An Innovative Actuation Method based on the Osmotic Principle Fabio Mattioli, Lucia Beccai and Barbara Mazzolai IIT – Istituto Italiano di Tecnologia Center for Micro-BioRobotics IIT@SSSA, Viale Rinaldo Piaggio, 34 - 56025 - Pontedera (PI), Italy email: [email protected] http://mbr.iit.it Motivation, Problem Statement and Related Works Motivation We propose an innovative, bio-inspired actuator based on forward osmosis principle to obtain a pressure suitable for actuation. The final aim is to conceive an actuation system characterized by energy efficiency, simple and robust structure, and easy to miniaturize in order to work in the milli-micro domain. Osmosis represents one of the fundamental natural processes, e.g. cellular chemical exchanges, and it is at the basis of some highperformances natural movements (e.g. Venus flytrap leaves closure, cnidocysts exocytosis in Cnidarian, etc.). Problem statement Osmosis is the spontaneous flow of a solvent across a selectively permeable membrane, from a region of higher water chemical potential (i.e. lower solute concentration) to a region of lower water chemical potential (i.e. higher solute concentration). Forward Osmosis (FO) is a powerless process, based on the chemical potential non-equilibrium of two chemicals separated by an osmotic membrane. The core idea is to induce FO to obtain actuation; to this aim, the major technological challenge is to vary the solute concentrations between two solutions. The performances are directly correlated with the solute used (because of its solubility in the selected solvent) and the dissociation coefficient. In addition, the efficiency of the osmotic actuation system strongly depends on the features of the osmotic membrane, which must be: a) a high mechanical strength, in order to resist to the high pressure obtained and limit its deflection; b) a high water permeability coefficient, which is directly correlated to the actuation velocity; c) a very low solute permeability, to avoid the loss of actuation reversibility. Related work Osmosis has been applied in many fields, from desalination methods (e.g. reverse osmosis [2]) to power production as renewable source of energy [3]. Interesting works in which osmosis is used for actuation are: i) an osmotic pump for drug delivery, described in [4], in which authors obtain a long time functioning at a requested drug release rate; ii) the chemo-mechanical actuator described in [5], based on protein transporters extracted from plant cell membranes, which can exert a force comparable with conducting polymer actuator (up to 1mN [5]); iii) an electro-osmotic actuator embedded in a robotic plant root inspired artefact [6], used as steering system. Technical Approach The actuator design is based on Organic Electronic Ion Pumps (OEIP) [7], modified to have a higher positive ion transport and faster response (in [7] the researchers obtain the transport of about 200 nmol in 10 minutes). To maintain electro-neutrality, an anionic membrane will be employed. The osmotic membrane will be the FO membrane developed by Hydration Technology Innovations (HTI), in which a polyester mesh is embedded within the polymeric osmotic Figure 1: A simple-shape two chambers osmotic actuator; the chambers are indicated in figure as “1” and “2” layer for mechanical support. The membrane thickness is less than 50 μm. designed experimental setup. Results A preliminary evaluation of the osmotic actuator performances were performed, based on a simple-shape architecture (Fig. 1), in which the lateral area is rigid while the top and down faces are flexible. Chamber 1 will contain a CaCl2-water solution (because its high osmolarity), whereas chamber 2 will include pure water. The performances were calculated at 4 different solution concentration levels. For an evaluation of the scale effect, three actuator diameters have been hypothesized. Table 1 shows the design data. Table 1: Actuator evaluation parameters Parameter Value geometry 1: 1 Diameter and height [mm] geometry 2: 5 geometry 3: 10 Molarity [mol l-1] 0.05, 0.1, 1, 6.5 Temperature [K] 293 5.00 · 10-6 (typical value taken Volumetric membrane water from [8]) permeability constant Av [m3 m-2 s-1 MPa-1] 0.98 (typical value taken from σ [8]) Stroke diameter/3 The results are presented in Table 2 and Fig. 2. The osmotic actuation shows high specific performances, especially for the small dimension geometries. Table 2: Results of performances evaluation Chamber 2 0,05 0,1 mol/l 1 mol/l molar mol/l concentration Osmotic 0,365 0,73 7,3 Pressure [MPa] Actuation 32,2 16,1 1,61 Time [s] Force [N] 0,287 0,573 5,73 6,5 mol/l Figure 2: Comparative analysis with other actuation technologies (adapted from [1]) 47,5 0,24 37,2 Experimental set-up An experimental set-up to study and validate the expected performances was developed. This set-up is characterized by its reduced dimensions (Φ = 26 mm, h = 55 mm), the full sensorization for an online control and monitoring, simple architecture and easiness of assembling. The structure has been designed to resist to up to 30 MPa of internal pressure. Fig. 3 shows some views of the Figure 1: Osmotic actuator experimental set-up Main Experimental Insights The insight of this work is to employ the osmotic pressure, coming from the spontaneous solvent flow derived by the difference in chemical potential, in a well controlled way. Technical advancements are coming from the study of biological examples that adopt osmosis as actuation strategies. Several applicative scenarios can be envisaged by developing the described osmotic actuator, such as, for example, a drug delivery pump for drug controlled release rate in real time, as well as an osmotic actuator system embedded in a microrobotic system inspired to plant apex root for elongation and steering movements during soil exploration tasks. More in general, this technology could be potentially applied in the design and construction of optimal nastic actuation models. References [1] [2] [3] [4] [5] [6] [7] [8] J. L. Pons, Emerging Actuation Technologies: A Micromechatronis Approach, Wiley, 2005. C. Fritzmann, J. Löwenberg, T. Wintgens, and T. Melin, "State-of-the-art of reverse osmosis desalination," Desalination, 216(1-3): 1-76, 2007. S. E. Skilhagen, J. E. Dugstad, and R. J. Aaberg, "Osmotic power - power production based on the osmotic pressure difference between waters with varying salt gradients," Desalination, 220(1-3): 476-482, 2008. Y.-C. Su and L. Lin, A water-powered micro drug delivery system. Vol. 13. New York, NY, ETATS-UNIS: Institute of Electrical and Electronics Engineers, 2004, 8. V. B. Sundaresan and D. J. Leo, "Modeling and characterization of a chemomechanical actuator using protein transporter," Sensors and Actuators B: Chemical, 131(2): 384-393, 2008. B. Mazzolai, A. Mondini, et al., "A Miniaturized Mechatronic System Inspired by Plant Roots for Soil Exploration," Mechatronics, IEEE/ASME Transactions on, PP(99): 1-12, 2010. J. Isaksson, P. Kjall, et al., "Electronic control of Ca2+ signalling in neuronal cells using an organic electronic ion pump," Nat Mater, 6(9): 673-679, 2007. L. K. Wang, Y.-T. Hung, and N. K. Shammas, Handbook of Environmental Engineering: Humana Press, 2009.
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