AP Chemistry Test (Chapter 3) (Autumn) Multiple Choice and FIB (45%) 1) Which of these lab errors would cause a low % yield O2 ? ∆ 2 KClO3 (s) 2 KCl (s) + 3 O2 (g) I) II) III) IV) A) C) E) 2) Using a crucible that has soot stuck to it Using a low mass of KClO3 Heating the crucible an insufficient length of time Spilling some of the KCl I and III II and IV None of these B) D) III and IV III What coefficients balance this reaction? Fe3P4 + K2SO4 Fe(SO4)2 + K3P A) C) E) 1, 1, 3, 4 3, 2, 3, 2 None of these B) D) 3) What is the name of NH4BrO4 ● 4 H2O? 4) Which one is an empirical formula? A) C) E) C13H26 C12H21O6 C10H20O3 1, 6, 3, 4 2, 3, 3, 2 B) D) P4O10 N2O6 Please use the following information to answer questions 5-8. 5.48 mol A4 reacts with 4.22 mol B7 in this reaction in a sealed flask: 35 A4 + 12 B7 28 A5B3 5) Which one is the limiting reagent? 6) How many mol A5B3 are produced? 7) How many mol of the excess reagent are consumed during the reaction? 8) How many total mol are in the flask at the end of the reaction? 9) Please consider these two samples. Sample #1 is a mixture of iron and sulfur in a mole ratio of 1:1. Sample #2 is FeS. Please choose all true statements about these samples. I) II) III) IV) V) A) C) E) Both samples are chemically combined. Sample #1 would show magnetic properties and sample #2 would not. Sample #1 would smell differently than sample #2. Both samples would have similar physical and chemical properties. Sample #1 is composed of atoms while sample #2 is composed of molecules. I, II, III, IV, V II, III, V None of these B) D) II, III, IV, V II, III 10) 29.0 g NaCl is dissolved in 60.0 g H2O. What is the % NaCl in the solution by mass? 11) What is the formula for chromium (III) sulfite heptahydrate? Please consider this container to answer questions 12-14. Hydrogen reacts with oxygen to form H2O. O O H O H H H H O H H O H H H O H H H O H O O O O O H Reactants 12) How many molecules of limiting reagent are consumed in this reaction? 13) How many molecules of water are produced? 14) How many molecules are in the flask at the end of the reaction? 15) Which one is the smallest quantity? A) C) E) 1 X 1012 Tm 1 X 1015 fm 1 X 10 –9 nm B) D) H H O H H O O H 1 X 10 –6 Mm 1 X 1012 pm O Problems (60%) 1) Please show all your work for any credit. The following lab results were obtained when copper was strongly heated in the presence of excess oxygen. What is the empirical formula of the metallic oxide? Assume the copper did not react with atmospheric N2. Mass of empty crucible & cover Mass of crucible, cover & copper (before combustion) Mass of crucible, cover & copper (after combustion) 50.0000 g 52.0000 g 52.4197 g 2) A 10.000-g sample of an organic compound composed entirely of carbon, hydrogen & oxygen was burned to produce 12.5647 g CO2 and 4.2872 g H2O. Assume complete combustion The molar mass of the compound is 735.56 g. What is the molecular formula of this hydrocarbon? 3) A phosphoric acid solution is 2.91% by mass. The density of the phosphoric acid solution is 1.11 g/ml. How many acetate ions will react with 70.82 mL of the phosphoric acid solution? 3 Fe (C2H3O2)5 + 5 H3PO4 15 HC2H3O2 + Fe3(PO4)5 4) A reaction mixture contains 7.51 L C6H14 and 42.1 L O2. What mass of excess reagent remains after the reaction has gone to completion? 2 C6H14 + 19 O2 12 CO2 + 14 H2O 5) A student uses 26.4 g of 11.0% HCl solution to neutralize 12.7 g Al2(CO3)3. The student then collects and dries 3.09 g AlCl3. What is the % yield? 6 HCl + Al2(CO3)3 2 AlCl3 + 3 H2O + 3 CO2 6) An ore (rock) contains 28.9 % emerald, Be3Al2(SiO3)6 by mass. What mass of rock would produce 4.11 X 1024 atoms of Si? AP Chemistry Test (Chapter 3) (Winter) Multiple Choice and FIB (45%) 1) Which of these lab errors would cause a low % yield O2 ? ∆ 2 KClO3 (s) 2 KCl (s) + 3 O2 (g) I) II) III) IV) A) C) E) 2) Using a crucible that has soot stuck to it Using a low mass of KClO3 Heating the crucible an insufficient length of time Spilling some of the KCl II and IV I and III None of these B) D) III III and IV What coefficients balance this reaction? Fe3P4 + K2SO4 Fe(SO4)2 + K3P A) C) E) 1, 1, 3, 4 3, 2, 3, 2 None of these B) D) 3) What is the name of NH4BrO ● 6 H2O? 4) Which one is an empirical formula? A) C) E) C13H26 C12H21O6 C10H20O3 1, 6, 3, 4 2, 3, 3, 2 B) D) P4O10 N2O6 Please use the following information to answer questions 5-8. 8.21 mol A4 reacts with 7.95 mol B7 in this reaction in a sealed flask: 35 A4 + 12 B7 28 A5B3 5) Which one is the limiting reagent? 6) How many mol A5B3 are produced? 7) How many mol of the excess reagent are consumed during the reaction? 8) How many total mol are in the flask at the end of the reaction? 9) Please consider these two samples. Sample #1 is a mixture of iron and sulfur in a mole ratio of 1:1. Sample #2 is FeS. Please choose all true statements about these samples. I) II) III) IV) V) A) C) E) Both samples are chemically combined. Sample #1 would show magnetic properties and sample #2 would not. Sample #1 would smell differently than sample #2. Both samples would have similar physical and chemical properties. Sample #1 is composed of atoms while sample #2 is composed of molecules. II, III, IV, V II, III None of these B) D) I, II, III, IV, V II, III, V 10) 19.0 g NaCl is dissolved in 70.0 g H2O. What is the % NaCl in the solution by mass? 11) What is the formula for chromium (II) phosphite tetrahydrate? Please consider this container to answer questions 12-14. Hydrogen reacts with oxygen to form H2O. O O H O H H H H O O H O H O O O O H How many molecules of limiting reagent are consumed in this reaction? 13) How many molecules of water are produced? 14) How many molecules are in the flask at the end of the reaction? 15) Which one is the smallest quantity? B) D) H H 12) 1 X 1012 Tm 1 X 10 –9 nm 1 X 10 15 fm O H Reactants A) C) E) O H H H H H H H H H O H H O O H 1 X 10 –6 Mm 1 X 1012 pm O H Problems (60%) 1) Please show all your work for any credit. The following lab results were obtained when copper was strongly heated in the presence of excess oxygen. What is the empirical formula of the metallic oxide? Assume the copper did not react with atmospheric N2. Mass of empty crucible & cover Mass of crucible, cover & copper (before combustion) Mass of crucible, cover & copper (after combustion) 50.0000 g 52.0000 g 52.4197 g 2) A 10.000-g sample of an organic compound composed entirely of carbon, hydrogen & oxygen was burned to produce 12.5647 g CO2 and 4.2872 g H2O. Assume complete combustion The molar mass of the compound is 735.56 g. What is the molecular formula of this hydrocarbon? 3) A phosphoric acid solution is 2.91% by mass. The density of the phosphoric acid solution is 1.11 g/ml. How many acetate ions will react with 70.82 mL of the phosphoric acid solution? 3 Fe (C2H3O2)5 + 5 H3PO4 15 HC2H3O2 + Fe3(PO4)5 4) A reaction mixture contains 7.51 L C6H14 and 42.1 L O2. What mass of excess reagent remains after the reaction has gone to completion? 2 C6H14 + 19 O2 12 CO2 + 14 H2O 5) A student uses 26.4 g of 11.0% HCl solution to neutralize 12.7 g Al 2(CO3)3. The student then collects and dries 3.09 g AlCl3. What is the % yield? 6 HCl + Al2(CO3)3 2 AlCl3 + 3 H2O + 3 CO2 6) An ore (rock) contains 28.9 % emerald, Be3Al2(SiO3)6 by mass. What mass of rock would produce 4.11 X 1024 atoms of Si? AP Chemistry Test (Chapter 3) Name______________________________ Form_____________________ Multiple Choice and FIB (45%) 1) _____ 11) _____ 2) _____ 12) _____ 3) _____ 13) _____ 4) _____ 14) _____ 5) _____ 15) _____ 6) _____ 7) _____ 8) _____ 9) _____ 10) _____ Problems (60%) Please show all your work for any credit. 1) Please use only the front side of each piece of paper. 2) Please number your problems clearly and consecutively. 3) Please staple your problems to the back of this page in numerical order. 4) Please write on the paper in the conventional manner. 5) Please do not make a separate list of answers. Record your answer at the end of the work supporting your answer. 6) Please circle/box your answer at the end of the problem.
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