The States of Matter and the Particle Theory The essentials of life — food, water, and air — are examples of substances that occur i n the three different states of matter: solid, liquid, and gas. As you learned in earlier science smdies: • Solid is the state of matter of a substance that has a definite shape and volume (for example, a sugar cube). • Liquid is the state of matter of a substance that has a definite volume, but no definite shape (for example, water). • Gas is the state of matter of a substance that has neither a definite shape nor a definite volume (for example, oxygen). By using the particle theory, you can explain why liquids and gases flow but solids do not. Gas According to the particle theon/, the particles of a gas will completely fill a container. If you removed the stopper in this flask, what would happen to the gas? Liquid This liquid is held in a container. You have probably noticed that liquids take the shape of the container in which they are placed. Solid This solid cube of sugar does not need a container to keep its shape. The five major points of the particle theory of matter are: 1 . A l l matter is made up of very small particles. 2. A l l particles in a pure substance are the same. Different substances are made of different particles. 3. There is space between the particles. 4. The particles are always moving. As the particles gain energy, they move faster. 5. The particles in a substance are attracted to one another. The strength of the attractive force depends on the type of particle. Viscosity: Tliiclc or Thin? 111 Changes of State As you may recall from earlier smdies, die process of melting is an example of a change of state, which occurs when the physical state of a substance is transformed into another state. Figure 4.3 shows changes of state. The change from solid to liquid is called melting, and the change from liquid to gas is called vaporization. These changes of state occur when the substance is heated and the particles of the substance gain energy. I f you were to cool the substance, the reverse changes of state would occur because the particles lose energy. The change from gas to liquid is called condensation, and the change from liquid to solid is called freezing. An unusual change of state occurs when a solid turns into its gaseous state without going through the liquid state. This change of state is known as sublimation. An example of sublimation occurs when dry ice is used at a rock concert — a chunk of frozen carbon dioxide (a solid) gains energy and gives off a thick cloud of fog (carbon dioxide gas). Figure 4.4 shows this change of state. The change from a gas directiy to a solid is called sublimation as well. An example of this occurs when frost forms on windows on bitterly cold days (water vapour in the air loses energy rapidly and forms snowy ice). Pause& Reflect How do raindrops form? If clouds contain water vapour and remain suspended in ttie sky, try to explain what you tfiink happens inside the clouds to form rain. Using the word "condensation," write an explanation in your Science Log. You may draw a sketch to illustrate your answer. mmCOMMECT What if you wanted to describe the change of Figure 4.3 state from liquid to solid Clianges of state for a metal, such as copper, or a non-metal, such as wax? Neither one of these substances can be said to "freeze" back into a solid. What verb would you use to describe this change of state? Look for a clue in Figure 4.3. nnelting (also called fusion) SOLID freezing (also called solidification) Figure 4.4 Solid carbon dioxide is called dry ice because it does not become a liquid before it becomes a gas. Dry ice is much colder than regular ice, so a fog of condensed water vapour forms as air surrounding it cools. This result is often used for special effects in television, film, and theatre. PidYnuKnow? What is the difference between a gas and a vapour? A substance is called a gas if it exists as a gas at room temperature (for example, oxygen gas or carbon dioxide gas). The same substance is called a vapour if it normally exists as a solid or a liquid at room temperature (for example, water vapour or perfume vapour). 115 Did you know that science fiction script writers often feature changes of state in imaginary ways? "Morphing" has become one of the most popular special effects developed for science fiction movies. By means of computergenerated graphics, characters on screen appear to metamorphose, or morph, into someone or something else. In some movies, for example, solid beings appear to morph into a liquid that can creep under doors, or slip through cracks, and then quickly resolidify. Morphing has also become a popular feature of music videos, television programs, Evaporation is slow vaporization. I t occurs over a wide range of temperatures. A wet towel will dry even i f the air temperamre is not high. On a cool day it will simply take longer for the water to evaporate from the towel. Boiling is rapid vaporization. It occurs at a specific temperamre, called the boiling point. The boiling point of water is 100°C (at sea level). Similarly, every substance has its own freezing point and melting point. The freezing point of water, for example, is 0°C (at sea level). This is the temperamre at which liquid water freezes. I t is also the temperamre at which ice melts — its melting point. Figure 4.5 illustrates the melting point of two other substances: paraffin Figure 4.5 Every substance has its own melting point. (wax) and silver. The picmres show how the properties of a substance, such as the melting point, can have valuable uses. When normally sofid substances are melted, the liquid can be poured into moulds of various shapes. When the substance is cooled, i t solidifies and takes the shape of the mould. The result can be a wax candle, a silver teapot, and many other products. The processes picmred here make good use of flowing Hquids and viscosity. and commercials. Check Your Understanding 1 . In your own words, what does "to flow" mean? 2 . Classify the following items as fluids or as non-fluids. shampoo pencil honey thumbtacks thread sap paper nail polish blood air molten lava smoke sugar namral gas ash gravel hairspray balloon perfume snow 3 . How could you test whether or not a substance is a fluid? COMMECT In your Science Log, 4 . A substance has a definite volume but an indefinite shape. Is the substance a sohd, a liquid, or a gas? 5 . Apply Use the particle theory to explain why ice cubes form in your freezer. write a short story that involves "morphing." Include an illustration of the morphing process that occurs in your story. 116 Fantastic Fluids 6 . Thinking Critically Describe a place or a simation in which you could find water as a solid, a liquid, and a gas all at the same time. 7 . Thinking Critically Which substances could you use to demonstrate "morphing"? Are these substances fluids? For each substance, explain your answer.
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