The Avenue For Teachers Burning Fossil Fuels (Key Stage 4) Teacher guidance and student stimulus sheets These activities look at what happens when fossil fuels burn. There are two parts to the activity: • demonstration of burning fuels • paper-based student activity to look at the breaking and formation of bonds during combustion. This activity relates to the former function of the Avenue as a coke-producing site. Curriculum The activities can be used to address areas of the 14-16 science and chemistry specifications that look at fossil fuels, reactions, equations and energy changes and energy level diagrams. The topic lends itself to a further debate on the use of energy for heating in houses and other buildings. How is the use of fossil fuels affecting the atmosphere? How can the burning of fossil fuels be reduced by, for example, the use of insulation or alternative energy sources. Risk assessment Before carrying out any activity, teachers must produce a suitable risk assessment. This should be compatible with any local rules or restrictions. Sufficient precautions must be in place when demonstrating the burning of fossil fuels and dealing with flammable materials. Some points to consider include: Fuels may be burned on a metal lid and disposed of in a metal bucket full of water after use to ensure they have extinguished. Take care with cobalt chloride paper. Keep handling to a minimum and wash hands after use. Students and the demonstrator must wear eye protection. The Avenue For Teachers Demonstration of burning fossil fuels Note that a risk assessment and suitable precautions must be taken when handling flammable materials and apparatus that may become hot when performing this demonstration. Ensure the room is well ventilated. to vacuum pump Resources Set up the apparatus as shown in the diagram below on a heat-resistant mat. heat-resistant glass funnel limewater anhydrous cobalt chloride paper burning fuel Students observe any deposits on the funnel, changes in the cobalt chloride paper (water) and in the limewater (carbon dioxide). Use fresh limewater and dry cobalt chloride paper with each different fuel. Do not burn materials that will give off toxic fumes, such as plastics. Suggested fuels include: • Coal (1cm3 is sufficient) • Wood (wooden spill) • Candle (wax) • Methane (Bunsen burner) – try with blue flame and also with white, sooty flame to demonstrate incomplete combustion in reduced oxygen. Discuss the observations to come to the conclusions that products of burning hydrocarbons are water and carbon dioxide. Incomplete combustion also results in particulates (sooty carbon). The Avenue For Teachers Combustion reactions These paper-based activities allow students to investigate the reactions taking place when hydrocarbons burn in oxygen. In its simplest form, students rearrange the molecules according to the word equation. This can be extended by having students physically break and make bonds using scissors and glue or sticky tape. This approach can also be used to illustrate the conservation of atoms and balanced equations. The activity can lead into a discussion of energy changes and energy diagrams. Resources • Student worksheet • Molecules sheet (additional sheets if balancing equations) • Energy change stimulus sheet • Scissors • Sellotape Combustion reactions When fuels burn, they combine with oxygen from the air. These reactions gives out heat. They are called exothermic reactions. Task Use the printed molecules to show what is happening during the combustion reactions listed below. For each reaction, use the printed molecules to show the reactants and the products that are formed. Answer these questions for each reaction. 1. What are the reactants and products? 2. How could you test the products to identify them? • Hydrogen gas burning in oxygen 3. Write a word equation for the reaction. 4. Write a formula equation for each reaction. • Methane gas burning in oxygen • Propane gas burning in oxygen • Coal burning in a rich supply of oxygen Think about the reaction of coal burning in air. 5. Suggest what would happen if coal was burned with a limited supply of oxygen. What problems could this cause? 6. What other problems are caused by the burning of fossil fuels? coal oxygen water methane hydrogen carbon dioxide propane The Avenue For Teachers Exothermic reaction energy changes An exothermic reaction can be represented with an energy level diagram. This is one for burning methane in oxygen. The energy of the products is lower than the energy of the reactants. The energy cannot simply disappear. It is given out as heat. Activation energy starts the reaction. energy It is the energy taken in which is needed to break the bonds between the oxygen, carbon and hydrogen atoms. Change in energy At the end of the reaction, this is the difference in energy between the reactants and the products. Use this information to calculate the amount of energy released when hydrogen is burned in oxygen. Energy taken in (kJ/mol) Energy given out (kJ/mol) 1,370 1,856 This is sometimes called 'delta H' - ΔH Energy of reactants Energy of products Energy is given out as the bonds form to make the products. reaction progress Draw and label an energy level diagram showing the energy changes during an endothermic reaction. This is one that takes in more energy than it gives out.
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