Issue 002 Section 3 Section Index CODY NO. 3. 3.1 The Design Task 3.1.1 3.1.2 3.2 DESIGN PHILOSOPHY Principal design considerations Basic combustor concepts Design Procedure 3.2.1 3.2.2 Preliminary considerations Stepwise procedure 3.2.2.1 3.2.2.2 3.2.2.3 Calculation of combustor cross-sectional area Bed maintenance and in-bed heat transfer Feedstreams and control 3.3 Computer Programs 3.4 Minimum Fluidising and Terminal Velocities 3.5 Effects of the Principal Operating Parameters 3.5.1 3.5.2 3.5.3 3.5.4 Fluidising velocity Bed temperature Excess air level Bed depth and splash height 3.5.4.1 3.5.4.2 3.5.4.3 3.5.5 Properties of bed solids 3.5.5.1 3.5.5.2 3.5.6 3.5.7 3.6 Static bed depth Expanded bed depth Splash height Materials Particle size Coal feed particle size Air and fuel distribution Combustion and Unit Efficiences 3.6.1 3.6.2 Combustion efficiency Overall thermal efficiency 3.7 Pattern of Heat Release 3.8 Heat Transfer from the Bed 3.9 Sulphur Retention 3.10 Turndown 3.10.1 3.10.2 3.11 General considerations Choice of method References Issue 002 Section 3 Page 1 of 56 Cony No. 3. 3.1 DESIGN PHILOSOPHY The Design Task 3.1.1 Principal desien considerations The design of a fluidised bed combustor involves satisfying the requirements of a minimum of three processes. They are a combustion process to generate the heat, a heat transfer process to remove the heat as it is released so that the bed is kept at a constant temperature and a fluidisation process to 5g provide a suitable bed of particles so that the other processes can operate steadily. The existence of this third process is the main reason why the design of fluidised bed combustors is fired equipment. different from that of conventionally When sulphur retention is desired the requirements-of the sulphur retention process must also be satisfied. The bed of a fluidised combustor is supported by the air distributor and is fluidised by the combustion air. place where the combustion occurs. Its primary function is to provide the The fuel is fed to the bed at one or more points so that the fluidisation process can disperse it quickly and evenly throughout the bed. In boiler applications the bed is also used for the transfer of heat to cooling surfaces immersed in it. In such applications it is desirable that the heat of combustion is released as far as possible within the bed as the rates of heat transfer from the bed to surfaces contacted by it are up to ten times greater than those to surfaces in the freeboard above the splash zone or from the gases downstream of the combustor. sulphur retention is desired, form of solid calcium sulphate. In addition, when the bed is used to trap the fuel sulphur in the The sulphur is more easily disposed of in this form than through the use of a flue gas desulphurisation stage. The processes of combustion, heat transfer, fluidisation and sulphur retention can interact on each other and values of the design parameters must often be a compromise between conflicting requirements. considerations are briefly as follows. The principal design Issue 002 Section 3 Pape 2 of 56 Copy No.t The mean bed temperature is a compromise. At low temperatures combustion efficiencies may become unacceptably low because of reduced reaction rates and increased elutriation of unburnt carbon. On the other hand, the temperature must never be too high because of the risk of sintering the bed material. The normal range of bed temperatures is 750 - 950C (1380 - 1740°F) but a temperature around 850°C (1560°F) is an optimum for sulphur retention. The bed depth is commonly in the range 0.15 - 1.0 m (6 - 40 in.) static. The depth must be sufficient to allow adequate dispersion of the fuel and sufficient reaction time for the combustion process. However, the shallower the bed the less the power required to provide the air supply. Also the rate of erosion of in-bed tube banks is decreased as the bed depth is reduced. Nevertheless the depth must be sufficient for the bed to cover any in-bed tubing at MCR conditions and values at the upper end of the above range may be necessary if a high degree of sulphur retention is required. For furnace and incineration applications the excess air level is dictated by the bed heat balance and is likely to be upwards of 100% depending on the calorific value of the fuel. For boiler applications the excess air level is commonly in the range 20 - 50%. With coal firing the combustion efficiency drops rapidly as the excess air level falls below about 20% while the flue gas heat losses increase with increasing excess air level. The fluidising velocity must be sufficient to give adequate fluidisation at all operating conditions and there is an economic incentive to increase the fluidising velocity as this will lead to a reduction in the combustor cross-sectional area. On the other hand, the rates of solids elutriation and of erosion of combustor and components both increase markedly with increasing fluidising velocity while the residence times for combustion and sulphur retention decrease. The fluidising velocity is generally in the range 1.0 - 2.5 m/s (3 - 8 ft/s) with values of 2.0 m/s (6.5 ft/s), or less, recommended for obtaining long component life. Issue 002 Section 3 Page 3 of 56 Cony No. The rate of elutriation of solids from the cornbustor is increased with increasing fluidising velocity and bed depth and with decreasing bed particle size and freeboard height. High elutriation rates may increase the proportion of heat release in the freeboard and, of course, increase the duty of the gas clean-up system. An initial bed of solids must be provided at start-up; sand is commonly used. graded silica This start-up bed persists for the combustion of gas, oil and coals that are washed, sized and relatively low in ash content. During the combustion of other solid fuels, and when sulphur retention is used, the initial bed may be replaced by one of ash from the fuel and/or sulphur retention sorbent. The bed particle size range and mean size must be appropriate for the bed material and fluidising velocity and for a given bed material must be maintained constant within close limits so that fluidisation conditions remain unchanged. The necessary bed maintenance measures range from simple solids top-up, which replaces the fines lost by elutriation, to bed cleaning procedures during the combustion of solid fuels for the removal and separation of oversize material and the recycle of specification size solids. In the heat transfer process the major part of the heat of combustion is removed either as sensible heat in the combustion gases or by transfer to in-bed cooling surfaces. In the absence of in-bed cooling the furnace and convection bank heat transfer designs will be similar to those for conventional firing although the gas temperatures will be lower. applications using in-bed cooling there is However for boiler an important interaction between heat transfer and bed conditions because the heat transfer rate is a function of the mean bed particle size as well as the in-bed tubing spacing and the tube wall and bed temperatures. It can be seen from the above that it is necessary to take a number of inter-related variables into account to find suitable values for many of the parameters of a fluidised bed combustor. requirements For some applications, of the three processes of combustion, the various heat transfer and fluidisation may be best met by using combinations of fluidised beds each operating under different conditions. Issue 002 Section 3 Page 4 of 56 op N An examnple of this division would be the use of a burn-up bed to complete the combustion of fine carbonaceous particles elutriated from the main combustion bed. See Section 4.5.2, Issue 002. 3.1.2 Basic combustor concepts Fluidised bed combustor designs can generally be classified into either of two basic concepts termed "deep bed` and "shallow bed" combustor designs. These terms are used to describe a complete design concept as well as an approximate bed depth. Shallow bed combustors generally have static bed depths in the range 0.1 - 0.5 m (4 - 20 in.) and use the above bed feeding method for solid fuels; see Section 4.2.2, Issue 002. Turndown is usually provided by the bed expansion method (see Section 3.10 below) in boiler applications but can be supplemented by on/off operation or the use of compartmented beds for greater flexibility. The scale of operation is relatively low from about 30MW (1 x 108 Btu/h) downwards. Deep bed combustors generally have static bed depths above 0.5 m (20 in.) and use the in-bed feeding method for solid fuels; see Section 4.2.2, Issue 002. Turndown is generally provided by the use of compartmented beds although other methods are possible. This concept is considered suited to the larger and more sophisticated applications greater than 30MW (1 x 108 Btu/h). Historically, deep bed combustors were developed first for the combustion of unwashed coals in power generation applications. Since much of the mineral matter in unwashed coals is present as discrete ash of a size similar to that of the combustible coal it was necessary to crush the coal so that the ash particles formed on combustion were sized correctly to act as the bed solids. At the same time the in-bed feeding method (Section 4.2 and 15.1.2) was developed to handle such crushed coals. Relatively deep beds, 0.5 - 1.0 m (20 - 40 in.) static depth, were used to provide a relatively long in-bed contact time to give the maximum once through combustion efficiency. An empirical mathematical model of the combustion process in both the bed and the freeboard has been developed for deep bed combustors with in-bed feeding; a computer programme of the method is available. See Section 4.3, Issue 002 and reference (3.1). The model is based on data obtained from a 1 m square pilot combustor at CRE. The deep bed concept is intended.primarily for large scale applications and an 18MW (60 x 106 Btu/h) cross type steam boiler has been converted successfully to fltiidised had rnmbustitnn using that concept (3.15). * Issue 002 Section 3 Page 5 of 56 CoPy No. -.- The shallow bed concept has been developed more recently following the discovery that relatively large particles of coal, up to 50mm (4 in.), could be dropped onto the surface of a comparatively shallow bed and could be dispersed sufficiently rapidly throughout the bed to burn with high combustion efficiencies similar to those obtained with the in-bed feeding method. The shallow bed concept uses beds with static depths in the range 0.1 0.5 m (4 - 20 in.) with overbed feeding of solid fuels. See Section 4.4, Issue 002. Turndown is obtained, in furnaces by varying the fluidising velocity at constant excess air level or, in boilers by, using the bed expansion method augmented for high degrees of turndown by on/off operation or the use of compartmented beds. Since the bed pressure drop is reduced in the shallow bed system and the overbed feeding of soid fuels is a simpler method than the in-bed feeding method, the shallow bed concept has been found to be better suited for the simpler and smaller scale applications than the deep bed concept. Currently, the shallow bed concept has been used successfully for several hundred industrial installations in the 1 - 30MW (3 - 100 x 106 Btu/h) range. No mathematical model of the combustion process has been developed for the shallow bed concept with above bed feeding but an empirical correlation for combustion efficiency is available based on extensive industrial scale data (see Section 4.4.3, Issue 002). An empirical model for predicting the output from a boiler when the bed expansion method of turndown is used is also available based on extensive industrial scale experience (3.3). Both the shallow and deep bed combustion concepts are suitable for use with fuels in any physical form. At similar operating conditions similar once through combustion efficiencies are obtained with either concept. For coal firing the once through efficiencies are generally sufficiently high for the smaller scale applications; see Section 3.6 below. The combustion efficiency can be further increased by grit refiring or by the use of a separate carbon burn-up bed; see Section 4.5. Although defined by the static bed depth the distinction between the two concepts is essentially one of solid fuel feeding method and the degree of sophistication. The shallow bed concept offers the following advantages in Issue 002 > * 2 ~~~~~~~~~~~~~~~~C Section 3 Page 6 of 56 on y N o: ' comparison with the deep bed concept: a) Lower power consumption. b) Little or no pretreatment of coal fuels. c) Can be accomodated in relatively low height combustion chambers without excessive elutriation of bed solids. d) Has a similar combustion efficiency but using a simpler solids feeding system. e) Has a reduced rate of erosion of combustor walls and in-bed tube banks. However, the shallow bed concept has the following disadvantages: i) It may be necessary to set a limit on the large stone content of a solid fuel or to use bed cleaning systems and/or sloping plate or sparge pipe air distributors. ii) A higher Ca/S ratio for a specified sorbent and specified sulphur retention may be required. Generally, the shallow bed concept is recommended for the smaller scale or simpler application while the deep bed concept is considered more suited to the larger scale and more sophisticated type of application. In this Section a procedure is outlined by which a complete fluidised bed combustor design may be built up step by step for either design concept. Subsequent Sections give detailed methods for individual design steps. A bed heat balance is calculated first to establish values for the basic operating parameters. For a given fuel flow and bed temperature the bed cross-sectional area is then determined by the fluidising velocity and excess air level while the combustor height is dependent on the bed depth and freeboard height. 3.2 DesignProcedure 3.2.1 Preliminaryconsiderations stages. Process design calculations for a fluidised combustor usually have two The first stage is a preliminary design and costing study to select a Issue 002 Section 3 Page 7 of 56 Cony No::_ design concept. In the second stage the detailed mechanical designs of the components of the selected concept are considered. It should be noted that the information in this Manual relates only to the fluidised bed combustor design although in selecting a suitable design it will be necessary to take into account the performance of associated equipment. is For the purposes of the preliminary design a fluidised bed combustor assumed to comprise, (a) Air plenum, distributor and, for oil-firing, (b) Fluidised bed and freeboard containment (c) Immersed cooling surfaces (walls and tube banks) contacted by the bed. Bed management systems (d) the oil nozzle design The main results of the procedure are a heat and mass balance over the combustor and an estimate of the following principal parameters. (a) The combustor cross-sectional area and the height needed for the expanded bed, splash zone and freeboard. (b) (c) The immersed cooling heat transfer surface area. The sorbent flowrate if sulphur retention is required. (d) The duty of the bed cleaning equipment. (e) The solids elutriation rate for the combustor and the duty of gas clean-up equipment. (f) The general arrangement of the air distributor and, for oil-firing applications, the design of the oil feeding nozzles. The subsequent physical arrangement of the combustor and its integration with any downstream equipment for convective heat transfer or other utilisation of the hot freeboard gases will be similar in principle to that for conventional combustion and is outside the scope of this Manual. The procedure should be used initially to establish the design parameters at MCR conditions and then again to check that the values Issue 002 Section 3 Page 8 of 56 Cony No.l established will allow operation at the desired turndown conditions. For the smaller, or more simple, application the parameter values determined using the procedure will be sufficiently accurate for use as a basis for the detailed mechanical designs of the second stage. For the larger and more complicated applications the resulting values may be used as the first approximation of an iterative process. Further iterations may be needed to give the required accuracy because of the interactions of the fluidisation, combustion, heat transfer and sulphur retention processes on each other. For all applications, however, it is desirable to select a method of turndown and to check that the combustor will operate correctly at the maximum turndown anticipated. This check is particularly important for oil or multi-fuel fired combustors. 3.2.2 StePwise procedure 3.2.2.1 Calculation of combustor cross-sectional area The suggested procedure is shown diagrammatically in Figures 3.1 to 3.3. Further amplification and explanation of the procedure at some of the steps is given below. It is suggested that the procedure should be used first for a design at MCR conditions and then to check that satisfactory operation can be obtained at the conditions of maximum turndown. A number of computational aids to this stepwise procedure are available; see Section 3.3 below. In step 1, at the outset of the design, it is assumed that the following items of preliminary data are available. 1. Combustor heat output, or for incineration applications, the fuel flowrate. 2. Fuel specification; calorific value, chemical analysis, relevant physical properties. Note that the use of a high ash fuel may affect the design of the air distributor system and/or the bed regrading system. Issue 002 Section 3 Paze 9 of 56 Cony No. V 3. The type of application. This item assumes a general idea of how the heat of combustion will be removed together with temperatures and pressures on the coolant side of heat transfer surfaces. If the combustion air is preheated an estimate of the air inlet temperature is needed. If the fuel is oil then 20% of the combustion air should be regarded as requirements. an initial estimate of the oil transport air A gas exit temperature may be needed for the estimation of stack gas heat losses. 4. Ambient conditions for the proposed installation. air and cooling water temperatures. 5. Mean and maximum Mean barometric pressure. Environmental regulations at the proposed site for the emission of sulphur dioxide, grit, nitrogen oxides and any other particular compounds present in, or generated by the combustion of, the fuel. This item will include the desired sulphur retention. 6. The requirements, in terms of allowable contamination and compatibility of operating conditions, of equipment immediately downstream, of the combustor. 7. Desired range and frequency of load variation. 8. Minimum acceptable combustion efficiency. 9. For some applications it may be necessary to specify the required combustor pressure drop. 10. Fuel feeding method. 11. The proposed start-up system. The combustor design may be affected by the type and availability of the start-up fuel as well as by the reactivity of the main fuel. For some applications experimental tests (See section 17) may be advisable to check that the proposed fuel does not introduce any features that might make a fluidised bed unworkable. Possible causes might be agglomeration or sintering of the bed particles; the escape of gross amounts of fuel from the bed unburnt, or the generation of toxic materials during combustion. The efficiency of the additive for sulphur dioxide retention may also require determination experimentally. Issue 002 Section 3 Page 10 of 56 Copy No. 1. Specify application _J_ 2. ' o parameters Assume operating paramelers Yee ei s | 3acombustion Calcuale. No_ 13. Calculate or estimate combustionj efficiency and heat release j 1 in4abed and freeboard 4LEslimate proportion of in-bed heat release 5. Calculate or estimate stoichiometric air. Calculate air and flue gas flows and gas composition retention Yes No aremeters. Calculate sorbent flow 7 Calculate bed heat balance per unit moss of main fuel Aulolhernmol, Yes \ No So. Adjust votue of bed temperalure or excess air or air preheat No 8b.Calcutlae auxiliary luel flow for autothermal conditions djusim ents or balance Bailer 9 Calculate immersed surface heat I transfer load to gire balance J f Furnace Incineralor or YesYes balance iain fue NooesNo 10. Specify heat output and overall thermal efficiency.or calculate heat loss)Calculate main fue flowJ Jr1. Calculate air and flue gas flows, for whole unit 12. Calculate bed cross-sectional area Figure 3.1 Design Procedure Part I: Bed Cross-Sectional Area No Issue 002 Section 3 Page 11 of 56 Copy No!>:. 2. From Part I Calculate Bed Cros-Sectionolt orea I3. Specity turndown method i /4. Estimate static bed depth Calculate exPonded deph 15. Culc late splash heighlht ecI nc mcudna mecn No psizend bed persists iGa gt7_ 7I.Calculate oed,Utn shandlin p.| es P eqapument Fuel c17buCalculale versize ash rate, b d me __r_a'te Solid bC'lute bed make-up rte ach etutri,tion rate I.I and makeup roles uc. e Iclancoing equipmen Ret r- ombto wall type tactry Water cooted P20.Calculate h.t. of.,surfac | area and heal load c; .r~n prolee]ion Assume PitCh 3. Calculate hi. coefl. tube surtface and lenh erosoon Protection ube ~~TrYes < _ ___No 25.Select and design start-up i equipmen Figure 3.2 Design Procedure Part II: Combustor Height and Cooling Issue 002 Section 3 Page 12 of 56 Cony No. From Part H 25. Select and design startup equipment 26. Estimate distributor Ap Design air nozzles Gas e Fue | Oil Sid |29a Design gas distribution grid S27a.pecity feeding method I Estimate No.o1 feed points 29. Design feed syste 30. I Specify oil nozzle type Calculate nozzle density |29~~~~~~~~~~~c' Yes b. Design UNo oil nozzles N Design sorbent teed ~~systte 31. Specify control philosophy and instrumentation Figure 3.3 Design Procedure Part El: Feedstreams, Start-up, Control Issue 002 Section 3 Page 13 of 56 Cony No.. In step 2 it is necessary to select probable values for the bed temperature, fluidising velocity, bed excess air level and the static bed depth. Guidance on the selection of appropriate values is given in later sub-sections below. An estimate of the air inlet temperature (or the air preheat temperature) is also required in step 2. Step 3 and 4. In multi-fuel applications the procedure should be used first for the main fuel and the resulting design parameter values checked for compatability with those for the alternative fuel. A new section of the Design Manual (Section 20) is currently being compiled on Multi-fuel Firing and reference should be made to the design approach outlined there. A complete model of the combustion process is only available for coal firing with in-bed feeding (Steps 3a and 4a). Empirical correlations for the combustion efficiency during coal firing with above bed feeding are available; see Section 4.4.3 Issue 002. For oil and gas firing the overall combustion efficiency is generally greater than 99%. The proportion of freeboard combustion is normally significantly less during oil-only or gas firing than during coal firing. In multi-fuel applications it is desirable to match as far as possible the bed/freeboard heat release ratio for oil firing to that for the combustion of the main fuel. A suitable match can be obtained through appropriate reductions in the oil feeding nozzle density. See Section 5 and also Section 3.7 below. In Step 5 note that in the absence of a complete fuel analysis the minimum information needed to use the procedure is the fuel gross calorific value and an estimate of the stoichiometric air ratio. An estimate of this ratio may be read from Figure 3.4 with sufficient accuracy for initial design purposes. When the fuel is coal and the stoichiometric air ratio is estimated it will also be necessary to assume a value for the combustion efficiency as the correlations used in Step 3 for the latter require a knowledge of the coal oxygen content. Issue 002 Section 3 Page 14 of 56 Cony No Calculation of the sulphur sorbent flow in Step 6 will need values for the sulphur retention required, for the sorbent top size and activity, for the carbon dioxide concentration in the flue gases and for the sulphur content of the fuel. Guidance on estimating suitable values is given in Section 3.9 below. In Step 7 the bed heat balance is calculated. As the bed must always remain in heat balance during steady operation the subsequent steps in the procedure depend on the nature of both the,fuel and the application. For premium fuels and furnaces the excess air leviel required to give a balance is calculated (Step 8a) while for premium fuels and boilers the area of cooling surfaces in contact with the bed that is necessary to provide a balance is calculated (Step 9). For lower grade fuels that are just autothermal it will generally be possible to obtain a balance through adjustments of the excess air or bed temperature values (Step 8a). Non-autothermal fuels can be burnt if additional heat is provided by preheating the air (Step 8a) or by the combustion of an auxiliary premium fuel (Step 8b). In the procedure of Figure 3.1 the heat balance is calculated on the basis of the unit mass of main fuel/unit time. This method has the advantage that any changes needed in the operating parameters to give a heat balance can be finalised before the need to calculate or estimate the overall thermal efficiency, which itself is dependent on the operating parameters. The bed heat balance includes the following items. Heat INPUT (a) in-bed heat release (i.e. fuel calorific value x combustion efficiency x proportion of heat release occurring within the bed)*. (b) sensible heat in the inlet air. (c) sensible heat in all the solids inlet streams. sorbent plus fines recycle if employed). * (fuel plus The form of item a) arises because the combustion efficiency is normally estimated for the combined bed and freeboard. Issue 002 Section 3 Page 15 of 56 4j~~~~~~~~~~~~~~ ~~~~~Cony No .. 40400 u---' Btu/lb 20000 40000 60000 (as fired basis) H2 30 Stoichiometric air ratio SR 20 kg air/kg fuel or lb air/lb fuel (as fuel basis) Ct 10 .Note. for bituminous coals SR 'r x 10 - 4 x EH For SI Units For British Units 0 EH - 50000 Gross e = 3.25 8 = 7.56 Fuel type · x $olid liquid i gas 100000 150000 calorific value (as fired basis) Figure 3.4 Variation of Stoichiometric Air Ratio with Calorific Value 9,. Issue 002 Section 3 Page 16 of 56 Copy Nott, Heat OUTPUT (i) heat transfer to in-bed and containment wall cooling surfaces. (ii) sensible plus latent heat in the bed off-gas.** (iii) sensible heat needed to raise the temperature of recycled fines to the bed temperature. (iv) heat of reaction of sorbent. (v) sensible heat of ash, sorbent, or other inert solids discharged from the bed. (vi) sensible heat of solids elutriated from the bed. (vii) radiation to and from the bed surface. (viii) heat transfer to and from the freeboard by solids splashing from the bed surface and falling back. Only items (i) and (ii) are of major significance in removing the heat release and the division of the heat load between them will depend primarily on the type of application, the bed temperature, the excess air level and the air inlet (preheat) temperature. Table 3.1 shows an approximate split of the heat output for typical values of these operating parameters. With no air preheat and an excess air level of 30% the proportion of the heat release that must be transferred to immersed cooling surface for a heat balance is in the range of 40-45% according to the bed temperature and the extent of freeboard combustion. For the less complicated applications and for design studies it will only be necessary to include the major items in the bed heat balance. These are items a), b), i) and ii) above. If sulphur retention is required item v) may also become significant. For the larger and more complicated application it will be necessary to include all the items in later iterations of calculation. ** Note that item ii) includes the heat to vapourise any water introduced with the fuel or formed during combustion. Issue 002 Section 3 Page 17 of 56 Cony No.. Step 10. Guidance on probable values of the overall thermal efficiency is given in sub-section 3.6 below. Step 12. step. The total bed cross-sectional area needed is given in this The area may be arranged in a circular or rectangular containment and sub-divided if required to suit the method of turndown and the needs of the application. In oil-firing applications when a tapered bed construction is used (see Section 5) the cross-sectional area calcutated in this step is that at the bed surface. 3.2.2.2 Bed maintenance and in-bed heat transfer Steps 13-15. Methods of turndown are outlined in section 3.10 and guidance on the selection of the static bed depth is given in Section 9.2.3, Issue 002 and of the height of the splash region in Section 3.5.4 or Section 10. Step 16. The characteristics needed in the bed solids of a fluidised bed combustor are outlined in Section 7 and the properties of suitable solids are given in Table 9.1.4 of Section 9, Issue 002. Steps 17-19. These steps in the procedure are concerned with the provision and maintenance of a suitable bed of solids and identification of the bed mean particle size. The matter is discussed in Section 9. Briefly, three situations are possible; (i) the start-up bed may remain and require only periodic make-up. (ii) the start-up bed may remain but require periodic or continuous cleaning to remove oversize material together with recycle and top-up of fresh material. (iii) the start-up bed may be replaced by one of coal ash or sulphur retention sorbent. Issue 002 Section 3 Page 18 of 56 Copy No.Y Table 3.1 Approximate Fractions of the In-bed Heat Release Removed as Sensible Heat in the Gases and Transfered to Immersed Cooling Surfaces Bed Temperature 900 'C (1550 'F) Excess air, % 0 30 50 1 100 165 Air preheat temperature 20 °C (68 OF) Fraction of heat to gases Fraction to immersed surfaces 0.44 0.56 0.55 0.45 0.61 0.39 0.78 0.22 1 0 Air preheat temperature 400 °C (750 OF) raction of heat to gases Fraction to immersed surfaces Conditions 0.30 0.70 Fluidising velocity Static bed depth Fuel calorific value Combustion efficiency Freeboard combustion 0.36 0.64 0.40 0.60 2 m/s 0.15 m 29 000 kJ/kg 97 % 5 % 0.50 0.50 0.63 0.37 Issue 002 Section 3 Page 19 of 56 Cony No''>' The measures necessary in each situation for maintaining a constant bed depth are outlined in Section 9.7, Issue 002. In situation iii) the bed composition and hence the mean particle size will alter during the initial period of operation until new equilibrium values are established. The addition of fresh solids to the bed will generally be required for maintaining the design bed depth but could also be needed to maintain a suitable bed particle size inventory. Steps 20-24 are only required when cooling surfaces in contact with the bed and splash solids are used. The heat transfer coefficient between bed solids and surfaces is significantly less if the surfaces are vertical walls as opposed to near horizontal tubes and in each case the coefficients reduce in the splash zone above the bed surfaces to values characteristic for convective heat transfer from a dusty gas. Methods of allowing for these effects are outlined in section 3.8 below and section 10. The design procedure suggested is to calculate the heat transfer rates from the bed and splash zone region to the water walls (if present) first. For some combustors the resultant heat transfer may be sufficient to give a bed heat balance. In general, however, additional bed cooling will be required, in the form of a bank of tubes immersed in the bed, to provide the necessary heat balance. The bed to tube surface heat transfer coefficient is a function of the bed mean particle size, adjacent tubes. the tube surface temperature and the gap between Approximate values for these latter two parameters may be assumed initially and modified later. When selecting a tube bank geometry Section 19 should be consulted for the measures recommended for minimising erosion on immersed tubes. The same section also contains recommendations for minimising erosion on the water walls. 3.2.2.3 Feedstreams and control Step 25. The start-up method adopted may have a marked influence on the type of air distributor that will be required and should, therefore, be specified before the air distributor design is undertaken in step 26. Details p Issue 002 Section 3 Page 20 of 56 Cony No. of start-up methods and their characteristics are given in Section 13, Issue 002. Recommendations for the value of the air distributor pressure drop (needed in step 26) are given in Section 15, Issue 003 and the size and number of the holes in the standpipe nozzles should be chosen to give the required pressure drop at MCR conditions. A method of calculating the nozzle pressure drop is also included in Section 15, Issue 003. Steps 27-30 are concerned with the design of the fuel and sorbent feed systems. Recommendations are given in Sections 4,5, 6 and 7 as appropriate for the fuel used. For oil firing a special procedure is given in Section 5.3 for the calculation of the number and dimensions of the oil feed nozzles. Step 31. The control requirements of a fluidised bed combustor are outlined in Section 13.6, Issue 002, together with a description of the control philosophies available. Choice of the most appropriate system will depend on the requirements of the particular application. The specification of any control hardware or instrumentation will be similar to that for conventional combustion systems and is outside the scope of this manual. 3.3 Computer Programs A number of computational aids are available on topics concerned with the whole fluidised bed combustion design procedure or with specific design aspects. For the complete procedure a program called "DESIGN" has been written at CRE in APLJ language using an IBM 3070 mainframe computer (3. 1). The program models the in-bed feeding of crushed coals in relatively deep beds in fluidised bed combustors. The combustion, bed maintenance, retention processes are modelled. Heat, mass and size fraction balances are carried out over the bed and freeboard. can be included if desired. heat transfer and sulphur Allowance for cooling in the freeboard Issue 002 Section 3 Page 21 of 56 Cony Non A program called "FBCDES" has been written in IBM BASIC for desktop microcomputers to carry out the preliminary design calculations for a fluidised bed conbustor (3.2). The program first calculates a heat balance, as described in Figure 3.1, for a given fuel to determine if it would burn autothermally. If the bed is not in heat balance the operating parameters can be adjusted or an amount of auxiliary fuel can be added to ensure a balance. If excess heat is generated in the bed the necessary bed cooling may be provided either by innersed surfaces or by an increased air flow. The sulphur retention process is also modelled. The output data include a bed heat balance and estimates of the bed cross-sectional area, the imnersed surface heat transfer area, the air, fuel and sorbent flows and the exhaust gas composition. Particular aspects of the design procedure are modelled in the following programs which are all written in IBM BASIC language for desktop microcomputers. Program "BEDEXP7". This program (3.3) carries out a heat balance for a fluidised bed boiler and can be used to predict the steady state operating parameters and heat output characteristics of different tube layouts when the bed expansion method of turndown is used. A knowledge of the variation of immersed surface heat transfer area and tube bank volume with bed depth is required as a subroutine in program BEDEXP7. This information can be calculated for any given tube bank configuration using program "SUBTUBE" (3.4). A program "HOTSTART" (3.5) has been developed to calculate the rating of the auxiliary burner used with the hot gas start-up system. The program uses the method of program BEDEXP7 to carry out a bed heat balance and estimate the fuel requirements during the start-up process. Program "PLENUW" (3.6). The heat losses from the plenum chamber of a fluidised bed combustor can be estimated using this program. On input of the plenum geometry and temperature, steady state conduction, convection and radiation heat transfer calculations are performed to estimate the heat loss. Issue 002 Section 3 Page 22 of 56 Cony No> Program "STANDPIP" (3.7). This program can be used to calculate the pressure drop characteristics of the standpipe nozzles in the fluidised bed combustor air distributor. The correlations used in the model are based on experimental work which is also described in reference (3.7). The calculation procedure for sulphur retention sorbents given in Section 11 of this Manual has been programmed separately; called "SUIRET". the program is This program can be used either to estimate the sorbent flow required for a given sulphur retention or the retention obtainable for a given sorbent flow. (3.8). The above programs on aspects of the design procedure and program FBCDES are all available on a disk file through Combustion Systems Ltd. (3.6). Additional programs concerning specific aspects of fluidised bed combustor design are program OHBURNER for the dynamic simulation of temperature increases in a fluidised bed during start-up using an oil or gas fired overhead burner, a program for the prediction of the behaviour of a fluidised bed furnace/drier system in which a proportion of the gas leaving the unit is recycled through the bed (3.9) and a program for the economic ranking of alternative technical solutions of erosion on in-bed tubing (3.10). These three programs are written in APL or IBM Basic languages. 3.4 Minimum Fluidising and Terminal Velocities The minimum fluidising velocity is the parameter that determines the onset of fluidisation in a bed of particles; it has a value characteristic of the mean particle size of the bed. The terminal velocity is that velocity at which a single particle is prevented from falling downwards and is carried away by the rising gas stream. velocity is Unlike the minimum fluidising velocity, the terminal a function of the diameter of an individual particle. Thus, although the terminal velocity determines the upper limit to bubbling Issue 002 Section 3 Page 23 of 56 Copy No.' fluidisation conditions there is no sharp cut-off point. Instead the elutriation rate rises with increasing fluidising velocity until eventually even the largest particles can no longer remain in the bed. Several equations are available for calculating the minimum fluidising velocity, Umf, and the terminal velocity, Ut.* For Umf equation 3.1, or the equivalent form, equation 3.2, is recommended. These equations are based on the Ergun pressure;drop relation. (3.11). Good agreement between calculated and experimental data has been found and these equations represent the best method of extrapolation. Armf where - 150 Remf (1-Emf)/E3mf + 1.75 Re2 mf/E3 mf Armf -[ g(4 dp)3 pg (fpsg)1 /j 2 and Remf .. [ ... ... ..... 3.1 dp, Umf tg] / An equivalent form is, U2 mf + Umf[150 (1-Emf)J]/[1.75 pgdp]-[g(ps-pg) E3mfap]/[1.75 pg] = 0 ... Note that in equations 3.1 and 3.2, dp is in metres if SI Units are used and in feet when British Units are used. For calculating the terminal velocity of spherical particles equations 3.3 to 3.5 may be used. Again note that as these equations are dimensionless dp must be in metres if SI Units are used and in feet if British Units are used. * Symbols are defined in Section 1 of this Manual 3.2 Issue 002 Section 3 Page 24 of 56 Copy No. Laminar (Stokes) region, where Ar t < 3.6 Art - 18 Ret or U Transition region, where 3.6 < Ar t < 105 Art - 18 Re t + 2.7 Retl 68 7 ... 3.3 pg)/(2 g ... ...... ... 3.4 Turbulent (Newton) region, where Ar t >>105 Art - (Ret) 2 /3 or U ttt a1 [ 3 g(ps-pg)/pg]e,~2/3 dx.3 ~[lp'p.p,r/p,]*P or13.5 where Art - [ £Pg(Ps1g) dx3] /I2 ... 5... and Ret - (dx Ut pg)/ Equation 3.4 is not convenient for rapid calculations and can be replaced by an approximate linear form. Ut [4 (pspg) 2 g 2 )/(225 p) ] dx (3.12). ..... 3.4a The bed particles in fluidised combustors are only approximately spherical. Beds of coal ash, for example, have a sphericity of about 0.8. The terminal velocities of non-spherical particles are always less than those for spheres and the reduction is greatest in the turbulent region. For calculating the U t of non-spherical particles equations 3.2 and 3.3 may be used with 4d x replacing dx . For the turbulent region equation 3.5a, taken from reference (3.13), is suggested. Ut 1.33 dx(pspg)g/(pg (5.31-4.88 Figures 3.5 and 3.6 ) for Art >,5 x 104.. 3.5a illustrate the variation of Umf and U t with pressure, temperature and particle size for typical ash particles of density 2100 kg/m 3 (130 lb/ft 3), Emf = 0.5 and a sphericity of 0.8, fluidised Si Issue 002 Section 3 Page 25 of 56 0 ~~~~~~~~~~~~~~~~Copy No.(. with air. 3.5a. The values have been calculated using equations 3.1 and 3.3, 3.4, In figure 3.6 smoothed lines have been drawn at the junctions between regions. 3.5 Effects of the Principal Operating Parameters 3.5.1 Fluidising velocity The fluidising velocity is the key parameter to the design of fluidised combustors. If the fluidising velocity is increased in a well-fluidised bed the following effects will occur. (i) An increase in the proportion of gas bubbles in the bed. (ii) Increased movement of bed solids and increased rates of diffusion of fuel particles. (iii) Increased rates of erosion of both the combustor walls and in-bed tube banks. (iv) An increased elutriation from the bed (v) A greater rate of attrition and, for a fixed system geometry, (vi) An increase in the oxygen supply. (vii) Increased distributor and gas cleaning equipment pressure drop. The operating value of the fluidising velocity must be a compromise in a range between the minimum fluidising velocity, and the terminal free-fall velocity corresponding to the mean bed particle size. Operation at minimum fluidising condition is not feasible as there is for the avoidance of hot spots. insufficient solids movement At all times the solids movement must. be sufficient to disperse the fuel and obtain an even bed temperature and to carry any oversize solids to bed drain ports at a sufficient rate. describes the term "good" fluidising conditions. This description A method of checking whether given operating conditions will result in "good" fluidisation is Section 9.6, Issue 002. given in In general it is recommended that the fluidising velocity should always be at least three times the minimum fluidising velocity. It follows that this recommendation will set the minimum allowable Section 3 Issue 002 Page 26 of 56 Copy No!~ ~ ~~0.04 0.02 0 0.08 F 0C 900 0 655 ____ - In,2 -6r m 1MW 0 5P~~~~~~~~L >0 ,jf -¶ r- I-F~ 4F E 20 1 6 o:,z~~~~ 0 0.24 100 KN/m2 -1 atmUm P 250C -750F 0 0.20 0.16 0.12 0 0 0 10 ~ ~ ~ ~~~~~~~~~~~ ~ it It ~~~~_____ 30 00 Mean Particle - Size -~~~~~n 10If,e~-m-1 0 00 40 60 pm~~~~~~~~~~~~~~~r Effet o Presur and TeprtrEnMnmmFudsn Veocty Section 3 Issue 002 Page 27 of 56 Copy No>, in. dix ~~0.02 0 0.12 0.08 0.04 0.16 5 Er~~~~~~4 0.20 0.24 KN/m2 - 6jatmP~i 610 10 0~~~~ tlPj 16 KNjiIrnt16 5 &JBSliI4LSt4. z. 20 ~~~~~~~~~~~~~~~~~~~~0 0~ ~ ~ ~ ~~~~~~~~~~~~~~~~~~~~7 20 4~~~~~~~~~~~~~~~ ' -, H15 10~~~~~~~~~~~~~~~~~~~~~~~~4 * jjj - j Patcl tize4 610 KN/m2 6atm r Figure 3 6~~~~~~~~~1 Velcit: Efectof Pessre ad Tmpertur TermnalFreeFal ft 30 Issue 002 Section 3 Paze 28 of 56 Copy No. ( air flow under turndown conditions; the MCR flow may be two to three times higher. There is an economic incentive to increase the MCR value of the fluidising velocity as much as possible as the combustor cross-sectional area will be proportionally reduced. However, the effects (i) to (viii) listed above are not all advantageous when the fluidising velocity is final choice will be an economic compromise. increasing fluidising velocity are as follows. combustible material from the bed. increased so the The undesirable results of an Firstly, the increasing loss of The combustibles loss from the combustor as a whole may remain unaffected, however, if the freeboard is to accommodate the increased combustion in it. sufficiently large Secondly, there will be an increasing need for greater static bed depths to give the residence time necessary both for combustion and sulphur retention. result in an increased bed pressure drop. This, in turn, will Thirdly, the increased attrition and elutriation may result in higher bed solids make-up requirements. Finally, the rates of erosion of both walls and tube banks will be increased. Current recommendations for the fluidising velocity are: for boilers - values in the range 1.0 - 2.5 m/s (3 - 8 ft/s) and preferably below 2.0 m/s (6.6 ft/s). The limiting factor is the need to minimise erosion. for furnaces - values up to 3 m/s (10 ft/s). The limiting factor is the need to avoid excessive entrainment. The above recommendations are made on the assumption that the size of the bed solids and the fuel can be chosen to match the fluidising velocity and avoid excessive elutriation. However, for one class of.fuels it will be necessary to select the fluidising velocity to suit the fuel size. In this class belong those solid fuels that are only available as fine powders, e.g. spent cracking catalyst. If the fluidising velocity is not appropriate to the particle size of such fuels, or if they are fed to an inert fluidised bed of Issue 002 Section 3 Page 29 of 56 Cony Nob larger sized particles, then the combustion efficiency in the bed may be low as the material will be substantially elutriated from the bed before combustion is completed. These remarks apply to dense phase fluidised combustors, the design of which is the subject of this Manual. It is possible to operate fluidised beds under such conditions that the entire bed is elutriated, separated from the gas stream and recycled (3.14). Such equipment is referred to variously as "dilute phase fluidised bed combustors", "solids transport combustors" or "fast fluidised bed combustors" and its design is 3.5.2 qutside the scope of this Manual. Bed temDerature The experimental rigs and prototype plant have been operated with mean bed temperatures up to 9500C (1750°F). Occasionally bed temperatures of 1000°C (1830°F) have been reached. The normal range of temperatures is considered to be 750 - 9500C (1380 - 1750°F). operating The lowest temperature for self ignition and sustained combustion is in the range 400-800°C (750-1470°F) depending on the fuel. See Table 13.2 of Section 13, Issue 002. At efficiency is poor. temperatures below 7500C (1380°F) the combustion Significant quantities of carbon monoxide and volatiles may escape from the bed unburnt and elutriated solids are comparatively rich in carbon compared with those for conventional firing. The upper limit to the bed temperature of 9500C (1750°F) is set for coal firing by the danger of sintering the ash (possibly plus sulphur retention sorbent) in the bed. In this connection it should be remembered that individual burning particles may be up to 2000C (360°F) hotter than the bulk bed temperature. For purely oil firing applications the upper limit to the bed temperature may be higher than 9500C (1750°F) and determined by the choice of bed solids. However, for multi-fuel firing applications the criteria for coal-firing will apply. The retention of sulphur by sorbents is markedly affected by the bed temperature during atmospheric pressure operation (see Figure 3.8 and Section 11) and the optimum temperature for both limestone and dolomite sorbents is in the range 800 - 8700C (1470 - 1600°F). Issue 002 Section 3 Page 30 of 56 Copy Not The bed temperature will very often be varied over the normal range to obtain load variation and designs must be checked at the extreme temperatures as well as at the nominal mean value. 3.5.3 Excess air level The operating excess air level will be determined by the type of application. For furnaces and applications without immersed surface bed cooling the excess air level will be that value necessary to maintain a bed heat balance, which will be of the order of 150 - 200% (see Table 3.1) when premium grade fuels are burnt. When immersed cooling surfaces are present, as in boiler applications, the bed heat balance is maintained by adjustment of the immersed surface area. There is an economic incentive to reduce the excess air level as far as possible to minimise the heat losses with the stack gases. The lower limit to the excess air is governed by the combustion requirements. During the combustion of solid fuels the combustion efficiency begins to drop rapidly at excess air levels below 20% (See Section 3.6) and an operating value of about 30% is recommended for normal operation with solid fuels. However, if staged combustion is used for the reduction of NOx emission levels then the bed itself is operated under slightly sub-stoichiometric conditions and additional secondary air is admitted to the freeboard to give an overall excess air level of around 30%. concept is the subject of ongoing research. This For the combustion of oil or gaseous fuels in boilers the excess air level can be reduced to 10% without any significant adverse effect on. the combustion efficiency. However, when these fuels are an alternative in multi-fuel applications it is generally most convenient to design for the combustion of all the alternative fuels at the higher excess air levels needed for the solid fuel combustion. Issue 002 Section 3 Page 31 of 56 Copy No.< 3.5.4 Bed depth and splash heifht 3.5.4.1 Static bed depth There is a considerable variation in the static bed depth recommended depending on the fuel burnt, application. the fuel feeding method and the type of There is an economic incentive to use the minimum possible static bed depth as the bed pressure drop, and hence the power for providing the air supply, are directly proportional to the bed depth. Also the rate of erosion of any tube banks inmersed in the bed is reduced as the bed depth is decreased; see Section 19, For Issue 001. gaseous fuels, provided they are fed in a premixed or pseudo-premixed form (see Section 6), low bed depths of the order of 50 mm (2 in.) are sufficient to obtain satisfactory combustion. Additional depth may be required to accommodate in-bed tube banks. For the over bed feeding of washed coals and similar solid fuels static bed depths in the range 0.15 - 0.2 m (6 - 8 in.) have been found sufficient to give high combustion efficiencies. These depths are also generally sufficient to accommodate the in-bed tube banks needed when the bed expansion method of turndown is used in boiler applications. When crushed coals and similar fuels are fed using the in-bed feeding method the static bed depth should be at least 0.5m (20 in.) to achieve the rates of fuel dispersion needed for high in-bed combustion efficiencies. For the combustion of oil fuels in a purely oil-firing mode a minimum static bed depth of 0.5m (20 in.) is recomnended to minimise both the number of oil feed nozzles required and the proportion of freeboard combustion. In multi-fuel applications when a higher proportion of the heat release is needed in the freeboard to match the characteristics of coal-firing the static bed depth may be reduced down to 0.3 m (12 in.). If the static bed depth is less than 0.56m (22in.) an adjustment to the number of oil nozzles needed (the oil Issue 002 Section 3 Page 32 of 56 Copy No. nozzle density) will also be required: see Section 5, Issue 002. - Oil firing with static bed depths less than 0.3 m (12 in.) is not recommended. When sulphur retention is desired any of the values of static bed depth recommended above may need to be revised upwards according to the reactivity of the sorbent and the degree of sulphur retention required. For example, Figure 3.10 shows that the Ca/S molar ratio needed to give a 50% sulphur retention using a sorbent of average activity (Reactivity index of 40) is reduced from 2.5 at a static bed depth of 0.15 m (6 in.) to 1.5 at a static bed depth of 0.4 m (16 in.). 3.5.4.2 Exuanded bed deuth Expanded bed depths depend on the type and mean particle size of the bed solids and on the fluidising velocity. Values of the expanded bed depth can be calculated using the correlations given in Section 9, Issue 002 or they may be estimated using Figure 9.2 of that section. As an example; sand beds at a fluidising velocity of 2 m/s (6.5 ft/s) and with mean particle sizes of 800 and 1200 u m (0.031 and 0.047 in.) have expanded bed depths 1.7 and 1.5 times their respective static bed depths. 3.5.4.3 Snlash heig-ht A splash zone exists above the notional expanded bed depth where the bed solids concentration reduces from that typical of the expanded bed to that typical of a dusty gas. The top of the splash zone - the splash height - is usually estimated as 1.5 times the expanded bed height. 3.5.5 Properties of bed solids 3.5.5.1 Materials The properties of materials that are suitable for forming the initial bed of a fluidised bed combustor are given in Table 9.1 of Section 9, and Table 13.1 of Section 13, Issue 002. Issue 002 Issue 002 Section 3 AW Page 33 of 56 Cony No. > For gas and oil firing applications and for the combustion of washed coals with less than 10% ash the initial bed will persist and become the bed for normal operation. When sorbents are added for sulphur retention and for unwashed coals and many solid fuels the initial bed becomes replaced by one composed of sorbent and/or fuel ash. Details of such beds are also given in Table 9.1. The ability of coal ash to form a suitable bed depends on the amount and properties of the ash formed. No hard and fast rules can be given because of the wide variations between different coals and Section 9.7, Issue 002 should be consulted for further details. 3.5.5.2 Particle size. The bed of inert particles will normally be comprised of a range of sizes. Indeed a bed of uniformly sized particles does not fluidise well and some fines are needed for good fluidisation. A bed of particles of varying sizes can be characterised by a mean particle size. The mean most suited for fluidisation purposes is the surface mean diameter, * dp, defined by ~~~~~~i=n ; 1 e % dp ~xii ... e>z *s 3.6 (di j) i-1 where xij is the weight fraction between the size limits di and d. The mean bed particle size and size range must suit the desired fluidising velocity and particle density. Suggested values of particle size are given in Table 13.1 of Section 13, Issue 002 for the initial beds. Issue 002 Section 3 Page 34 of 56 Cony No:'57 In normal operation the bed material tends to an equilibrium state provided all feed and take-off streams remain constant. Fines in excess of the equilibrium requirements will be quickly elutriated while the larger size fractions remain until either they are gradually reduced in size by abrasion and elutriated, or they are removed in the bed overflow stream. Variations in feed streams are therefore only self correcting if excess under-sized material is fed. All oversized solids that are fed must be removed otherwise they will collect at the bottom of the bed and eventually cause defluidisation. When the bed overflow stream (see Figure 9.1 of Section 9, Issue 002) is substantial, usually during the combustion of high ash solid fuels or when sulphur retention sorbents are added, the bed solids offtake ports should be sited to remove the lower layers of the bed solids and prevent any build-up of oversize material. When oversize materials enter, but the overflow stream is small or non-existent, then bed cleaning equipment will be necessary. The terml bed cleaning means the removal, periodically or continuously, of a portion of the bed solids followed by their separation into an oversize fraction, which is rejected, and a within-specification fraction, which is returned to the bed. Bed cleaning equipment is described in Section 9, Issue 002 along with methods for calculating the size of the overflow stream that is necessary for effective bed cleaning. Thus the match between mean solids particle size and the fluidising velocity is maintained during operation either through the attainment of a suitable equilibrium particle size distribution or through the use of suitable bed cleaning techniques. Fresh bed solids can also be added to maintain the desired particle size distribution. A method of checking that the quality of fluidisation of a given bed is suitable is given in Section 9, Issue 002. That Section also shows how the separate effects of those factors that may alter the bed size composition may be calculated so that the equilibrium particle size distribution and mean particle size may be estimated. Issue 002 Section 3 Page 35 of 56 ~~~~~~~~~~~~~~~Copy No. / * 3.5.6 Coal feed narticle size It may be necessary to regulate the top size of the coal feed during coal-firing so that the inert materials formed during combustion can be handled by the overflow stream and/or the bed cleaning equipment. The in-bed feeding method was developed for the combustion of unwashed coals using a flat plate nozzle standpipe type, of distributor (see Section 15, Issue 003). Unwashed coals require crushing If the combustor is operating at fluidising velocities in the recommended range and also so that they can be transported pneumatically. Table 3.2 gives suggested values for the coal top size at various fluidising velocities. Table 3.2 Suggested Values of Unwashed Coal Feed Top Size for Various Fluidising Velocities Coal top size in mm 1/4 3/16 1/8 1/16 6.34 4.74 3.17 1.58 Fluidising velocity pm 6340 4740 3170 1580 ft/s 9 6 4 2 - 14 9 6 4 m/s 2.7 1.8 1.2 0.6 - 4.3 2.7 1.8 1.2 Unwashed coals may contain inert materials of the same top size as the coal itself. For this reason the use of material with a top size larger than those quoted in Table 3.2 would require specialised designs of distributors and arrangements for the removal of ash in the overflow stream. See also Section 4 and 15, Issue 002. Washed coals are generally available in the UK in a graded form "singles", sized 25 - 12 mm or "doubles" sized 50 - 25 mm - or in an - Issue 002 Section 3 Page 36 of 56 Cony No.< - ungraded form "smalls", sized 25 - 0 mm. All these forms are suitable for firing without further treatment using the flat plate nozzle standpipe type of distributor and the technique of above bed feeding to the surface of the bed. By using this technique it is possible to "float" comparatively large particles of coal on the fluidised bed. As the coals have been washed the ash formed during combustion is very fine and is almost wholly elutriated. 3.5.7 Air and fuel distribution The performance of a fluidised combustor can be profoundly affected by the manner of distribution of air and fuel into the bed and it extremely important to use appropriate methods. is therefore Any performance figures and design recommendations given in the Manual are only valid if the distribution methods recommended in Section 15, Issue 003, are adhered to. 3.5.7.1 Air distribution The preferred distributor design is the nozzle standpipe type with the holes or slots in the nozzles being horizontal to prevent the back flow of solids from the bed. The hole size and number of nozzles should be calculated according to the recommendations of Section 15, Issue 003. 3.5.7.2 Solid fuel distribution Alternative feeding methods are available. For the method of in-bed feeding the feed is crushed to a top size, see Table 3.2 above, and is delivered by pneumatic transport to nozzles feeding to the base of the bed through the air distribution plate. Nozzle spacing must be as uniform as possible over the combustor cross section and areas of up to 1.8 m2 (20 ft 2 ) may be fed satisfactorily from each nozzle. (3.15). In general the greater the number of fuel nozzles, the higher the combustion efficiency. In- bed feeding is also reconmended if the fuel is in the form of a fine powder as it will result in the highest proportion of in-bed combustion. . Issue 002 Section 3 Page 37 of 56 Copy No.., The alternative method is termed overbed feeding where the fuel is fed directly onto the bed surface via a chute or spreading device. has been used extensively for feeding washed coals in fines content. This method lump form with a low The combustion efficiencies obtained using overbed feeding are similar to those found with the in-bed feeding method. 3.5.7.3 Oil distribution Special arrangements are required to overcome feeding difficulties such as cracking of the oil on entry to the bed. The oil is fed at an appropriate rate and temperature to injection nozzles situated near the base of the bed at points where the bed solids movement is most rapid. Methods for calculating the number of oil feed nozzles and their detailed design are given in Section 5, Issue 002. 3.5.7.4 Gas distribution It is generally desirable that the heat release of the fuel occurs as far as possible within the fluidised bed so that advantage can be taken of the higher rates of heat transfer from the bed solids compared with the conventional rates of convective heat transfer. To obtain combustion within the bed with gaseous fuels it is necessary that they are fed in a premixed or pseudo-premixed form with air as described in Section 6. 3.6 3.6.1 Combustion and Unit Efficiencies Combustion efficiency The term combustion efficiency is used to describe the extent of combustion in the bed and freeboard acting together as one unit. efficiency of combustion may be affected by the following factors. (i) (ii) (iii) excess air bed temperature fluidising velocity The Issue 002 Section 3 Page 38 of 56 Copy No.; (iv) (v) (vi) bed depth method of fuel feeding air distribution (vii) properties of fuel (viii) operating pressure The factors which have the largest effect are the excess air level, the fuel properties, which include the reactivity of solid fuels, and the bed temperature. The fluidising velocity and static bed depth have very little effect provided their values are in the ranges recommended in the previous sections. For all fuels it is important that the air distribution is uniform over the entire combustor cross-section; otherwise some localised regions may operate at a low excess air level with adverse effects on the combustion efficiency. The combustion efficiency of gaseous fuels is virtually 100% when they are fed with air in a premixed or pseudo-premixed form at excess air levels above 10% and at bed temperatures in the normal operating range of 750-9500C (1380-17500 F). The combustion efficiency of oil fuels is generally greater than 99% provided the excess air level is above 10%. The combustion losses are mainly in the form of carbon monoxide and increase rapidly as the excess air level is reduced below 10%; see Section 5, Issue 002. S The combustion efficiency of solid fuels is more affected by the excess air level than is that of oil or gaseous fuels. As an illustration the variation in combustion efficiency of a bituminous coal is shown as a function of excess air level in Figure 3.7 for both the in-bed and above bed feeding methods. At high excess air levels and a given bed temperature similar combustion efficiencies are given by either feeding method but the above bed method is somewhat more sensitive to changes in the excess air level. Combustion losses through unburnt volatiles or carbon monoxide are normally negligible. The main loss occurs through the elutriation of fine Issue 002 Section 3 Page 39 of 56 Copy No, c E<~~ o o -4~~~ oE~a 0 ° am I a - Cn I O I ( m._ i o0 o c o T- a1 -W 30 C- 9~~~~~~~~~~~~. (Bituminous Oxygen cols, 10% content W/w dmmf) . Issue 002 Section 3 Page 40 of 56 Si Copy No. carbonaceous material from the freeboard. No significant correlation has been found between the combustion loss and either the proportion of fines or the mineral content in the feed. However a limited amount of evidence suggests that above average losses may occur with coals having both a high mineral content and a high proportion of fines in the feed. The overall combustion efficiency for once through operation can be improved by the recycle of fines back to the main bed. To obtain very high overall efficiencies for atmospheric pressure operation, however, it will probable be necessary to refire the carbon fines in a separate burn-up bed. For the in-bed feeding method, and providing the excess air level is above 15%, the changes in the combustion efficiency caused by any one variable are only a few percentage points in the areas of interest. The effect of bed temperature is similar to that shown for above bed feeding in Figure 3.7. The effect of bed depth is very slight in the range 0.6-1.4 m (2-4 ft) static depth. The effect of fluidising velocity is also sligit. At a bed temperature of 850 C (1560°F) and an excess air level of 13% the combustion efficiency was found to increase from 93 to 96% as the fluidising velocity decreased from 0 2 to 0.5 m/s (6.5 to 1.6 ft/s) (3.16). Table 3.3 suggests values of overall combustion efficiency that * should be attainable by various modes of operation at atmospheric pressure. Table 3.3 Suggested Values of Overall Combustion Efficiency In-bed coal feeding. Mode of Operation Atmospheric pressure operation. Overall Combustion Efficiency Once through 92 - 94 Once through + recycle 94 - 97 Once through + recycle + carbon burn-up bed > 97 Issue 002 Section 3 PaEe 41 of 56 ConY NoA..t No experimental data is available for the influence of coal reactivity on combustion efficiency with in-bed feeding but trends similar to those found with above bed feeding would be anticipated. See Figure 3.8 and Section 4, Issue 002. For the above bed feeding method Figure 3.7 shows that it is desirable to operate at an excess air level over 30% (or even above 40% at low bed temperatures) to obtain high values of combustion efficiency. Reduction of the bed temperature through the normal operating range decreases the combustion efficiency by about two percentage points!. (Figure 3.7). The fuel reactivity is the other principal parameter affecting the combustion efficiency during above bed feeding. For coals the oxygen content has been found to characterise their reactivity and Figure 3.8 shows how the combustion efficiency is reduced as the coal becomes less reactive, other conditions being kept constant. Provided the fluidising velocity is below 3 m/s (9.8 ft/s) the combustion efficiency is not significantly affected by variations of the fluidising velocity. A gain of one percentage point may be obtained if the fluidising velocity is reduced over the range 3.0-1.7 m/s (9.8-5.6 ft/s). However, as the fluidising velocity is increased above 3 m/s (9.8 ft/s) the elutriation rates of solids increase sharply and the combustion efficiency can be reduced significantly (3.17). The extent of the reduction will depend on the freeboard design. Variations in the bed depth have little effect on the combustion efficiency provided the beds meet the recommendations for minimum depth given in Section 3.5.4 above. Correlations for predicting the combustion efficiency for above bed feeding are available; see Section 4.4.3, Issue 002. Issue 002 Section 3 Page 42 of 56 Copy No - 100 Anthrocites Bituminous Combustion efficiency ed temperature Excess air 9000 C (1650 0 F) 30% Static bed depth 150mm(6On.) Fluidising 80 0 2 Coaol 4 oxygen 6 8 content % w/w Figure 10 velocity 2m/s (6.5ft/s) I 12 dmmf basis 3.8 Effect of Coal Reactivity on Combustion Efficierncy for Overbed Feeding 9 Issue 002 Section 3 Page 43 of 56 Cop 3.6.2 No. Overall thermal efficiency No firm values can be quoted for the overall thermal efficiency as it depends on the design of the heat recovery system downstream of the combustor, which is outside the scope of this Manual. For fluidised bed boilers of similar design the overall thermal efficiency will be mainly influenced by the combustion efficiency. Results from a number of industrial installations less than 10 MW (3.4 x 107 Btu/h) in heat output suggest that the following equation may be used for estimating purposes. not - 0.84 x1n ... ... ... ... ... 3.7 A slightly larger constant term in equation 3.7 may be appropriate for larger scale applications. 3.7 Pattern of Heat Release A knowledge of the proportion of the fuel heat release that occurs in the bed is required for calculating the bed heat balance. For the combustion of crushed coals using in-bed feeding methods a model of the combustion process is available that allows the heat release in the bed and freeboard to be calculated separately. See Section 4, Issue 002. For other fuels and feeding methods estimates of the proportion of freeboard heat release are available based on industrial operating experience. For the combustion of washed, graded coals (UK singles or doubles) using above bed feeding methods it is estimated that 5% of the heat release occurs in the freeboard. If such coals are ungraded and contain all the fines (UK smalls) then up to 10% of the heat release may occur in the freeboard. For oil fuels the proportion of the heat release occurring in the freeboard depends on the oil grade, the excess air level and the oil feed nozzle density. With a nozzle density of 4 per square metre (0.37 per Issue 002 Section 3 Page 44 of 56 Cony No.\ / square foot), which is the minimum value recommended for multi-fuel firing applications with an untapered bed, the proportion of heat release in the freeboard can be estimated from Figure 5.23 of Section 5, Issue 002, for various oil grades and excess air levels. The freeboard heat release is generally in the range 2-10% which is similar to that for coal firing. As the otk-nozzle-density-iwsiicreased1abive -this inimnum value the proportion of heat release in the freeboard will reduce but no precise estimates of the reduction are currently available. For gas firing with the gas fed in a premixed or pseudo-premixed form (See Section 6) the proportion of heat release in the freeboard is estimated to be less than 5% of the total heat release. 3.8 Heat Transfer from the Bed The only situation in fluidised bed combustors where the heat transfer rates differ from those found during conventional combustion is where surfaces are contacted by the bed solids. In all other respects heat transfer rates are similar to those for conventional convective heat transfer and design considerations for them are outside the scope of the Manual. The heat transfer coefficient to immersed surfaces is made up of a convective and a radiative component which are considered to be additive. The convective component is affected by the bed particle size, the temperature of the surface through which heat is being transferred and the gaps between adjacent surfaces allowing flow of the fluidised solids. The convective component is generally in the range 200-500 J/m2s (35-90 5o Btu/ft 2 hOF). The radiative component similarly is in the range 100-200 J/m2SoC (17-35 Btu/ft2 hoF). When the heat transferred to the in-bed surface is removed by boiling water and if the tube-to-water film heat transfer coefficient is assumed to be 850 J/rn2sC (150 Btu/ft 2 hOF), and the conduction through the tube wall is neglected, a value of 250 J/m2 soC (45 Btu/ft 2 hOF) for the overall Issue 002 Section 3 Page 45 of 56 ! ~~~~~~~~~~~~~~~~~~~Cony No. a'~ heat transfer coefficient is suggested for estimating purposes or as the first iteration of the design calculations. For more detailed design Section 10 should be consulted. It is necessary to differentiate between surfaces, such as tube banks, lying wholly or partially within the bed and those, such as containment walls, that are contacted only on one side by the bed. The splash zone above the bed also requires separate consideration. Equations for calculating both heat transfer components in various bed geometries are given in Section 10. The equations for the convective component of heat transfer were developed from data obtained with relatively deep beds of coal ash and corrections may be necessary when they are applied to shallow bed combustion (bed less than 400 mm (16 in)). Further details are given in reference (3.3) and Section 10. 3.9 Sulphur Retention The sulphur retention process involves the addition of a solid sorbent which retains the sulphur evolved during combustion in the form of a solid sulphate for subsequent disposal. The sorbent is a source of calcium carbonate which decomposes to calcium oxide at the bed temperature. Graded limestones, or less commonly dolomites, are the usual sorbents for atmospheric pressure operation. The sorbent flow depends on the chosen calcium/sulphur molar ratio which varies with the degree of sulphur retention required. Figure 3.9 shows how the retention varies with the Ca/S molar ratio for a typical limestone sorbent used in a boiler application. Other factors which affect the molar ratio needed for a given retention are the bed temperature, the sorbent top size , the sorbent activity and the bed depth and fluidising velocity which together determine the gas residence time in the bed. The manner in which each of these factors, when varied on its own with all other values kept constant, is illustrated in Figure 3.10 for a limestone sorbent. The selected set of conditions chosen is that for average operation and each individual graph illustrates the calculated change in Ca/S molar ratio for variation of one particular parameter. Issue 002 Section 3 Pave 46 of 56 Copy No " 100 90 80 70 /60 ~Typical ~ 60 ~ Sulphur retention Limestone Sorbent % 8500°C 2 ms 3000pm Static 0.3 m so50 Bed temperature Fluidising velocity Sorbent top size bed depth Sorbent 40 activity Excess air Flue gas C02 / 40 30% 13% 30 20 0' 1 2 3 Ca/S 4 5 molar ratio 6 7 8 Figure 3. 9 Variation of Sulphur Retention with Ca/S Molar Ratio S~~~Vaito Issue 002 Section 3 Page 47 of 56 Copy NNo.A Typical Limestone 1400 1500 6 1600 1700 Performance OF 0 5 10 ft/s 6 5 4 4 3 2 2 0 0 750 0 800 850 900 Bed temperature °C 950 0.04 0.16 in. 0.12 0.08 1 2 3 Fluidising velocity m/s 0 12 6 18 in. 4 0 -2 . 1 . 0 1000 2000 3000 4000 Sorbent top size microns 6 5000 0 Selected conditions EBed temperature 850°C Fluidising velocity 2 m/s Sorbent top size 3000pm Static bed depth 0.3m Sorbent. activity 40 o Selected condition for Limestone sorbent 5 4 0.2 0.4. 0.6 Static bed depth m 3 Excess air 30% Flue gas C02 10 00X 13% 3 10 20 30 40 Sorbent SO 60 70 activity Figure 3.10 Effect of Operating 50% m, Parameters on Ca /S Sulphur Retention Ratio for Issue 002 Section 3 Page 48 of 56 Copy No.W _ When the bed temperature is in the middle of the normal operating range about 850 0 C (1560°F) the next most important factors are the bed depth and the sorbent reactivity. found to be very variable. The activity of limestones as sorbents has been It depends on the stone pore size and pore size distribution, on its hardness and on other factors which are not yet completely understood. A laboratory test rig is available for the determination of sorbent reactivity. See Section 17. For estimating purposes a value of 40 is suggested for the activity of an average limestone. 3.10 3.10.1 See also Sections 11 and 17. Turndown General considerations Any plant of which a fluidised combustor is a component will almost certainly be required to operate over a range of loads. The requirements of load regulation must be considered at the inception of any proposal because they may have far reaching effects on the design. For example, in some applications low turndown ratios (< 1.5:1) may be easily obtainable with a single bed combustor but high ratios (> 4:1) can only be obtained using compartmented or multiple bed combustors. The combustion rate in a fluidised combustor is reduced by feeding less fuel, which may be carried out in four different ways. (a) The fuel rate alone is reduced. The air rate stays the same and consequently the excess air increases. (b) Both the fuel and air rates are reduced together to maintain a constant excess air value. (c) A portion of the total bed cross-sectional area is shut down and normal operating conditions maintained in the remainder. (d) The combustor is operated in an on/off mode with periodic bed slumping. In (a) and (b) above the combustion intensity is reduced. In c) it remains the same in the active portion of the combustor providing the combustion efficiency Issue 002 Section 3 Page 49 of 56 Cony No. remains constant. In d) the combustion intensity remains the same when operating in the "on" mode. Whatever method of load control is adopted the heat balance of the fluidised bed for all applications must be such that the bed temperature is maintained within the normal operating limits of 750-950°C (1380-1750°F). Also the fluidising velocity must be such as to give "good" fluidising conditions at all loads. A definition of 'good" in this context is given in Section 9.6, Issue 002. The use of in-bed tubing in boiler applications imposes further constraints on the fluidised combustor design. The constraints arise because heat is transferred predominantly by convection in fluidised combustion. In this respect fluidised combustors are different from conventionally-fired equipment where heat is transferred predominantly by radiation and where the transfer rate, being proportional to the fourth power of the absolute temperature, may undergo large changes for quite small changes in combustion temperature. In fluidised combustion the effect of reducing the bed temperature depends on the coolant cycle conditions. For steam raising applications the temperature difference between the bed and the boiling water is large (of the order of 6000C (1080%F)). Therefore only a limited change in the rate of heat transfer to the in-bed surfaces can be achieved by variation of the bed temperature. Reduction of the bed temperature through the entire operating range will give a load reduction of only 20-40%; the exact value will depend on the proportion of heat removed by in-bed surfaces and that as sensible heat in the off-gases. For air heating cycles the coolant temperatures are higher and the bed-to-coolant temperature differences correspondingly lower. Changes in the bed temperature therefore cause much larger changes in the heat transfer rate. Nevertheless the effect of bed temperature on in-bed heat transfer is always limited and must be carefully considered during load reduction. At any given bed temperature the balance between the heat transferred to in-bed surfaces and that transferred in other ways must remain unaltered at all combustion rates. If this balance is disturbed the bed will either overheat or cool off. Issue 002 Section 3 Page 50 of 56 Copy No. Unless on/off operation is used it follows, therefore, that when significant load reductions are required the heat transfer to the in-bed tubing must be reduced by changing some other parameter than the bed temperature. The following alternative methods have been examined. (a) Shut-down of a part of the combustor cross-section by using a compartmented bed or multiple beds. (b) Exposure of a portion of the in-bed tubing to the splash zone, where heat transfer rates are lower, by reducing the bed depth. (c) Separation of the combustion and heat transfer functions into two separate beds with circulation of hot bed material between them. Shut down of a part of the combustor, method a), reduces the total in-bed heat transfer proportionately. It also reduces the air flow proportionately and allows the fluidising velocity to be maintained in the active part of the bed with a smaller total air flow. One difficulty with this method is that on shutting down one part of the bed, the bed temperature in the remaining active part must be instantaneously increased from a minimum to a maximum value to give a smooth variation of load between steps. The choice between a single compartmented bed or multiple beds will depend largely on economics and heat transfer surface layout. Compartmented beds if shallow (lm (3 ft) or less) may require merely a zoned air supply to the distributor but a physical separation in the bed between different compartments is always recommended. See Section 13, Issue 002. Method b) is termed the bed expansion method; the principle of operation is illustrated in Figure 3.11. The heat transfer rates to tubes are a power of ten less in the freeboard than they are in the expanded bed; the transition occurs gradually throughout the splash zone. If the tube bank is situated just below the expanded bed surface at MCR conditions (as in Figure 3.11 (a)) the natural contraction of the bed as the fluidising velocity, and hence load, is reduced will cause the tube bank to be exposed to splash zone conditions (as in Figure 3.11 (b)). If the resulting reduction in heat transfer to the tube bank matches the change in load the bed will remain Issue 002 Section 3 Page 51 of 56 Copy No. >.: )' 2 16. 5) Fluidising velocity m/s (ft/s) 1 13.3) Bed depth m. Bed depth in. 0.5 18 0.4 0.Figure 3.11 The Bed Expansion Method of Turndown -Bed Variations for 14/25 Mesh Sand 0~~~~~~~~~iue31 Level Issue 002 Section 3 Page 52 of 56 Copy No., in heat balance at constant bed temperature and excess air level. The same effect could also be achieved by the physical removal of bed solids. The bed expansion method has been used extensively on industrial units up to 30 NW (1 x 108 Btu/h) heat output. It is best suited to those applications where the tube bank consists of only one or two rows of tubes. Method (c) is more complicated than the other methods. It has not been developed although cold model studies (3.20) have demonstrated its technical feasibility. 3.10.2 Choice of method The choice of the method of load variation depends on the type of application and the level of turndown required. Furnaces. combustors without immersed surfaces. For coal-fired combustors it fuel and air rates while still is usually possible to halve both the maintaining "good" fluidising conditions. This variation, in conjunction with a reduction of the bed temperature through the normal operating range, can give a turndown of up to 2.5:1. For oil-firing and multi-fuel applications the need to maintain the oil transport air flow at MCR values at all times restricts the degree of turndown obtainable through air flow reductions. Air flow and bed-temperature reductions together can give a turndown of up to 2:1. If a greater degree of turndown is required then the use of multiple or compartmented beds should be considered. Issue 002 Section 3 Page 53 of 56 Cp No. Boilers. combustors with immersed surfaces. For both oil and coal-firing applications the bed expansion method can generally be used to obtain a turndown of up to 2:1. For higher degrees of turndown multiple bed operation can be combined with the bed expansion method. A 6:1 turndown (2:1 bed expansion plus 3:1 multiple beds) has been demonstrated on a 30 MW (1 X 108 Btu/h) unit (3.19). Turndown ratios greater than 2:1 can; also be obtained through on/off operation. This method is probably best suited for hot water boilers and smaller scale applications because of the temperature cycling involved and is only applicable if periods of zero output can be tolerated. *3~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ 4i Issue 002 Section 3 Pave 54 of 56 to Copy No., 3.11 3.1 References Collop, D.J. & Merrick, D. "Design manual program user manual". Brit. Coal, CRE Report No. PADB/79/15, (April 1979). 3.2 Ellis, J.E. "Program FBC DESIGN for IBM PC: A Microcomputer program for the design of an atmospheric fluidised bed combustor" Combustion Systems Ltd., Report, (1988). 3.3 Moodie, J., Stockwell, D.H., Vickers, M.A. & Blenkin.P. "BEDEXP7 - A computer program to aid the design of fluidised bed boilers using a procedure to predict the effect of in-bed tubing arrangement on boiler output characteristics", Brit. Coal, CRE Report No PH8, 1987). 3.4 (Dec See also version with program listing CSL Report, (1988) Stockwell, D.H. "SUBTUBE - A computer program to calculate the heat transfer surfaces and volumes of immersed tubes in fluidised bed boilers" Brit. Coal. CRE Report No. P373. 3.5 Moodie, J., Stockwell, D.H., Vickers, M.A. & Loynes, D. "Fluidised bed combustors - a revised mathematical model of hot gas start-up.". Brit. Coal, CRE Report No. PH 27/8, (Dec 1987). 3.6 Combustion Systems Ltd. "IBM Basic computer programs." Disk file containing 7 microcomputer programs. 3.7 (July 1987). Iles, A.E., Moodie, J., Stockwell, D.H. & Vickers, M.A. development of "The a mathematical model to predict the pressure drops through standpipe air distributor". Section Report No 271 (Dec 1985). Brit Coal, CRE Combustion Issue 002 Section 3 Page 55 of 56 Copy No.! 3.8 Ellis, J.E. " ) A computer program for the calculation of sulphur retention in fluidised bed combustors". Combustion Systems Ltd., Report (1988). 3.9 Atkinson, P.A. "Fluidised bed driers - a mathematical model to investigate the effect of recycling the exhaust gases". Brit. Coal, CRE Report No PI 40, (July 1986). 3.10 Davidson, J.E. & Waye, A.D. "An economic comparison of technical solutions to tube wastage in AFBCS". Brit Coal, CRE Technical Note 87/972/2, (March 1987). 3.11 Davidson, J.F. and Harrison, D., ed. "Fluidisation", Academic Press, London, (1971). 3.12 Kunii, D. & Levenspiel, 0. "Fluidisation Engineering" pub J. Wiley (1969), p.76 . 3.13 Pettyjohn, E.S. & Christianson, E.B. Chem. Eng. Progr. 44, 157, (1948). 3.14 Engstrom, F., Ahlstrom, A. & Sahagain, J. "Circulating fluidised bed technology", ed. P.Basu. Proc. 1st. Int. Conf. on CFB Technology, Halifax, Nova Scotia, P.309-316, 3.15 "Fluidised Bed Combustion - Industrial Applications: and 2". 3.16 (Nov 1985). Report No 1/77/762A. (9 March 1977). NCB, CRE "Run reports for the 3ft combustor". 58, 64, 68, (1970). Test series 1 Report Nos. 54, 57, Issue 002 Section 3 Pave 56 of 56 Copy No. 3.17 Fisher, M.J., 3.18 NCB, CRE "Run reports for the 3ft combustor". Ford, N.W.J. & Robinson, A.W. "Report of the development of the high velocity Thermraiser fluidised bed boiler at CRE". British Coal, CRE, Report ID 25, (Sept 1985). Report Nos. 19, 21, 22, 24, 25, 31, (1969). 3.19 Fisher, M.J. "The application of fluidised combustion of coal to a low cost industrial water tube boilir integrated in a combined heat and power system". British Coal, CRE. Contract No. EE 129/81 Consolidated Technical Report for 1/11/81 to 31/3/86, (Jan 1988). 3.20 BCURA Reports Nos. FCP 13, (May 1970) and FCP 21, (July 1971).
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