3% Hydrogen Peroxide Solution

Analytical Instruments
Material Safety Data Sheet
Issue Date:
Supersedes:
19-JAN-2012
New
3% Hydrogen Peroxide Solution______________ _____________________________________
1 Identification of Product and Company
Identification of substance or preparation
Hydrogen Peroxide Solution
Synonyms: Hydrogen Dioxide Solution, Hyperoxide
Product Application: This MSDS provides health and safety information for any 3% hydrogen peroxide component of
the following vials or kits.
GE Analytical Instruments Part Number
STD 90080-01
Product Name
TOC 9XX – Hydrogen Peroxide Rinse
Company/Undertaking Identification
GE Analytical Instruments Inc
6060 Spine Road
Boulder, CO 80301
T303-444-2009
Emergency Telephone
1-800-535-5053 INFOTRAC (North America)
Outside of N.A.,call collect: 1-352-323-3500
GE (800) 877-1940
Prepared by EHS Manager: 720-622-0153
2 Composition / Information On Ingredients
Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed.
Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation.
Compound Name
NIOSH
RTECS
Concentration
ZC0110000
NA
96-98%
2-4%
CASRN
Water
7732-18-5
Hydrogen Peroxide 7722-84-1
OSHA PEL
ACGIH
TLV
NIOSH REL
DFG MAK
None
None
None
None
1 ppm TWA; 1 ppm 1 ppm TWA; Not found
1.4 mg/m3
1.4 mg/m3
TWA
HAZARDOUS INGREDIENTS: This product is not hazardous as defined by OSHA regulations.
3 Hazards Identification
EMERGENCY OVERVIEW
MAY BE HARMFUL IF SWALLOWED IN LARGE QUANTITIES. CAUSES EYE IRRITATION.
GE Analytical Instruments, Inc. 2012H
Page 1 of 6
DIN 90080 Rev. A
MSDS, 3% HYDROGEN PEROXIDE
Material Safety Data Sheet
POTENTIAL HEALTH EFFECTS
ACUTE SKIN EFFECTS: No adverse effects expected on intact skin. Contact on burns or open abrasions/wounds may
cause stinging pain or irritation.
ACUTE EYE EFFECTS: Causes irritation, redness, and pain.
ACUTE RESPIRATORY EFFECTS: Not expected to be a health hazard under normal conditions.
INGESTION EFFECTS: Large oral doses may cause irritation and blistering to the mouth, throat, and abdomen. May
also cause abdominal pain, vomiting, and diarrhea.
MEDICAL CONDITIONS AGGRAVATED: Not known.
4 First Aid Measures
SKIN CONTACT: Not expected to require first aid measures. Wash exposed area with soap and water. Get medical
advice if irritation develops.
EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids
occasionally. Get medical attention immediately, especially if irritation/burning persists.
INGESTION: Give several glasses of water to drink to dilute. If large amounts are swallowed, get medical advice.
NOTES TO PHYSICIANS: No special instructions
5 Fire Fighting Measures
Flash Point
Will not flash
Ignition Temperature
Will not flash
L.E.L.
Will not support an explosion
U.E.L.
N.A.
FIRE FIGHTING INSTRUCTIONS: There are no special precautions for fire fighting. Not considered to be a fire hazard at
the 3% concentration.
EXTINGUISHING MEDIA: Use any means suitable for extinguishing surrounding fire. Wear full protective clothing and
NIOSH-approved self-contained breathing apparatus with full facepiece operated in the
pressure demand or other positive pressure mode.
6 Accidental Release Measures
PROTECTION AND SPILL CONTAINMENT: Ventilate area. Wear personal protective equipment as specified in Section
8. Contain and recover large quantities of liquid. Do not use combustible
materials such as sawdust to absorb waste; use inert material such sand,
earth, vermiculite. Small amounts of liquid residue may be flushed to sewer
with plenty of water (unless restricted by local codes).
GE Analytical Instruments, Inc. 2012H
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DIN 90080 Rev. A
MSDS, 3% HYDROGEN PEROXIDE
Material Safety Data Sheet
7 Handling & Storage
HANDLING/STORAGE: Store in a cool, well-ventilated dark area. Protect from freezing. Isolate from incompatible
substances.
8 Exposure Controls / Personal Protection
EXPOSURE LIMITS: This product is not hazardous as defined by OSHA regulations.
ENGINEERING CONTROLS: Standard household ventilation is expected to be adequate to control exposures.
PERSONAL PROTECTIVE EQUIPMENT: Wear appropriate chemical safety glasses, gloves, and clothing to prevent eye
and skin exposure.
RESPIRATORY PROTECTION: When used according to the manufacturer's instructions, no reasonably anticipated
exposure could warrant the use of respiratory protection. Follow respirator
regulations if material is used in bulk quantities.
9 Physical & Chemical Properties
Characteristic
Boiling point (°C):
Specific gravity:
Melting point:
Estimated vapor density:
Estimated vapor pressure:
Molecular weight:
Water Solubility (%v/v):
Photoreactive VOCs:
pH:
Evaporation rate (Water =1):
Estimated % volatility:
Odor threshold:
Odor:
Appearance:
Description
Approximately 100°C @ 1 Torr
Approximately 1.0 @ 4°C
No information available
>1.00
Approximately 23.3 mm Hg at 30°C
34
Soluble
None
No information available
No information available
Greater than 99%
None
Slight
Clear colorless liquid
10 Stability & Reactivity
STABILITY: Light sensitive.
HAZARDOUS POLYMERIZATION: Spontaneous polymerization will not occur. Hazardous polymerization does not
occur.
INCOMPATIBILITIES: Powdered metals, powdered metal salts.
DECOMPOSITION PRODUCTS: Oxygen.
GE Analytical Instruments, Inc. 2012H
Page 3 of 6
DIN 90080 Rev. A
MSDS, 3% HYDROGEN PEROXIDE
Material Safety Data Sheet
11 Toxicological Information
Component Information
Component
LD50 Oral
Hydrogen peroxide
801 mg/kg ( Rat )
Carcinogenicity
Component
ACGIH
Hydrogen peroxide
A3
IARC
Not listed
LD50 Dermal
2000 mg/kg ( Rabbit )
4060 mg/kg ( Rat )
NTP
Not listed
OSHA
Not listed
LC50 Inhalation
2 mg/L ( Rat ) 4 h
Mexico
Not listed
ACGIH: (American Conference of Governmental Industrial Hygienists)
A1 - Known Human Carcinogen
A2 - Suspected Human Carcinogen
A3 - Animal Carcinogen
ACGIH: (American Conference of Governmental Industrial Hygienists)
12 Ecological Information
Ecotoxicity
.
Component
Freshwater Algae
Hydrogen peroxide EC50 2.5 mg/L/72h
Freshwater Fish
Not listed
Microtox
Not listed
Water Flea
EC50 7.7 mg/L/24h
Persistence and Degradability No information available
Bioaccumulation/ Accumulation No information available
Mobility No information available
Component
Water
log Pow
-1.87
13 Disposal Considerations
If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is :
Not applicable.
Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise
different from federal regulations. Consult state and local regulations regarding the proper disposal of this material.
14 Transport Information
DOT: Not Regulated
IATA: Not regulated
GE Analytical Instruments, Inc. 2012H
Page 4 of 6
DIN 90080 Rev. A
MSDS, 3% HYDROGEN PEROXIDE
Material Safety Data Sheet
15 Regulatory Information
TSCA: All components of this product are listed in the TSCA inventory.
U.S. Federal Regulations
TSCA 12(b) - Not applicable
SARA 313 - Not applicable
SARA 311/312 Hazardous Categorization
Acute Health Hazard - No
Chronic Health Hazard - No
Fire Hazard - No
Sudden Release of Pressure Hazard - No
Reactive Hazard - No
Clean Water Act - Not applicable
Clean Air Act - Not applicable
OSHA
Component
Hydrogen peroxide
Specifically Regulated Chemicals
-
Highly Hazardous Chemicals
TQ: 7500 lb
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the
Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Component
Hazardous Substances RQs
CERCLA EHS RQs
Hydrogen peroxide
1000 lb
California Proposition 65
This product does not contain any Proposition 65 chemicals.
State Right-to-Know
Component
Massachusetts
Hydrogen peroxide
X
New Jersey
X
Pennsylvania
X
Illinois
-
Rhode Island
X
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant: N
DOT Severe Marine Pollutant: N
U.S. Department of Homeland Security
This product contains the following DHS chemicals:
Component
DHS Chemical Facility Anti-Terrorism Standard
Hydrogen peroxide
2000 lb STQ (concentration of at least 30%)
Other International Regulations
Mexico – Grade: No information available
Canada - This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS Hazard Class - Non-controlled
GE Analytical Instruments, Inc. 2012H
Page 5 of 6
DIN 90080 Rev. A
MSDS, 3% HYDROGEN PEROXIDE
Material Safety Data Sheet
16 Other Information
NFPA/HMIS
CODE TRANSLATION
Health
1
Can cause irritation if not reated
Fire
1
Ignites after considerable preheating.
Reactivity
0
Normally stable. Not reactive with water.
Special Reactivity
NONE
No special Hazard
(1) Protective Equipment A
Safety Glasses
(1) refer to section 8 of MSDS for additional protective equipment recommendations.
_______________________________________________________________________________________
CHANGE LOG
EFFECTIVE DATE
19-JAN-2012
GE Analytical Instruments, Inc. 2012H
REVISIONS TO SECTION
New
Page 6 of 6
SUPERSEDES
New
DIN 90080 Rev. A
MSDS, 3% HYDROGEN PEROXIDE