Analytical Instruments Material Safety Data Sheet Issue Date: Supersedes: 19-JAN-2012 New 3% Hydrogen Peroxide Solution______________ _____________________________________ 1 Identification of Product and Company Identification of substance or preparation Hydrogen Peroxide Solution Synonyms: Hydrogen Dioxide Solution, Hyperoxide Product Application: This MSDS provides health and safety information for any 3% hydrogen peroxide component of the following vials or kits. GE Analytical Instruments Part Number STD 90080-01 Product Name TOC 9XX – Hydrogen Peroxide Rinse Company/Undertaking Identification GE Analytical Instruments Inc 6060 Spine Road Boulder, CO 80301 T303-444-2009 Emergency Telephone 1-800-535-5053 INFOTRAC (North America) Outside of N.A.,call collect: 1-352-323-3500 GE (800) 877-1940 Prepared by EHS Manager: 720-622-0153 2 Composition / Information On Ingredients Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. Compound Name NIOSH RTECS Concentration ZC0110000 NA 96-98% 2-4% CASRN Water 7732-18-5 Hydrogen Peroxide 7722-84-1 OSHA PEL ACGIH TLV NIOSH REL DFG MAK None None None None 1 ppm TWA; 1 ppm 1 ppm TWA; Not found 1.4 mg/m3 1.4 mg/m3 TWA HAZARDOUS INGREDIENTS: This product is not hazardous as defined by OSHA regulations. 3 Hazards Identification EMERGENCY OVERVIEW MAY BE HARMFUL IF SWALLOWED IN LARGE QUANTITIES. CAUSES EYE IRRITATION. GE Analytical Instruments, Inc. 2012H Page 1 of 6 DIN 90080 Rev. A MSDS, 3% HYDROGEN PEROXIDE Material Safety Data Sheet POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: No adverse effects expected on intact skin. Contact on burns or open abrasions/wounds may cause stinging pain or irritation. ACUTE EYE EFFECTS: Causes irritation, redness, and pain. ACUTE RESPIRATORY EFFECTS: Not expected to be a health hazard under normal conditions. INGESTION EFFECTS: Large oral doses may cause irritation and blistering to the mouth, throat, and abdomen. May also cause abdominal pain, vomiting, and diarrhea. MEDICAL CONDITIONS AGGRAVATED: Not known. 4 First Aid Measures SKIN CONTACT: Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation develops. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately, especially if irritation/burning persists. INGESTION: Give several glasses of water to drink to dilute. If large amounts are swallowed, get medical advice. NOTES TO PHYSICIANS: No special instructions 5 Fire Fighting Measures Flash Point Will not flash Ignition Temperature Will not flash L.E.L. Will not support an explosion U.E.L. N.A. FIRE FIGHTING INSTRUCTIONS: There are no special precautions for fire fighting. Not considered to be a fire hazard at the 3% concentration. EXTINGUISHING MEDIA: Use any means suitable for extinguishing surrounding fire. Wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6 Accidental Release Measures PROTECTION AND SPILL CONTAINMENT: Ventilate area. Wear personal protective equipment as specified in Section 8. Contain and recover large quantities of liquid. Do not use combustible materials such as sawdust to absorb waste; use inert material such sand, earth, vermiculite. Small amounts of liquid residue may be flushed to sewer with plenty of water (unless restricted by local codes). GE Analytical Instruments, Inc. 2012H Page 2 of 6 DIN 90080 Rev. A MSDS, 3% HYDROGEN PEROXIDE Material Safety Data Sheet 7 Handling & Storage HANDLING/STORAGE: Store in a cool, well-ventilated dark area. Protect from freezing. Isolate from incompatible substances. 8 Exposure Controls / Personal Protection EXPOSURE LIMITS: This product is not hazardous as defined by OSHA regulations. ENGINEERING CONTROLS: Standard household ventilation is expected to be adequate to control exposures. PERSONAL PROTECTIVE EQUIPMENT: Wear appropriate chemical safety glasses, gloves, and clothing to prevent eye and skin exposure. RESPIRATORY PROTECTION: When used according to the manufacturer's instructions, no reasonably anticipated exposure could warrant the use of respiratory protection. Follow respirator regulations if material is used in bulk quantities. 9 Physical & Chemical Properties Characteristic Boiling point (°C): Specific gravity: Melting point: Estimated vapor density: Estimated vapor pressure: Molecular weight: Water Solubility (%v/v): Photoreactive VOCs: pH: Evaporation rate (Water =1): Estimated % volatility: Odor threshold: Odor: Appearance: Description Approximately 100°C @ 1 Torr Approximately 1.0 @ 4°C No information available >1.00 Approximately 23.3 mm Hg at 30°C 34 Soluble None No information available No information available Greater than 99% None Slight Clear colorless liquid 10 Stability & Reactivity STABILITY: Light sensitive. HAZARDOUS POLYMERIZATION: Spontaneous polymerization will not occur. Hazardous polymerization does not occur. INCOMPATIBILITIES: Powdered metals, powdered metal salts. DECOMPOSITION PRODUCTS: Oxygen. GE Analytical Instruments, Inc. 2012H Page 3 of 6 DIN 90080 Rev. A MSDS, 3% HYDROGEN PEROXIDE Material Safety Data Sheet 11 Toxicological Information Component Information Component LD50 Oral Hydrogen peroxide 801 mg/kg ( Rat ) Carcinogenicity Component ACGIH Hydrogen peroxide A3 IARC Not listed LD50 Dermal 2000 mg/kg ( Rabbit ) 4060 mg/kg ( Rat ) NTP Not listed OSHA Not listed LC50 Inhalation 2 mg/L ( Rat ) 4 h Mexico Not listed ACGIH: (American Conference of Governmental Industrial Hygienists) A1 - Known Human Carcinogen A2 - Suspected Human Carcinogen A3 - Animal Carcinogen ACGIH: (American Conference of Governmental Industrial Hygienists) 12 Ecological Information Ecotoxicity . Component Freshwater Algae Hydrogen peroxide EC50 2.5 mg/L/72h Freshwater Fish Not listed Microtox Not listed Water Flea EC50 7.7 mg/L/24h Persistence and Degradability No information available Bioaccumulation/ Accumulation No information available Mobility No information available Component Water log Pow -1.87 13 Disposal Considerations If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : Not applicable. Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material. 14 Transport Information DOT: Not Regulated IATA: Not regulated GE Analytical Instruments, Inc. 2012H Page 4 of 6 DIN 90080 Rev. A MSDS, 3% HYDROGEN PEROXIDE Material Safety Data Sheet 15 Regulatory Information TSCA: All components of this product are listed in the TSCA inventory. U.S. Federal Regulations TSCA 12(b) - Not applicable SARA 313 - Not applicable SARA 311/312 Hazardous Categorization Acute Health Hazard - No Chronic Health Hazard - No Fire Hazard - No Sudden Release of Pressure Hazard - No Reactive Hazard - No Clean Water Act - Not applicable Clean Air Act - Not applicable OSHA Component Hydrogen peroxide Specifically Regulated Chemicals - Highly Hazardous Chemicals TQ: 7500 lb CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Component Hazardous Substances RQs CERCLA EHS RQs Hydrogen peroxide 1000 lb California Proposition 65 This product does not contain any Proposition 65 chemicals. State Right-to-Know Component Massachusetts Hydrogen peroxide X New Jersey X Pennsylvania X Illinois - Rhode Island X U.S. Department of Transportation Reportable Quantity (RQ): N DOT Marine Pollutant: N DOT Severe Marine Pollutant: N U.S. Department of Homeland Security This product contains the following DHS chemicals: Component DHS Chemical Facility Anti-Terrorism Standard Hydrogen peroxide 2000 lb STQ (concentration of at least 30%) Other International Regulations Mexico – Grade: No information available Canada - This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class - Non-controlled GE Analytical Instruments, Inc. 2012H Page 5 of 6 DIN 90080 Rev. A MSDS, 3% HYDROGEN PEROXIDE Material Safety Data Sheet 16 Other Information NFPA/HMIS CODE TRANSLATION Health 1 Can cause irritation if not reated Fire 1 Ignites after considerable preheating. Reactivity 0 Normally stable. Not reactive with water. Special Reactivity NONE No special Hazard (1) Protective Equipment A Safety Glasses (1) refer to section 8 of MSDS for additional protective equipment recommendations. _______________________________________________________________________________________ CHANGE LOG EFFECTIVE DATE 19-JAN-2012 GE Analytical Instruments, Inc. 2012H REVISIONS TO SECTION New Page 6 of 6 SUPERSEDES New DIN 90080 Rev. A MSDS, 3% HYDROGEN PEROXIDE
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