Calibration and Measurement Capabilities Amount of substance, Gases, France, LNE (Laboratoire national de métrologie et d'essais) The expanded uncertainty range is expressed as the uncertainty of the smallest value of the quantity to the uncertainty of the largest value of the quantity. The expanded uncertainties correspond to k = 2 (level of confidence 95%) The notation Q[a, b] stands for the root-sum-square of the terms between brackets: Q[a, b] = [a Measure NMI ment Service Service Identifier SubCategory Measurand Dissemination Range of Measurement Capability 2 + b2]1/2 Range of Expanded Uncertainties as Disseminated CMI-37-1 Environm ental nitrogen carbon monoxide CMI-37-2 Environm ental nitrogen carbon monoxide CMI-37-3 Environm ental nitrogen carbon monoxide CMI-37-4 Environm ental nitrogen carbon dioxide CMI-37-5 Environm ental nitrogen carbon dioxide CMI-37-6 Environm ental nitrogen carbon dioxide CMI-37-14 Other gases nitrogen CMI-37-14 Other gases argon CMI-37-14 Other gases carbon monoxide CMI-37-14 Other gases carbon dioxide CMI-37-14 Other gases propane CMI-37-14 Other gases methane Quantity Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance flow Amount-ofsubstance flow Amount-ofsubstance flow Amount-ofsubstance flow Amount-ofsubstance flow Amount-ofsubstance flow The BIPM key comparison database, August 2015 Range of Expanded Uncertainties for Certified Value From To Unit From To Unit Is the expanded uncertainty a relative one? Mechanism(s) for Measurement Service Delivery From To Unit From To Unit Is the expanded uncertainty a relative one? 10 50 mmol/ mol 0.3 0.2 % Yes 10 50 mmol/ mol 0.2 0.2 % Yes 500 10000 µmol/m ol 0.4 0.3 % Yes 500 10000 µmol/m ol 0.2 0.2 % Yes 10 500 µmol/m ol 0.7 0.4 % Yes 10 500 µmol/m ol 0.3 0.2 % Yes 10 200 mmol/ mol 0.35 0.35 % Yes 10 200 mmol/ mol 0.35 0.35 % Yes 500 10000 µmol/m ol 0.35 0.35 % Yes 500 10000 µmol/m ol 0.35 0.35 % Yes 100 500 µmol/m ol 0.35 0.35 % Yes 100 500 µmol/m ol 0.35 0.35 % Yes 0.00005 1.5 mol/mi n 0.3 0.2 % Yes Instrument calibration 0.00005 1.5 mol/mi n 0.3 0.2 % Yes Instrument calibration 0.00005 1.5 mol/mi n 0.3 0.2 % Yes Instrument calibration 0.00005 1.5 mol/mi n 0.3 0.2 % Yes Instrument calibration 0.00005 1.5 mol/mi n 0.3 0.2 % Yes Instrument calibration 0.00005 1.5 mol/mi n 0.3 0.2 % Yes Instrument calibration Matrix Analyte or Component Range of Certified Values in Reference Materials Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Comments Approved on 19 July 2010 Approved on 19 July 2010 Approved on 19 July 2010 Approved on 08 July 2015 Approved on 08 July 2015 Approved on 08 July 2015 Approved on 01 March 2005 Approved on 01 March 2005 Approved on 01 March 2005 Approved on 01 March 2005 Approved on 01 March 2005 Approved on 01 March 2005 1/4 Calibration and Measurement Capabilities Amount of substance, Gases, France, LNE (Laboratoire national de métrologie et d'essais) The expanded uncertainty range is expressed as the uncertainty of the smallest value of the quantity to the uncertainty of the largest value of the quantity. The expanded uncertainties correspond to k = 2 (level of confidence 95%) The notation Q[a, b] stands for the root-sum-square of the terms between brackets: Q[a, b] = [a Measure NMI ment Service Service Identifier SubCategory Environm CMI-37-15 ental Measurand Dissemination Range of Measurement Capability 2 + b2]1/2 Range of Expanded Uncertainties as Disseminated Matrix Analyte or Component Quantity nitrogen carbon monoxide Amount-ofsubstance fraction From From To Unit Is the expanded uncertainty a relative one? To Unit 1 100 µmol/m ol 2.0 0.7 % Yes Range of Certified Values in Reference Materials From To Unit Range of Expanded Uncertainties for Certified Value From To Unit Is the expanded uncertainty a relative one? CMI-37-16 Environm ental purified air carbon monoxide Amount-ofsubstance fraction 1 100 µmol/m ol 2.0 0.7 % Yes CMI-37-20 Environm ental nitrogen nitrogen dioxide Amount-ofsubstance fraction 0.01 1 µmol/m ol 2.0 1.0 % Yes CMI-37-21 Environm ental air nitrogen dioxide Amount-ofsubstance fraction 0.01 1 µmol/m ol 2.0 1.0 % Yes CMI-37-24 Environm ental purified air ozone Amount-ofsubstance fraction 0 1000 nmol/m Q[1.1, 0.022 x (O )] nmol/m 3 ol ol No CMI-37-28 Environm synthetic air ental benzene 1 100 µmol/m ol 2.0 1.0 % Yes 1 100 µmol/m ol 0.3 0.2 % Yes CMI-37-29 Environm ental benzene 1 100 µmol/m ol 2.0 1.0 % Yes 1 100 µmol/m ol 0.3 0.2 % Yes CMI-37-30 Environm synthetic air ental toluene 1 100 µmol/m ol 2.0 1.0 % Yes 1 100 µmol/m ol 0.3 0.2 % Yes CMI-37-31 Environm ental toluene 1 100 µmol/m ol 2.0 1.0 % Yes 1 100 µmol/m ol 0.3 0.2 % Yes CMI-37-32 Environm synthetic air ental 1 100 µmol/m ol 2.0 1.0 % Yes 1 100 µmol/m ol 0.3 0.2 % Yes nitrogen nitrogen o-xylene Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction The BIPM key comparison database, August 2015 Mechanism(s) for Measurement Service Delivery Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Analyser and gas standard generator calibration Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Comments Approved on 19 July 2010 Approved on 19 July 2010 Approved on 08 July 2015 Approved on 01 March 2005 Approved on 01 March 2005 Approved on 01 March 2005 Approved on 01 March 2005 Approved on 01 March 2005 2/4 Calibration and Measurement Capabilities Amount of substance, Gases, France, LNE (Laboratoire national de métrologie et d'essais) The expanded uncertainty range is expressed as the uncertainty of the smallest value of the quantity to the uncertainty of the largest value of the quantity. The expanded uncertainties correspond to k = 2 (level of confidence 95%) The notation Q[a, b] stands for the root-sum-square of the terms between brackets: Q[a, b] = [a Measure NMI ment Service Service Identifier SubCategory CMI-37-33 Environm ental Measurand 2 + b2]1/2 Dissemination Range of Measurement Capability Range of Expanded Uncertainties as Disseminated Analyte or Component Quantity From To Unit From To Unit Is the expanded uncertainty a relative one? o-xylene Amount-ofsubstance fraction 1 100 µmol/m ol 2.0 1.0 % Yes 1 100 nmol/m ol 2.0 0.7 % Yes Matrix nitrogen U ( C i ) 2 * 1 1 10 , . 2 C 2 ( 0 28 , ) 2 CMI-37-22- Environm rev ental nitrogen benzene Amount-ofsubstance fraction CMI-37-23- Environm rev ental air benzene Amount-ofsubstance fraction 1 100 nmol/m ol 2.0 0.7 % Yes CMI-37-34- Environm rev ental nitrogen toluene Amount-ofsubstance fraction 1 100 nmol/m ol 2.0 0.7 % Yes CMI-37-35- Environm rev ental air toluene Amount-ofsubstance fraction 1 100 nmol/m ol 2.0 0.7 % Yes CMI-37-36- Environm rev ental nitrogen o-xylene Amount-ofsubstance fraction 1 100 nmol/m ol 2.0 0.7 % Yes CMI-37-37- Environm rev ental air o-xylene Amount-ofsubstance fraction 1 100 nmol/m ol 2.0 0.7 % Yes Environm ental air Amount-ofsulfur dioxide substance fraction 50 500 µmol/m ol 1.0 1.0 % Yes CMI-37-17- Environm rev ental air Amount-ofsulfur dioxide substance fraction 100 500 nmol/m ol 1.5 0.6 % Yes CMI-37-38 The BIPM key comparison database, August 2015 Range of Certified Values in Reference Materials Range of Expanded Uncertainties for Certified Value From To Unit From To Unit Is the expanded uncertainty a relative one? 1 100 µmol/m ol 0.3 0.2 % Yes Mechanism(s) for Measurement Service Delivery Provision of gravimetric gas mixtures Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Comments Approved on 01 March 2005 Approved on 06 December 2011 Approved on 06 December 2011 Approved on 06 December 2011 Approved on 06 December 2011 Approved on 06 December 2011 Approved on 06 December 2011 Approved on 06 September 2012 Approved on 27 March 2013 3/4 Calibration and Measurement Capabilities Amount of substance, Gases, France, LNE (Laboratoire national de métrologie et d'essais) The expanded uncertainty range is expressed as the uncertainty of the smallest value of the quantity to the uncertainty of the largest value of the quantity. The expanded uncertainties correspond to k = 2 (level of confidence 95%) The notation Q[a, b] stands for the root-sum-square of the terms between brackets: Q[a, b] = [a Measurand Measure NMI ment Service Service Identifier SubCategory Matrix CMI-37-7- Environm rev ental nitrogen nitrogen monoxide CMI-37-8- Environm rev ental nitrogen nitrogen monoxide CMI-37-11- Environm rev ental nitrogen propane CMI-37-12- Environm rev ental nitrogen propane CMI-37-18- Environm rev ental nitrogen nitrogen monoxide CMI-37-19- Environm rev ental air nitrogen monoxide Analyte or Component CMI-37-41 Environm synthetic air ental carbon dioxide CMI-37-42 Environm synthetic air ental carbon dioxide CMI-37-43 Environm synthetic air ental carbon dioxide CMI-37-39 Forensic synthetic air ethanol CMI-37-40 Forensic nitrogen ethanol Dissemination Range of Measurement Capability 2 + b2]1/2 Range of Expanded Uncertainties as Disseminated Range of Certified Values in Reference Materials Range of Expanded Uncertainties for Certified Value From To Unit From To Unit Is the expanded uncertainty a relative one? 0.5 20 mmol/ mol 0.3 0.2 % Yes 0.5 20 mmol/ mol 0.2 0.2 % Yes 10 500 µmol/m ol 0.6 0.3 % Yes 10 500 µmol/m ol 0.4 0.2 % Yes 1 20 mmol/ mol 0.3 0.2 % Yes 1 20 mmol/ mol 0.3 0.2 % Yes 10 1000 µmol/m ol 0.3 0.3 % Yes 10 1000 µmol/m ol 0.3 0.3 % Yes Amount-ofsubstance fraction 100 1000 nmol/m ol 1.5 0.7 % Yes Amount-ofsubstance fraction 100 1000 nmol/m ol 1.5 0.7 % Yes 10 200 mmol/ mol 0.35 0.35 % Yes 10 200 mmol/ mol 0.35 0.35 % Yes 500 10000 μmol/m ol 0.35 0.35 % Yes 500 10000 μmol/m ol 0.35 0.35 % Yes 100 500 μmol/m ol 0.35 0.35 % Yes 100 500 μmol/m ol 0.35 0.35 % Yes 50 500 µmol/m ol 0.5 0.5 % Yes 50 500 µmol/m ol 0.5 0.3 % Yes 50 500 µmol/m ol 0.5 0.5 % Yes 50 500 µmol/m ol 0.5 0.3 % Yes Quantity Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction Amount-ofsubstance fraction The BIPM key comparison database, August 2015 From To Unit From To Unit Is the expanded uncertainty a relative one? Mechanism(s) for Measurement Service Delivery Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Instrument calibration and calibration of gas standards Instrument calibration and calibration of gas standards Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Provision of gravimetric gas mixtures Comments Approved on 27 March 2013 Approved on 27 March 2013 Approved on 27 March 2013 Approved on 27 March 2013 Approved on 27 March 2013 Approved on 27 March 2013 Approved on 08 July 2015 Approved on 08 July 2015 Approved on 08 July 2015 Approved on 08 July 2015 Approved on 08 July 2015 4/4
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