4-Log and CT What is 4-Log? • 4-log is a treatment technique that ensures the removal/inactivation of microorganisms, including viruses, and is generally measured on a logarithmic scale (i.e., in terms of orders of magnitude). Many water systems must provide 4-log treatment due to microbial contamination of the source water. What do I need to know? • To understand 4-log, we need to understand the mathematical relationships between the physical and environmental components of a water system (i.e. peak flow rates, tank and pipe volumes, water temperature and pH, disinfectant residuals, and baffling factors.) From these parameters, we can calculate CT. What is CT? • CT is a measure of disinfection effectiveness. It is the product of the residual disinfectant concentration (C) in mg/l and the corresponding disinfection contact time (T) in minutes. CT (minutes-mg/l) = C x T, where: • C = residual disinfectant concentration (ultimately measured at the first customer during peak flow), in mg/l • T = Time during peak flow, measured in minutes, from the point of disinfection to a point where the residual is measured before or at the first customer. • Results of CT calculations can be compared with published data to determine whether 4-log virus removal can be achieved. A little history lesson… • Approximately 300 B.C. Euclid is thought to have come up with the concept of ∏ (pi) • Archimedes is credited with giving an a accurate approximation of pi •In 2600 B.C., the ancient Egyptians used an approximation of pi in their monuments • Indian texts from the 8th Century B.C. indirectly reference pi • The Bible indirectly references pi in 1 Kings 7:23 What is pi? No, not that kind of pie… This pi • In its simplest terms, pi is defined as the ratio of a circle’s circumference to its diameter. • Numerically, it’s approximately equal to 3.14 Why is pi important? • In relation to water systems, pipes and most tanks are circular • In order to determine the volumes of pipes and tanks, pi is an integral part of the formula Vcylinder = ∏r2L (where r= ½ the diameter of the pipe and L= the length of the pipe) • To simplify the equation and because we need initial volumes in cubic feet, we must use algebra to convert the pipe radius to diameter: V = ∏r2L ∏(d)2 x L 4 and from inches to feet, so: V = ∏(d”/12”)2 x L 4 • As a quick example, what is the diameter in feet of a 2” pipe? 2 inches 12 inches foot 2 inches x 1 foot = 0.167 foot 12 inches What is dimensional analysis? • • • In physics and all science, dimensional analysis is a tool to find or check relations among physical quantities by using their dimensions. The dimension of a physical quantity is the combination of the basic physical dimensions (usually mass, length, time, electric charge, and temperature) which describe it; for example, speed has the dimension length per unit time, and may be measured in meters per second, miles per hour, or other units. Dimensional analysis is routinely used to check the plausibility of derived equations and computations. How many seconds are in a year? 60 sec x 60 min x 24 hr x 365 days = 31,536,000 sec yr 1 min 1 hr 1 day 1 yr What are baffling factors and why must we use them? • Since poor circulation (i.e. short circuiting) in a storage or contact tank will reduce the contact time, T as calculated above is typically multiplied by a conversion or baffling factor to account for poor circulation. The diagrams on the following page show typical types of storage tanks, inlet/outlet pipe configurations, and corresponding recommended baffling factors (BF). • Note that bladder tanks and atmospheric or hydropneumatic tanks with a single inlet and outlet are not given contact time credit since during a pump-on cycle, some of the water is bypassing the tank. What is the BF for Lake Jesup? Example # 1 100’ of 2” pipe x 20’ of 4” pipe well Cl2 injection 1,000 gal H tank • Here’s what we know: – – – – Well pump flow rate = 25 gpm pH = 7.9 Temperature = 24⁰C Cl2 at 1st customer = 1.2 mg/L x Sample tap before or at 1st customer Segment 1 (20’ of 4” pipe) T = V = ∏(d/12”)2 x L x 7.48 gal Q 4 ft3 Q (Where T = detention time in minutes, V = volume in gallons, d = diameter in inches, L = length of segment in feet, and Q = the peak flow rate in gpm) Find the numerator (the volume) first V = ∏(4”/12”)2 x 20’ x 7.48 gal 4 ft3 Calculate V (volume in gallons) V = ∏(4”/12”)2 x 20’ x 7.48 gal 4 ft3 V = (0.785)(0.33333’)2 x 20’ x 7.48 gal ft3 V = (0.785)(0.11111 ft2) x 20 ft x 7.48 gal ft3 V = 0.087 ft2 x 20 ft x 7.48 gal ft3 V = 13.0152 gal Calculate T (contact time in minutes) • Remember: T = V Q We calculated the volume (V) to be 13.0152 gal We were given the peak flow rate (Q) of 25 gpm T = 13.0152 gal 25 gal min 13.0152 gal x 1 min = 0.52 min 25 gal Segment 2 (tank) • Because it is an H-tank, only 10-20% of the total volume of 1,000 gallons is usable at cut-in pressure (lowest water level) • Additionally, because the tank is not baffled, we must use a baffling factor of 0.1 T = V x BF Q T = 200 gal x 0.1 200 gal x 1 min x 0.1 = 0.8 min 25 gal 25 gal min Segment 3 (100’ of 2” pipe) • Remember T = V Q • As in Segment 1, the first step is to calculate volume: V = ∏(2”/12”)2 x 100’ x 7.48 gal 4 ft3 V = (0.785)(0.166666’)2 x 100’ x 7.48 gal ft3 V = (0.785)(0.027778 ft2) x 100 ft x 7.48 gal ft3 V = 0.021805 ft2 x 100 ft x 7.48 gal ft3 V = 16.3105 gal Calculate T (contact time in minutes) • Remember: T = V Q We calculated the volume (V) to be 16.31 gal We were given the peak flow rate (Q) of 25 gpm T = 16.31 gal 16.31 gal x 1 min = 0.65 min 25 gal 25 gal min What is the total T? • Total T = Segment 1 + Segment 2 + Segment 3 • Total T 0.52 min + 0.8 min + 0.65 min = 1.97 min Now let’s calculate the theoretical CT CT = C x T CT = 1.2 mg x 1.97 min L CT = 2.36 mg-min L Does this system meet 4-log CT requirements? • From the instructions for MOR Form 62-555.900(3) • The required CT to meet 4-log at 24⁰C is 2.2 mg-min/L • 2.36 > 2.2, so yes this system meets 4-log at the given parameters • Would this system still meet CT requirements at 18⁰C? CT values at 18°C • 2.36 < 3.4, so no this system does not meet 4-log at 18°C • What can this system do to meet 4-log CT requirements at worst case scenario? – Hire an engineer to modify the treatment plant by adding storage, treatment options which provide a log credit, or tank baffling. – Operational changes such as increasing disinfectant residuals, relocating injection point, or increasing minimum tank water level *Beware of simultaneous compliance issues (DBP production due to increased residuals or detention times) Adding storage tanks to increase CT WTP modification to increase CT What would our disinfectant residual have to be to meet 4-log at 18⁰C? CT = C x T C = CT C = 3.4 mg-min T L 1.97 min = 1.73 mg/L C = 3.4 mg-min x 1 L 1.97 min Treatment processes which provide log credit • Currently in the Central District, there are two types of treatments providing a 2-log credit – Conventional filtration • Must maintain combined filter effluent turbidity below 1 NTU at all times. – Reverse osmosis • Must maintain a permeate effluent salt passage below 5% at all times. Example #2 Wells Cl2 injection Clarifier x NH3 x 10’x10’x10’ Clearwell 10’ of 10” Transfer pumps GST 100’ of 10” VFD HSP House Plant office • • • • Wells – 3 @ 50 gpm each Transfer pumps – 2 @ 100 gpm each, shut off at 5’ HSP – 2 @ 100 gpm each GST – diameter 20’ - max water depth 18’ - min water depth 10’ • Here’s what we know: – pH = 10.2 – Temperature = 18⁰C – Free chlorine residual = 1.0 mg/L – Combined residual = 0.8 mg/L Segment 1 - Clearwell T = V x BF Q T = 500 ft3 x 7.48 gal ft3 200 gal min x 0.3 BF 500 ft3 x 7.48 gal x 1 min x 0.3 BF ft3 200 gal T = 18.7 min x 0.3 BF T = 5.61 min • CTfree = C x T 1.0 mg/L x 5.61 min CTfree = 5.61 mg-min/L Segment 2 – Pipe T = V = ∏(10”/12”)2 x 110’ x 7.48 gal 4 ft3 Q 200 gal min T = 2.24 min • CTChloramine = 0.8 mg/L x 2.24 min CTChloramine = 1.8 mg-min/L Segment 3 - GST T = V = ∏(20 ft)2 x 10 ft x 7.48 gal x 0.5 BF Q 4 ft3 200 gal min T = 117.4 min x 0.5 BF T = 58.7 min • CTChloramine = 0.8 mg/L x 58.7 min CTChloramine = 46.96 mg-min/L Does this system meet 4-log CT requirements? • Since part of the CT is from free chlorine and part of it is from chloramines, a direct comparison is not possible. • Therefore, we must use ratios of the respective CT. – If the sum of the ratios is greater than 1.0, then we meet 4-log. Does this system meet 4-log CT requirements? Total CTratio = CTfree Segment 1 + CTchloramine Segment 2 + CTchloramine Segment 3 Required CTFree Required CTChloramine Required CTChloramine Total CTratio = 5.61 + 1.8 + 46.96 25.2 845 845 = 0.22 + 0.002 + 0.055 = 0.278 • 0.278 < 1.0, therefore the system does not meet 4-log at the given parameters Does this system meet 2-log CT requirements? • Since this is a conventional filtration plant, and they continuously monitor and keep their CFET below 1 NTU, they receive a 2-log credit. Therefore, they only have to meet 2-log CT through disinfection. Does this system meet 2-log CT requirements? Total CTratio = 5.61 + 1.8 + 46.96 12.6 364 364 = 0.445 + 0.005 + 0.129 = 0.579 • 0.579 < 1.0, therefore the system still does not meet 4-log at the given parameters Questions? • Email: [email protected]
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