the WATMAN project is the largest project in the field of real-time monitoring of surface waters undertaken so far in Romania. 1.5. Data management and assessments under the WFD and/or others In Romania, the database for monitoring of surface waters - surface water quality in river basins and quality categories - under the Waters Integrated Monitoring System in Romania (SMIAR) is kept in Word files, there is no specific software to manage it. The data are not online and are not accessible by public. The status of surface waters is being annually assessed in line with the WFD requirements. The assessment of surface water quality is made in accordance with the provisions of Order no. 161 of 16 February 2006 for approving the Norms regarding the classification of surface water quality in order to establish the ecological status of water bodies. The classification and assessment system of the ecological status of water bodies has been prepared in accordance with the principles and recommendations of the Water Framework Directive and European Guidelines Guidance document no 13 - Overall approach to the classification of ecological status and ecological potential and Guidance document no 4 - Identification and designation of Heavily Modified and Artificial water Bodies, being specific for categories of surface water. Characterization of the environmental status in accordance with the requirements of the Water Framework Directive (transposed into Romanian legislation through Water Law no. 107/1996 as amended and supplemented), is based on a classification system in five classes, namely: very good, good, moderate, poor and bad, defined and represented as follows: blue colour - for very good status – the values of biological elements are characterized by values associated with those from unaltered areas (as reference) or with minor anthropogenic alterations. The values of hydromorphological and physico-chemical elements of surface waters are characterized by values associated with those in unaltered areas (as reference) or with minor anthropogenic alterations areas; green colour - for good status – the values of biological elements are characterized by slight deviations from values characteristic to unaltered areas (as reference) or with minor anthropogenic alterations. The values of general physico-chemical elements are characterized by minor deviations from values characteristic to unaltered areas (as reference) or with minor anthropogenic alterations areas; yellow colour - for moderate status - the values of biological elements for surface water deviate moderately from values characteristic to unaltered areas (as reference) or with minor anthropogenic alterations areas; orange colour - for poor status - there are major alterations of biological elements; relevant biological communities differ substantially from those normally associated with unaltered conditions in unaltered areas (as reference) or with minor anthropogenic alterations areas; red colour – for bad status – there are severe alterations of the biological elements values, a large number of relevant biological communities are absent from those present in unaltered areas (as reference) or with minor anthropogenic alterations areas. Biological elements are taken into account when defining all those 5 classes, based on the principle that biological elements are the integrator of all kinds of pressures. Physico-chemical elements are taken into account 70 December, 2015 Black Sea Rivers Monitoring in the characterization of "very good" and "good" status and the morphological characterization only for "very good" status, for the rest of states there is no specific definition. For specific synthetic pollutants, very good ecological status is defined by values close to zero or at least below the limits of detection of the most advanced analytical techniques used. For specific non-synthetic pollutants very good ecological status is defined by concentrations which remain within the range normally associated with background values. Good environmental status, both for specific synthetic pollutants, and those non-synthetic is defined by concentrations which do not exceed the environmental quality standards; for specific non-synthetic pollutants these values do not involve the reducing of pollutant concentrations below natural background. Global (overall) status of surface waters is determined taking into account the ecological and chemical status. To illustrate the level of the chemical status of a water body two colors are used: • Blue for good chemical status; • Red for other status than good. In 2013, in the Danube River, Danube Delta, Dobrogea River Area and Coastal Waters, 115 water bodies were examined and characterized in terms of status / ecological potential 93 (81%) of water bodies (79 natural (69%) and 14 heavily modified / artificial (12%)) of which: 57 (61%) water bodies are in good ecological status and 8 (9%) water bodies in maximum ecological and good potential. The remaining 22 water bodies are lakes for fish and therapeutic purpose for which environmental status was not evaluated as there are no definitions of specific environmental objectives for them. Also, all 115 bodies were analyzed and characterized chemically of which 112 (97%) water bodies achieve good chemical status and 3 (3%) water bodies do not. Figure 32 illustrates the ecological status and ecological potential of water bodies in the Danube River, Danube Delta, Dobrogea River Area and Coastal Waters in 2013. 71 December, 2015 Black Sea Rivers Monitoring Figure 32. Ecological status and ecological potential of surface waters in the Danube catchment area in 2013 (Romania) References: Management plan of Danube River, Danube Delta, Dobrogea Hydrographic area and Coastal waters, 2009-2015 Conservation and protection of the Black Sea Diversity – report made under MISIS project (2012) Project of the Management plan of Danube River, Danube Delta, Dobrogea Hydrographic area and Coastal waters, Cycle II, 2016 - 2021 Website of "Romanian Waters" National Administration: www.rowater.ro Conclusions The monitoring of Romanian surface waters is conducted in line with EU Directives and national legislation requirements. The important issues of water management, both nationally and within basins/hydrographic spaces, are similar to those set out in the International Danube River Basin as described in the document Significant Water Management Issues 2013 developed by the International Commission for the Protection of the Danube River (ICPDR), with the contribution of Danube countries (https://www.icpdr.org/main/SWMI-PP). 72 December, 2015 Black Sea Rivers Monitoring Emissions of nitrogen and phosphorus in the Danube River contribute to eutrophication of the north-western part of the Black Sea. Regarding the nutrient contribution of the Danube River to the Black Sea in 2000-2008, in the draft second Management Plan of the International Danube River Basin (http://www.icpdr.org/main/draftplans2015) it is specified that Danube loads are estimated to be approx. 670 kt/year for nitrogen and approx. 44 kt/year for total phosphorus. Therefore, the quantity of pollutants collected by the Danube River from the entire catchment area is a significant pressure on Romanian coastal waters. During 2015, the activities for completion of the Management Plan of the International Danube River Basin (second planning cycle) include update of scenarios aimed at reducing nutrient loading in the Black Sea basin. In scenarios updates the MONERIS model (https://www.icpdr.org/main/activitiesprojects/moneris-modelling-nutrient-emissions-river-systems) will be used to prepare the needed estimates of inputs from point and diffuse sources in the Danube catchment area. Romania participates in TNMN (Trans-national monitoring network, https://www.icpdr.org/main/activitiesprojects/tnmn-transnational-monitoring-network), established under ICPDR in 1996. The TNMN is a good example to achieve rivers monitoring harmonization in the Black Sea region, following: Harmonising monitoring and assessment methods concerning water quality in rivers (including hydromorphology and hydrobiology parameters as required to assess ecological status of rivers); Developing co-ordinated monitoring systems applying also stationary or mobile measurement devices, and shared communications and data processing facilities; Elaborating and implementing joint programmes for monitoring riverine conditions, including flow rates, water and sediments quality, as a basis for the assessment of impacts on the Black Sea. TURKEY The most important concept in WFD (Water Framework Directive) is river basin management and for each river basin preparing RBMP (River Basin Management Plan) shall be developed. In the participation process of the candidate countries, they have to fulfil the requirements of WFD. Carrying out studies on the properties of the river basin, impacts of human activities and economic analysis of water usage are important in terms of meeting the WFD requirements. According to WFD, RBMP milestones are enlisted below (Legislations equivalent to these in Turkey are given also as currently available); River basin characterization, Summary of the significant pressure and impacts of human activities, Determining and mapping protection areas, Map of monitoring nets, Environmental targets list, Economic analysis, Precautions program, Listing and summarizing detailed precautions, Public information and consulting on the subject, summarizing in a way to include the results of exchanging ideas and information sharing, List of competent authorities, Determining contact points to obtain background information and comment from public and procedures 73 December, 2015 Black Sea Rivers Monitoring to be followed (Tanık, 2007). Apart from WFD, other EC Directives taken into consideration in Turkey as related to surface water management are: Urban Wastewater Treatment Directive, (91/271/EEC); (In Turkey 2006), Nitrate Directive (91/676/EEC); (In Turkey 2004), Drinking Water Directive, (98/83/EC); (In Turkey 2005- TS 266–2005) Integrated Pollution Prevention and Control (IPPC) Directive (2008/1/EC)16; Bathing Water Quality Directive (76/160/EEC)17; (In Turkey 2006). Generally, boundaries of river basins may not match administrative boundaries (provinces and towns) and a river basin may include more than one administrative region. This is also valid for Turkey. Figure 33 demonstrates the boundaries of TR Black Sea river basins. A high level management structure on the basis of river basins has the potential of creating administrative, social and political problems and is a subject of examination and research within itself in order to recommend on its institutional and legal framework. Figure 33. Black Sea river basins of Turkey When looking at the situation in Turkey, the European Union association process contributed to advancements in the field of rivers management. Specifically, the Ministry of Environment and Urbanization and the Ministry of Forestry and Hydraulic Affairs have played an active role in the process and they have progressed their work taking into consideration European Union requirements and standards in the Water Quality Sector. Accordingly, River Basin Protection Action Plans were completed by TUBITAK MRC in 2011 under the coordination of the mentioned ministries. In Turkey, the regularly monitored rivers along Black Sea coasts are Yeşilırmak, Kızılırmak, Sakarya, Melet and Filyos Rivers. Water and wastewater management issues are shared among many governmental organizations (Table 19). Each of these organizations has developed plans, monitoring systems and regulatory precautions for 16 17 Replaced by the Industrial Emissions Directive (2010/75/EU) Replaced by the revised Bathing Water Directive (2006/7/EC) 74 December, 2015 Black Sea Rivers Monitoring management and control of water pollution. Along with crossing and/or overlapping activities of the involved organizations, there are significant gaps specifically in terms of the scope of water quality monitoring. In 2007, SHI (State Hydraulic Affairs) was included in the institutional framework of state environmental protection agencies. Thus, an important step was undertaken in building integrated water resources management and a ground for planning of more efficient surface water monitoring (in compliance with WFD) was established. In Turkey, current water and wastewater management system is not based on river basins as stipulated in WFD, but is established at the provinces and Municipalities scale. In the TR association process to EU, and specifically when the Phase of Environment was opened, studies on restructuring the current water management sector to meet the requirements of WFD were well advanced. In Turkey, drinking water supply, sewage (wastewater/rainwater) and wastewater treatment/removing services are under the responsibility of the Municipalities. The duties and responsibilities of the municipalities are given in Table 20. Table 19. Governmental Organizations involved in River Basin Management (Turkey) ORGANIZATION MAIN DUTIES AND RESPONSIBILITIES State Planning Organization • Planning investments on water sources (example: dams, reservoirs, water supply and pollution control (example: sewage and canalization treatment) The Ministry of Forestry and Water Affairs • Developing and approving environmental plans and providing for their implementations Avoiding water pollution Establishing water quality laboratories Implementing national ÇED (Environmental Impact Assessment) arrangements Determining RAMSAR cites Coordinating the process ensuring Turkish water legislation is compatible with EU communautaire Determining water resources quality classification Determining quality criteria related to water resources including bathing water quality standards Approval of projects on wastewater treatment facilities of industrial plants Preparing river basin protection plans and river basin Action Plans Preparing response plans for protection of water resources Rehabilitation of water beds Arrangement of water discharge permissions, monitoring discharges from industrial and wastewater treatment facilities Water resource evaluations and analysis Development of river basins Planning, construction and finance of water and wastewater treatment facilities Water management by 25 Regional Directorates Protecting underground and surface waters Allocation of ground water and keeping under record Flood control Examination, planning, design, construction and operation related to watering, domestic water supply, hydroelectric energy and environment Determining bathing water quality standards, implementing and monitoring these standards Monitoring urban waste collection and treatment quality Drinking water legislation, drinking water standards, implementing and monitoring these standards And The Ministry of Environment and Urbanization • • • • • • • • • • • • General Directorate for State Hydraulic Works • • • • • • • • The Ministry of Health • • • 75 December, 2015 Black Sea Rivers Monitoring ORGANIZATION MAIN DUTIES AND RESPONSIBILITIES The Ministry of Agriculture and Rural Affairs • • • • Fishery and aquaculture legislation Protection of water resource use in agriculture Monitoring nitrate parameters for freshwater and ground water Controlling and monitoring pesticides The Ministry of Culture and Tourism The Bank of Provinces • Planning and constructing wastewater infrastructure in tourism areas • Designing and financing public works on drinking water supply and process, waste systems and urban wastewater treatment and solid waste disposal for the municipalities Table 20. Municipality Environmental Services (Turkey) MUNICIPALITIES/SETTINGS INSTITUTION IN CHARGE Settlements in the Metropolitan Municipalities Service Areas (County/Town Municipalities and Villages) Water and Sewerage Administrations (SKI’s) SHI (In country-wide large water drinking water supply projects) Municipalities out of metropolitan municipalities Service Areas (Municipalities which do not include Service Area Province Boundary ) Other Province/ County/Town Municipalities Rural Settlements Directorate of Technical Affairs of County, Town Municipalities Directorate of Provincial Special Administration (With Model of Teams Bringing Service to Villages) Note: Municipalities with a population between 3,000~100,000, water procurement, sewage and wastewater Water quality monitoring studies, which is a crucial part of the river basin management, includes establishing or extending monitoring networks required both at surface waters and ground waters and continuous monitoring as stated in WFD. Current water quality monitoring along rivers and their tributaries in Turkey is being managed or observed by many institutions, primarily by the State Hydraulic Institute (SHI) within the framework of water usage (Table 21). These institutions are the Ministry of Environment and Urbanization, the Ministry of Forestry and Water Affairs, General Directorate of Electric Power Resources Survey and Development Administration (EIEI), metropolitan municipalities, the Ministry of Health, Provincial Directorates of Agriculture (TIM) and General Directorate of State Meteorology Affairs (DMI). Each involved state institution performs monitoring according to own purposes/responsibilities, however, there is no governmental requirement the collected data on surface waters to be jointly stored and managed. Thus, a Joint Water Quality Monitoring System is absent, as well as a Joint Water Quality Data/Information Sharing Platform. Establishment of the latter would significantly improve the access of stakeholders, including general public, to such an important data/information as the quality of surface waters. 76 December, 2015 Black Sea Rivers Monitoring Table 21. Municipality Environmental Services (Turkey) Monitoring of Receiving Environment Water Quality: Intra-continental Water resources (river, lake, dam, wetland area and ground waters) flow, drinking and irrigation, water quality monitoring SHI Regional Directorates Regional Directorates of Electric Power Resources Survey and Development Administration (EIEI) (currents, hydrological observations) At some pilot river basins/lakes the Ministry of Environment and Forestry Monitoring water quality at coasts (beach), estuaries and seas Monitoring water quality at waters where aquaculture production is in place Monitoring water quality at drinking water supply Monitoring nitrate pollution generated as a result of agriculture/stock raising Some Metropolitan Municipalities Water and Sewerage Administrations (at dams) ÇOB Department of Coast and Sea Management Some Metropolitan Municipalities SK Administrations Provincial Directorates of Health/Provincial Sanitation Laboratories The Ministry of Agriculture and Rural Affairs Regional Directorates of Aquaculture Provincial Directorates of Health Provincial Directorates of Sanitation Water and Sewerage Administrations of Metropolitan Municipalities Provincial Directorates of Agriculture and Rural Affairs Ministry Acting policy: Legal/policy documents, which regulate rivers monitoring in Turkey are given below: Water Pollution Control Regulation (no of OG: 25687, date: 31.12.2004) Surface Water Quality Management Regulation (no of OG: 28483, date: 30.11.2012) Water Protection Regulation against pollution caused by nitrates from agricultural sources (No of OG: 25377, date: 18.02.2004) Regulation on Protection of Water Basins and Preparing Management Plans (Official Gazette dated October 17, 2012 and numbered 28444) Regulation on the Surface Water and Groundwater’s Monitoring (no of OG: 28910, date: 11.02.2014) Protection of Water against Pollution Directive, taking samples and analysis methods, (no of OG: 27372, date: 10.10.2009) Purpose of “Regulation on Protection of Water Basins and Preparing Management Plans” is to arrange principles and procedures on protecting surface waters and ground waters in terms of quantity, physical, chemical and ecological aspects with an integrated approach and on preparing water basins management plans. In this 77 December, 2015 Black Sea Rivers Monitoring context, Communiqué on Formation, Duties and Working Principles and Procedures of Basin Management Committees is put into practice by publishing in the Official Gazette dated June 18, 2013 and numbered 28681. Thus, 26 basin management Committees have been established for 25 basins in Turkey. Related Projects: A chain of projects have been initiated to be able to completely apply the Water Framework Directive on TR coastal, transitional, and inland waters. While some of the aforementioned projects reveal the primary components for the classification of the shore areas and the determination of environmental targets, another project group targets the production of data through various methods (gathering the data which will be used for classifications) and carrying out the necessary monitoring activities to fill in data gaps. Aims, scopes, operating areas, time intervals of related projects with river basin monitoring are given below: Project on Control of Dangerous Substances in River Basin Areas (TMKK) (2011-2013) Detection of Hazardous Materials in Turkey’s Coastal and Transitional Waters and Ecological Coastal Dynamics Project (KIYITEMA) (2012-2014) Detection of Water Pollution Caused by the Use of Plant Preservation Products and Determination of Environmental Quality Standards on a Material or a Material Group Basis(BiKoP) (2012-2014) Integrated Pollution Monitoring Projects (since 2013) River Basin Protection Action Plans (HKEP) (2011-2013) Determination of Water Quality Targets and Sensitive Areas in Terms of Basins in Turkey (HHAP)(2012-2016) EU Twinning Project on water quality monitoring (ÇŞB ve EU) (2011-2013) Brief descriptions of the mentioned projects are given in Annex II to this Report. 1.1. Hydromorphology As published in the Official Gazette No. 28,910, dated February 11, 2014, the Regulation on monitoring of surface and ground water, provisional article 1 - (3) came into the force, which stated that biological and hydromorphological indices shall be determined within eight years. In other words, hydromorphological monitoring should be completed in 8 years in all water bodies in Turkey. In addition to that, a project “Determination of Sensitive Areas and Quality Targets for River Basins in Turkey” has started in 2013 under the Ministry of Environment and Water Affairs and TUBITAK MRC coordinates it. This project will provide crucial inputs for further hydromorphological studies by producing data on rivers depth and width change, passage of fishes, rivers bed structure, velocity, channel structures, water flows and other dynamics studies. So far, hydromorphological studies have been conducted in the Büyük Menderes, Susurluk, Konya Closed Basin and Meriç-Ergene basins. The Black Sea rivers will be soon attended and regular monitoring programmes, where hydromorphology is included once per 6 years as minimum, will be developed. 78 December, 2015 Black Sea Rivers Monitoring 1.2. Physico-chemical and hydrobiological parameters In Turkey, river basins have been monitored by the State Hydraulic Institute (SHI) since 1950’s serving flood protection, agricultural activities, hydrological energy production and drinking water supply. Because of the aobove mentioned missions, SHI has not been focused on environmental pollution of river basins in detail. Only conventional parameters like TSS, BOD5, COD, nitrate, nitrite, orthophosphate, total nitrogen, total phosphorus, ammonia, and Heavy Metals (Hg, Cd, Cr, Cu, Zn, Ni) have been analysed monthly or on 2 months intervals. With the same frequency flow rates of rivers have been measured as well. For the Black Sea Coasts of Turkey, Yeşilırmak, Kızılırmak, Sakarya, Filyos and Melet Rivers have been monitored monthly by SHI. Distribution of monitoring stations along Black Sea river basins is given in Figure 34. Figure 34. Distribution of monitoring stations along Black Sea river basins (Turkey) Pesticides have been measured sporadically in scientific research and projects in 1998-2000 (Yeşilırmak and Kızılırmak Rivers) and later to evaluate inputs of rivers to the Black Sea. The same stands for metals. For instance, in 2000, a study was undertaken for heavy metals (Cd2+, Pb2+, Zn2+ , Cu2+ , Ni2+ and Co2+ concentrations) (Altas and Büyükgüngör, 2006), Table 22 gives information on the sampled stations. Table 22. Selected sampling stations and their features (Altas and Büyükgüngör, 2006) (Turkey) No. Sampling Station No. Sampling Station 17 Samsun Sewage System Çark Stream Origin of the Wastes Domestic and industrial Industrial 1 Sakarya River 2 18 Mert River 3 Melen Stream Industrial 19 4 5 Alaplı Stream Erdemir South Collector Industrial Industrial 20 21 TÜGSAŞ Fertilizer Industry Inc. KBİ Copper Industry Yeşilırmak River 6 Erdemir North Collector Industrial 22 Miliç Stream 7 Gülüç Stream Industrial 23 Civil Stream 79 Origin of the Wastes Domestic Domestic and industrial Industrial Industrial Domestic and industrial Domestic industrial Industrial and December, 2015 Black Sea Rivers Monitoring No. Sampling Station Origin of the Wastes 8 Çatalağzı Stream 9 Kozlu Stream 10 11 Zonguldak Stream ÇATEŞ-B Ash Canal Domestic industrial Domestic industrial Domestic Industrial 12 Filyos Stream 13 Bartın Stream 14 15 Sinop Sewage System Kızılırmak River 16 Kürtün Stream Domestic industrial Domestic industrial Domestic Domestic industrial Domestic No. Sampling Station Origin of the Wastes and 24 Melet River and 25 Ordu Sewage System Domestic industrial Domestic 26 27 Giresun Sewage System Aksu Stream and 28 Fol Stream and 29 Söğütlüdere Stream and 30 31 Trabzon Sewage System Değirmendere Stream 32 Rize Sewage System Domestic Domestic industrial Domestic industrial Domestic industrial Domestic Domestic industrial Domestic and and and and and The Project “Monitoring the Black Sea” (2006- 2010), continued the efforts to trace riverine pollution stemming to the Black Sea. For example, according to the results of this project, Yenice (Filyos River) is one of the most important pollution sources along the Black Sea coast. Other impotent sources are the rivers Sakarya, Kızılırmak and Yeşilırmak. Regular measurements of trace metals are carried out at Sakarya and Filyos Rivers. Additionally, Feryal Akbal et al. (2009) carried out studies on water and sediment quality along Turkey’s Central Black Sea coasts rivers in 2007. Samplings were conducted at 6 stations located in the following rivers: Yeşilırmak, Abdal, Mert, Kürtün, Engiz, and Kızılırmak Rivers. The studied parameters were total carbon (TC), total inorganic carbon (TIC), total organic carbon (TOC), ammonium nitrogen (NH4-N), nitrate-nitrogen (NO3-N), nitrite nitrogen (NO2-N), total phosphorus (TP), sulphate, total bitterness, methylene blue active materials (MBAS), phenol, absorbable organic halogens (AOX), dissolved oxygen (DO), pH, electrical conductivity (EC) in water; TC, TIC, TOC, TP, pH, electrical conductivity (EC), redox potential (Eh), and water contents (WC) in sediments. In line with WFD-related harmonization studies in Turkey, since 2014 work on classification of water bodies and specific pollutants determination has been started in the projects KIYITEMA and TMKK. Priority substances are monitored seasonally and monthly. The list of specific pollutants has not been officially announced yet. This list and respective quality standards (EQS) will be published as an Attachment to the “Regulation on Surface Water Quality Management (2012)” by the end of 2015. SHI prepares a large scale project to start monitoring specific and priority pollutants in all river basins in Turkey in 2016. Hydrobiological parameters are not yet attended in TR rivers monitoring. The same stands for biota contamination and pollution of sediments. References Akbal, F., Gürel, L., Bahadır, T., Güler, I., Büyükgüngör, H. 2009, Seasonal and Spatial Variations in Surface Water Quality at the Mid-Black Sea Coast of Turkey. 5th BBCAC, 23-26 September Fatsa-Ordu Altas, L., ve Büyükgüngör, H. 2006, Heavy metal pollution in the Black Sea shore and offshore of Turkey. Environ Geol (2007) 52:469-476 80 December, 2015 Black Sea Rivers Monitoring Sur, H. İ., Yüksek A., Altıok H., Sur, M., Ünlü, S., Taş, S., Yılmaz, N. Ve Demirel, N. 2010, Monitoring Black Sea Pollution Final Report Karadeniz Monitoring Project Final Report, Istanbul University, Marine Sciences and Administration Institue (2010) 1.3. Calculation of loads The “Regulation on Protection of Water against Pollution, taking samples and analysis methods” (no of OG: 27372, date: 10.10.2009) gives a very general description how to calculate pollution loads in rivers. For velocity-area measurement method: determining flow rate by multiplying velocity in the section by the section area of the mass flowing into this specific section. Consequently, the most significant aspect of this method is velocity measuring. Various velocity measuring systems and devices successfully used are enlisted: Current meters (propeller type) Electrical methods (thermal conductivity, hot-wire anemometers, hot-film anemometers) Float flowmeters Pitot tubes Measurements by monitoring substances Water level and flow rate measuring in streams are carried out at flow observation stations sustained by the State Hydraulic Works (DSI) and Electric Power Resources Survey and Development Administration (EIE). For flow rate measuring, the below given TSE Standards are followed. TS 3417/June 1979, Measuring Fluid Flow in the Pipes - Velocity-Area Method in which Pitot tubes are used TS 2353/April 1976, Measuring Water Flow in the Pipes –Monitoring Methods TS 1423/April 1973, Measuring Fluid Verdi by Orifice Plates and Nozzles TS 1424/April 1973, Measuring Fluid Verdi by Fluid Venturi Tubes Mixtures of samples taken from various points on cross-sections of rivers are used to determine average composition or total pollution loads. Preparation of this type of samples requires a special tool to collect sample from a known depth. However, as local changes are generally much more important than total or average values in natural water masses, samples should be taken and examined separately. 1.4. Other types of monitoring Limited operational monitoring studies have been carried by the Ministry of Environment and Urbanization since 1990. Unfortunately, this operational monitoring (for water bodies at risk) was not sustained on a permanent basis. Eutrophication-related parameters were mainly monitored in these studies. On February 11, 2014 (as published in the Official Gazette No. 28910), the Regulation on Surface Water and Ground Water Monitoring came into force. It states that the governmental institutions and organizations will implement monitoring activities on water quality, creating monitoring infrastructure in the course of five years and will work to establish regular monitoring of surface water and groundwater bodies. Article (4) of this regulation indicates that the national monitoring network shall be established (and should start functioning) within five years 81 December, 2015 Black Sea Rivers Monitoring at latest after entry into force. Thus, as envisaged by the referenced Regulation, in TR operational monitoring of surface waters should fully function by 2019 together with surveillance and investigative monitoring as required by the WFD. Protected areas In Turkey, natural and biodiversity-rich areas are protected by several different statuses such as national park, nature park, nature reserve, nature monument, wildlife reserve, specially protected area, biosphere reserve and Ramsar site. As a result of the diversity of protection statuses, protected areas are managed under different laws, regulations or international conventions and by different authorities. Currently, about 7.2% of Turkey’s land area is protected and these designations focus on forest, wetland and mountain habitats and include 40 national parks, 31 nature conservation areas, 184 nature parks, 81 wildlife reserve areas, 15 special environmental protected areas, 14 Ramsar sites and 1 biosphere reserve. Figure 35 shows national protected areas located within the Black Sea coasts: 1 national park, 1 nature parks, 5 national reserves, 5 wildlife conservation areas and 1 Ramsar site. Figure 35. Protected Areas in the Black Sea coasts of Turkey Igneada Longoz Forests National Park; the area is defined as a National Park in 2007. The national park covers an area of 3,155 ha (7,800 acres) and is located at Igneada town on the Turkish-Bulgarian border at 25 km (16 mi) far from Demirkoy District of Kırklareli Province. This protected area with the high habitat and biological diversity and many different ecosystems (sand dunes, wetlands, longos (flooded alluvial) forests, deciduous forests, and many streams) is the most important floodplains (Longos) forests on a national and European scale. The Longos forests which are completely covered with water during winter and spring has a floristic composition of mixed forest trees of 8-15 meters tall. Since the alluvial soils have more intensive micro-organism activities, the forests and the other plants in this region start vegetation earlier than the other plants. Kasatura Körfezi Nature Reserve; the Kasatura Gulf is located at the Black Sea coast, southwards of Kıyıköy (Vize). In the area, there are forests composed of various trees, longoz forests, sand dunes, maquis, black pine and oak forests. The place is important since there are various habitats and thriving plant diversity in the field, along with the plant species which are under protection of international conventions. 82 December, 2015 Black Sea Rivers Monitoring Demirciönü Nature Reserve: The nature reserve is in the Akçakoca district of Düzce, in the Black Sea region. It has a unique ecosystem that is very rich in flora and fauna, and wildlife inhabiting the park includes bears, wild boars, foxes, rabbits, wolves, jackals, deer, partridge, eagles, crows and sparrow hawks. Hamsilos Nature Park: This area is a rare example of fjords in Sinop, Black Sea coast of Turkey. Due to its extraordinary natural beauty, Akliman-Hamsilos area was declared as a first degree natural protected area. Sarıkum Nature Reserve: The area is in Abali village, near merkez in the province of Sinop, in the western Black Sea region. The 78 hectares of the area are situated in a combination of sea, sand, lake and forest. There are many species of water birds and birds of prey, and animals like roe deer, lynx, bustard and swan. There is a dense presence of the wild colt plant, and species of trees also include beech, horn-beam and oak, a rare combination, plus a pure ash forest. Kızılırmak Delta Ramsar Convention Area and The Wildlife Development Area: It is the biggest wetland in the Black Sea Region. Delta has a great ecological value not only tor Turkey but also worldwide due to including 20 different lagoons, swamps and torb areas and great area (56.000 ha). In 1994 Kızılırmak delta was determined as an Important Bird Area. In order to protect the natural properties of Delta, all of the wetlands in eastern part of the Delta were declared as Natural Sit Area and it is under protection since 1994. Hacıosman Nature Reserve: The forest ecosystem is a rare one, and the most common species are ash, oak, walnut and silver birch. Because of the nourishment qualities of the area, there are also many species of animals inhabiting the forest, which include mole, turtle and grey heron. In order to protect and preserve the area, the 86 hectares were given official natural protection in 1987. Hacıosman Nature Reserve; This area with habitat diversity, bird richness and bottomland forest (longos) ecosystem have been designated as Strict Nature Reserves in Black Sea coast of Turkey. Çamburnu Nature Reserve: The Park is in Sürmene in the Eastern Black Sea. The main characteristic of this 180-hectare park is the Scotch pine (Pinus sylvestris ssp. Kochiana) which normally grows only at an altitude of between 1300 – 2700m, but here is near sea level. The area is also the first point at which migrating birds arrive when coming from the north over the Black Sea, to the mountain range of it. Legal Aspects and Responsible Organization for National Protected Areas As mentioned above, protected areas are managed under different laws, regulations or international conventions, and by different administrative institutions. Institutional responsibility for the establishment and management of MCPAs lies with four agencies: (i) the Authority for the Protection of Special Areas (EPASA), (ii) the Fisheries Department, Ministry of Agriculture and Rural Affairs, (iii) the General Directorate for Nature Conservation and National Parks (GDNCNP) and (iv) the Ministry for Culture and Tourism (MCT). Table presents an overview of the national protected areas. Table 23. Types of Protected Areas and Legislations (Turkey) Type of Protected Area Nature Monuments National Parks Nature Reserves Responsible Organization Legislation General Directorate for Nature N. Parks Law 2873 Conservation and National Parks (GDNCNP) GDNCNP N. Parks Law 2873 GDNCNP N. Parks Law 2873 83 December, 2015 Black Sea Rivers Monitoring Type of Protected Area Nature Parks Natural Sites (SITs) Responsible Organization GDNCNP Ministry of Culture and Tourism (MOCT) GDF GDNCNP Legislation N. Parks Law 2873 Law for Protection of Cultural and Natural Assets 2863 Protective Forests Forest Law 6831 Ramsar Sites National Regulation for Protection of Wetlands Special Environmental Protection Environment Protection Decree 383 Area Agency for Special Areas (EPASA) Wildlife Development Areas GDNCNP Terrestrial Hunting Law 4915 Source: Documentary of MoEF, GDNCNP, GDF, EPASA The “Black Sea Biodiversity and Landscape Conservation Protocol” (to the Bucharest Convention) came into force and this was published in the official newspaper dated July, 6, 2004 with number 25514 in Turkey. There exists no specific monitoring programme for surface waters in protected areas in Turkey. Drinking water In Turkey, Ministry of Health is the only official authority in protection of human health. It is responsible for implementation of related national legislation/policy and also for transposition of relevant EC Directives (concerned with human health) in Turkey. "Regulation on Water Intended for Human Consumption" in Turkey was released in the Official Gazette No. 25,730, dated 17.02.2005. It was prepared in accordance with the Council Directive 98/83 EC and requires: Supervisory monitoring of drinking water quality at points of delivery to consumers with specified frequency, Monitoring programs at sources of drinking water, i.e. springs, drinking water catchments, wells and similar structures, Preparation of other appropriate monitoring programs with the minimum conditions laid down in the Regulation, Determination of sampling points by competent authorities, Implementation of sampling programs throughout the year to control the quality of water consumed. Real-time monitoring Real-time monitoring is existent in Turkey and is well developed, however, not exactly in the field of rivers monitoring. Automated measurements of various parameters on a pilot basis are taking place for river discharges and for atmospheric pollution. An important Project was once implemented aiming at development of real-time rivers monitoring. 84 December, 2015 Black Sea Rivers Monitoring Central Real Time River Pollution Monitoring Project (2006-2008) The aim of this project was: to monitor pollution loads of wastewaters (industrial and domestic) and from other sources throughout the river basin, to make predictions for appropriate precautions. The scope of the Project was: establishing stations on Yeşilırmak River which is flowing into the Black Sea in order to monitor the changes in water quality by on-line systems, processing the data in real time and collect them on a main server system, predicting the effects of pollution by using model-like systems in order to establish a control mechanism for clean and efficient use of water resources. This Project was financed by TUIBITAK and coordinated by Ankara University. Hitit University was partner of the Project and client was the Ministry of Environment and Forestry (old name of the Ministry of Environment and Urbanization). In 2008, two stations for real-time monitoring of the Yesilirmak River were established at the exit of the Amasya City (highly pollutes area). The data from these stations were being transferred to a “Monitoring Center of Yeşilırmak” which was established at the Ankara University Engineering Faculty. At stations, flow, pH, conductivity, DO, NH4-N, NO3-N, TOC, Cl, Phosphate, and Chlorophyll-a were monitored with sensors. However, after the completion of the project, nobody took the responsibility of the operation of these automated stations and no more data were produced by them. 1.5. Data management and assessments under the WFD and/or others There is a project-based development process to manage the river basin data and match the WFD requirements. Alas, as mentioned above, a Joint Water Quality Monitoring System is absent, as well as a Joint Water Quality Data/Information Sharing Platform. There are river basins management reports for 11 river basins, including Yesilirmak and Kizilirmak Basins. In these reports, water quality maps are included. The reports are available on the webpage of the Ministry of Environment and Urbanization (http://www.cygm.gov.tr/CYGM/AnaSayfa/SuToprakYonetimi/HavzaKoruma.aspx?sflang=tr). However, there is no regular system of communication to public the results of monitoring activities managed by SHI (State Hydraulic Affairs). Conclusions Within the framework of the Turkey’s Acquis Communautaire Accordance Programme, WFD transposition into national legislation is of highest priority. During this process, important integrated environmental projects have been realized, which inter alia aimed to advance surface water monitoring in Turkey. In Turkey, water and wastewater management issues are shared among many governmental organizations. Each of these organizations has developed plans, monitoring systems and regulatory precautions for management and control of water pollution. Along with crossing and/or overlapping activities under such a complicated institutional framework, there are still significant gaps in surface water quality monitoring. In 2007, SHI (State Hydraulic Affairs) was incorporated in the structure of environmental governmental organizations. Thus, an important step was made 85 December, 2015 Black Sea Rivers Monitoring toward development of an integrated water resources management. In this, a strong ground for planning of more efficient water resources monitoring in compliance with WFD has been established. Since 2015 SHI is responsible for surface waters monitoring implementation which should take into consideration WFD requirements. So far, there is no regular monitoring in rivers for hydromorphological and hydrobiological parameters, including biota contamination. In chemical monitoring, oxygen, nutrients, BOD5, COD and trace metals (zinc, copper, chromium, lead, and cadmium) are regularly measured. (Note: trace metals monitoring is conducted in Sakarya and Filyos Rivers only). River sediments are not monitored. However, for 19 river basins, monitoring programmes have been already prepared by the Ministry of Forestry and Water Affairs including all parameters required by the WFD (biological monitoring as well). Other 6 river basins are pending in the Agenda, by the end of 2015 their monitoring programmes shall be completed as well. In the process of EU accession, Turkey intends to develop river basin management plans for its twenty five river basins. Until 2019 these plans will be developed in line with WFD requirements. UKRAINE In Ukraine, monitoring of rivers is regularly conducted. The number of stations varies from 49 to 137, the major set of traced variables include from 3 to 25 parameters depending on the frequency required by the national legislation. Some stations and parameters are observed every 10 days, others – monthly, and there are stations and parameters which are monitored on a seasonal basis. The monitoring is regulated by: 1. Resolution of the Cabinet of Ministries of Ukraine “On the approval of the Regulations of the state environmental monitoring system” (Nr 391 date: 30.03.1998). 2. Resolution of the Cabinet of Ministries of Ukraine “On the approval of the Regulation of state water monitoring” (Nr 815 date: 20.07.1996). 3. Resolution of the Cabinet of Ministries of Ukraine “On the approval of the Regulations of the state environmental monitoring system” (Nr 391 date: 30.03.1998). Specific national programs are enlisted below: 1. State Special-Purpose Environmental Programme on Performance of Environmental Monitoring (Resolution of the Cabinet of Ministries of Ukraine Nr 1376, date: 05.12.2007). 2. Regional Environmental Monitoring Programme – Odessa Oblast for the period 2011-2017. 3. Environmental Monitoring Programme – Mykolaiv Oblast (Resolution of Mykolaiv Oblast Council Nr 4, date: 23.12.1999). 4. Environmental Monitoring Programme – Kherson Oblast for the period 2010-2015 (Resolution of Kherson Oblast Council Nr 1376, date: 06.08.2010). The standard operational procedures, guidelines and manuals in UA are: 86 December, 2015 Black Sea Rivers Monitoring Organisation and carry out of monitoring of surface water pollution (under the Ministry of Ecology and Natural Resources of Ukraine) (КНД 211.1.1.106-2003) (Order of the Ministry of Ecology and Natural Resources of Ukraine Nr 89-M, date: 04.06.2003). Single Inter-departmental Guidelines on organisation and performance of the state monitoring of waters (Nr 485, date: 24.10.2001). Guidelines of hydrological researches/observations of estuary (river mouth). – M.: Hydrometizdat, 1965. Analyses are performed according to special methods and methodologies, they can be found here: Gagarina O. V. Assessment and establishment of norms of natural waters: criteria, methods, existing problems (http://www.twirpx.com/file/1267393/). SEV. Unified methods for water quality research/analysis. Part 1 – Methods for chemical analysis (http://www.geoversum.by/catalog/item298.html). There are four large rivers in Ukraine, flowing into the Black Sea (Danube, Dniester, Dnieper and Southern Bug). Among rivers, the most important contributors to the pollution/eutrophication of the Black Sea are the large rivers Dnieper (with Bug), Dniester and Danube (the branch Chilia). The catchment area of these three rivers is about 1400000 km2 and average annual river flow is 222 km3/yr. In Ukraine, the monitoring is not classified as surveillance, operational, investigative or any other type as given in EC legislation and terminology. It is organized on the principle of ‘agency’ conducting it, as described further below. Surface waters monitoring There are four “agency-level” monitoring systems for surface waters: 1) 2) 3) 4) State Hydrometeorological Service of Ukraine (State Emergency Service of Ukraine); State Environmental Inspection (Ministry of Ecology and Natural Resources of Ukraine); State Agency for Water Resources; Sanitary-Epidemiological Service (Ministry of Health of Ukraine); State Hydrometeorological Service of Ukraine performs monitoring (hydrochemical parameters) on 151 water bodies and carries out hydrobiological observations on 45 water bodies. 46 parameters are monitored. Such approach gives the possibility to assess chemical composition of water, nutrients parameters, content of suspended solids, heavy metals, pesticides, etc. Total 8 water bodies are monitored for chronic water toxicity level. Radiation level is also traced. Map of monitoring network is presented below in Figure 36. 87 December, 2015 Black Sea Rivers Monitoring Figure 36. Surface water monitoring stations – the Hydrometeorological Service under the State Emergency Service of Ukraine State Environmental Inspection of Ukraine monitors about 60 parameters in surface waters (rivers, lakes, etc.). Map of monitoring network is given below in Figure 37. Figure 37. Surface water monitoring stations – the State Environmental Inspection under the Ministry of Ecology and Natural Resources of Ukraine State Agency for Water Resources performs monitoring of surface waters. Monitoring of physical and chemical parameters is performed on 72 reservoirs, 164 rivers, 14 irrigation networks, 1 coastal lake and 5 channels. Also radionuclides are monitored in surface waters. Map with monitoring stations is given in Figure 38. The list of monitored parameters for Laboratories of the State Agency for Water Resources is similar to the list of the State Environmental Inspection (currently does not perform the monitoring of marine and surface waters) and Hydrometeorological Service. In the framework of State Agency for Water Resources there are also River Basin Management Authorities: Danube River Basin Management Authority - http://www.dbuvr.od.ua/ (stations in Figure 39) 88 December, 2015 Black Sea Rivers Monitoring Dniester-Prut River Basin Management Authority - http://dpbuvr.gov.ua/category/news/ Dnieper River Basin Management Authority - http://dbuwr.com.ua/ Southern Bug River Basin Management Authority - http://www.buvr.vn.ua/ Figure 38. Surface water monitoring stations – the State Agency for Water Resources (Ukraine) Figure 39. Danube River monitoring stations - Danube River Basin Management Authority (Ukraine) 89 December, 2015 Black Sea Rivers Monitoring Sanitary-Epidemiological Service is responsible of monitoring under sources for centralized drinking water supply and in recreational areas (along river banks and Black Sea coast line). Also it performs monitoring (chemical parameters) of ground water used for drinking purposes. Map of monitoring stations is presented in Figure 40. Sanitary-Epidemiological Service (Ministry of Health of Ukraine) monitors the following parameters: temperature, odor, colour, turbidity, SS, pH, dissolved oxygen, BOD5, permanganate oxidability, alkalinity, total hardness, dry residue, calcium, magnesium, total iron, chlorides, sulphates, ammonia nitrogen, nitrate nitrogen, nitrite nitrogen, fluorine, anionic surfactants, oil products, cooper, lead, zinc, chromium(VI), nickel, cadmium, aluminum and bacteriological parameters (coli-phage, total saprophytic bacteria, coli-index, pathogenic microflora). Some laboratories under the Ministry of Health of Ukraine also monitor radiation parameters (total activity). Figure 40. Surface water monitoring stations – the Sanitary-Epidemiological Service under the Ministry of Health of Ukraine Same as in Georgia, there were several international projects dealing with rivers monitoring in UA, building capacities for WFD-compliant observations. The last one is the EPIRB Project, which included pilot studies in the Prut Basin (between Moldova and Ukraine). In general, for all types of monitoring in UA, the equipment used is often outdated. It is very important to improve the technical basis of water quality observations and analytical control. An inter-departmental program to improve the technical layout and equipment of monitoring should be created and implemented. 1.1. Hydromorphology Hydromorphological changes are caused mainly by overregulation of river flow (i.e. hydro-energy facilities), urbanisation process and agriculture activity. Local dams protect separate settlements and industrial enterprises. So, the following components of hydromorphological changes are fixed: interruption of free river water flow and free migration of fish; 90 December, 2015 Black Sea Rivers Monitoring hydrological modifications; modifications of river morphology. Unfortunately, nobody is responsible for performing regular hydromorphological monitoring. However, it is possible to find data on the following parameters in scientific literature and in some statistical sources. Table 24. Hydromorphological parameters (Ukraine) № Quality element Parameters Rivers Lakes 1 River continuity River continuity Yes N/A Quantity and dynamics of river flow Yes N/A 2 3 Hydrological regime Morphological conditions Connection with groundwater bodies No Residence time (for lakes) No River depth and change of the width Yes N/A Structure and substratum of river bottom Yes N/A Structure of river zone Variation of lake depth No N/A N/A No Quantity, structure and substratum of lake bottom N/A No Structure of lake shore N/A No 1.2. Physico-chemical and hydrobiological parameters The list of monitored parameters varies. The key monitored parameters are as follows: Table 25. UA key monitored parameters for rivers Ammonia nitrogen N total Nitrite nitrogen Nitrate nitrogen Synthetic surface active substances BOD pH Hydrocarbonates Hardness CO2 Suspended solids Fe total Odour K Ca Dissolved oxygen Colour Cr 91 December, 2015 Black Sea Rivers Monitoring Alkalinity Mg Mn Cu Mineralisation Na Oil products Permanganate oxidation Conductivity Transparency Oxygen saturation Salinity Sulphates Sum of nitrogen compounds Sum of ions Temperature Phenols Phosphates P total P mineral Chlorides Cr (VI) Cr total Chloroorganic pesticides COD Zn 1.3. Calculation of loads Methodology does not exist but load can be calculated according to the following document: Temporary methodological recommendation on calculation of movement of organic, biogenic substances, pesticides and microelements with river flow. – M.: Hydrometizdat, 1983. 1.4. Other types of monitoring Depending upon objectives there are three types of monitoring: Routine (regular or standard) monitoring – it is implemented in the framework of national and regional programmes and many institutions are involved – detailed information is given above; Crisis monitoring – it is implemented in case of emergency, mostly the State Emergency Service of Ukraine and State Sanitary-Epidemiological Inspection are responsible. The list of monitored parameters depends upon the problem and emergency situation; Background (scientific) monitoring – it is performed in the framework of international, national and local projects. Usually it is performed only during 3-5 years. The list of parameters and responsible institution is defined by the project and monitoring area features. It is performed also in protected areas (see below). 92 December, 2015 Black Sea Rivers Monitoring Protected areas According to the Law of Ukraine “On natural protected fund of Ukraine” the following types of protected areas in Ukraine are in place: State natural reserves National parks Natural parks State nature reserves Nature sites Dendrological parks and botanical gardens Therapeutic area and resorts Each type of protected area has a list of permitted activities. According to the Law of Ukraine “On natural protected fund of Ukraine” protected areas can be used for background monitoring activity and for background (scientific) monitoring activities. Drinking water The Act of Ukraine No 2455-IV dated March 3, 2005, approved the National Program "Drinking water of Ukraine for 2006-2020". The responsible authority for Program implementation is: at national level: Ministry of Housing and Communal Services of Ukraine, and at regional and local levels: Council of Ministers of the Autonomous Republic of Crimea, regional, Kyiv and Sevastopol City State Administrations, rural, village, district and city councils. Besides, Ministry of Housing and Communal Services of Ukraine and state (regional, district state administrations) and local authorities are responsible for execution of the National Program of Reforming and Development of Communal Services for 2009-2014 (approved by the Act of Ukraine No 1511-VI dated June 11th, 2009). In 2014 a new state standard DSTU 7525:2014 “Water drinking. Requirements and control methods of quality” was approved. It contains new lists of organoleptic, chemical, microbiological, virological, parasitological, mycological, toxicological parameters of water quality which should be monitored and controlled; also water toxicity level, radiation safety level should be controlled. According to the national legislation (GOST 17.1.1.03-86 “Nature protection. Hydrosphere. Classification of water usage”), there are two types of water bodies: Category 1 – water bodies which can be used for drinking water intake and for water intake for food industries Category 2 – water bodies used for culture-and-community purposes and water bodies, located within settlement borders Corresponding MAC values should be observed in each type of water body. 93 December, 2015 Black Sea Rivers Monitoring Real-time monitoring Real-time monitoring system is still not created, especially for rivers. 1.5. Data management and assessments under the WFD and/or others For rivers data management the Central Geophysical Observatory (Kiev, http://www.cgo.org.ua/) sustains a database, which is not in open access and is not on-line. The database includes data on hydrology, hydrography, meteorology/climatology, and pollution of the natural environment. Specifically for rivers the data are on rivers flow and pollution level. Each 4 months Bulletin on surface waters pollution is compiled. Information can be provided on request, but raw data are not freely available. Conclusions UA national monitoring system includes three types of monitoring: Routine (regular or standard) monitoring – is implemented in the framework of national and regional programmes and many institutions are involved – detailed information is given above Crisis monitoring – is implemented in case of emergency, mostly the State Emergency Service of Ukraine and State Sanitary-Epidemiological Inspection are responsible. The list of monitored parameters depends upon the problem and emergency situation Background (scientific) monitoring – is performed in the framework of international and local projects. Usually it is performed only during 3-5 years. The list of parameters and responsible institution is defined by the project and monitoring area features. It is performed also in protected areas. There are following problems: many institutions are involved and there is no real coordination among them; there is no data exchange, data correlation and analysis between institutions; number and location of monitoring points as well as monitoring parameters are outdated and should be revised; monitoring data are stored and not processed; data are rarely used for the development of recommendations and there are no data products, which can be used by decision-makers; equipment is obsolete and should be urgently replaced with new and modern devices; hydromorphology is not regularly studied; hydrobiology is not included in the state monitoring, including biota contamination; river sediments are not studied; old methods for water analysis are used (due to outdated equipment); basin approach to river management is declared but it is not fully introduced. 94 December, 2015 Black Sea Rivers Monitoring The implementation of the WFD in Ukraine is a very complex process. Implications are to be found in the legislative, institutional, scientific and technical fields. From legal point of view Ukraine has no difficulties to comply with WFD standards, since the existing UA standards are comparable or even stricter than those valid in the EU countries. The major problem in Ukraine, however, is the standards enforcement. There are a large number of governmental and interdepartmental normative documents - regulations, orders, resolutions, Guidelines, etc. – with requirements to be followed obligatory, which complicates the work of practitioners. Furthermore, in contrast to the EU Water Framework Directive, the Ukrainian water legislation focuses on very stringent limit values for emissions but without defining environmental targets for receiving water bodies and the period in which these targets shall be achieved. Therefore, the state monitoring is concentrated on controlling effluents (against the established standards) but without the obligation to intertwine them with the monitoring on quality of the environment. Thus, programmes of measures aimed at water quality (for the receiving water bodies) improvements are of low efficiency. The existing classification system for surface water, which differs slightly from the EU system, gives a picture of actual state of water quality but it is not used to prepare pressure/impact analysis and risk assessments which should be the basis of an action plan on water quality protection and rehabilitation, and inter alia of relevant monitoring programmes. Hence, much effort should be invested to harmonise the Ukrainian river monitoring systems with the European ones following the ‘combined18’ approach required by the WFD. 3. International level (Black Sea regional) At regional level, rivers monitoring is required by the Bucharest Convention and its Protocols, namely the Protocol on LBS. The latter was revised in 2005-2008 and signed by the BS coastal states on 17th of April 2009. However, the revised Protocol is not in force as being so far ratified by GE only. Thus, the acting Protocol is the one of 1992 (ratified in 1994, http://www.blacksea-commission.org/_convention-protocols.asp), which is considered quite outdated. The BS SAP200919 (http://www.blacksea-commission.org/_bssap2009.asp) is the Guiding document toward improvement of the governance of environment protection at the regional level. It contains targets which are directly or indirectly addressed to rivers monitoring: Target 30: Introduce cost efficiency approach to nutrient management in all BS countries Target 37: Harmonise the monitoring and assessment of N & P (concentrations and loads) in major rivers and straits. Target 51: Develop/improve the existing monitoring system to provide comparable data sets for pollutant loads (from direct discharges and river inputs) and for other parameters Target 52: Improve the “List of Black Sea-specific priority pollutants” to help target monitoring priorities. Therefore, the BSSAP2009 speaks about rivers monitoring and the importance of its harmonization at the regional level. In this “combined approach”, control and prevention of water pollution is only possible when applying environmental quality standards (EQS) and emission limit values (ELV) together. 19 Strategic Action Plan for the Environmental Protection and Rehabilitation of the Black Sea, signed on 17 th of April 2009 by all coastal states. 18 95 December, 2015 Black Sea Rivers Monitoring However, BSIMAP (the regional Black Sea Integrated Monitoring and Assessment Programme, http://www.blacksea-commission.org/_bsimap.asp) does not regulate rivers monitoring. It only requires reporting on river loads (specifies on what parameters) and such reporting takes place on annual basis. Thus, there is no regional document, which would ensure harmonization of rivers monitoring, and would specify how exactly this or these types of monitoring should take place. Under the BSC, reports on LBSs are being annually prepared including Black Sea Basin rivers, however, they include very limited information on riverine loads which is besides not publicly available. The BSC 5-yearly SoE Reports do not include budgets of nutrients and pollutants where loads of all Black Sea rivers should be taken into consideration. Conclusions and Needs in harmonization 1. General conclusions The analysis of current river monitoring in the HBS Project beneficiary countries shows serious differences in strategies and the comparability of generated data is thus doubtful. Even in the very short List of rivers parameters reported to the BSC, the BS countries rivers monitoring programmes have little in common as demonstrated below. Table 26. List of rivers parameters reported by the BS countries to the BSC Parameters (Estimated loads per year) BULGARIA GEORGIA ROMANIA TURKEY UKRAINE Nitrate (N-NO3) Yes Yes Yes Yes Yes Nitrite (N-NO2) Yes Yes Yes Yes Yes Orthophosphate (P-PO4) Yes Yes Yes Yes Yes Total Nitrogen Yes Yes Rarely No (TIN only) Total Phosphorus Yes Yes Rarely Yes Ammonia (N-NH4) Yes Yes Yes Yes Yes Zinc (Zn) - Dissolved Copper (Cu) - Dissolved Chromium (Cr) - Dissolved Lead (Pb) - Dissolved Cadmium (Cd) - Dissolved Mercury (Hg) - Dissolved Nickel (Ni) - Dissolved Total Zinc Total Copper Yes Yes Rarely Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 96 December, 2015 Black Sea Rivers Monitoring Parameters (Estimated loads per year) Total Chromium Total Lead Total Cadmium Total Mercury Total Nickel Iron Lindane (instead of Gamma-HCH) TSS (instead of Suspended Particulate Matter) BULGARIA GEORGIA Rarely ROMANIA Yes (dissolved since 201020) Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Total Hydrocarbons Anionic active surfactants (instead of detergents) Phenols PCB-28 PCB-52 PCB-101 PCB-118 PCB-153 PCB-138 PCB-180 Total PCBs BOD-5 COD-Cr Rarely Yes Yes TOC Yes Yes TURKEY Yes Yes Yes Yes Yes Yes Long Term Annual Average for the Riverine Flow Yes Rarely (only for some rivers) Yes Yes Yes Yes Yes Yes Only Suspended Particulate Matter Yes Yes Yes Yes Yes Yes (occasionally) Yes (occasionally) Yes Yes Yes Yes Yes Yes Yes (Strontium90; Cesium137)occasionally Yes Yes Yes Yes AOX Tritium Other Radionuclides (please name) Average Riverine Flow for the Year UKRAINE Other rivers parameters, outside of the BSC reporting, are enlisted in the table below. Among them, only pH is measured by all BS states. Meanwhile, Total Iron is indicated in the Table of Basic Parameters, see Annex I. For the rest of the BS countries there is no indication whether they report on dissolved or on total iron. 20 97 December, 2015 Black Sea Rivers Monitoring Table 27. Other rivers parameters (outside of BSC reporting) monitored in the BS states rivers monitoring Parameters рН Temperature, T0C Odour Chromaticity Transparency Colour Turbidity Fluoride Conductivity (electroconductivity, fixed residue), µS/cm CaCO3-Hardness, mg CaCO3/l Dissolved oxygen, mg/l Oxygen saturation Total mineralization Sulphates Chlorides Ca Total magnesium (Mg) Carbon dioxide Potassium Total silicon Alkalinity Total manganese (Mn) Total sodium Oil products (visual) Permanganate oxidation (COD-Mn) Hydrogen sulphide Alachlor Anthracene, µg/l Atrazine, µg/l Benzene (Benzo (a) pyrene), µg/l Benzo (b) floroanthene), µg/l Benzo (g,h,i) perylene, µg/l (Benzo (k) fluoroanthene), µg/l Brominated diphenylethers C10 – 13 chloralkanes Chlorfenvinphos Chlorpyrifos µg/l 1,2-Dichloroethane, µg/l Dichloromethane, µg/l Di(2-ethylhexyl) phthalate (DEHP) Diuron Endosulfan alpha-endosulfan Flouranthene, µg/l Hexachlorobenzene Hexachlorobutadiene, µg/l Hexachlorocyclohexane (gamma-isomer,lindane) Isoproturon Indeno (1,2,3-cd) pyrene, µg/l Naphthalene BULGARIA Yes Yes GEORGIA Yes Yes Yes ROMANIA Yes TURKEY Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Rarely Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes 98 Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes UKRAINE Yes Yes Yes Yes Yes Yes Yes Yes Rarely Yes Yes Yes Yes Yeas Rarely Yes Rarely Rarely December, 2015 Black Sea Rivers Monitoring Parameters Nonylphenols (4-(para)-nonylphenol) Octylphenols (para-tert-octylphenol) Pentachlorobenzene Pentachlorophenol Polyaromatic hydrocarbons Simazine, µg/l Tributyltin compounds (Tributyltin-cation) 1,2,4 – Trichlorobenzene, µg/l Trichloromethane (Chloroform), µg/l Trifluralin, µg/l Prometon, µg/l Prometryn, µg/l Propazine, µg/l Ametrin, µg/l Simetryn, µg/l Terbutryn, µg/l Chl a Macroinvertebrates Macrophytes Phytobenthos Fish Hydromorphological parameters BULGARIA GEORGIA Yes Yes Yes ROMANIA Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes TURKEY UKRAINE Yes Yes Yes Yes Yes Yes Yes Rarely Rarely Yes Yes Comparing frequencies of monitoring for some major rivers parameters, the picture is as follows: Table 28. Frequency of sampling in rivers Parameters Frequency of measurements per month BULGARIA Nitrate (N-NO3) Nitrite (N-NO2) Orthophosphate (P-PO4) Total Nitrogen Total Phosphorus Ammonia (N-NH4) 1 (4 times per year) 1 (4 times per year) 1 (4 times per year) 1 (4 times per year) 1 (4 times per year) 1 (4 times per year) GEORGIA ROMANIA 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) TURKEY21 1 1 1 1 1 1 1 1 1 1 1 1 Silica Zinc (Zn) - Dissolved UKRAINE22 1 1 (4 times per year) 1 (6 times per year) 21 - - Only conventional parameters like TSS, BOD5, COD, nitrate, nitrite, orthophosphate, total nitrogen, total phosphorus, ammonia, and trace metals (Hg, Cd, Cr, Cu, Zn, Ni) are analysed monthly or on 2 months intervals. 22 As per the Hydromet monitoring system. The frequency depends on the stations sampled. Some stations with their set of parameters are observed every 10 days, others – monthly, and there are stations with parameters monitored on a seasonal basis. 99 December, 2015 Black Sea Rivers Monitoring Parameters Frequency of measurements per month BULGARIA Copper (Cu) - Dissolved GEORGIA 1 (4 times per year) Chromium (Cr) - Dissolved Lead (Pb) - Dissolved Cadmium (Cd) - Dissolved 1 (12 times per year) 1 (12 times per year) Mercury (Hg) - Dissolved Nickel (Ni) - Dissolved 1 (12 times per year) Total Zinc 1 (4 times per year) 1 (4 times per year) Total Copper Total Chromium Total Lead Total Cadmium Total Mercury Total Nickel Iron Manganese Lindane (instead of GammaHCH) TSS (instead of Suspended Particulate Matter) Total Hydrocarbons Depends on type of monitoring 1 (4 times per year) 1 (12 times per year) 1 1 (12 times per year) Oil products (visual) Anionic active surfactants (instead of detergents) Phenols PCB-28 PCB-52 PCB-101 PCB-118 PCB-153 PCB-138 PCB-180 Total PCBs BOD-5 COD-Cr TOC ROMANIA TURKEY21 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) - - - - - - 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) - - - - - - 1 1 1 1 1 1 1 - 1 - 1 - 1 - - 1 1 1 1 (12 times per year) 1 (12 times per year) 1 1 1 1 1 (12 times per year) 1 (12 times per year) 1 (4 times per year) 1 (4 times per year) 1 (4 times per 1 (12 times per year) 100 UKRAINE22 1 (12 times per year) 1 (12 times per year) occasionally 1 1 1 1 1 December, 2015 Black Sea Rivers Monitoring Parameters Frequency of measurements per month BULGARIA GEORGIA ROMANIA TURKEY21 UKRAINE22 year) AOX Tritium Other Radionuclides (please name) Average Riverine Flow for the Year daily daily (water level) daily 1 1 Long Term Annual Average for the Riverine Flow Hydrobiology Phytoplankton Macroinvertebrates (zoobenthos) Macrophytes Phytobenthos (microalgae) Fish fauna Water level (rivers) Water flow (velocity/quantity and dynamics of rivers) Connectivity with groundwater bodies River continuity Variation of river depth and width Structure and substrate of the riverbed The structure of the riparian area (for rivers) - once every 3 years once every 3 years once every 3 years once every 3 years once every 3 years once every 3 years once every 3 years once every 3 years once every 3 years Hydromorphology daily 2 times daily 2-60 times per year continuously 1 once per 3 days month once per 6 years once per 6 years once per 6 years once per year continuous monthly once per 6 years once per 6 years once per 6 years once per 6 years 1 1 The national gaps in hydromorphological and hydrobiological monitoring are visible in the Table above. Additionally, in rivers monitoring the BS countries poorly study biota contamination and sediments pollution. Note: Attend also the Conclusion section of each country for country-specific gaps. 2. Conclusions as per priorities in harmonization 2.1. Definitions The terminology, hence, definitions are common for BG and RO, as required by EU legislation/policies. However, in GE, UA and TR national legislation does not identify or differently identifies important elements of monitoring and assessments, such as: 101 December, 2015 Black Sea Rivers Monitoring 1. Types of monitoring 2. Types of rivers 3. Types of water bodies 4. Reference conditions 5. Environmental quality standards 6. Environmental targets Any legal/policy document starts with definitions and a ’River monitoring strategy’ or a Programme cannot be an exception. Common definitions for the terms specified above are needed in the BS region to ensure national rivers monitoring programmes are built in a compatible way. 2.2. Identification of river types, water bodies and those, which are at risk or not They took place in BG and RO, however, GE, TR and UA do not conduct monitoring, which takes into consideration the type of a river or its water bodies classifications (first as a hydromorphologically homogeneous entity, and second – depending on the status – at risk or not at risk). Harmonization in river types and water bodies identification at regional level will ensure the countries common approach revising their stations networks, choice of monitoring parameters and frequencies. 2.3. Choice of monitoring parameters and frequencies Table 29 shows that there are very few rivers parameters (basic physic-chemical), which are monitored in all beneficiary countries, but not the same frequencies are followed in their sampling. In the Lists of other basic physico-chemical parameters there are differences, whereas priority and specific substances are mostly not monitored in GE, TR and UA. Table 29. Common rivers parameters in the monitoring programmes of the beneficiary countries Parameters (Estimated loads per year) BULGARIA GEORGIA ROMANIA TURKEY UKRAINE pH Yes Yes Yes Yes Yes Nitrate (N-NO3) Yes Yes Yes Yes Yes Nitrite (N-NO2) Yes Yes Yes Yes Yes Orthophosphate (P-PO4) Yes Yes Yes Yes Yes Ammonia (N-NH4) Yes Yes Yes Yes Yes BOD-5 Average Riverine Flow for the Year Long Term Annual Average for the Riverine Flow Yes Yes Yes Yes Rarely Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes The choice of monitoring parameters and frequencies is especially important to ensure comparability of data at regional level. As shown in the Tables above (Tables 26-28), even in BG and RO the chosen frequencies differ substantially as well as the lists of parameters. 102 December, 2015 Black Sea Rivers Monitoring Clearly, the parameters and frequencies of sampling should not be the same for all stations monitored along rivers. However, the stations used for calculation of loads stemming to the Black Sea should follow the same Protocol in choice of parameters and frequencies. A serious gap is that BSIMAP does not contain anything about riverine sediments. Well-known is that these sediments are a major factor controlling the Black Sea ecosystem functioning. 2.4. Quality assurance/Quality control (common procedures in sampling and processing of samples) IN BG, GE and RO – ISO standards In UA – national In TR – national, taking into consideration ISO standards Common procedures in sampling and samples processing are not agreed in the BS region for rivers monitoring. Set of recommended SoPs (standard operational procedures) and Guidelines is missing. 2.5. Environmental standards, reference conditions and environmental targets Reference conditions and environmental targets exist in BG and RO only. Environmental standards differ considerably in the BS region, as in GE and UA the standards are those set in Soviet times. A common approach to identification of reference conditions and environmental targets for rivers is needed in the Black Sea region. However, at regional level, more important gap is the lack of knowledge on threshold loads for the BS rivers. Riverine loads might be poorly comparable due to different frequencies of parameters measured or different methods used in sampling, laboratory analysis and calculation of loads. Alas, the missing threshold loads are of higher priority. Because in their absence we cannot denominate the impact on the Black Sea for a river, which would be a more valuable result than simple comparison of loads. The latter says nothing about negative impacts on the Black Sea, as naturally some rivers are larger than others, and logically, their loads are larger. It is understandable that a larger load does not automatically mean a larger negative impact. 2.6. Calculation of riverine loads In none of the beneficiary countries the calculation of riverine loads is well defined in policy. Thus, the comparability of riverine loads reported to the BSC is doubtful. Regional methodology for riverine loads is missing. 2.7. Quality classifications of rivers status The used national classifications in rivers quality identification (hydromophological, chemical, biological and general ecological, where available) are not harmonised, except between BG and RO. Thus, the respective approaches of countries differ very much and results cannot be compared to conclude on which BS rivers have deviated mostly from their pristine status in the long-term run. Regional methodology on identification of rivers ecological status (with common classes of status) is missing. 2.8. Data management and assessments They are also among the weakest links in the BS countries as well as at regional level. 103 December, 2015 Black Sea Rivers Monitoring In none of the BS countries there is a tool for rivers data (all available) storage and management. For data storage Excel or Word files are used. Data are manually managed to generate data products. Sharing of data/information is critically low if any, especially at the level of public. At regional level, data on riverine loads are stored in Excel files and are also manually managed. Each country produces assessments on rivers following own practices. The main problem at regional level is the absence of common understanding on how to assess the level of BS rivers influence on the status of the Black Sea. There are no pressure/impact analyses in regional annual or 5-yearly reports prepared under the BSC. Besides, recently the BSC LBS Advisory Group agreed on the following parameters to be included in the annual reports of the BSC: Parameter (tonnes/year) Annual Flow TP TN Inorganic N Inorganic P Trace Metals TSS TPH BOD5 As discussed above, the BS countries have little in common in their parameters in rivers monitoring, thus, among the selected above indicators the following short List is currently feasible in regional compilations of riverine loads: Parameter (tonnes/year) Inorganic N Inorganic P BOD5 Understandable, that such assessments will hardly contribute to improved understanding of the Black Sea functioning, where inorganic nutrients are not the single source of environmental problems of the sea. The lack of regional requirement (in BSIMAP) to monitor and/or report on riverine sediments –flow and pollution – is seen as one of the major gaps at regional level as well. Recommendations Recommendations further are given along with the harmonization needs specified above building a road-map toward common understanding of rivers monitoring (within its various domains) at Black Sea regional level. 1. Definitions The List below contains priorities and is not a full inventory of missing definitions in adopted Black Sea regional documents. 104 December, 2015 Black Sea Rivers Monitoring Agree on: 1. Types of monitoring (taking into consideration the WFD types: surveillance, operational and investigative) 2. Types of rivers (taking into consideration the WFD requirements, e.g. System ‘B’ in Annex II of the WFD and the criteria included: ecoregion, geology, average height over the sea level, substrate, character of the flow, and drying) 3. Types of water bodies (first specify what is a water body taking into consideration WFD, as well as the types of water bodies identified under this Directive) 4. Reference conditions (consider pristine state and the definition given in this Report as well as the ‘good environmental status’ definition of MSFD) 5. Environmental quality standards (WFD definition) 6. Environmental targets (consider the MSFD definition) 2. Identification of river types, water bodies and those, which are at risk or not Harmonization is needed not only at the level of definitions but also in approaches employed to identify river types and water bodies. Recommended Guidelines: WFD Guidance document N2, Identification of water bodies, https://circabc.europa.eu/sd/a/655e3e313b5d-4053-be19-15bd22b15ba9/Guidance%20No%202%20%20Identification%20of%20water%20bodies.pdf WFD Guidance document N4, Identification and designation of heavily modified and artificial water bodies, https://circabc.europa.eu/sd/a/f9b057f4-4a91-46a3-b69ae23b4cada8ef/Guidance%20No%204%20-%20heavily%20modified%20water%20bodies%20%20HMWB%20(WG%202.2).pdf WFD Guidance document N10, River and lakes – typology, reference conditions and classification systems, https://circabc.europa.eu/sd/a/dce34c8d-6e3d-469a-a6f3b733b829b691/Guidance%20No%2010%20-%20references%20conditions%20inland%20waters%20%20REFCOND%20(WG%202.3).pdf 3. Choice of monitoring parameters and frequencies To harmonise regional assessments of riverine loads, the following list of parameters and frequencies is recommended. The List is meant for all stations where riverine loads stemming to the Black Sea are calculated. The choice of these stations should take into consideration the river mouths specifics (delta, estuary, etc.) to correctly evaluate the riverine loads directly entering the Black Sea. 105 December, 2015 Black Sea Rivers Monitoring 3.1. Mandatory parameters in water The following rivers parameters are recommended to consider as mandatory at the regional level of reporting to the BSC (BSIMAP sensu): Parameters Required frequency of measurements per month Nitrate (N-NO3) 1 (12 times per year) Nitrite (N-NO2) 1 (12 times per year) Ammonia (N-NH4) 1 (12 times per year) Orthophosphate (P-PO4) 1 (12 times per year) Silica (SiO2) 1 (12 times per year) Total Nitrogen 1 (12 times per year) Total Phosphorus 1 (12 times per year) Zinc (Zn) - Dissolved Copper (Cu) - Dissolved Chromium (Cr) - Dissolved Lead (Pb) - Dissolved Cadmium (Cd) - Dissolved Mercury (Hg) - Dissolved Nickel (Ni) - Dissolved Total Zinc Total Copper Total Chromium Total Lead Total Cadmium Total Mercury Total Nickel Total Iron Manganese (Mn 2+) Lindane (instead of Gamma-HCH) TSS (instead of Suspended Particulate Matter) Total Petroleum Hydrocarbons Anionic active surfactants (instead of detergents) Phenols (total) Total PCBs23 BOD-5 COD-Cr TOC Riverine Flow 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (6 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (12 times per year) 1 (4 times per year) 1 (12 times per year) 1 (12 times per year) 1 (4 times per year) daily 3.2. Optional parameters in water (which can be in future considered in BSIMAP, they are selected taking into consideration the current monitoring practices in BG and RO) 3.2.1. Trace metals Aluminium, Arsenic (dissolved and compounds), Cobalt (Co 2+), Vanadium 23 Measuring PCB-28, PCB-52, PCB-101, PCB-118, PCB-138, PCB-153, PCB-180. 106 December, 2015 Black Sea Rivers Monitoring 3.2.2. Pesticides Note: Lindane is included as optional for more frequent measurements than those specified in the Table of mandatory parameters. 3.2.3. Radioactive substances Tritium, Radium, Strontium, Uranium 3.2.4. Chlorinated organic substances 3.2.5. Other organic substances Recommended Guidelines: WFD Guidance document N 19, Surface water chemical monitoring, https://circabc.europa.eu/sd/a/e54e8583-faf5-478f-9b11-41fda9e9c564/Guidance%20No%2019%20%20Surface%20water%20chemical%20monitoring.pdf 107 December, 2015 Black Sea Rivers Monitoring WFD Guidance document N 28, Preparation of an inventory of emissions, discharges and losses of priority and priority hazardous substances, https://circabc.europa.eu/sd/a/6a3fb5a0-4dec-4fde-a69d5ac93dfbbadd/Guidance%20document%20n28.pdf Attend also the Lists of specific and priority substances given in the Directive 2013/39/EC on environmental standards. 3.3. Riverine sediments monitoring This domain of rivers monitoring is open for utilising existing studies and initiating new research activities in order to better understand the influence of riverine sediments and their pollution on the Black Sea. First of all, BSIMAP should include reporting on the flow of riverine sediments to the Black Sea. Next, the stations used for calculation of riverine loads (by water) should be also sampled for the following parameters: 1. Nutrients 2. Trace metals (see the mandatory list for river water) 3. Pesticides 4. Total petroleum hydrocarbons and polycyclic aromatic hydrocarbons 5. Polychlorinated biphenyls 6. Radionuclides 7. Others to be decided Recommended Guideline: WFD Guidance document N25 on Chemical monitoring of sediment and biota under the WFD, https://circabc.europa.eu/sd/a/7f47ccd9-ce47-4f4a-b4f0-cc61db518b1c/Guidance%20No%2025%20%20Chemical%20Monitoring%20of%20Sediment%20and%20Biota.pdf 3.4. Hydromorphology and hydrobiology These domains of rivers monitoring are recommended for inclusion in national river monitoring programmes, taking into consideration the parameters and frequencies recommended by the WFD. Recommended Guidelines: WFD Guidance document N32, On Biota monitoring, https://circabc.europa.eu/sd/a/62343f10-57594e7c-ae2b-12677aa57605/Guidance%20No%2032%20-%20Biota%20Monitoring.pdf WFD Guidance document N33, Analytical methods for biota monitoring, https://circabc.europa.eu/sd/a/9cf535ba-14f2-4f0f-b75e-e334ad506caf/Guidance%20No%2033%20%20Analytical%20Methods%20for%20Biota%20Monitoring.pdf 108 December, 2015 Black Sea Rivers Monitoring 3.5. Building river monitoring programmes at national level (general, including choice of stations) Attend the experience already compiled in BG and RO, see for details Annex I as an example. Recommended Guideline: WFD Guidance document N7, Monitoring under the WFD, https://circabc.europa.eu/sd/a/63f7715f-0f45-4955b7cb-58ca305e42a8/Guidance%20No%207%20-%20Monitoring%20(WG%202.7).pdf Also, trace the achievements of EPIRB Project, which acted to prepare surface water monitoring programmes in GE (see http://blacksea-riverbasins.net/en/georgia) and UA (http://blacksea-riverbasins.net/en/downloads-librarysearch?f[0]=field_country%3A36&f[1]=field_downloads_type%3A59). 4. Quality assurance/Quality control (common procedures in sampling and monitoring) Set of recommended SoPs (standard operational procedures) and Guidelines needs to be prepared. 5. Environmental standards, reference conditions and environmental targets The approaches to identification of environmental standards, reference conditions and environmental targets need to be harmonised at the regional level. Recommended Guidelines: WFD Guidance document N27, WFD Technical Guidance for deriving environmental quality standards, https://circabc.europa.eu/sd/a/0cc3581b-5f65-4b6f-91c6-433a1e947838/TGD-EQS%20CISWFD%2027%20EC%202011.pdf WFD Guidance document N20, Exemptions to the environmental objectives, https://circabc.europa.eu/sd/a/2a3ec00a-d0e6-405f-bf6660e212555db1/Guidance_documentN%C2%B020_Mars09.pdf For Reference conditions recommended Guideline: WFD Guidance document N10, River and lakes – typology, reference conditions and classification systems, https://circabc.europa.eu/sd/a/dce34c8d-6e3d-469a-a6f3-b733b829b691/Guidance%20No%2010%20%20references%20conditions%20inland%20waters%20-%20REFCOND%20(WG%202.3).pdf 6. Calculation of riverine loads The TNMN methodology is recommended (see also ICPDR TNMN Yearbooks, https://www.icpdr.org/main/publications/tnmn-yearbooks). Where several sampling sites in a profile (river cross-section) are included in monitoring, the average concentration at a site is calculated for each sampling day. In case of values “below the limit of detection”, the value of the limit of detection is used in the further calculation. The average monthly concentrations are calculated according to the formula: 109 December, 2015 Black Sea Rivers Monitoring where Cm - average monthly concentrations Ci - concentrations in the sampling days of each month Qi - discharges in the sampling days of each month The monthly load is calculated using the formula: Where: Lm - monthly load Qm - average monthly discharge If discharges are available only for the sampling days, then Qm is calculated from those discharges. For months without measured values, the average of the products Cm.Qm in the months with sampling days is used. The annual load is calculated as the sum of the monthly loads: 12 La [tones] = Σ Lm [tones] m=1 7. Quality classifications of rivers status Approaches to classifications of river status need to be harmonised. Follow the practices employed in BG and RO under the WFD. Recommended guidelines: WFD Guidance document N13, Overall approach to the classification of ecological status and ecological potential, https://circabc.europa.eu/sd/a/06480e87-27a6-41e6-b1650581c2b046ad/Guidance%20No%2013%20%20Classification%20of%20Ecological%20Status%20(WG%20A).pdf 110 December, 2015 Black Sea Rivers Monitoring WFD Guidance document N 30, Procedure to fit new or updated classification methods to the results of a completed intercalibration exercises, https://circabc.europa.eu/sd/a/5aee6446-276c-4440-a7de0d4dec41ed4b/IC_manual_2015_to%20be%20published.pdf Note: Intercalibration exercises involving BS countries are crucial to ensure the systems of classification employed are commonly understood See also: WFD Guidance document N6, Towards a guidance on establishment of the intercalibration network and the process on the intercalibration exercises, https://circabc.europa.eu/sd/a/a091506c-6fc8-45a8-a5885c6397ed2aa4/Guidance%20No%206%20-%20intercalibration%20(WG%202.5).pdf WFD Guidance document N14, Intercalibration Process, https://circabc.europa.eu/sd/a/366c3e9c-47804c9d-bb39-c47262915c45/Guidance%20No%2014%20-%20Intercalibration%20process.pdf 8. Data management and assessments Use the regional LBS Database created by the HBS Project. It allows collection of meta data and data on Black Sea rivers as well as generates data products. The latter could be useful in regional assessments – both annual and 5-yearly. Elaborate a common template for Rivers quality assessment, as well for the evaluation of riverine pressures on the Black Sea against impacts observed in the sea. Apply the MONERIS model to calculate loads from point and diffuse sources stemming to Black Sea rivers to build scenarios of rivers protection. Implement GIS (geographical information system) technologies to visualise river status and related issues. For river water quality visualisations use the example of the ICPDR TNMN Yearbooks (https://www.icpdr.org/main/publications/tnmn-yearbooks). Recommended Guidelines: WFD Guidance document N 3, Analysis of pressures and impacts, https://circabc.europa.eu/sd/a/7e01a7e0-9ccb-4f3d-8cec-aeef1335c2f7/Guidance%20No%203%20%20pressures%20and%20impacts%20-%20IMPRESS%20(WG%202.1).pdf WFD Guidance document N 9, Implementing the geographical information system elements (GIS), https://circabc.europa.eu/sd/a/4786fb8a-e489-438a-8ca5-8d1762a93238/Guidance%20No%209%20%20GIS%20(WG%203.1).pdf WFD Guidance document N23, Eutrophication assessment in the context of European Water Policies, https://circabc.europa.eu/sd/a/9060bdb4-8b66-439e-a9b0a5cfd8db2217/Guidance_document_23_Eutrophication.pdf WFD Guidance document N 31, Ecological flows in the implementation of the WFD, https://circabc.europa.eu/sd/a/4063d635-957b-4b6f-bfd4-b51b0acb2570/Guidance%20No%2031%20%20Ecological%20flows%20(final%20version).pdf 111 December, 2015 Black Sea Rivers Monitoring WFD Guidance document on the application of water balances for supporting the implementation of the WFD, https://circabc.europa.eu/sd/a/820ec306-62a7-475c-8a98699e70734223/Guidance%20No%2034%20%20Water%20Balances%20Guidance%20(final%20version).pdf 112 December, 2015 Black Sea Rivers Monitoring ANNEX I: Rivers surveillance and operational monitoring programme in the Bulgarian Black Sea Basin, 2010-2015 S IМ 2 Batova River mouth S EC,ND S IМ Provadijska River 26.844 43.43445 1-3, 6-19 1-4, 6-8, 10 4 3, 9, 24, 25, 28 12 S IМ Provadijska River 27.1492 43.31444 1-3, 6-19 1-4, 6-8, 10 4 3, 6, 9, 20, 23, 24, 25, 28 12 S ND Provadijska River 27.435 43.20932 1-3, 6-19 1-4, 6-8 4 - S EC Provadijska River 27.6273 43.17864 1-3, 6-19 1-4, 6-8, 10 4 S IМ Provadijska River 27.1458 43.30778 1-3, 6-19 1-4, 6-8, 10 S EC Kamchia River 26.4283 42.96617 1-3, 6-19 S IМ Kamchia River 26.6348 43.02848 S IМ Kamchia River 26.6733 S EC Kamchia River S IМ Kamchia River 6 7 8 9 10 11 12 Devnenska River - mouth Madara River mouth Ticha River – above Ticha village Ticha River – Mengishevo village Gerila River – after Varbitza village Kamchia River – Milanovo village Andere River mouth PS,PB*, PF R,PS,P F,PH PS,PH, PF X Y I group II group frequency substance frequency Black sea Dobrudja Rivers 27.8839 43.33533 1-3, 6-19 1-4, 6-8, 10 4 3, 9, 19, 20, 23, 24, 25, 28, 33 12 Black sea Dobrudja Rivers 28.0564 43.35781 1-3, 6-19 1-4, 6-8, 10 4 3, 6, 8, 9, 11, 15, 16, 20, 21, 23, 24-28, 33 12 Hydromorpholog ical elements**** Specific pollutants*** 1, 2, 3 4/0 RLVarna 1, 2 4 1, 2, 3 12/0 RLVarna 1, 2 4 - - RL Shumen 10 1, 2 4 - - RL Shumen - - - - - - - RLVarna 6, 9, 10, 12, 20, 21, 23, 24, 25, 30, 32 12 1, 2, 12 1, 3-5 1, 2 4 1, 2, 3 12/0 RLVarna 4 3, 9, 20, 24, 25 12 2 1, 8, 9, 10 4 1, 2, 3 12/0 RL Shumen 1-4, 6-8, 10 4 24, 25 12 1, 2 4 1, 2, 3 12/0 RL Shumen 1-3, 6-19 1-4, 6-8, 10 4 - - - - - - 1, 2, 3 4/0 RL Shumen 42.99858 1-3, 6-19 1-4, 6-8, 10 4 - - - - - - 1, 2, 3 4/0 RL Shumen 26.8688 43.18058 1-3, 6-19 4 6, 9, 20, 23, 24, 25 12 1, 2, 1824, 29 1, 2, 3, 4 - 4 1, 2, 3 12/0 26.5239 43.36055 1-3, 6-19 4 3, 9, 24, 25 12 12 1, 2 - 4 1, 2 12/0 113 1-4, 6-8, 10 1-4, 6-8, 10 2 III group 4 II group 1, 2 I group frequency 5 Priority substances** elements 4 Provadijska River - Dobri Voynikovo village Provadijska River - before Madara River Provadijska River - Zlatina vilage Basic* frequency 3 FS,PH, PF,PS, PB Physico – chemical quality elements Geographical coordinates laboratory Type of report Izvorska River – above Dolishte village Sub – basin Monitoring type 1 № type of the station Name of the station Note: For abbreviations and monitored parameters see Tables 1, 2, 3, 4, and 5 below this Table. Note: Currently, the monitoring programmes for 2016-2021 are under revision taking into consideration lessons learnt and results from the monitoring conducted in 2010-2015. RL Shumen RL Shumen December, 2015 II group frequency substance frequency I group II group III group frequency elements frequency S IМ Kamchia River 26.6128 43.23003 1-3, 6-19 1-4, 6-8, 10 4 3, 9, 24, 25 12 - 1, 2 - 4 1, 2 12/0 RL Shumen S IМ Kamchia River 26.7593 43.24058 1-3, 6-19 1-4, 6-8, 10 4 3, 9, 24, 25 12 - 1, 2 - 4 1, 2 12/0 RL Shumen Y Basic* Priority substances** Specific pollutants*** laboratory X I group type of the station Sub – basin 14 Hydromorpholog ical elements**** Type of report 13 Kalaigidere River – On the road Targovishte – Veliki Preslav towns Kalaigidere River - Nadarevo Physico – chemical quality elements Geographical coordinates Monitoring type № Name of the station Black Sea Rivers Monitoring 15 Kralevska River – Dalgach village S IМ Kamchia River 26.7299 43.21616 1-3, 6-19 1-4, 6-8, 10 4 3, 9, 24, 25 12 - - - - 1, 2 12/0 RL Shumen 16 Brestova River mouth S IМ Kamchia River 27.0682 43.07258 1-3, 6-19 1-4, 6-8, 10 4 6, 9, 20, 23, 24, 25 12 2 1, 2 - 4 1, 2 12/0 RL Shumen 17 Kamchia River – Grozdjovo village S EC PS,PF Kamchia River 27.5441 43.03455 1-3, 6-19 1-4, 6-8, 10 4 3, 9, 23, 24, 25, 28 12 - 1, 2 1 4 1, 2, 3 12/0 RLVarna 18 Kamchia River "Poda" area S EC,ND, EA R,FS,P B,PH,P F,PS Kamchia River 27.8214 43.01981 1-3, 6-19 1-4, 6-8, 10 4 2, 3, 6, 9, 10, 11, 17, 20, 21, 23, 24, 25, 27, 28, 29, 31, 32, 33 12 18-23 1, 2 1 4 1, 2, 3 12/0 RLVarna 19 Kamchia River – Beronovo village S EC,EA PS,PF, PH,PB Kamchia River 26.6806 42.83147 1-3, 6-19 1-4, 6-8, 10 4 9, 19, 24, 25 12 - 1, 2 1 4 1, 2, 3 12/0 RL Burgas S ND, IМ Kamchia River 26.9455 42.88418 1-3, 6-19 1-4, 6-8, 10 4 24, 25 12 - 1, 2 1 4 - - RL Burgas S ND,EA Kamchia River 27.222 42.93614 1-3, 6-19 1-4, 6-8, 10 4 24, 25 12 - 1, 2 1 4 1, 2, 3 12/0 RL Burgas S IМ Kamchia River 27.2055 42.81467 1-3, 6-19 1-4, 6-8, 10 4 - - - 1, 2 - 4 - - RL Burgas North Bourgas Rivers 27.8768 42.82644 1-3, 6-19 1-4, 6-8, 10 4 5, 7, 12, 13, 19, 24, 25, 27, 30 12 - 1, 2 1 4 1, 2, 3 12/0 RL Burgas North Bourgas Rivers 27.3989 42.78789 1-3, 6-19 1-4, 6-8, 10 4 - - - - - - 1, 2, 3 4/0 RL Burgas North Bourgas Rivers 27.6553 42.70106 1-3, 6-19 1-4, 6-8, 10 4 5, 6, 7, 12, 13, 19, 20, 24, 25, 27, 30 12 - 1, 2 - 4 1, 2, 3 12/0 RL Burgas 20 21 22 Luda Kamchia River- after " Kamchia" reservoir Luda Kamchia River – Bilka village Alma dere River – Vresovo village 23 Dvojnitza River before Black sea S EC,EA 24 Hadjiiska River – Rajitza village S IМ 25 Hadjiiska River – Tankovo village S ND,EA FS,R,P B,PF,P S FS 114 December, 2015 Type of report type of the station Sub – basin 26 Aheloj River – Aheloj camp S EA FS North Bourgas Rivers 27 Azmak River – before mouth S IМ S IМ S IМ S IМ S IМ Mandra Rivers 27.1636 42.48747 1-3, 6-19 S IМ Mandra Rivers 27.2598 42.42503 1-3, 6-19 S IМ Mandra Rivers 27.2335 42.36731 1-3, 6-19 S IМ Mandra Rivers 27.2762 42.38452 1-3, 6-19 S IМ Mandra Rivers 27.0867 42.18881 1-3, 6-19 S IМ Mandra Rivers 27.3974 42.39389 1-3, 6-19 S ND, IМ South Bourgas Rivers 27.6649 42.26889 1-3, 6-19 1-4, 6-8, 10 4 5, 7, 12, 13, 19, 24, 25, 27, 30 12 - 1, 2 - 4 1, 2, 3 12/0 RL Burgas 37 elements frequency 36 Fakijska River – Fakia vilage Fakijska River mouth Dyavolska River 5 km before Primorsko town frequency 35 Sredetzka River mouth III group 34 II group 33 I group 32 Y frequency 31 X substance 30 Hydromorpholog ical elements**** Specific pollutants*** frequency 29 Sanardere River mouth Chakarlijka River – Ravnetz village Chakarlijka River – Bratovo village Rusokastrenska River – Jelyazovo village Rusokastrenska River - mouth Sredetzka River – after Sredetz town Priority substances** II group 28 Basic* I group № Physico – chemical quality elements Geographical coordinates laboratory Monitoring type Name of the station Black Sea Rivers Monitoring 27.6405 42.63411 1-3, 6-19 1-4, 6-8, 10 4 5, 7, 12, 13, 19, 24, 25, 27, 30 12 - 1, 2 - 4 1, 2, 3 12/0 RL Burgas North Bourgas Rivers 27.4789 42.60303 1-3, 6-19 1-4, 6-8, 10 4 6 12 - 1, 2, 3, 4, 5 1 4 1, 2, 3 12/0 RL Burgas 27.3053 42.50964 1-3, 6-19 4 19, 24, 25 12 - 1, 2 - 4 1, 2, 3 12/0 27.2224 42.52061 1-3, 6-19 4 19, 24, 25 12 - 1, 2 - 4 1, 2, 3 12/0 27.3017 42.49722 1-3, 6-19 4 19, 24, 25 12 - 1, 2 - 4 1, 2, 3 12/0 4 - - - 1, 2 - 4 1, 2, 3 4/0 4 19, 24, 25 12 - 1, 2 - 4 1, 2, 3 12/0 4 12, 19, 24, 25 12 - - 4 1, 2, 3 12/0 4 - - - - 4 1, 2, 3 4/0 4 24, 25 12 - 1, 2 - 4 1, 2, 3 12/0 4 19, 24, 25 12 - 1, 2 - 4 1, 2, 3 12/0 North Bourgas Rivers North Bourgas Rivers North Bourgas Rivers 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1, 2, 3, 4 1, 2, 3, 4, 5 RL Burgas RL Burgas RL Burgas RL Burgas RL Burgas RL Burgas RL Burgas RL Burgas RL Burgas 38 Karaach River mouth S IМ South Bourgas Rivers 27.7481 42.19486 1-3, 6-19 1-4, 6-8, 10 4 5, 7, 12, 13, 19, 24, 25, 27, 30 12 - 1, 2, 3, 4, 5 - 4 1, 2, 3 12/0 RL Burgas 39 Mehmechkojska River - mouth S IМ South Bourgas Rivers 27.6199 42.31245 1-3, 6-19 1-4, 6-8, 10 4 - - - - - - 1, 2, 3 4/0 RL Burgas 40 Ropotamo River – Veselie village S EC,ND, EA South Bourgas Rivers 27.6238 42.31078 1-3, 6-19 1-4, 6-8, 10 4 5, 7, 12, 13, 19, 24, 25, 27, 30 12 - 1, 2 - 4 1, 2, 3 12/0 RL Burgas 41 Veleka River – above Brashlyan village S IМ Veleka River 27.4294 42.08317 1-3, 6-19 1-4, 6-8, 10 4 5, 7, 12, 13, 19, 24, 25, 27, 30 12 - 1, 2 - 4 1, 2, 3 12/0 RL Burgas PS,PF, PH 115 85 Rezovska River 27.6595 41.96061 1-3, 6-19 S IМ Rezovska River 28.0246 41.98053 1-3, 6-19 O EC PS Provadijska River 27.1586 43.45111 1-3, 6-19 O EC PS,PF Provadijska River 27.2125 43.30945 1-3, 6-19 O EC PS,PF Provadijska River 27.17 43.30805 O EC PS,PF Provadijska River 27.4761 O EC PS,PF Provadijska River O EC PS,PF, PB O EC O Kriva River – Enevo village (mouth) Provadijska River - after Kaspichan town Provadijska River – after “Provadsol” Provadijska River – Sindel village Provadijska River - mouth Glavnitza River mouth Stara reka River – between Vehtovo and Vertishte villages Vrana River – after Targovishte town Vrana River – at Kochovo village Vrana River – at Han Krum village Grand Kamchia River – Kalnovo village 1-4, 6-8, 10 4 5, 7, 12, 13, 19, 24, 25, 27, 30 12 - 1, 2 - 4 1, 2, 3 12/0 4 - - - - - - - - 4 - - - - - - - - 4 - - - - - - - - 1-4, 6-8, 10 4 7, 9, 20, 23, 24, 25, 28 12 10, 24, 25 1-5, 7, 10, 11 - 4 - - RL Shumen 1-3, 6-19 1-4, 6-8, 10 4 6, 9, 20, 23, 24, 25 12 1, 2, 24, 26, 30, 31 1, 2 4 - - RL Shumen 43.12591 1-3, 6-19 1-4, 6-8, 10 4 3, 5, 6, 9, 20, 21, 23, 24, 25, 28 12 1, 2, 24, 27 1, 2 4 - - RLVarna 27.5986 43.11702 1-3, 6-19 1-4, 6-8, 10 4 3, 9, 24, 25, 28 12 18-23 - - 4 - - RLVarna Provadijska River 27.6504 43.18175 1-3, 6-19 1-4, 6-8, 10 4 3, 5, 6, 9, 14, 20, 21, 23, 24, 25, 28 12 1, 2, 3, 4, 5 - 4 - - RLVarna PS,PF Provadijska River 27.475 43.10863 1-3, 6-19 1-4, 6-8, 10 4 3, 9, 24, 25, 28 12 2, 10, 12, 1824, 31 3-6, 16, 18-23 1, 2 - 4 - - RLVarna EC PS Kamchia River 27.0622 43.18182 1-3, 6-19 1-4, 6-8, 10 4 3, 6, 9, 20, 23 12 - 1, 2 - 4 - - RL Shumen O EC PS,PF Kamchia River 26.637 43.29269 1-3, 6-19 1-4, 6-8, 10 4 6, 9, 20, 21, 23, 24, 25 12 1, 2, 10 1-5, 7, 10 1 4 - - RL Shumen O EC,EA PS,PF Kamchia River 26.7903 43.2168 1-3, 6-19 12 1, 2, 24 1 4 - - O EC PS,PF Kamchia River 26.8859 43.20111 1-3, 6-19 12 1 1 4 - - O EC PS,PF Kamchia River 27.0392 43.095 1-3, 6-19 12 - - 4 - - Y I group frequency 84 IМ elements 83 S Rezovska River – Slivarovo village Rezovska River – mouth Kriva River – Tzarkvitza village frequency 82 27.9667 III group 81 Veleka River II group 80 FS,R,P B,PF,P H,PS I group 79 EC,EA frequency 78 S Hydromorpholog ical elements**** Specific pollutants*** substance 77 Veleka River – Sinemotetz village Priority substances** frequency 76 X Basic* II group 75 Sub – basin 74 type of the station 44 Type of report 43 Monitoring type 42 Name of the station № Physico – chemical quality elements Geographical coordinates laboratory December, 2015 Black Sea Rivers Monitoring 42.0605 1-3, 6-19 116 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 1-4, 6-8, 10 4 4 4 6, 7, 9, 20, 21, 23, 24, 25 6, 9, 20, 21, 23, 24, 25 5, 6, 9, 20, 21, 23, 24, 25 1, 2, 3, 4, 5 1, 2, 3, 4, 5 1-5, 7, 10 1-5, 7, 10 1, 2 RL Burgas RL Burgas RL Burgas RL Shumen RL Shumen RL Shumen RL Shumen December, 2015 Monitoring type Type of report type of the station Sub – basin X I group II group frequency substance frequency I group II group III group frequency elements frequency Kamchia River – at ”HMP Arkovna" O EC,ND, EA PS,PF, PB Kamchia River 27.2792 43.01933 1-3, 6-19 1-4, 6-8, 10 4 3, 6, 9, 24, 25, 28 12 18-23 1, 2 1 4 - - RLVarna O EC PS,PF, PB Kamchia River 27.3781 43.04966 1-3, 6-19 1-4, 6-8, 10 4 3, 6, 9, 24, 25, 28 12 18-23 1, 2 1 4 - - RLVarna O IМ Kamchia River 27.0064 43.22972 1-3, 6-19 1-4, 6-8, 10 4 6, 20, 21, 23 12 1, 2, 24, 29 5 1, 2 4 - - RL Shumen O IМ Kamchia River 27.015 43.18556 1-3, 6-19 1-4, 6-8, 10 4 6, 7, 20, 21, 23, 28 12 1, 2, 10, 24, 29 5 1, 2 4 - - RL Shumen O EC,ND PS,PF, PB, PH North Bourgas Rivers 27.3381 42.50733 1-3, 6-19 1-4, 6-8, 10 4 19, 24, 25 12 - 1, 2 1 4 - - RL Burgas O EC PS,PF North Bourgas Rivers 27.3027 42.56106 1-3, 6-19 1-4, 6-8, 10 4 19, 24, 25, 28 12 - 1, 2 1 4 - - RL Burgas № 86 87 88 89 90 91 Grand Kamchia River – after Dalgopol town Porojna River – Dibich village Porojna River – Radko Dimitrievo village Ajtoska River mouth Ajtoska River – after Kameno town Physico – chemical quality elements Geographical coordinates Y Basic* Priority substances** Hydromorpholog ical elements**** Specific pollutants*** laboratory Name of the station Black Sea Rivers Monitoring 92 Ajtoska River (Alansko dere) – Topolitza village O EC PS,PF North Bourgas Rivers 27.1308 42.72889 1-3, 6-19 1-4, 6-8, 10 4 19, 24, 25 12 - 1, 2 - 4 - - RL Burgas 93 Ajtoska River (Alansko dere) – Polyanovo village O EC PS,PF North Bourgas Rivers 27.1784 42.83294 1-3, 6-19 1-4, 6-8, 10 4 19, 24, 25 12 - 1, 2 - 4 - - RL Burgas Abbreviations tabl. 1 Basic* tabl.2 Priority substances** tabl.3 Specific pollutants*** tabl.4 Hydromorphological elements**** tabl.5 117 December, 2015 Black Sea Rivers Monitoring Table 1. Abbreviations types of monitoring S surveillance O operational I investigative type reporting IM station in internal monitoring network EC station reported on ЕC EA station on Euronet network DP station on ISPDR IC intercalibration station ND station under Nitrate Directive D station under Directive 98/83/ЕC (drinking water) type of the station R referent station FS mouth (in Black sea) FCB before STATE border PH station in protected area for Habitats, Natura 2000 PS station in Sensibility area PF station in protected area for Fish PSH station in protected area for Shellfish 118 December, 2015 Black Sea Rivers Monitoring Table 2. Basic physico – chemical indicators № 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 І № 1 2 3 4 5 6 7 8 9 10 11 12 13 ІІ pH Temperature Suspended solids Transparency (Secci disk)** Chlorophyll “A”** Electrical conductivity Dissolved oxygen Oxygen saturation % BOD5 COD Nitrogen ammonium N – NH4 Nitrogen nitrate N – NO3 Nitrogen nitrite N – NO2 Orthophosphates Р –РО4 Chlorides Sulphates NO3 Ammonium ion Nitrogen on Keldal Oxidization (K- Mn) Total extracted substances ** For lakes, reservoirs and coastal sea waters *** Analyses are made when necessary and in the opinion of the Basin Directorate Total nitrogen Total phosphorus Calcium Magnesium Total hardness *** Total iron Manganese Calcium – carbonate hardness Hydrogen sulphide*** Total organic carbon Silicon ** Salinity, ‰ ** Turbidity (FNU/NTU) ** 119 December, 2015 Black Sea Rivers Monitoring Table 3. Priority substances № CAS number EU number Name of priority substance 1 15972-60-8 240-110-8 Alachlor 2 120-12-7 204-371-1 Anthracene 3 1912-24-9 217-617-8 Atrazine 4 71-43-2 200-753-7 Benzene 5 n.a. n.a Brominated diphenylethers 6 7440-43-9 231-152-8 Cadmium and its compounds 7 85535-84-8 287-476-5 C10 – 13 chloralkanes 8 470-90-6 207-432-0 Chlorfenvinphos 9 2921-88-2 220-864-4 Chlorpyrifos 10 107-06-2 203-458-1 1,2-Dichloroethane 11 75-09-2 200-838-9 Dichloromethane 12 117-81-7 204-211-0 Di(2-ethylhexyl) phthalate (DEHP) 13 330-54-1 206-354-4 Diuron 14 115-29-7 204-079-4 Endosulfan 959-98-8 n.a. alpha-endosulfan 15 206-44-0 205-912-4 Flouranthene 16 118-74-1 204-273-9 Hexachlorobenzene 17 87-68-3 201-765-5 Hexachlorobutadiene 18 608-73-1 210-158-9 Hexachlorocyclohexane 58-89-9 200-401-2 (gamma-isomer,Lindane) 19 34123-59- 251-835-4 Isoproturon 20 7439-92-1 231-100-4 Lead and its compounds 21 7439-97-6 231-106-7 Mercury and its compounds 22 91-20-3 202-049-5 Naphthalene 23 7440-02-0 231-111-4 Nickel and its compounds 120 December, 2015 Black Sea Rivers Monitoring Table 3. Priority substances № CAS number EU number 24 25154-52-3 246-672-0 Nonylphenols 104-40-5 203-199-4 (4-(para)-nonylphenol) 1806-26-4 217-302-5 Octylphenols 25 Name of priority substance 140-66-9 n.a. (para-tert-octylphenol) 26 608-93-5 210-172-5 Pentachlorobenzene 27 87-86-5 201-778-6 Pentachlorophenol 28 n.a. n.a. Polyaromatic hydrocarbons 50-32-8 200-028-5 (Benzo(a)pyrene) 205-99-2 205-911-9 (Benzo(b)fluoroanthene) 191-24-2 205-883-8 (Benzo(g,h,i)perylene) 207-08-9 205-916-6 (Benzo(k)fluoroanthene) 206-44-0 205-912-4 (Fluoroanthene) 193-39-5 205-893-2 (Indeno(1,2,3-cd)pyrene) 29 122-34-9 204-535-2 Simazine 30 688-73-3 211-704- Tributyltin compounds 36643-28-4 n.a. (Tributyltin-cation) 12002-48-1 234-413-4 Trichlorobenzenes 120-82-1 204-428-0 (1,2,4-Trichlorobenzene) 32 67-66-3 200-663-8 Trichloromethane (Chloroform) 33 1582-09-8 216-428-8 Trifluralin 31 121 December, 2015 Black Sea Rivers Monitoring Table 4. Specific pollutants № 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 Organic substances І № Phenols Oil products Aldrin Dieldrin Endrin Isodrin Carbontetrachloride Tetrachloroethylene Trichloroethylene Polychlorinated biphenyiles (PCB 28, PCB 52, PCB 101, PCB 105, PCB 118, PCB 138, PCB 153, PCB 156, PCB 180) EOX (extractable) AOX (absorbable) o,p - DDE p,p- DDE o,p - DDD p,p - DDD + o,p DDT p,p - DDT Prometon Prometryn Propazine Ametrin Simetryn Terbutryn Dichlorodifluoromethane Chloromethane Bromomethane Bromodichloromethane 1,4 - dichlorobenzene 1,2 - dichlorobenzene Bromoform Dichloromethane Trans-1,2-dichloroethene Tetrachloroethane 1 2 3 4 5 6 7 8 9 Heavy metals and metalloids ІІ Zink Copper Chrome 6 valence Chrome 3 valence Arsenic Selenium Silver Potassium Sodium 10 Fluorides 11 12 13 14 15 16 17 18 19 Antimony Magnesium Aluminium Vanadium Cobalt Uranium (natural) Radium Total β radioactivity Total Chrome 122 № 1 2 3 4 5 6 7 8 9 Other ІІІ Surface active substances Cyanides Sulphides Carbonates Bicarbonates Vegetable oils and fats Fluorohydrogen Lithium Xylenes (p+m Xylene) December, 2015 Black Sea Rivers Monitoring Table 4. Specific pollutants № 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 Organic substances І № Heavy metals and metalloids ІІ Ethylene O, m, p-xylene Toluene Benzo(а)anthracene Pyrene Fenantrene Chrysene Ethylbenzene Styrene Acetone DIBP Bentazone DEP DBP Linuron MCPA Acetochlor Bisphenol А 123 № Other ІІІ December, 2015 Black Sea Rivers Monitoring ANNEX II. Projects in Turkey in support of surface waters management advancements Project on Control of Dangerous Substances in River Basin Areas (TMKK) Supporting Institution Republic of Turkey Ministry of Forestry and Water Affairs, General Directorate of Water Management Project Manager Establishment IO Environmental Solutions Project Start – End Dates 2011 – 2014 The main goal of the Project (in Inland Waters) is to provide the means for the determination of Environmental Quality Standards, which should be adhered in order to prevent dangerous substance pollution caused by human activities in basin terms. With the purpose of preventing the hazardous material pollution in all of the receiving water environments, detection of hazardous materials in domestic and industrial waste waters, development of an industry based hazardous material inventory, determination of Environmental Quality Standards and Discharge Standards, and the development of a Web based Hazardous Material Information System are the most important targets of the project. To be able to carry out the activities necessary within the scope of the project, determination of the size of the hazardous material pollution caused by the industries is targeted. Domestic and industrial wastewaters will be studied, considering the dangerous substances list; put together after the aforementioned study, within the borders of Ergene Basin, Susurluk Basin, Konya Closed Basin, which were selected as pilot basins. Within this framework, a sector based inventory will be formed as a result of the studied industries. Moreover, Environmental Quality Standards will be determined while studying the surface water sources in detail and considering the current status of water environments; and consequently, the discharge standards of industries and domestic waste water processing facilities will be detected. Detection of Water Pollution Caused by the Use of Plant Preservation Products and Determination of Environmental Quality Standards on a Material or a Material Group Basis (BiKoP) Supporting Institution Republic of Turkey Ministry of Forestry and Water Affairs, General Directorate of Water Management Project Manager Establishment TUBITAK MRC, Environment and Cleaner Production Institute Project Start – End Dates 2012 – (in progress) Provided that the active materials list included in the plant protection products used in Turkey and the active material and plant protection product groups prepared by the European Union are predicated on, taking plant protection products that are used and still being used along with the related Turkish regulations and the Acquis Communautaire, and the amount of grown agricultural products and the agricultural lands in consideration, the study and the identification of the pollutants in mainland surface waters and coastal waters located in the pilot river basins of the Aegean (Büyük Menderes Water Basin), Eastern Mediterranean (Çukurova-Seyhan Water Basin), and South-Eastern Anatolian (Fırat-Dicle Water Basin) regions, where agricultural activities are high, the study and the 124 December, 2015 Black Sea Rivers Monitoring identification of methodologies for the determination of Environmental Quality Standards for the active materials, which are the source of the aforementioned pollutants, and the plant protection products containing these materials, determination of a suitable methodology and the determination of Environmental Quality Standards for the related articles are the goals of the project. Integrated Pollution Monitoring Projects Supporting Institution Project Manager Establishment Ministry of Environment and Urbanization– Directorate General of Environmental Management The project manager is determined by tender every 4 years by the Ministry First monitoring studies started in 2013 For Black Sea TUBITAK MRC, Environment and Cleaner Production Institute “Integrated Pollution Monitoring Projects could not be implemented due to the restructuring of the Ministry and the transfer of the aforementioned work from the Ministry to some other establishment. However, the project is scheduled to be continued in the next phase.” The aim of the Integrated Pollution Monitoring in the Marine Environments Project is to understand the ecological and pollution status, using pollution and ecosystem parameters in transtional, coastal, and marine waters; to carry out the necessary studies in order to determine and classify the typologies of the water masses, in accordance with these and additional physical data. It is intended to create a base for EU-like regulations that are compatible with the Water Framework Directive (WFD, 2000) and the Marine Strategy Framework Directive (MSFD, 2008), while evaluating the future long term integrated (suppression-status-effect) monitoring activities and the studies from former phases. Within the context of the project, monitoring studies were carried out at 66 stations in the Marmara Sea, at 52 stations in the Aegean Sea, at 34 stations in the Mediterranean Sea, and at 70 stations in Black Sea. In this context, there are river basins mouth stations on coastal discharge ares for Black Sea as well. The parameters, whose samplings were made in the aforementioned stations, were gathered under 3 groups, consisting of physicochemical parameters, ecological parameters, and chemical (pollutant) parameters. Temperature, conductivity (salinity), turbidity, dissolved oxygen and oxygen saturation, total phosphorus, dissolved inorganic phosphorus, total inorganic nitrogen (total of nitrate + nitride nitrogen and ammonium nitrogen), silicate, and chlorophyll-a were identified as the physiochemical parameters. The parameters determining the ecological status are phytoplankton, zooplankton, macro flora, zoobenthos, and demersal fish biodiversity, under the biological parameters. River Basin Protection Action Plans (HKEP) Republic of Turkey Ministry of Forestry and Water Affairs, General Supporting Institution Directorate of Water Management Project Manager Establishment TUBITAK MRC, Environment and Cleaner Production Institute HKEP Project 1st Phase Start – End Dates 2009 – 2011 HKEP Project 2nd Phase Start – End 2011 - 2013 125 December, 2015 Black Sea Rivers Monitoring Dates: “The Preparation of Basin Conservation Action Plans” studies have been started by the Mülga Ministry of Forest and Water Affairs in year 2009, with the purpose of managing the water sources on a basin scale in our country. Initially, 25 hydrological basins were graded, considering their water quality, pollutant sources, protected areas, and drinking water sources. In accordance with this prioritization, the task of preparation of the action plans for the 11 basins was given to TUBITAK – MRC who possesses the ample competence and experience due to its gathering of different disciplines under the same roof and the implementation of many relevant projects in the past. The aforementioned project was implemented between August 2009 and December 2010, and was successfully accomplished. For the remaining 14 basins, a protocol has been signed between the Ministry of Forest and Water Affairs of the T.R and the Presidency of TUBITAK at the end of 2011, for “The preparation of Basin Conservation Action Plans” project, which contains the revising of draft conservation action plans which were previously had prepared for 4 basins by the Ministry, and the preparation of basin conservation plans in the remaining 9 basins. The time span of the aforementioned project is 2 years, and it is scheduled to be accomplished in the year 2013. The studies for the preparation of the Basin Conservation Action Plans, forms the base for the processes of the creation and the application of the River Basin Management Plans, which include the necessities of the Water Framework Directive, which forms the framework for all of the EU water directives for Turkey as a EU member candidate and came into effect in the year 2000, for the basins of our country. Primarily, Determination of the current situation while considering the water source potentials, point and distributed pollution sources, and current water quality, for the prevention of the pollution in the basin, and for the conservation and the rehabilitation basin, Planning of technologically economical and suitable urban waste water processing facilities for all of the settlements in each basin. As a result of the studies, preparation of short, medium, and long-term, “Action Plans,” aimed for the problems in the basins and their solution proposals. Preparation of all the data, utilizing GIS technologies, to be integrated into the Ministry of Forest and Water Affairs’ system, Sharing of all the studies with the accountable establishments and organizations, primarily the Ministry of Forestry and Water Affairs, in the basin activities are carried out in the project. A long-term conservation plan, which depends on the principles in the EU Water Framework Directive, which came into effect along with the Basin Conservation Actions Plans, in the year 2000, will be determined. Furthermore, with the help of these projects and again within the context of the WFD, an important base is formed for the “Preparation of River Basins Management Plans” and the “Classification of Marine and Coastal Areas.” Determination of Water Quality Targets and Sensitive Areas in Terms of Basins in Turkey (HHAP) Ministry of Forestry and Water Affairs, General Directorate of Water Supporting Institution Management Project Manager Establishment TUBITAK MRC, Environment and Cleaner Production Institute Project Start – End Dates: 2012 – (in progress) In the HHAP Project, which is supported by the Republic of Turkey Ministry of Forestry and Water Affairs and which is carried out by TUBITAK – MRC Environment and Cleaner Production Institute, determination of the 126 December, 2015 Black Sea Rivers Monitoring sensitive areas within the context of the “Urban Waste Water Processing Regulation” which was prepared taking the Urban Waste Water Processing Directive, a sub directive of the Water Framework Directive, as a base, and the determination of nitrate sensitive areas and the introduction of water quality targets in the aforementioned areas within the context of the “Conservation of Waters Against Pollutions with Agricultural Origin Regulation” which was prepared taking the EU Nitrate Directive as a base are being planned. Primarily, Identification of the current surface water masses in the 25 water basins in Turkey for the determination of the pressures formed in the water masses due to urban, industrial, and agricultural actives and the determination of pollution loads in terms of basins, Introduction of the eutrophication status through the identification of water pollution in the environment with the monitoring activities, which will be carried out after the introduction of potential sensitive water areas, as a result of the evaluations carried out utilizing the existing data, Determination of final sensitive water areas and nitrate sensitive regions, in terms of water pollution, in surface and subterranean waters, while evaluating the calculated pollutions loads and the monitoring data together, Determination of water quality objectives for the designated sensitive areas, Review of the water quality measures introduced in the designated pilot areas through a model, activities are targeted in the project. Determination of Specific Pollutants in Coastal/Transitional Waters and Ecological Coastal Dynamic in Turkey (KIYITEMA) Supporting Institution Ministry of Forestry and Water Affairs, General Directorate of Water Management Project Manager Establishment TUBITAK MRC, Environment and Cleaner Production Institute Project Start – End Dates: 2012 – 2014 According to the WFD, Member States should implement measures necessary to prevent or limit the input of pollutants into the water bodies. In this respect, the progressive reduction, cessation or phasing-out of pollutant discharges are required in order to achieve good water quality. The pollutants are defined as priority substances and specific pollutants in WFD. Priority substances were determined for the first time by 2455/2001/EC Council Directive; then, revised according to the 2011/0429(COD) Proposal Directive. The proposed list composed of 48 chemical substances should be monitored by Member States per months a year. On the other hand, specific pollutants can be national, regional or river basin pollutants and identified as being discharged in significant quantities into the water body. WFD requires that Member States identify and develop standards for specific pollutants. Many EU countries have determined their specific pollutants in the context of WFD and have been monitoring these pollutants in the aquatic environment periodically. Regarding to EU harmonization process of Turkey, the pollution caused by discharge of specific pollutants to coastal/transitional waters should be detected and necessary measures should be taken in order to achieve good water quality. In this content, the project named “Determination of Specific Pollutants in Coastal/Transitional Waters and Ecological Coastal Dynamic in Turkey” has been signed between Ministry of Forestry and Water Affairs, and TUBITAK Marmara Research Center. The purpose of this project is the selection of probable specific pollutants discharged directly into the coastal/transitional waters caused by urban/industrial activities, and the determination of environmental quality standards (EQSs) and corresponding emission limit values (ELVs). In this study, the methodology applied for the selection of specific pollutants that are of possible concern to the aquatic environment throughout the country was assessed. Initially, “list-based approach” was used to establish a list of polluting substances of concern that might be considered as specific pollutants covered by existing national/international Regulations/conventions, Turkey’s Chemical Inventory Information System, BREF documents and sectoral 127 December, 2015 Black Sea Rivers Monitoring capacity reports. Afterwards, specific pollutants were screened through a three-step process by taking into account hazard classifications (risk phrases), persistency-bioaccumulation-toxicity (PBT) characteristics and expert judgement. Finally, the chemicals were ranked by three different risk-based prioritization processes in terms of chemical hazards and environmental exposures; then, candidate specific pollutants in coastal/transitional waters were identified as a draft to be reviewed on an ongoing basis in the next phase of the study, monitoring programmes will be performed in both coastal/transitional waters and wastewaters of pilot urban/industrial facilities in Turkey within 2-month intervals during a year; thereby, specific pollutants may be revised according to the monitoring data. Then, EQSs and corresponding ELVs will be determined for each specific pollutant. In context of this project, Yeşilırmak and Kizilirmak rivers mouths have been monitored with 2 months intervals for a year to evaluate specific and priority pollutants. Project on Transforming Basin Protection Action Plans to River Basin Management Plans (20142017) Supporting Institution Ministry of Forestry and Water Affairs, General Directorate of Water Management Project Manager Establishment TUBITAK MRC, Environment and Cleaner Production Institute Project Start – End Dates: 2014 – ongoing By this project, it is intended for all waters to achieve to environmental targets by transforming Basin Protection Action Plans to River Basin management Plans. Purpose of this project is performing the studies on transforming Basin Protection Action Plans to River Basin management Plans (RBMP) in compliance with the European Union Water Framework Directive numbered (2000/60/EC) and with other sister directives and develop national capacity within this process. This project is being carried out for 4 basins to be a model for the others. The Black Sea basins are not among these basins. However, with all other basins in Turkey, RBMP’s shall be prepared also for the Black Sea Basins in time. These plans shall include monitoring plans for each basin. 128
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