Ch 9 section 1 Need books and notes Background knowledge: what do you already know? vocab? Check that you can answer the essential questions as you study #1 is signs of a chemical reaction! Performance Goal: Writing a Chemical Equation: ◦ Must be balanced and include proper symbols What is the difference between: Word equation Skeleton equation Chemical equation Read and discuss in small groups for 2 minutes Word- no formulas Skeleton- formulas but not balanced Chemical- formulas AND it’s balanced is a BALANCED equation reactants, products and how much of each (visual page 285) Which one is the performance goal? We must start and end with the same stuff. WHY? P. 288 Besides formulas: See page 283 vocab and symbols used Conservation of Mass In your notes ADD this symbol: ∆ When heating a reaction– place the symbol ∆ above the arrow subscripts tell you ◦ When balancing: ◦ You add coefficients in front of the compounds ◦ but you may not change the subscripts. ◦ how many atoms of a particular element are in a compound. (chapter 7 and 8) The coefficient tells you ◦ about the quantity of that compound in a reaction ◦ WHY???? (chapter 9) Al (s) + O2 (g) Al2O3 (s) Use LCM idea: 2 and 3 of oxygen: use total of 6 Al (s) + 3 O2 (g) 4Al (s) + 3 O2 (g) 2 Al2O3 (s) 2 Al2O3 (s) take the coefficient TIMES subscript so there are 6 O’s on the left and the right 1) Polyatomics that are on BOTH sides- balance these as a unit FYI: Time saver- instead of doing individual atoms making up the poly, you do the whole unit 2) Singletons (“solo”acts) Balance atoms (except H and O) that appear only ONCE on EACH side 3) Balance other atoms • 4) Usually save H or O for last (they may appear in several compounds) and are then easier if last • There is no one right way every time • (your book has a general guide on p. 286-288) AgNO3 + Cu Cu(NO3)2 + Ag Balance polys first 2 AgNO3 + Cu Cu(NO3)2 + Ag Then Ag falls out nicely 2 AgNO3 + Cu Cu(NO3)2 + 2 Ag ◦ No need for N or O if you do the poly as a whole! Ag NO3 1 1 Cu 1 Cu NO3 1 2 Ag 1 2 AgNO3 + Cu 2 2 1 Cu(NO3)2 + Ag 1 2 1 2 AgNO3 + Cu 2 2 1 Cu(NO3)2 + 2 Ag 1 2 2 Al2O3 + CuCl2 CuO + AlCl3 This type you can start anywhere; (every element is a “solo act”!) Al2O3 + CuCl2 CuO + 2AlCl3 Then balance Cl Al2O3 + 3 CuCl2 CuO + 2 AlCl3 Then Cu Al2O3 + 3 CuCl2 3CuO + 2 AlCl3 I used Al first for this ex. O is already done! PbSO4 + AlF3 Where do you start? PbF2 + Al2(SO4)3 Do sulfate first 3 PbSO4 + AlF3 PbF2 + Al2(SO4)3 ◦ Then Pb (or Al, F, doesn’t matter!) 3 PbSO4 + AlF3 3 PbSO4 + 2 AlF3 Last check Al 3 PbF2 + Al2(SO4)3 3 PbF2 + Al2(SO4)3 There is a category of equations called COMBUSTION It is a C and H compound burning in oxygen (remember the element oxygen is a diatomic!) PRODUCTS are CO2 and H2O EX: __ CH4 + __ O2 This is the order of elements to balance Works EVERY time! Carbon 1st, using CO2 then H using the water then finish with O on the left with the diatomic oxygen ___ CO2 + ___ H2O __ CH4 + __ O2 ___ CH4 + __ O2 ___ CO2 + ___ H2O ___ CO2 + _2_ H2O Oxygen: Have 4 oxygen on the right Carbons are equal, move to H (2 from CO2 and 2 from H2O) 4 H on left, Need 2 water on right ◦ put a 2 for oxygen on the left ___ CH4 + __ O2 ___ CO2 + _2_ H2O 4 H’s on left and now 4 H’s on right CH4 + 2 O2 CO2 + 2 H2O EX: ___ C4H10 + __ O2 __ CO2 + __ H2O 4 C’s need 4 CO2’s ___ C4H10 + __ O2 4 CO2 + __ H2O Tip: Odd # of O on the right? Put it over 2, (Why? X times 2 = 13, Solving for X) then double all coefficients. ___ C4H10 + 13/2 O2 10 H’s need 5 waters ___ C4H10 + __ O2 ___ C4H10 + __ O2 4 CO2 + 5 H2O On right side: 8 O + 5 O = 13 O 4 CO2 + 5 H2O 2 C4H10 + 13 O2 4 CO2 + 5 H2O 8 CO2 + 10 H2O Why double- no half molecules! EX: __C3H8O3 + __ O2 __C3H8O3 + __ O2 __CO2 + __ H2O __C3H8O3 + __ O2 3 CO2 + 4 H2O Right side: 6 O + 4 O = 10 O 3 CO2 + __ H2O Left: 3 are already in formula, __C3H8O3 + __ O2 Watch out here 3 CO2 + 4 H2O Need 10-3 = 7 oxygens needed using the O2 molecule X times 2 = 7 X = ? (7/2) __C3H8O3 + 7/2 O2 3 CO2 + 4 H2O Last DOUBLE all coefficients: On to the packet of 50 balancing equations 2 C3H8O3 + 7 O2 Do not put 1’s in the blanks 1’s are understood 6 CO2 + 8 H2O If an equation is already balanced (all 1’s) simply mark it so- check mark, or write balanced (bal.) or write done for example Sodium phosphate + iron (III) oxide sodium oxide + iron (III) phosphate Skeleton first: NEED FORMULAS!! Sodium phosphate + iron (III) oxide sodium oxide + iron (III) phosphate Na3PO4 + Na2O + Fe2O3 FePO4 Poly is equal on both sides; Your choice, either Fe or Na first Na3PO4 + Fe2O3 Na2O + Sodium phosphate + iron (III) oxide oxide + iron (III) phosphate FePO4 2 Na3PO4 + Fe2O3 sodium 3 Na2O + 2 FePO4
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