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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2017
Revision: 05.01.2017
Version number 3
1 Identification of the substance/mixture and of the company/undertaking
· Product identifier
· Trade name: Arsenic standard solution 1000 mg/L for AAS
· Article number: A2442
· Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture
Chemical analytics
Biochemistry
Laboratory chemical
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
AppliChem GmbH
Ottoweg 4
D-64291 Darmstadt
Tel.: +49 (0)6151 93570
Fax.: +49 (0)6151 935711
[email protected]
· Further information obtainable from: Dept. Compliance
· Emergency telephone number: +49(0)6151 93570 (Inside normal buisness hours)
2 Hazards identification
· Classification of the substance or mixture
Met. Corr.1
H290 May be corrosive to metals.
Skin Irrit. 2
H315 Causes skin irritation.
Eye Irrit. 2A
H319 Causes serious eye irritation.
Carc. 1A
H350 May cause cancer.
Aquatic Acute 3
H402 Harmful to aquatic life.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· Label elements
· GHS label elements
The product is classified and labelled according to the Globally Harmonised System (GHS).
· Hazard pictograms
GHS05
GHS08
· Signal word Danger
· Hazard-determining components of labelling:
nitric acid
diarsenic trioxide
· Hazard statements
H290 May be corrosive to metals.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H350 May cause cancer.
H412 Harmful to aquatic life with long lasting effects.
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2017
Revision: 05.01.2017
Version number 3
Trade name: Arsenic standard solution 1000 mg/L for AAS
(Contd. of page 1)
· Precautionary statements
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P273
Avoid release to the environment.
P201
Obtain special instructions before use.
P309+P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
*
3 Composition/information on ingredients
· Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
7697-37-2 nitric acid
Ox. Liq. 2, H272; Met. Corr.1, H290; Skin Corr. 1A, H314
1327-53-3 diarsenic trioxide
Acute Tox. 2, H300; Carc. 1A, H350; Skin Corr. 1B, H314; Aquatic Acute 1, H400;
Aquatic Chronic 1, H410
· SVHC
1327-53-3 diarsenic trioxide
· Additional information: For the wording of the listed hazard phrases refer to section 16.
>2,5-≤ 3%
>0,1-≤ 1%
0,25%
4 First aid measures
· Description of first aid measures
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Rinse out mouth.
make victim drink water (maximum of 2 drinking glasses)
Seek medical treatment.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture Nitrogen oxides (NOx)
· Advice for firefighters
· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2017
Revision: 05.01.2017
Version number 3
Trade name: Arsenic standard solution 1000 mg/L for AAS
(Contd. of page 2)
· Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Contain escaping vapours with water.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures Avoid substance contact.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Clean up affected area.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep container tightly sealed.
Open receptacle only under localised extractor facilities.
Store receptacle in a well ventilated area.
Store under lock and key and with access restricted to technical experts or their assistants only.
· Recommended storage temperature: 15-25 °C
· Storage class: 6.1 D
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
1327-53-3 diarsenic trioxide
TLV Long-term value: 0,01 mg/m³
as As
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2017
Revision: 05.01.2017
Version number 3
Trade name: Arsenic standard solution 1000 mg/L for AAS
(Contd. of page 3)
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Filter ABEK
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· For the permanent contact gloves made of the following materials are suitable:
Nitrile rubber, NBR
Recommended thickness of the material: ≥ 0,11 mm
Value for the permeation: Level ≥ 480 min
· As protection from splashes gloves made of the following materials are suitable:
Recommended thickness of the material: ≥ 0,11 mm
Value for the permeation: Level ≥ 480 min
· Eye protection:
Tightly sealed goggles
· Body protection:
Use protective suit.
Protective clothing should be selected specifically for the working place, depending on concentration and
quantity of the hazourdous substances handled.
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Fluid
Form:
Colourless
Colour:
Characteristic
· Odour:
Not determined.
· Odour threshold:
· pH-value:
Not determined.
· Change in condition
Undetermined.
Melting point/freezing point:
Initial boiling point and boiling range: Undetermined.
· Flash point:
Not applicable.
· Ignition temperature:
Decomposition temperature:
Not determined.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2017
Revision: 05.01.2017
Version number 3
Trade name: Arsenic standard solution 1000 mg/L for AAS
(Contd. of page 4)
· Auto-ignition temperature:
Product is not selfigniting.
· Explosive properties:
Product does not present an explosion hazard.
· Explosion limits:
Lower:
Upper:
Not determined.
Not determined.
· Vapour pressure:
Not determined.
· Density:
· Relative density
· Vapour density
· Evaporation rate
Not determined.
Not determined.
Not determined.
Not determined.
· Solubility in / Miscibility with
water:
Fully miscible.
· Partition coefficient: n-octanol/water:
Not determined.
· Viscosity:
Dynamic:
Kinematic:
Not determined.
Not determined.
· Solvent content:
Organic solvents:
0,0 %
Solids content:
· Other information
0,1 %
No further relevant information available.
10 Stability and reactivity
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity
· LD/LC50 values relevant for classification:
· Components
Type
Value
Species
1327-53-3 diarsenic trioxide
Oral LD50 15,1 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation Irritant to skin and mucous membranes.
· Serious eye damage/irritation Irritant effect.
· After inhalation: Irritant to skin and mucous membranes.
· Respiratory or skin sensitisation No sensitising effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2017
Revision: 05.01.2017
Version number 3
Trade name: Arsenic standard solution 1000 mg/L for AAS
(Contd. of page 5)
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Carc. 1A
12 Ecological information
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Danger to drinking water if even extremely small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Chemicals must be disposed of in compliance with the respective national regulations.
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
Packagings that may not be cleansed are to be disposed of in the same manner as the product.
14 Transport information
· UN-Number
· ADR, IMDG, IATA
UN1760
· UN proper shipping name
· ADR, IMDG, IATA
CORROSIVE LIQUID, N.O.S. (NITRIC ACID)
· Transport hazard class(es)
· ADR
· Class
· Label
8 (C9) Corrosive substances.
8
· IMDG, IATA
· Class
· Label
8 Corrosive substances.
8
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2017
Revision: 05.01.2017
Version number 3
Trade name: Arsenic standard solution 1000 mg/L for AAS
(Contd. of page 6)
· Packing group
· ADR, IMDG, IATA
III
· Environmental hazards:
· Marine pollutant:
No
· Special precautions for user
· Danger code (Kemler):
· EMS Number:
· Segregation groups
· Stowage Category
· Stowage Code
Warning: Corrosive substances.
80
F-A,S-B
Acids
A
SW2 Clear of living quarters.
· Transport in bulk according to Annex II of Marpol
Not applicable.
and the IBC Code
· Transport/Additional information:
· ADR
· Limited quantities (LQ)
· Excepted quantities (EQ)
· Transport category
· Tunnel restriction code
· IMDG
· Limited quantities (LQ)
· Excepted quantities (EQ)
· UN "Model Regulation":
5L
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
3
E
5L
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN 1760 CORROSIVE LIQUID, N.O.S. (NITRIC
ACID), 8, III
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· GHS label elements
The product is classified and labelled according to the Globally Harmonised System (GHS).
· Hazard pictograms
GHS05
GHS08
· Signal word Danger
· Hazard-determining components of labelling:
nitric acid
diarsenic trioxide
· Hazard statements
H290 May be corrosive to metals.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H350 May cause cancer.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P273
Avoid release to the environment.
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 05.01.2017
Revision: 05.01.2017
Version number 3
Trade name: Arsenic standard solution 1000 mg/L for AAS
(Contd. of page 7)
P201
Obtain special instructions before use.
P309+P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I diarsenic trioxide
· National regulations:
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57
1327-53-3 diarsenic trioxide
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
0,25%
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H272 May intensify fire; oxidiser.
H290 May be corrosive to metals.
H300 Fatal if swallowed.
H314 Causes severe skin burns and eye damage.
H350 May cause cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
· Department issuing SDS: Dept. Compliance
· Contact: Mr. Th. Stöckle
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Ox. Liq. 2: Oxidizing liquids – Category 2
Met. Corr.1: Corrosive to metals – Category 1
Acute Tox. 2: Acute toxicity – Category 2
Skin Corr. 1A: Skin corrosion/irritation – Category 1A
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A
Carc. 1A: Carcinogenicity – Category 1A
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Acute 3: Hazardous to the aquatic environment - acute aquatic hazard – Category 3
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered.
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