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Printed: November 23, 2011 Author Richard Parsons Contributor Dolly Kim i www.ck12.org Contents 1 The Solution Process Worksheets 1.1 1 Measuring Concentration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . www.ck12.org ii 1 Chapter 1 The Solution Process Worksheets 1.1 Measuring Concentration Concentration by Percent Mass Worksheet CK-12 Foundation Chemistry Name______________________ Date_________ The definition of percent mass concentration is the ratio of the mass of solute divided by the total mass of the solution and multiplied by 100 to convert to a percentage. percent by mass = mass o f solute × 100 mass o f solution Example: What is the percent concentration by mass of a solution formed by dissolving 100. grams of ethanol, C2 H5 OH, in 100. grams of water? Solution: percent by mass = mass o f solute mass o f solution × 100 = 100. g 200. g × 100 = 50.0% Example: If the density of a 10.0% by mass KNO3 solution in water is 1.19 g/mL, how many grams of KNO3 are present in 100. mL of the solution? Solution: We can multiply the volume times the density to the mass of the 100. mL of solution and then take 10.0% of the mass of the solution to get the mass of the potassium nitrate. grams o f solution = (100. mL)(1.19 g/mL) = 119 grams grams o f KNO3 = (0.10)(119 grams) = 11.9 grams Exercises 1. If 30.0 grams of AgNO3 are dissolved in 275 grams of water, what is the concentration of the silver nitrate by mass percent? 2. How many grams of MgF2 are present in 100.0 g of a 20.0% MgF2 in water solution? 3. How many grams of water are present in the solution in question #2? 4. The density of a 30.0% by mass solution of NaOH in water is 1.33 g/mL. How many grams of NaOH are required to prepare 500. mL of this solution? 1 www.ck12.org 5. The density of pure water is 1.00 g/mL. What is the concentration gy percent mass of a solution prepared by dissolving 85.0 grams of NaOH in 750. mL of water? 6. A solution is prepared by dissolving 66.0 grams of acetone, C3 H6 O, in 146.0 grams of water. The density of the solution is 0.926 g/mL. What is the percent concentration of acetone by mass? 7. A 35.4% solution of H3 PO4 in water has a density of 1.20 g/mL. How many grams of phosphoric acid are present in 300. mL of this solution? Mole Fraction and Molality Worksheet CK-12 Foundation Chemistry Name______________________ Date_________ Mole Fraction The definition of mole fraction is the ratio of the moles of solute divided by the total moles of the solution. mole f raction = moles o f solute moles o f solution Example: What is the mole fraction of ethanol in a solution prepared by dissolving 100. g of ethanol, C2 H5 OH, in 100. g of water? Solution: 100. g = 2.17 moles 46.0 g/mol 100. g moles water = = 5.56 moles 18.0 g/mol 2.17 mols = 0.281 mole f raction o f ethanol = 7.73 mols moles ethanol = Molality The definition of molality is the ratio of the moles of solute divided by the kilograms of solvent. molality = moles o f solute kilograms o f solvent Example: What is the molality of a solution prepared by dissolving 100. g of ethanol, C2 H5 OH, in 100. g of water? 100. g = 2.17 moles 46.0 g/mol 2.17 mols = 21.7 m molality o f ethanol = 0.100 kg moles ethanol = Example: A 35.4% solution of H3 PO4 in water has a density of 1.20 g/mL. What is the mole fraction of H3 PO4 in this solution and what is the molality? Solution: We can choose a sample volume of this solution and get the mass of it by multiplying the volume times the density. Suppose we choose a 1.00 L sample. www.ck12.org 2 mass of solution = (1000. mL)(1.20 g/mL) = 1200. grams mass of H3 PO4 in the solution = (0.354)(1200. grams) = 425 grams mass of H2 O = 1200. grams − 425 grams = 775 grams 425 g moles H3 PO4 = = 4.34 moles 98.0 g/mol 775 g moles H2 O = = 43.1 moles 18.0 g/mol 4.34 mol mole fraction of H3 PO4 = = 0.0916 47.4 mol 4.34 mol molality = = 5.60 m 0.775 kg Exercises 1. What is the mole fraction of MgF2 in a solution that has 20.0 g of MgF2 dissolved in 80.0 grams of water? 2. What is the molality of the solution in question 1? 3. The density of a 30.0% by mass solution of NaOH in water is 1.33 g/mL. What is the mole fraction of NaOH in this solution? 4. What is the molality of the solution in problem 3? 5. What is the molality of a solution prepared by dissolving 4.00 g of NaCl in 100. g of water? 6. How many grams of beryllium chloride would you need to add to 125 g of water to make a 0.500 m solution? 7. What would be the mole fraction of BeCl2 in the solution in problem 6? 8. A solution is prepared by dissolving 66.0 g of acetone, C3 H6 O, in 146.0 g of water. The density of the solution is 0.926 g/mL. What is the molality of this solution? 9. What is the mole fraction of acetone in the solution in problem 8? Molarity Worksheet CK-12 Foundation Chemistry Name______________________ Date_________ The definition of molarity is the ratio of the mols of solute divided by the volume of the solution. molarity = moles o f solute liters o f solution Example: What is the molarity of a solution prepared by dissolving 60.0 grams of NaOH in sufficient water to produce 2.00 liters of solution? Solution: 60.0 g = 1.50 moles 40.0 g/mol 1.50 mol molarity = = 0.750 M 2.00 L moles NaOH = Example: What volume of 0.750 M NaOH solution will contain 10.0 gram of NaOH? 3 www.ck12.org 10.0 g = 0.250 moles 40.0 g/mol mol 0.250 mol volume = = = 0.333 L M 0.750 mol/L moles NaOH = Exercises 1. 2. 3. 4. 5. 6. 7. 8. What is the molarity of a solution in which 4.50 g of NaNO3 is dissolved in 265 mL of solution? How many grams of ammonia, NH3 are present in 5.0 L of 0.100 M solution? How many milliliters of 0.200 M NaOH solution is necessary to contain 6.00 grams of NaOH? How many liters of 0.500 M CaF2 solution is required to contain 78.0 g of CaF2 ? What mass of ammonium phosphate is needed to make 100. mL of 0.500 M (NH4 )3 PO4 solution? What is the molarity of a solution prepared by dissolving 198 g of BaBr2 in 2.00 liters of solution? How many grams of glycerine, C3 H8 O3 , are needed to make 100. mL of 2.60 M solution? A test tube contains 10.0 mL of 3.00 M CaCO3 solution. How many grams of calcium carbonate are in the tube? www.ck12.org 4
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