Methane Gas ( CH4 ) as Alternative Source of Renewable Energy A Research Proposal Submitted to The Faculty of the School of EECE Mapua Institute of Technology In Partial Fulfillment of The Requirements of the Degree of Bachelor Science of Electrical Engineering By Miraflores, Vincent Samarita, Dan Ehrald Ulitin, Dave Everlee Engr. George Vallestero June 2009 APPROVAL SHEET This is to certify that we have supervised the preparation of and ready the practicum paper prepared by Miraflores Vincent, Samarita Dan Ehrald, and Ulitin Dave Everlee entitled “Methane Gas as Alternative Source of Renewable Energy” and that the said research proposal has been submitted for final examination by the Oral Examination Engr.George C. Vallestero Academic Adviser As members of the Oral Examination Committee, we certify that we have examined this research proposal presented before the committee on June 16, 2009 and hereby recommend it to be accepted as partial fulfillment of the requirement for the degree in Bachelor of Science in Electrical Engineering. Engr. Federico V. Cudia Panel Member 1 Engr. Maria Criselda Loyola Panel Member 2 This research is hereby approved and accepted by the School of EE-ECE-CoE as partial fulfillment of the requirement for the degree in Bachelor of Science in Electrical Engineering. Engr. Felicito S Caluyo Dean, School of EECE Acknowledgments First of all we would like to thank God Almighty for giving us strength and intelligence to make this research somehow a small achievement in our part. Engr. George C. Vallestero for guiding us and providing us sufficient instructions about our chosen topic. To our parents, for their love, support and patience in giving us additional for this study and to our beloved friends who makes us happy every time we work on this study. TABLE OF CONTENTS Preliminaries Approval Sheet i Acknowledgement ii Table of Contents iii-iv Research Study Chapter I: Introduction Background of the study 1 Statement of the problem 1 Objectives of the Study 1 Hypothesis 1 Scope and Delimitation 2 Significance of the study 2 Chapter II: Review of Related Literature and Conceptual Framework Introduction 3 Local Literature 3-5 Foreign Literature 6-8 Conceptual Framework 9 Definition of Terms 10 Chapter III: Methodology of Research Introduction- 11-12 Research Design 13-18 Statistical Data 19-22 Appendices; Sample Survey References Interview Questions Researchers Profile CHAPTER 1 INTRODUCTION Landfill gas is generated as a result of decomposition of solid waste in landfills. Landfill gas primarily consists of carbon dioxide and methane. Both carbon dioxide and methane gas are considered as a form of greenhouse gas that leads to global warming. Since all landfills generate methane, it makes perfect sense to use this landfill gas for energy generation rather than emitting it to the atmosphere. Methane gas is a form of greenhouse gas that is over 20 times more effective than carbon dioxide in trapping heat in the atmosphere. Methane gas can remain in the atmosphere for about 9 to 15 years. This research aims to provide information and awareness to the people on the details on how methane gas can be use as alternative source of renewable energy and to know what appropriate way of converting methane gas into renewable energy. The objective of the research is to study that methane gas energy does not have to be harmful in any way, and can be produced in a friendly way to both mankind and the earth. The importance of this study is to know that landfill gas for energy is a win opportunity. Landfill gas emitted from decomposing garbage is a reliable and renewable fuel option that remains largely untapped at many landfills This research covers data regarding Methane gas as energy source that methane gas is also a primary component of natural gas and an important energy source. As a result, efforts to prevent or utilize methane emissions can provide significant economic, energy and environmental benefits. CHAPTER 2 REVIEW OF RELATED LITERATURE INTRODUCTION This chapter presents literature and studies of local and foreign origin discussing the theories and supposition about the application of methane gas as alternative source for renewable energy. It provides readers information about previous and relevant topics to the process of study. It provides the findings and conclusion of previous investigation which may be related to the finding and conclusion of the research. LOCAL LITERATURE The Philippines has numerous opportunities for methane capture and reuse projects in agricultural waste and landfill gas extraction and utilization. The Philippines’ experience in promoting agricultural biogas systems in the countryside will be a relevant factor in further improving the technology’s viability. The Philippines will also contribute its experience in landfill gas assessment and extraction arising from its pilot trial on existing sanitary landfills and dump sites. Additional opportunities may arise in the form of dispatch of experts, technology deployment, training and capacity building, tools and databases with information on methane emissions, and potential sites for country-wide methane reduction programs. Based on data in EPA's Global Anthropogenic Emissions of Non-CO2 Greenhouse Gases report, in 2005, Philippines's estimated anthropogenic methane emissions ranked 32nd in the world. Approximately 18 percent of its anthropogenic methane emissions—7.1 MMTCO2E—come from agriculture (manure management), coal mines, and landfills. The Philippines has urged the international community to adopt the necessary measures to reduce drastically global greenhouse gas emissions by as much as 80 percent if low-lying and archipelagic countries like the Philippines are to avoid the worst impacts of climate change. Presidential Adviser on Climate Change Secretary Heherson Alvarez said this was the instruction of President Gloria Macapagal-Arroyo given to him before he left last month for the March 29April 28 United Nations Framework Convention on Climate Change (UNFCCC) in Bonn, Germany. “The President has given instruction to move for an 80 percent cut (of greenhouse gas emissions) which we filed and re-substantiated with the resolution we filed in Bonn recently,” The Bonn proposal will be presented and voted upon by nations at the Conference of Parties (COP-15) in Copenhagen this December 2009. Other archipelagic countries, including Vietnam and Indonesia, have expressed strong support for the Philippine proposal, Alvarez said. Alvarez briefed the President on the Philippines’ call for the international community to reduce greenhouse gas emissions during her visit to the Quezon City Controlled Disposal Facility at Barangay Payatas this morning which was attended by 142 barangay chairmen of Quezon City. The project also provides free electricity to two major streets in Barangay Payatas and the Plantsahan ng Bayan, where residents iron their clothes for free. According to a study by the Renewable Energy Coalition, the Philippines produces over 264,228 megawatts via renewable energy sources. Here’s the breakdown that actually totals more: Geothermal - 4,531 MW Hydro electric - 13,097 MW Wind -76,600 MW Wave - 170,000 MW Biomass - 277 Million Barrels Fuel Oil equivalent (MBFOE)/year Solar Power - 5 ~ 5.1 KwH per square meter per day. renewable energy in the Philippines suffers from reliability problems. While Geothermal and Hydroelectric are relatively constant, you can’t count on Wind to always blow, for waves to always be strong, and the sun to always shine. Maybe that’s why this significant amount of capacity hasn’t filtered down into the general energy usage of Philippine society. FOREIGN LITERATURE Methane is a gas and is the main component of natural gas. Methane’s molecular formula is CH4. When it is burned, it produces water and carbon dioxide as byproducts. It can burn only when mixed with oxygen. As it is relatively abundant and clean when burning, methane is a quite attractive fuel source. However, its transportation is associated with some difficulty as it is a gas. Usually, it is transported via pipelines with only a few countries that use trucks for transport. Most of us know how methane smells if we have a gas oven at home, but methane is actually an odorless gas. The smell many of us associate with this gas is actually an artificial odor added to the gas to provide a signal in case of a leak. By burning methane in gas turbines or steam boilers, the gas is used for electricity production. Many homes have methane gas piped in, which is used for heating systems and cooking appliances. Its energy content equals to 39 megajoules per cubic meter. Methane is also used as a fuel for vehicles. Before it can be used for that purpose, it needs to be compressed. It is considered to be environmentally friendly, even friendlier than petroleum and diesel fuels. Interesting research is being conducted by NASA regarding methane as a potential rocket fuel. A positive conclusion was found about methane. It can be found in many parts of our universe, meaning that it’s extremely abundant. This means, of course, that methane could be collected onthe-spot and used accordingly. Methane is also used in the chemical industry. Hydrogen, acetic acid and methanol are also produced using methane. Methane’s boiling point is 161 degrees Celsius under a pressure of 1 atmosphere. This gas is flammable when its concentration is between 5 and 15 percent. If it is in liquid form, methane may burn only at the pressure of 4 to 5 atmospheres. Another important point about methane is that it can be harmful to human health and is a contributing factor to global warming. Even though methane is non-toxic when it doesn’t reach its explosive limit of five percent, it can be a dangerous asphyxiant. Asphyxiants cause oxygen deprivation, which happens when oxygen is superseded by methane. The minimal presence of oxygen in air should be not less than 18 percent. Liquefied methane, which is used in refrigerators, may cause frostbite. In this case, the skin becomes waxy, white or yellow. Tissue death may occur if the frostbite is severe enough. Needless to say, contact with the eyes may result in even worse effects. Another thread is associated with the abundance of landfills. The matter is that methane is being produced in landfills as well from decaying organic matter. Soil allows methane to migrate underground, which may cause an explosion hazard in adjacent homes. Methane travels through soil into basements. This is why methane monitors should be used on and near landfills where methane is being released. Such monitors burn methane off avoiding its spreading and underground migrating. Today, just about every waste collector is examining its fleet of trucks to conserve energy. That includes working with manufacturers to develop more fuel efficient, cleanerburning vehicles powered with alternative fuels and using hybrid engines,” said Parker. Hybrid technology is particularly promising for garbage trucks because of their stop-and-go nature. “The industry has for years invested in trucks fueled by liquefied natural gas, ultra-low sulfur fuel and other low-emission fuels. Now, many operators are looking to alternative fuels like biodiesel and even methane gas from landfills to run their trucks,” said Parker. Both alternative fuel and hybrid trucks have been used in many cities, including San Diego, San Francisco, Seattle, Fort Worth and Denver. “Landfill-gas-to-energy projects address global warming by capturing methane, which is a greenhouse gas,” Parker noted. The EPA estimates that using methane as renewable, “green” energy brings environmental and energy benefits equivalent to eliminating the CO2emissions of 195 million barrels of oil a year. The Nobel Prize-winning Intergovernmental Panel on Climate Change (IPCC) has noted that landfill-gas recovery directly reduces greenhouse gas emissions. Recycling and composting offer another greenhouse-reduction success story. The industry recycled or composted slightly more than one third of all municipal solid wastes in 2007, conserving precious resources, protecting air and water from potential pollution and leading to a 2.5 percent reduction in America’s total greenhouse gas emissions “The solid waste industry is proud of its environmental achievements, but we’re not sitting on our laurels. Independent research determined that between 1974 and 1997, greenhouse gas emissions from solid waste and recycling declined by 78 percent, even while waste generation increased by 70 percent. Our collective efforts have made a difference, and we continue to raise the bar,” said Parker. CONCEPTUAL FRAMEWORK The main concept of the study is methane Gas as Alternative Source of Renewable Energy. The study utilizes the input, process of the study and output models as shown. Input Process of study Output Periodical Articles Data gathering Book Sources Data analysis gas as a renewable Internet sources Data energy source Seminars Use of Methane interpretation The researcher considered the factors affecting the Methane Gas as Alternative Source of Renewable Energy with regards to the use of energy source and these are the following; internet sources, periodical articles, books, seminar attended. To determine Methane Gas as Alternative Source of Renewable Energy, data must be gathered and processed. The data that will be gathered would be very important for the development of the study. They are necessary to be able to search the possible solutions to the problems stated. Collection of data can also be achieved through researching and reading some articles from the internet. After gathering and processing the necessary data, these must be analyzed. After all the processes states, interpretation of the results will be designed to be able to state the conclusion and make some recommendations. DEFINITION OF TERMS Biogas - typically refers to a gas produced by the biological breakdown of organic matter in the absence of oxygen. Biogas originates from biogenic material and is a type of biofuel. Greenhouse gases - are gases in an atmosphere that absorb and emit radiation within the thermal infrared range. This process is the fundamental cause of the greenhouse effect. Methane - is a chemical compound with the molecular formula CH4. It is the simplest alkane, and the principal component of natural gas. EPA - Environmental Protection Agency NSWMA - National Solid Waste Management Association UNFCCC - United Nations Framework Convention on Climate Change NASA - National Aeronautics and Space Administration IPCC - Intergovernmental Panel on Climate Change Asphyxia - is a condition of severely deficient supply of oxygen to the body that arises from being unable to breathe normally. An example of asphyxia is choking. Methanogenic bacteria - are archaea that produce methane as a metabolic byproduct in anoxic conditions. They are common in wetlands. CHAPTER 3 METHODOLOGY Introduction This chapter presents the methodology to be used in this study. Descriptive method is being used in the study. It is a method that describes what actually exists on the present time of study such as practices, description, an analysis and interpretation of current conditions. Research Design is presented and serves as a guide in doing the Research. It is also presents the research Instruments and procedure as well as the research tool to be used in the study. Identification of the Problem “Methane Gas as Alternative Source of Renewable Energy” Conclusion and Recommendations Analyzing the situation and planning of methods to be use Research Materials Used Figure 3.1 In order for us to obtain results, we take some research materials like internet, books, periodicals and seminars this are the data we gathered Biogas Production Conversion of organic waste from agriculture, livestock, industries, domestics and other human activities into energy and bio-fertilizer by anaerobic process (strictly no oxygen).Produced by methanogenicbacteria The use of biogas as energy and fertilizer sources can lead to better environment, health and other socio-economic gains. Biogas Composition Composed of 50 to 70 percent methane, 30 to 40 percent carbon dioxide and low amount of other gases as hydrogen, nitrogen, hydrogen sulphide and water vapour. Why Scrub? - CO2and N2 are inert which are fillers and add nothing to biogas as an energy source CO2and N2also dilute the energy in the biogas, A liter of 66% methane biogas = 5.3 calories of heat energy, equivalent to 590 BTU/ft3, whereas, A liter of pure CH4= 8 calories of available heat energy equivalent to 900 BTU/ft3 Removal of the inert ingredients will result to smaller storage facility which will be less expensive BLOCK DIAGRAM Biogas Digester “Waste Source” 13 hp gasoline fed generator “Electricity generation” Compressor “Processing the waste” Use of scrubbers “Used for filtering CO2 and N2” Figure 3.2 Biogas Sampling Raw biogas (unscrubbed) from the 18 m3biogas digester. Scrubbed biogas from the 500 liter capacity gas storage tanks. The unscrubbedand scrubbed biogas were collected using a gas sampling plastic bag. Biogas Qualitative Analysis The quality of biogas was analyzed using an Orsat Gas Analyzer. THE PURIFICATION PROCESS 18 m3Biogas Digester Compressor Converted 13hp gasoline fed Generator Series of scrubbers Storage tanks for scrubbed biogas Electricity Generation for lighting, refrigeration, and computer operation Biogas Digester Biogas digester are semi-continuous type made of concrete outer and inner walls, has an inlet and outlet pipes for loading and discharge of solid waste and slurry. Fitted with gas holder made of gauge 16 iron sheet for biogas collection. Has a water seal to prevent the scape of gas. Gas Holder GAS HOLDER The Scrubbers - Consisting of 4 units of 8 inches diameter PVC pipes each of 50 liter capacity. - It is either packed with: - NaOHflakes for the removal of CO2 - Iron fillings for the removal of H2S Technical Design of the Scrubber Biogas Storage Tanks Consisting of 2 units of 500 liter capacity steel tanks with movable gas holder It is water sealed to prevent the escape of gas. Provided with gas inlet and outlet pipes for the inflow and outflow of gas into the generator. 13 hp Hybrid Type Generator Installation of the Converter Electricity Utilization About 2.5 m3scrubbed biogas was used to fuel the modified generator and produced a 220 V that power some electrical appliances such as exhaust fan, light, refrigerator and industrial fan for 1 hour. Qualitative Analysis of Raw Biogas Biogas Source 18 m3 biogas demo Facility Portable biogas digester Biogas Composition (%) Methane (CH4) 70 65 Carbon Dioxide (CO2) 30 35 Respondents Q1 Q2 Q3 Q4 Q5 Q6 Q7 Q8 Q9 Q10 total 1 2 3 4 5 6 7 8 9 10 Total 1 1 1 1 0 1 1 1 1 1 1 1 0 1 0 1 1 1 0 0 1 1 1 0 1 0 0 1 1 1 1 1 1 1 1 1 1 0 1 1 1 1 1 1 1 1 0 1 1 1 1 1 1 0 0 1 1 1 1 0 0 1 1 0 1 1 1 1 1 0 1 1 0 1 1 1 1 1 1 1 1 1 0 1 0 1 1 0 1 0 1 1 1 0 0 1 1 0 1 0 9 6 Statistical Data 7 9 9 7 7 9 6 6 Summary : Yes = 1; No = 0 Total Tally: Yes = 75 No = 25 Correlation Summary using Pearson Correlation: Respondents 1 2 3 4 5 6 7 8 9 10 Total x 1 1 1 0 1 0 0 1 1 0 6 y 9 10 7 3 5 1 2 7 9 5 58 x2 1 1 1 0 1 0 0 1 1 0 6 y2 81 100 49 9 25 1 4 49 81 25 424 xy 9 10 7 0 5 0 0 7 9 0 47 9 10 7 7 5 9 8 7 9 5 76 n 10 ∑X 6 ∑X 2 6 ∑Y 58 ∑Y2 424 r 0.8414 The Purpose of this survey is to know what the reactions of selected citizens of Manila, Regarding the implementation and effects of “methane gas as renewable source”. EE018D / B6 Name:__________________________________ Occupation:________________________________ Directions: Kindly put 1 if yes and 0 if No in the box reference to your desired compliance. 1. Are you aware of as Renewable Energy source “methane gas”? 2. Do you think methane gas is more efficient To use than any other renewable energy source? 3. Do you think methane gas is much economical To use than any other renewable energy source? 4. Do you think using Methane gas as new source of Energy will improve the status of our economy? 5. Are you in favor of using methane gas as renewable Energy source? 6. Some companies are against Methane gas as renewable Energy source, are you willing to help the country to Implement the use of methane gas as new energy source? 7. Do you think that the implementation of methane gas will Make our world a better place to live in? 8. The Price of Energy cost is increasing, do you think That methane gas as renewable source is the solution to This problem? 9, Do you think it is helpful in our environment to use Methane gas? 10. Do you think that the implementation of methane gas Will increase the employment status in our country? Comments and Suggestions: _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ Appendices DAVE EVERLEE A. ULITIN Address: 1217 Sta. Clara St. Sampaloc Manila Mobile Number: 09276536150 Email Address: [email protected] CAREER OBJECTIVE: To be accepted in a company that would allow me to practice my knowledge and skills in the field of Electrical Engineering, and consequently gain further information on the same discipline. SKILLS Proficient in different Software like Microsoft Office, Microsoft Visio, Knowledgeable in AutoCAD, EDraw Software, Tina Pro, Pspice OrCAD, MatLab, Motor Control, Electrical Design, Electrical Relays, Power System Protection, Surge Protection. ACADEMIC BACKGROUND Tertiary: 2004 – Present Electrical Engineering Mapua Institute of Technology Intramuros Manila Secondary: 2000 – 2004 La Consolacion – Tanauan Tanauan City, Batangas PERSONAL DATA Born in Laurel, Batangas on March 19, 1987. Single, Filipino citizenship, Roman Catholic. Can communicate in English and Filipino. Knows how to drive. Likes playing basketball and listening to music. Dependable, responsible and hardworking. Can work with minimal supervision. REFERENCES : Available Upon Request DAN EHRALD G. SAMARITA Address: 9D-Dama De Noche Ext. Manuela Las Pinas City Telephone Number: (02) 501-61-84 Mobile Number: 09063231296 Email Address: [email protected] CAREER OBJECTIVE: To be accepted in a company that would allow me to practice my knowledge and skills in the field of Electrical Engineering, and consequently gain further information on the same discipline. SKILLS Educational background on applications of C++ Programming, PSPICE & MultiSim circuit simulation, MATLAB, AUTOCAD, ACADEMIC BACKGROUND Tertiary: 2004 – Present Electrical Engineering Mapua Institute of Technology Intramuros Manila Secondary: 2000 – 2004 Saint Mary’s Academy 525 P. Burgos St., Pasay City PERSONAL DATA Born in Cuenca, Batangas on March 15, 1987. Single, Filipino citizenship, Roman Catholic..Loves Outdoor Adventure and music. Has a good interpersonal and organizational skill. Has a sense of responsibility, Has an effective Communication skill, Eager and quick to learn. REFERENCES : Available Upon Request VINCENT L. MIRAFLORES Address: 8070 Honradez st. Makati City Mobile Number: 09162592120 Email Address: [email protected] CAREER OBJECTIVE: To be accepted in a company that would allow me to practice my knowledge and skills in the field of Electrical Engineering, and consequently gain further information on the same discipline. SKILLS Proficient in different Software applications like Microsoft Office, Excel and Powerpoint, Knowledgeable in AutoCAD, Tina Pro, MatLab ACADEMIC BACKGROUND Tertiary: 2004 – Present Electrical Engineering Mapua Institute of Technology Intramuros Manila Secondary: 2000 – 2004 Paco Catholic School Paco Manila PERSONAL DATA Born in Makati on June 11, 1987. Single, Filipino citizenship, Roman Catholic. Can communicate in English and Filipino. Knows how to drive. Likes Body-Building and Playing Dota. Dependable, responsible and hardworking. Can work with minimal supervision. REFERENCES : Available Upon Request REFERENCE http://www.energyconservationinfo.org/altenergy.htm#Methane http://www.methanetomarkets.org/partners/country/philippines.htm http://www.renewableenergymagazine.com/paginas/Contenidosecciones.asp?ID=3468&Tip o=&Nombre=BioEnergy ttph://technogra.ph/20080611/sections/rundowns/renewable-energy-produces-at- least-264228-mw-in-the-philippines Owen, Dimebag Petrucci, RENEWABLE ENERGY MAGAZINE, 2003 Drake Francis, GLOBAL WARMING
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