Small Size, High Value: Composition and Manufacture of Second Millennium AD Copper-Based Beads from Northern Zimbabwe Downloaded by University Arizona - Library on September 28 2010 Thomas Panganayi Thondhlana & Marcos Martinón-Torres Abstract Résumé This investigation introduces a new dimension to the previous typological analyses of the metal bead assemblages from Zimbabwean archaeological sites. Here we present the microstructural and chemical characterisation of 50 copper-based metal beads from the collections of the Zimbabwe Museum of Human Sciences (ZMHS) in Harare, most of them from Later Farming Community period sites in northern Zimbabwe (AD 1000 to AD 1900). The analytical study employed optical microscopy, ED-XRF and SEM-EDS. Cette étude ajoute une nouvelle dimension aux analyses typologiques précédemment réalisées sur des assemblages de perles métalliques provenant de sites archéologiques zimbabwéens. Nous présentons dans cet article la caractérisation microstructurale et chimique de 50 perles en alliage à base de cuivre qui proviennent des collections du Musée de Sciences Humaines du Zimbabwe à Harare, la plupart étant originaires de sites du nord du Zimbabwe et datant de la période dite des « Communautés Agricoles Finales » (1000 ap. J.-C. – 1900 ap. J.-C.). Dans le cadre de cette étude analytique, la microscopie optique, la spectroscopie de fluorescence X à dispersion d’énergie, et la microscopie électronique à balayage à dispersion d’énergie ont été utilisées conjointement. Compositionally, unalloyed copper, arsenical copper and tin bronzes were identified in the earlier sites, with some significant regional variations. From the seventeenth century, brass becomes the preferred alloy. The potential sources of these metals and their spatial and temporal patterning are discussed with reference to both the socio-economic dynamics prevailing in Zimbabwe during the period, and the symbolic value of metal beads in these communities. The metallographic study showed a preponderance of wrought beads, with a small but significant presence of cast forms. These fabrication technologies reflect little outside influence and are in line with indigenous African metal smithing methods. En termes de composition chimique, des cuivres non alliés, des cuivres à l’arsenic et des bronzes cuivre-étain ont été identifiés sur les sites les plus anciens, montrant d’importantes variations sur le plan régional. A partir du dix-septième siècle, le laiton devient l’alliage de prédilection. Les sources potentielles pour ces métaux et leur distribution spatiale et temporelle sont discutées, tenant compte des dynamiques socio-économiques qui prévalaient au Zimbabwe à cette époque et de la valeur symbolique des perles métalliques dans ces communautés. L’étude métallographique a montré la prépondérance de perles forgées par rapport aux formes coulées, moins nombreuses, mais dont la présence est cependant significative. Ces techniques de fabrication ne reflètent qu’une faible influence extérieure et sont en accord avec les méthodes indigènes de travail du métal en Afrique. Keywords: archaeometallurgy, Zimbabwe, Later Farming Communities, copper and copper alloys, technology, composition Thomas Panganayi Thondhlana 8 [email protected] / Marcos Martinón-Torres 8 [email protected] * Institute of Archaeology, University College London, 31-34 Gordon Square, London WC1H 0PY, United Kingdom. DOI 10.3213/1612-1651-10119 Published online in February 2009 © Africa Magna Verlag, Frankfurt M. Journal of African Archaeology Vol. 7 (1), 2009, pp. 79-97 79 T.P. Thondhlana & M. Martinón-Torres Downloaded by University Arizona - Library on September 28 2010 Introduction Decades of archaeological excavations in northern Zimbabwe have resulted in the accumulation of a fairly large corpus of copper-based metal artefacts. These artefacts came from a variety of sources, such as human burials, hoards and some represent occasional accidental losses. The prevalence of these artefacts confirms the observation that copper and its alloys played a pivotal role in the spheres of politics, religion and economics in most past African societies (Bisson 1975, 1997, 2000; Herbert 1984). These copper-based artefacts were largely produced for non-utilitarian purposes in the form of jewellery. Noteworthy in Zimbabwean Iron Age contexts is the prevalence of metal beads of various shapes and sizes. Previous stylistic analyses have suggested a shift over time from simple cylindrical and barrel-shaped beads to complex biconical and octahedral forms (Robinson 1959: 145–146; Soper 2002: 161; Thondhlana 2005). Although these studies have helped to illuminate diachronic changes, some basic questions concerning these artefacts are yet to be addressed, such as the sources of metal, alloys employed, manufacturing techniques and technological innovations, as well as the specific roles and uses of the beads. These questions are particularly important if one considers the lack of evidence for copper production during the Farming Community period in most areas on the Zimbabwe plateau (Soper 2002: 262), meaning that it remains unclear whether these beads were manufactured locally. The main goal of this paper is to employ archaeometallurgical investigations to address some of these questions, whilst increasing our understanding of the economic, ideological, social and political dynamics of the Later Farming Communities in northern Zimbabwe. Though small in size, it will be shown in this paper that these metal artefacts are archaeologically informative. Archaeologists have recognised the importance of metal artefacts and metal working debris in the understanding of past societies and their technologies in southern Africa (Childs 1991; Miller & van der Merwe 1994; Miller, Boeyens & Küsel 1995; Childs & Dewey 1996; Miller 1996, 2001, 2002; Chirikure & Rehren 2004, 2006; Chirikure 2006). These technological studies have contributed immensely to mainstream archaeology. The present study was carried out on the premise that the physical and mechanical properties of material culture have a critical effect upon their use and perception (Jones 2004: 331). This paper therefore is not limited to discussions of techniques and characterisation of materials but goes further to ascertain the close link between human beings and artefacts. According to Tilley et al. (2006: 2), tech- 80 nological studies should be concerned with deepening our insight into how persons make artefacts and how artefacts make persons in return. At the core of such an objective is the concept of materiality, anchored on the premise that the material or physical components of the environment together with the related social practices are mutually reinforcing, to the extent that they are analytically indivisible (Jones 2004: 330). The processes of production and use of artefacts are embedded in their socio-cultural context and as such they should be studied together. Through making, using, exchanging, consuming, interacting and living with artefacts, people make themselves in the process (Tilley 2006: 61). This paper thus contributes to the recent studies of pyrotechnological materials in southern Africa, which have strived to document the metal compositions and fabrication techniques at Farming Community period sites in the Tsodilo area in Botswana (Miller 1992, 1996) and in South Africa (Miller et al. 1995; Miller 2001, 2002), helping to fill the gaps in our knowledge of pre-colonial copper metallurgy in southern Africa. Brief site profiles and description of samples The artefacts subjected to analyses in this study came from fifteen Farming Community period sites in northern Zimbabwe and additional comparative materials were sourced from two sites in southern Zimbabwe (Fig. 1). These artefacts are part of the archaeological collections held at the Zimbabwe Museum of Human Sciences (hereafter ZMHS) in Harare, Zimbabwe. As previously defined by Pikirayi (1993: 24), Northern Zimbabwe comprises the northern extension of the Zimbabwe plateau, a belt of highland over 1000 m above sea level, and the adjacent middle and lowveld areas with the Zambezi River marking the northern limits. In the East and West, the Mazowe-Ruenya and the Manyame-Angwa valleys form natural boundaries and the modern city of Harare is taken as the arbitrary southern boundary. In this work, samples were also collected from sites west of the Angwa River in northwestern Zimbabwe. This section summarises the cultural groups and broad chronologies of the sites which are discussed in this paper. As a result of their repeated and structured design sets, ceramics are the most useful tool in the development of Farming Community cultural sequences in Zimbabwe (Huffman 1974: 1). The earliest known ceramic unit of importance in this paper is Gokomere. Cylindrical metal beads were recovered from several early Gokomere Tradition contexts in southern Zimbabwe. They include ten beads from the site of Mabveni, which possibly represent the earliest known copper Journal of African Archaeology Vol. 7 (1), 2009 Downloaded by University Arizona - Library on September 28 2010 Small Size, High Value 1490 ± 120 [SR-1259]) for Gadzema (Huffman 1971: 29). Contemporary pottery decorative styles to the north-east of the Harare Tradition sites have been attributed to the Musengezi Tradition (Huffman 1971; pwiti 1996; Burrett 1998; piKirayi 2001). Metal beads were excavated at the Monk’s Kop (Mbagazewa) ossuary of the Musengezi Tradition. Two radiocarbon dates AD 1270 ± 95 (SR-100) and AD 1285 ± 95 (SR-101) are available for this multicomponent burial site (Crawford 1967: 379). The beads from this site were cylindrical in shape with some striking similarities between themselves which suggest some form of standardisation and mass production. Another bead was collected from the Musengezi Tradition site of Wazi (Soper & pwiti 1988). Archaeological evidence suggests that at the same time the area to the west of the Angwa River was occupied by Ingombe Ilede groups. These Ingombe Ilede cultural groups appear to be related to the Farming Community groups in Zambia more so than their eastern counterparts (Huffman 1974: 3). An important Fig. 1. Map of Zimbabwe showing the distribution of sites menfeature of the Ingombe Ilede groups was tioned in the text. MUY (Muyove), RYD (Rydings), KAS (Kasekete), their production and trade of copper (BurMYC (Matanda yaChiwawa), WAZ (Wazi Hill), CHE/W (Chenguruve rett 1998). garlaKe (1970) excavated two Hill East & West), BAR (Baranda), BRC (Beryl Rose Claims), MUH Ingombe Ilede sites, Rydings (Chedzurgwe) (Muchekayawa Hill), LUA (Luanze), RR (Ruanga Ruins), MK (Monk’s Kop), AE (Arlington Estate), LO (Little Over), MAB (Mabveni), GZ and Muyove which yielded one metal bead (Great Zimbabwe). each. The quantity of copper-based metal beads from these sites supposedly associated with renowned copper workers is surprisproducts on the Zimbabwe Plateau (Swan 1994), alingly very low, considering the fact that 162 sites with though some scholars question the status of these beads cross-shaped copper ingots were recorded in this area as the earliest evidence of copper production in Zim(Swan 1994: 25, 2007). The same scenario was also babwe (see miller 2003). Two calibrated radiocarbon noted at the Ingombe Ilede burials (type site) where, dates are available for the site of Mabveni: AD 180 despite extensive excavations, only five copper beads ± 120 (SR-43) and AD 570 ± 110 (SR-79) (Huffman were recorded (fagan et al. 1969: 72). 1980). A metal bead was recovered from Little Over, a site assigned to the Maxton phase of the Gokomere From the fifteenth century we see the appearance Tradition. Elsewhere, at Coronation Park in northern of Zimbabwe Tradition groups in northern Zimbabwe Zimbabwe, Maxton pottery has been dated to AD 980 (pwiti 1996: 153). This development may have been ± 100 (N-979) (Huffman 1971: 28). Three cylindrical linked to the demise of the Great Zimbabwe State in metal beads from Mabveni and Little Over were sethe South (piKirayi 2001). There have been suggestions lected from the ZHMS museum collections for further that the decline of the Great Zimbabwe State was partly study. caused by Ingombe Ilede groups in northern Zimbabwe who took control of the intraregional trade of copper Samples were also collected from a Harare Tradiand other metals, depriving their southern neighbours tion burial in the Arlington Estate which yielded metal of their earlier interests (pwiti 1991; piKirayi 2001). beads in the form of bicones, barrels and cylinders. Metal beads and artefacts were also collected from five There are no absolute dates for the site, however related Zimbabwe Tradition sites. These included Kasekete Harare Tradition burials date between the thirteenth and Matanda yaChiwawa, both located in the middle century (AD 1270 ± 60 [GRN-2341]; AD 1280 ± 100 Zambezi Valley (pwiti 1996: 77), Ruanga, a zimbabwe [Y-722]) for Graniteside to the fifteenth century (AD dry-stone structure (garlaKe 1972), Beryl Rose Claims Journal of African Archaeology Vol. 7 (1), 2009 81 T.P. Thondhlana & M. Martinón-Torres Downloaded by University Arizona - Library on September 28 2010 (Pikirayi 1998) and Baranda (Pikirayi 1993). Cylindrical shaped beads dominated all of these Zimbabwe Tradition sites in northern Zimbabwe. For comparative purposes, beads were also collected from the zimbabwe type site of Great Zimbabwe in the south-central part of Zimbabwe. By the sixteenth century Afro-Portuguese trading settlements or Feiras were established in the eastern part of northern Zimbabwe. These lasted up until the 1690s, when most of the Portuguese were expelled from northern Zimbabwe (Huffman 1971: 41; Pikirayi 1993: 113). Metal beads from Luanze, an important Portuguese period site were also collected for further laboratory studies. Contemporary to the Portuguese period settlements in northern Zimbabwe is the indigenous archaeological entity known as the Mahonje Tradition, with dates between the seventeenth century and the nineteenth century. Mahonje Tradition sites are characterised by loopholed stone-wall fortifications, often located in inaccessible high grounds that reflect defensive locations against violent Portuguese activities and those of competing local groups (Pikirayi 1993, 1996, 2001: 182). A total of fifty-two metal beads were excavated from three Mahonje Tradition sites, namely Chenguruve Hill East, Chenguruve Hill West and Muchekayawa Hill, all of which are located in the middle Mazowe River basin (Pikirayi 1993: 156). The majority of these were small biconical beads made from short triangular cross-section wire (Soper 2002: 262). A dozen of beads were collected from these Mahonje Tradition sites for further analyses. However, details of heavily tarnished and corroded articles could not be established by this method. Energy Dispersive X-Ray Fluorescence Spectrometry (ED-XRF): ED-XRF was used in this study as a screening non-invasive technique, to obtain a first assessment of the chemical composition of the beads. The analyses were performed with a Spectro X-Lab Pro 2000, using three polarising secondary targets and an evaluation method optimised for alloys. Given the small size of the beads (typically <10 mm, compared to the detector window of 25 mm), and the fact that they were placed in the chamber without any preparation or removal of corrosion patinas or encrusted soil, these results can only be reported as qualitative. The analytical totals for this type of analyses were in the range of 10 %, which highlights the low accuracy of the results. Comparisons between XRF and SEM-EDS results performed on the same beads also showed significant discrepancies. However, this technique was useful as a way of screening a relatively large number of artefacts (~50), to discriminate between alloys and to assess whether the results from the beads analysed by SEM-EDS could be extrapolated to the rest of the samples in the same type category. In addition, thanks to the low detection limits of this technique, the presence/absence of some trace elements could also be determined on a qualitative basis. Artefacts selected from the archaeological collections held at ZMHS were subsequently subjected to laboratory studies at the Wolfson Archaeological Science Laboratories of the UCL Institute of Archaeology in London, using the methods described below. Reflected-light Microscopy: Metallographic analysis of a number of these metal artefacts was carried out to understand their fabrication techniques. Metals are made up by minute crystals with distinct shape, structure, alignment and size. The factors controlling the microstructure of metals include, among others, their composition and fabrication processes (Bailey 1982: 32). Thus, analyses of the microstructure of metal objects indicate their composition and technological history. To study these crystals at microscopical level, polished metal surfaces were required. Stereomicroscopy: The surface morphology of the metal articles is a crucial element in the understanding of their construction. Initial laboratory work involved the inspection of specimens under low magnification to reveal details not readily visible to the naked eye. A stereoscopic microscope with a camera attachment was used for a first assessment of manufacturing technology, surface appearance and tool marks. This microscope offers the necessary depth of field which is useful in the establishment of three-dimensional features of specimens (Ogden 1992: 20). Surface features of the specimens sought and captured on camera included striations, gas cavities, signs of wear, tool marks and seam treatments. With permission from the ZMHS, 15 beads were sampled invasively for metallographic study. A jeweller’s saw was used to remove these specimens, which were mounted in epoxy resin and subsequently ground and polished to a ¼ µm finish. A Leica DM LM polarised reflected light optical microscope equipped with a digital camera was used to capture features such as phases, inclusions, grain structure and size, defects like shrinkages and porosity. For some specimens, the grain structure was revealed by selective intergranular corrosion; however, in some cases it was necessary to etch the polished blocks, using ferric chloride with 20 % HCl, after the SEM-EDS analyses. Analytical methods 82 Journal of African Archaeology Vol. 7 (1), 2009 Downloaded by University Arizona - Library on September 28 2010 Small Size, High Value Scanning Electron Microscopy with Energy Dispersive X-Ray Spectrometry (SEM-EDS): Detailed characterisation of a number of artefacts was carried out with a scanning electron microscope equipped with an energy dispersive spectrometer. The SEM uses electrons to generate images with better resolution at high magnification, whilst the EDS system allows compositional analyses to be carried out on very small areas or phases of the sample. The sampling size for invasive quantitative analyses was limited by the need to preserve the artefacts in line with the conditions given by the ZMHS. Therefore, SEM-EDS was used on both the metallographic polished blocks (following carboncoating to reduce charging), and on complete beads. For the complete beads, a ~1 mm2 area was abraded with a 4000 grade polishing paper to remove the patina and reveal the underlying sound metal matrix. A Hitachi S-3400N instrument, with an INCA Oxford energy dispersive spectrometer (EDS) was used for the analysis. This instrument was used at the following working conditions: working distance 10 mm; excitation voltage of 20 kV; probe current of 56.4–64.3 and a detector deadtime of 35–45 %. To enable valid composition comparisons between specimens, compositional analyses were systematically carried out by measuring three areas of 160 by 112 μm on each sample. SEM-EDS values reported here are averages of these three measurements, expressed as weight percent and normalised to 100 %. Unlike ED-XRF, SEM-EDS was carried out on sound metal, and thus the composition of different phases and inclusions was established with more confidence. As discussed below, the concentration of zinc in brass beads was considered crucial for subsequent interpretations, and thus a certified brass standard (35.7 % Zn) was analysed to check the accuracy of the instrument. The relative error for zinc was found to be of only 3.1 %. Analytical results Sample Code Type Cu Zn Sn Co Ni As Ag Sb Au Pb Gokomere Tradition MAB 1 Cylinder MAB 2 Barrel LOM 1 Cylinder ● ○ ○ ○ ● ● ○ ○ ○ ● ○ ● ○ ○ ○ ○ ○ ● ○ Musengezi Tradition WAZ 1 Disk ○ ○ ○ ○ ○ Harare Tradition AE 1 AE 2 AE 3 AE 4 AE 5 AE 11 AE 12 Barrel Barrel Barrel Bicone Cylinder Bicone Cylinder ● ● ● ● ● ● ● ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ● ○ ○ ○ ○ ○ Ingombe Ilede Tradition MUY 1 Ring RYD 1 Cylinder ● ● ○ ○ ● ○ ○ ○ ● ○ ○ ○ Zimbabwe Tradition GZ 1 MYC 1 MYC 2 MYC 3 BAR 2 BAR 3 BRC 1 BRC 2 BRC 3 BRC 5 BRC 6 BRC 7 BRC 8 BRC 9 RR 1 RR 2 RR 3 RR 4 Bicone Cylinder Barrel Cylinder Cylinder Pendant Octahedral Barrel Cylinder Cylinder Cylinder Cylinder Cylinder Ring Cylinder Cylinder Cylinder Cylinder ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ● ○ ○ ○ ● ○ ● ○ ● ○ ● ○ ○ ● ○ ● ○ ● ○ ● ○ ○ ○ ○ ● ○ ● ○ ● ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ● ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ Portuguese Tradition LUA 1 LUA 2 LUA 3 LUA 5 Barrel Barrel Barrel Barrel ● ● ● ● ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ● ○ ○ ● ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ Mahonje Tradition Gokomere Tradition materials (2nd–11th century AD) Artefacts in this group included a single cylindrical bead (LOM1) from Little Over, a site assigned to the Maxton phase of the Gokomere Tradition, and two beads (MAB1 and MAB2) from the site of Mabveni, which possibly represent the earliest known copper products on the Zimbabwe Plateau (Swan 1994: 26). These three well-preserved beads were initially analysed with ED-XRF (Tab. 1), which revealed that one was made of pure copper, whilst the other two were bronzes. Further SEM-EDS of these beads confirmed the presence of relatively high tin bronzes (Tab. 2). As CHW 1 CHW 2 CHW 3 CHW4 CHE 1 CHE 2 CHE 3 CHE 4 CHE 5 MUH 1 MUH 2 MUH 4 Bicone Bicone Bicone Bicone Bicone Bicone Bicone Bicone Bicone Cylinder Barrel Bicone ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● ● Tab. 1. Qualitative results of the ED-XRF compositional analyses of copper-based artefacts from archaeological sites in Zimbabwe (Legend: ●= major elements; ○= trace elements). Journal of African Archaeology Vol. 7 (1), 2009 83 Downloaded by University Arizona - Library on September 28 2010 T.P. Thondhlana & M. Martinón-Torres Sample Code Type MAB 1* MAB 2* MK 1* MK 2 MK 3* MK 11 MK 27 MK 28 MK 29 AE 1* AE 11 AE 12 AE 13* MUY1* RYD 1 GZ 1 BRC1* BRC 5 KAS 1 MYC 4 LUA 1* CHW 1 CHW 2* CHE 1* MUH 3 MUH 4* Cylinder Barrel Cylinder Cylinder Cylinder Cylinder Cylinder Cylinder Bicone Barrel Cylinder Bicone Bicone Ring Cylinder Bicone Octahedral Cylinder Cylinder Debris/Lump Barrel Bicone Bicone Bicone Barrel Bicone Broad chronology S (centuries AD) 2nd–7th 2nd–7th 12th–14th 12th–14th 12th–14th 12th–14th 12th–14th 12th–14th 12th–14th 13th–15th 13th–15th 13th–15th 13th–15th 15th–16th 15th–16th 13th–15th 16th–17th 16th–17th 14th–16th 14th–16th 16th–17th 17th–19th 17th–19th 17th–19th 17th–19th 17th–19th Fe 0.7 0.7 0.7 0.9 0.6 1.4 0.6 0.2 Cu 100.0 88.2 93.1 93.1 94.1 94.9 90.0 98.2 90.7 100.0 92.7 100.0 100.0 97.5 98.5 98.7 77.9 88.3 100.0 98.1 100.0 63.1 66.9 63.4 94.1 58.7 Zn As Sn Pb 11.8 6.2 6.2 5.3 5.1 9.2 1.8 8.7 Musengezi Tradition materials (12th–16th century AD) 7.3 2.5 1.5 1.3 20.7 11.7 1.2 36.5 33.1 36.6 3.1 41.3 0.4 2.8 Tab. 2. Bulk SEM-EDS results of the abraded surfaces samples* and prepared polished blocks (Results presented as wt% and normalised to 100 %). Fig. 2. Strikingly similar beads from the Musengezi Tradition site of Monk’s Kop (Mbagazewa). 84 discussed in the next section, this composition is not consistent with the known copper-based artefacts from the first millennium AD archaeological contexts in southern Africa, where it has been suggested that tin bronzes only appear in the second millennium AD (miller et al. 1995; miller 2003). The largest assemblage of metal beads in northern Zimbabwe was excavated at the Monk’s Kop (Mbagazewa) ossuary. The beads from this site were mostly cylindrical and barrel in shape (Fig. 2). Most of the Musengezi Tradition materials were in a bad state of preservation, and thus initial stereoscopic and ED-XRF analyses were inconclusive. To compensate for this, seven specimens (MK1, MK2, MK3, MK11, MK27, MK28 and MK29) from Monk’s Kop were subjected to SEM-EDS analyses after the removal of corrosion products. The SEM-EDS results revealed that they were tin bronzes with significant traces of iron (Tab. 2), and containing few inclusions. Metallographic analyses showed important fabrication information. For example the etched section of bead MK2 revealed deformed grains and strain lines, suggesting that there was heavy working after annealing (SCott 1991: 8). The seam of the same specimen was unique, consisting of a straight edge with vertical striations parallel to it (Fig. 3). Thus it is likely that the seam was not hammered into shape, but that a tong was used from the outside to squeeze together the metal ends to meet. The other four specimens showed a well developed recrystallised structure with twin lines, indicating that the beads were annealed after cold-working (SCott 1991: 7). Unlike the MK2 specimen, the metallographic analyses of the seams of these four beads revealed compressed grains at the edge of the metal strip (Fig. 4). This grain compression is associated with the oblique cutting with a chisel (miller & Van der merwe 1994: 108). A single disc bead was recovered from the Wazi Hill, another Musengezi Tradition site (Soper & pwiti 1988). This is the only disc bead known from northern Zimbabwe; however, similar disc beads are prevalent in western Zimbabwe Later Farming Community contexts (roBinSon 1959: 145; tHondHlana 2005). ED-XRF analyses of the Wazi disc bead show copper as the main element, but they also reveal potentially significant levels of arsenic (Tab. 1). However, considering the accuracy levels discussed above, further analyses Journal of African Archaeology Vol. 7 (1), 2009 Downloaded by University Arizona - Library on September 28 2010 Small Size, High Value 250 µm 250 µm would be needed to confirm this alloy as arsenical copper. Indeed, in the bead BRC5 from Beryl Rose Claims, discussed below, ED-XRF results indicated similar traces of arsenic, but subsequent SEM-EDS of sound metal showed no significant levels of this metal. Harare Tradition materials (13th–15th century AD) Beads from the Harare Tradition burial at Arlington Estate were relatively larger and heavier than those from other sites in northern Zimbabwe. The bead assemblage Fig. 3. Longitudinal section of cylindrical bead (MK2), unetched, showing deformation of the outside part of the seam as the metal ends were squeezed together. Photomicrograph under plane polarised light (50x). Fig. 4. Section of cylindrical bead (MK11), unetched, showing grain deformation caused by cutting the edge with a chisel. Photomicrograph under plane polarised light (50x). from this site included well preserved bicones, barrels and cylinders. Initial qualitative chemical characterisation of seven beads with the ED-XRF indicated that the majority of these beads were nominally pure coppers (Tab. 1). This pattern was confirmed through SEMEDS of four samples (Tab. 2). Another highlight of the compositional results was the lack of traces of zinc and lead, elements found in many beads from other sites (Tab. 1). Metallographic analyses of two beads (AE 11 and AE 12) revealed prominent longitudinal cracks Journal of African Archaeology Vol. 7 (1), 2009 85 Downloaded by University Arizona - Library on September 28 2010 T.P. Thondhlana & M. Martinón-Torres 250 µm 25 µm within the well-preserved metal matrix (Fig. 5). These cracks were certainly not caused by corrosion because they do not show any penetration of corrosion products, and are therefore likely to originate from the manufacturing process. Midsection cracking of this nature is often associated with overworking, and it is difficult to remove with further annealing and working (SCott 1991: 101). This was also supported by the examination of etched sections, showing slip lines resulting from cold working in the final stage (Fig. 6). 86 Fig. 5. Section of cylindrical bead (AE11), unetched, showing internal deformities. Photomicrograph under plane polarised light (50x). Fig. 6. Section of cylindrical bead (AE11), etched in ferric chloride solution, showing slip lines. Photomicrograph under plane polarised light (500x). Ingombe Ilede Tradition materials (15th–16th century AD) Two well preserved beads (MUY1 and RYD1) were excavated from two Ingombe Ilede sites, Rydings and Muyove (garlaKe 1970). The ‘bead’ from Rydings, formed by spiral turns, possibly represents a fragment of a heavy bangle. The bead from Muyove can best be classified as a ring rather than a cylinder because of its short length. Both ED-XRF and SEM-EDS results showed that the two beads were made of arsenical copper (Tabs. 1 and 2). In our current state of knowledge, Journal of African Archaeology Vol. 7 (1), 2009 Small Size, High Value Downloaded by University Arizona - Library on September 28 2010 these compositional results only have parallels with specimens from the site of Great Zimbabwe, in southern Zimbabwe (Tab. 2). Noteworthy is the suggested trade of copper from Ingombe Ilede metal workers to Great Zimbabwe during the period under consideration (Walsh 1997), which might explain this finding and thus deserves further attention. However, the inclusion chemistry of the Ingombe Ilede arsenical copper beads differed from the Great Zimbabwe specimens. One biconical bead (GZ1) from Great Zimbabwe contained elongated bismuth and copper sulphide inclusions, whereas the specimen (RYD1) from Rydings contained numerous lead globules (Tab. 3). Metallographic analysis of the arsenical copper beads was not possible because the etching process was not successful. However, the stereomicroscopy investigation of a bead (MUY1) from Muyove also provided an important insight into the fabrication technology. It was established that there were variations in the thickness and absence of longitudinal striations on the square-sectioned wire used in the manufacture of this bead, which suggests that it was made with the wrought technique, rather than by drawing (see below for comparison). Zimbabwe Tradition materials (14th–17th century AD) Metal beads and artefacts were also collected from five Zimbabwe Tradition sites of Ruanga Ruin, Beryl Rose Claims, Baranda, Matanda yaChiwawa and Kasekete. Although cylindrical beads dominated at these sites, materials collected for analyses also included a unique pendant from Baranda, two non-ferrous metal lumps from Matanda yaChiwawa and an octahedral bead from Beryl Rose Claims (Figs. 7–9). Beads from the site of Great Zimbabwe were also analysed for comparison (Fig. 10). Both ED-XRF and SEM-EDS compositional analyses of the Zimbabwe Tradition samples from the North revealed the incidence of pure copper beads, but also the abundance of relatively high-tin bronzes. Potentially noteworthy are also the generally higher traces of other elements, including zinc, nickel, arsenic, silver and lead, which (although not reported quantitatively here) differentiate these beads from those of sites predating the Zimbabwe Tradition in northern Zimbabwe (Tabs. 1 and 2). These compositions also differ from the analysed bead from Great Zimbabwe (GZ1), which consists of arsenical copper (Tab. 2). Metallographic analysis could not be carried out on unique specimens like the pear-shaped pendant from Baranda (BAR3), or the octahedral bead from Beryl Rose Claims (BRC1), although both of them clearly constitute cast bronze artefacts (Figs. 7 and 9). The latter bead is strikingly similar to others reported from contemporary Nyanga Complex sites of Leaping Waters and Matinha in the Eastern Highlands of Zimbabwe (Soper 2002: 262). Another unique specimen which was not analysed metallographically is the copper bead MYC1 from Matanda yaChiwawa. Stereomicroscopic examination of this bead showed the remnants of a casting sprue (Fig. 11). The shape of the bead, together with the absence of flash lines, makes it implausible that it could have been cast by any method other than lost-wax. Although cast copper and copper alloy beads are very rare, locally-made cast gold beads have been recorded at several second millennium AD sites in southern Africa (Oddy 1984, 1991). The metallographic study of beads BRC5 and KAS1 showed twin lines on recrystallised grains, indicative of working and annealing. The latter bead contained a good number of copper sulphide inclusions. Finally, one of the two amorphous lumps of metal found at Matanda yaChiwawa, of approximately 2 cm in diameter, was also analysed. This consisted of copper containing small amounts of tin (1.2 %) and very profuse sulphide inclusions, resulting in an average sulphur content of 0.6 % (Tab. 2). The abundance of shrinkage porosity, together with the lack of any indication for hot or cold working beyond the melting, reinforce the initial interpretation of this sample as resulting from metal spillage, probably during casting. As such, this suggests that beads, or any other copper-based objects, could have been manufactured locally at the site. The identification of a cast bead on the same site strengthens Sample Code S Fe Ni Cu Zn As Se Sn Pb Bi MK2 84.7 14.2 1.1 MK11 83.7 4.6 11.7 AE12 71.2 28.8 RYD1 12.4 87.6 RYD1 48.1 49.2 0.5 2.2 MYC4 20.4 79.6 MYC4 15.3 2.4 20.3 62.1 KAS1 84.4 11.7 3.9 GZ1 17.7 82.0 GZ1 13.9 0.9 85.3 LUA1 17.2 81.1 2.2 CHW1 8.3 5.4 86.3 MUH3 69.9 2.5 19.5 5.0 Tab 3. SEM-EDS results of the analyses of primary inclusions in the metal matrix. Elements in weight % and normalised to 100 %. Journal of African Archaeology Vol. 7 (1), 2009 87 T.P. Thondhlana & M. Martinón-Torres Downloaded by University Arizona - Library on September 28 2010 Fig. 7. Unique pendant (BAR3) from the Zimbabwe Tradition site of Baranda. Fig. 8. Melted metal lumps from the Zimbabwe Tradition site of Matanda yaChiwawa. Fig. 9. A unique octahedral bead (BRC1) from the Zimbabwe Tradition site of Beryl Rose Claims. 88 Journal of African Archaeology Vol. 7 (1), 2009 Small Size, High Value Downloaded by University Arizona - Library on September 28 2010 Mahonje Tradition materials (17th–19th century AD) The majority of Mahonje Tradition beads, from three sites in the middle Mazowe River basin, were small biconical beads made from a short triangular-section wire. These metal beads were previously published as copper beads (Pikirayi 1993: 157, 2003). However, ED-XRF surface analyses showed that most of the specimens — notably, including all of the bicone beads — were highzinc brasses (Tab. 1). SEM-EDS analyses confirmed zinc contents above 33 wt% in all cases (33–41 %), together with traces of lead (Tab. 2). The few Mahonje Tradition beads not found to be brasses were some cylinder and barrel specimens from Muchekayawa Hill. SEM-EDS on one of them showed the presence of both tin and zinc in levels of 3 % each (Tab. 2), which might constitute an unintentional alloy resulting from scrap recycling. Fig. 10. Biconical beads from the Zimbabwe Tradition site of Great Zimbabwe attached on a fibre core. Fig. 11. Cast bead (MYC1) from the Zimbabwe Tradition site of Matanda yaChiwawa with a casting sprue still adhering on its surface. Portuguese period materials (16th–17th century AD) The site of Luanze has distinctive glazed wares, rectangular buildings of European style, and the absence of locally made pottery, all of which suggest definite Portuguese presence (Garlake 1967; Pikirayi 2001: 177). The beads from Luanze were all barrel shaped and in a good state of conservation. Initial ED-XRF chemical analyses of four barrel beads from this site revealed that they were made of pure copper. Only one bead from this site was subjected to metallographic study, which revealed an annealed grain structure, containing elongated sulphide inclusions. Close stereoscopic inspection of the brass beads revealed parallel longitudinal striations, clearly indicating that the wire was manufactured by drawing. Wire drawing is a process whereby a cast or hammered rod of metal is made longer and thinner by pulling it through a hole in a ‘draw-plate’ (Ogden 1992: 46). The wire drawing process is repeated through consecutively smaller perforations until the wire is of the desired gauge. In this case, the holes in the draw-plate would have been triangular, to achieve the desired shape. It is interesting to note that the mechanical properties of brasses change quite dramatically in this compositional range: with zinc contents in excess of 35 %, brasses become much harder, and their percentage elongation decreases (CDA 1962, 1963). Thus, the drawing of these brass wires must have been quite labour intensive, and probably required hot working, as reflected in their microstructure (Fig. 12). It can thus be suggested that a particular colour was sought with the alloy compositions, rather than a technically easier manufacture. Discussion: metal sources, manufacturing techniques and social values The analytical study of beads from northern Zimbabwe has revealed some insights upon which the questions outlined in the introduction can begin to be addressed. The technical information embodied in these archaeological artefacts reflects the context in which they were manufactured, traded and used. Not only can we identify the range of metals and alloys available to different groups, and changes over time, but also patterns in the selection and use of metals and manufacturing techniques that might be attributed to specific technological or cultural traditions. This information is also important in suggesting possible sources of raw materials and/or finished products. Journal of African Archaeology Vol. 7 (1), 2009 89 Downloaded by University Arizona - Library on September 28 2010 T.P. Thondhlana & M. Martinón-Torres 25 µm Fig. 12. Section of biconical bead (CHW1), etched in ferric chloride solution, showing grains Figure 12: Section biconical bead (CHW1), etched in ferric showing with annealing twinsof and inclusions. Photomicrograph under planechloride polarisedsolution, light (500x). grains with annealing twins and inclusions. Photomicrograph under plane polarised light BeadWidth compositions (500x). of the image 0.2 mm. The compositional analyses allowed us to establish the range of metals and alloys available to manufacturers and consumers in northern Zimbabwe. Besides copper, at least three copper alloys were utilised, namely tin bronze, arsenical copper and brass. A ternary alloy of copper, zinc and tin was also represented by one specimen (MUH3) from the seventeenth to nineteenth century site of Muchekayawa Hill. Although the sample is still small, it is worth highlighting some trends that may be further questioned in future studies. The following discussion on bead compositions is based on the data reported in Tables 1 and 2, and summarised graphically in Figures 13 and 14. Copper and tin bronze appear as the metals most frequently used for beads during the first half of the second millennium AD (Fig. 13). Noteworthy is the occurrence of two high tin bronze beads in Early Farming Community (first millennium AD) contexts at Mabveni and Little Over. According to current knowledge, tin bronzes were not used in southern Africa before 1000 AD (Miller et al. 1995: 44). The possibility that these beads represent an intrusion into earlier Gokomere Tradition contexts is therefore highly plausible. Indeed such an argument was presented for European glass beads that post date 1836, found in association with Gokomere pottery at the same site of Mabveni (Wood 2000: 78). 90 The earliest securely dated tin bronze beads from northern Zimbabwe in this study were excavated at Monk’s Kop (Mbagazewa) a site dating between the twelfth and fourteenth century AD (Crawford 1967). Tin bronzes are also present in the roughly contemporary (although possibly later) Harare Tradition burial at Arlington Estate, although the majority of the beads here appeared to have been made of copper. The binary alloy appears again as the prevalent metal in Zimbabwe Tradition sites, dated to the third quarter of the second millennium AD. The appearance of tin bronzes during the first half of the second millennium AD, although not exceptional, raises some critical issues. Archaeomining and archaeometallurgical studies have established that indigenous miners and metalworkers produced copper at least from the second half of the first millennium AD in southern Africa (Summers 1969; Swan 2002). Tin bronze metallurgy, however, presents some major problems because the history of tin mining before the middle second millennium AD in the region still remains obscure (Chirikure et al. 2007). The only unequivocal source of tin during the pre-colonial period in southern Africa is Rooiberg, in South Africa, where an estimated 18,000 tonnes of ore had been mined in preindustrial times (Grant 1990). Available calibrated radiocarbon and AMS dates of tin mining and smelting operations at Rooiberg are AD 1426– 1633 (Grn-5138) and AD 1436–1648 (ETH-5127) Journal of African Archaeology Vol. 7 (1), 2009 Cultural Affiliation Mabveni Gokomere Mabveni Gokomere Monks Kop Musengezi Object MAB 1 MAB2 MK1 100,0 88,2 93,1 11,8 6,2 0,7 Monks Kop Musengezi 100% Monks Kop Musengezi 95% MK2 93,1 6,2 0,7 MK3 94,0 5,3 0,7 Monks Kop Musengezi 90% MK11 94,9 5,1 Monks Kop 85% Musengezi MK27 90,0 9,2 Chemicalcomposition(wt%) Site Cu Sn Zn As Fe Pb S Small Size, High Value 0,9 Beryl Rose Zimbabwe Claims 88,3 MUH4 MUH3 CHE1 CHW2 LUA1 CHW1 KAS1 BRC1 GZ1 RYD1 MUY1 AE13 AE12 AE11 AE1 MK29 MK28 MK27 MK11 MK3 MK2 MK1 MAB2 BRC5 KAS1 Kasekete Zimbabwe Mahonje Luanze Portuguese LUA1 Chenguruv Mahonje CHW1 e Hill West Cultural affiliation Downloaded by University Arizona - Library on September 28 2010 MAB1 MK28 98,2 1,8 As 75% Monks Kop Musengezi MK29 90,7 8,7 0,6 Zn 70% Sn Arlington Harare AE1 100,0 65% Estate Cu Cultural affiliation Unalloyed copper Arsenical copper Bronze Brass Arlington Harare AE11 92,7 7,3 Musengezi 1 7 60% Estate Harare 7 1 Arlington 55% Harare AE12 100,0 Ingombe Ilede 3 Estate Zimbabwe 6 16 Arlington 50% Harare AE13 100,0 Portuguese 4 Estate Mahonje 1 13 Muyove Ingombe MUY1 97,5 2,5 Ingombe RYD1 98,5 1,5 Rydings Beadcodes Zimbabwe GZ1 98,7 1,4 Great Zimbabwe Beryl Rose 77,8(in wt%20,7 1,4 analysed Fig. 13.Zimbabwe Elemental BRC1 concentrations and normalised) of the samples Claims BRC5 Monks Kop 80% Musengezi with SEM-EDS. 11,2 100,0 100,0 63,1 36,5 66,9 33,1 63,4 36,6 0,4 Portuguese Chenguruv Mahonje e Hill West CHW2 Zimbabwe Chenguruv Mahonje e Hill East CHE1 MuchekayaIngombe Mahonje Ilede MUH3 wa Hill Muchekaya Mahonje MUH4 wa Hill 94,2 2,9 58,7 3,0 41,3 Harare Musengezi 0% 20% 40% 60% Percentage of beads Unalloyed copper Arsenical copper respectively (Grant 1994), which are slightly later than the introduction of tin bronzes in southern Africa and indeed at Monk’s Kop. Other sources of tin in pre-colonial southern Africa have been suggested, including Rusape and Masvingo, in the south-eastern part of Zimbabwe (Prendergast 1979; Swan 1994: 28, 1996), but the archaeological evidence for these is inconclusive (Chirikure et al. 2007). Against this background, it is not possible to make any firm suggestion as to the potential origins of the tin present in the Zimbabwean bronze beads. It is worth mentioning, however, that a good number of the bronze beads analysed by SEM-EDS showed traces of iron, which were not identified in the pure copper or brass samples (Tab. 80% Bronze 100% Brass Fig. 14. Trends of metal and alloys use against cultural affiliation in northern Zimbabwe. 2). This might imply that iron was added as an impurity with the tin. Previous analyses of Rooiberg tin ingots have shown significant amounts of iron (Killick 1991; Grant 1994; Miller et al. 1995: 43), and hence a link between the two is plausible. Only further analytical work, ideally involving lead isotope analyses, will be able to ascertain this point. Another aspect deserving attention is the apparently different patterns of impurities detected in the bronze beads found in Zimbabwe tradition sites when compared to those of Gokomere and Harare Tradition sites. As noted above, Zimbabwe Tradition beads show generally stronger signatures of nickel, arsenic, silver and lead. Journal of African Archaeology Vol. 7 (1), 2009 91 T.P. Thondhlana & M. Martinón-Torres Downloaded by University Arizona - Library on September 28 2010 Given the qualitative nature of our XRF data (which discouraged us from presenting numerical values in Tab. 1), these observations should only be taken as strands for further enquiry. Should these dissimilarities be confirmed, they would be indicative of different sources of copper and/or tin, or at least suggestive of different technological processes resulting in distinctive chemical signatures. The best known copper mine in the region, exploited during the second millennium AD, is that of Copper Queen, located within the area of influence of Ingombe Ilede groups (Swan 2002). However, no data are available regarding the mineralogy and composition of these ores, nor is there any definitive archaeological evidence of copper smelting in the area. Turning to arsenical copper beads, these artefacts were confined to the Ingombe Ilede Tradition sites found to the west of northern Zimbabwe, and it seems that arsenical copper was not widely used in our study area. Intentional production of arsenic usually requires advanced production processes, owing to the fact that arsenic is a volatile metal and an attempt to smelt it from its ore will normally produce just gas (Craddock 1995: 284). Moderately arsenicrich coppers, however, could be produced more easily by the direct co-smelting of copper and arsenic ores (Lechtman & Klein 1999), and this is probably the case here. Occasional occurrences of arsenical coppers have been encountered in Later Farming Community period contexts in southern Africa. They include two arsenical copper ingots from Rooiberg, dated to the eleventh and thirteenth centuries AD, containing arsenic ranging from 14 % to 19 % (Grant et al. 1994: 90). Such high arsenic levels would make the metal unworkable, and indeed it has been suggested that these ingots were produced from the erroneous addition of annabergite, a hydrated nickel arsenate similar in colour to copper ore, to a copper smelt (Friede 1975: 185). Thus arsenic-rich ores were plausibly exploited in Rooiberg, but it is also possible that they were available further North, in northwest Zimbabwe. If one subscribes to the idea that Ingombe Ilede groups sourced and distributed copper metal to their eastern neighbours (Pwiti 1991; Burrett 1998; Pikirayi 2001), it is intriguing that the only arsenical copper beads documented in northern Zimbabwe come precisely from the Ingombe Ilede area. In view of the overall scarcity of beads in these sites, and the fact that they are made of a different metal, it is tempting to think that Ingombe Ilede groups held a somewhat different value system, where beads were a lesser important component even as burial goods. the southern site of Great Zimbabwe, as this would appear to strengthen the suspected links between Ingombe Ilede and Great Zimbabwe (Walsh 1997). In contrast, the Zimbabwe Tradition sites in the North yielded only copper and bronze beads. Thus, although Zimbabwe Tradition communities maintained customs such as building and pottery styles, the beads indicate an adaptation to the potentially different availability of metals in the North. At the Portuguese period site of Luanze, pure copper seems to have prevailed. This is a rather interesting point, as one would have expected to find an assortment of exotic copper alloy metals since this was a Portuguese settlement. Lastly, brass metal beads were confined to the later Mahonje Tradition sites. Brassmaking technology presented practical challenges to pre-modern metal workers in many regions. Zinc is an extremely volatile metal, which explains why it was a relatively late comer in the history of metallurgy. Before the inception of zinc distillation, brass was made by a process known as cementation, which involved the heating of metallic copper with zinc ore and charcoal in a closed crucible, thus making the alloy directly (Martinón-Torres & Rehren 2002; Craddock & Eckstein 2003; Rehren & Martinón-Torres 2008). However, the maximum zinc content achievable in cementation brasses is between 28 % and 33 % (Newbury et al. 2005), that is below the zinc levels in the Mahonje beads (33–41 %). Furthermore, cementation brasses generally contain small levels of iron (Craddock 1985: 26), which were not detected in these objects. Based on historical evidence, the exploitation of zinc ores in sub-Saharan Africa was unknown before the nineteenth century; hence brasses in early archaeological contexts in southern Africa can only be explained in relation to contacts with other regions (Herbert 1984: 97; Bisson 1997: 130). On the basis of both technological and historical facts, the plausible source of brass metal in the later Mahonje sites is India, a region where zinc was produced by distillation since the early second millennium AD (Craddock et al. 1998). Contact between southern Africa and India was long established even before the coming of the Portuguese to the region. Evidence of imported brass is also consistent with glass beads of Asian origin recovered from the same Mahonje Tradition sites (Pikirayi 1993, 2003). Elsewhere in the region, brass beads with similar zinc contents were found in early second millennium AD deposits at the sites of Phalaborwa, Parma and Mapungubwe in South Africa (Miller 2001, 2002: 1127). It is also interesting to point out that the only other arsenical copper beads identified come from 92 Journal of African Archaeology Vol. 7 (1), 2009 Small Size, High Value Downloaded by University Arizona - Library on September 28 2010 Manufacturing techniques The manufacturing techniques used in the crafting of these beads also help us address issues of source and technological innovations. It was established that most of these artefacts were manufactured by a relatively simple repertoire of techniques, typically involving the use of short rods of wire that were folded into a circular shape, typically with a final annealing stage. Only mechanical joins in the form of overlapping seams, carefully treated from the outside, were noted on some beads. Importantly, without metallographic analyses, those beads could have been misidentified as cast forms. Both metallographic and compositional analyses of the seams revealed that soldering, i.e. the joining of metals with an alloy of lower melting temperature, was not employed. The absence of the soldering technique has also been noted for second millennium AD gold articles in southern Africa (Oddy 1984, 1991), which led Oddy (1984) to conclude that the artefacts were crafted by indigenous Africans. The same argument may be extended for these copper-based metal beads from northern Zimbabwe. The fabrication methods employed in the production of these artefacts seem consistent with our knowledge of the technology of the second millennium AD (Miller & van der Merwe 1994; Miller 1996, 2001). The same cold working and annealing techniques were used by indigenous metalworkers from the Tsodilo area in Botswana from the first millennium AD (Miller 1996). proposes that it was introduced by contacts along the east coast. The absence of wire drawing knowledge in Central Africa, an area with a long history of metal production, cements the argument for foreign influence (Bisson 2000: 105). Although it would be possible for the Mahonje beads to have been imported in their final shape, it is more likely that indigenous metalworkers manufactured the beads from imported metal. This assertion is supported by seventeenth-century and later historical accounts recording such a practice (Ellert 1993: 109–110; Maggs & Miller 1995; Miller 2002: 1127); but also by the fact that the peculiar bead shape seems adapted to the African style. Although their recovery was low, cast forms were also recorded in our sample. Only three beads were positively identified as cast forms after stereomicroscopic analysis, all of them from Zimbabwe Tradition sites. There is a possibility that for the more complex forms like the octahedrals, the lost-wax technique was employed, but these beads were possibly not manufactured in it the region since such technical sophistication was absent outside West Africa during the pre-colonial period (Herbert 1984: 87). However, the fact that one unfinished cast bead was found at Matanda yaChiwawa, where melted metal lumps were found too, is strongly suggestive of indigenous workmanship. Consumption and value Beads with identical shapes, however, were manufactured using different techniques, and thus subtle “technological choices” may indicate a diversity of technological traditions. Noteworthy here are the triangular-section metal wires used to produce biconical beads. These wires were either hammered into shape, as represented in the bicones from Arlington and Great Zimbabwe, or they were drawn through a plate, as was the case with the Mahonje Tradition beads. In this regard, the technological studies add another dimension to typological analyses based on shape. The presence of wire-drawn biconical beads with longitudinal surface striations deserves further comment. The chronological development of the wire drawing technique has been studied by historians of technology. The technique appears in the early Middle Ages in Europe (Oddy 1991: 193). In southern Africa, wire drawing devices like drawing plates and tongs were excavated at several archaeological sites dating to the fourteenth century AD (Fagan et al. 1969: 92–93). Oddy (1991: 194) suggests that wire drawing was an independent invention in Africa, whilst Bisson (2000: 105) highlights the confinement of the technique to eastern, east-central and southern Africa, and therefore After a metal is won from an ore, it is given social roles that may change during its lifetime (Childs & Killick 1993: 330). The social roles and values of different metals are largely dependent on their physical properties, including aspects such as hardness and corrosion resistance but also sensorial dimensions such as colour or smell. The value of different metals is thus conditioned by physical factors but also culturally constructed (Jones 2004), resulting in a variety of economic and symbolic values given to specific metals and object forms by different societies. Paradigmatic examples of the culture-specific value of metals are provided by various historical societies in different regions that, unlike Europeans, esteemed brass much more highly than gold (Miller & Markell 1993; Garenne-Marot & Mille 2007; Martinón-Torres et al. 2007). The overall significance of copper and its alloys to traditional African institutions has been firmly established (Herbert 1984, 1996) but the internal diversity of the values of different metals within southern African communities is more difficult to reconstruct. As stated by Caple (2006: 9), the context in which the objects appear in the archaeological record invariably helps define their Journal of African Archaeology Vol. 7 (1), 2009 93 T.P. Thondhlana & M. Martinón-Torres Downloaded by University Arizona - Library on September 28 2010 meaning, and unfortunately the contexts for the beads analysed here are not well understood in all cases. There is no doubt that copper and bronze were used as prestige commodities in northern Zimbabwe, as supported by the evidence of the beads deposited in burials associated with the elite at Arlington Estate and Monk’s Kop. At Ingombe Tradition sites, however, although the importance of copper is widely attested in the form of ingots, the archaeological evidence suggests that beads did not play such an important role in personal or funerary contexts. While no overall correlations were found between bead types and metal composition across the different sites, there is a prominent trend in the fact that certain alloys are apparently constrained to specific sites, and vice versa (Fig. 14). Although this could simply be a bias of our relatively small sample size, it may also be an indication of the different accessibility of different groups to certain metals, or perhaps a diversity of cultural appreciations. Another very significant pattern across all of the beads analysed is the lack of ternary alloys, with only one exception to this out of approximately fifty objects. Ternary or quaternary copper alloys containing combinations of arsenic, tin and/or zinc are often taken as indicative of haphazard recycling, where different copper alloys are melted together in order to be recast into new objects. The well-defined compositions of these beads denote that they were not normally a part of a metal recycling system, not even when they were not deposited in burials. This further highlights the important cultural value they may have held, beyond their economic value as metals. Finally, some of the metal articles are a clear testimony of trade and as such allow us to interpret the changing trading relations in northern Zimbabwe during the second millennium AD. Copper-based metal articles were excavated in areas which are unlikely to have produced them due to lack of copper ores and production evidence. The predominance of brass beads from the seventeenth century can be explained with reference to the coast-interior trade, initiated by the Swahili merchants and later by the Portuguese in the last half of the second millennium AD (Pikirayi 2003). This, however, is not meant to claim that these beads were used as a currency. Whereas the value of copper ingots in the form of manilas (West Africa), H-shaped, flanged and handa type ingots (Central Africa) as general purpose currency has been established beyond any reasonable doubt (Bisson 1975, 2000), these beads are unlikely to have functioned as a form of general purpose currency, due to their size variability and overall lack of standardisation (Bisson 1975). 94 Conclusion and future prospects This preliminary analytical study of copper based metal articles from northern Zimbabwe showed that four different alloys were employed. Stereomicroscopic and metallographic analyses revealed a range of manufacturing methods that, in general, do not suggest foreign influence, and as such credit should be given to indigenous African metal workers. The compositional results indicate that there was a shift from the use of copper and bronze to high zinc brasses through time. Overall, these data conform well to the socio-economic and political dynamics of the second millennium AD in northern Zimbabwe. However, future work should focus on the internal diversity noted to assess the extent to which environmental, political or cultural factors conditioned the different trends observed across the sites. Lacking reliable contextual information and a larger data set, it is difficult to determine the socioideological role of copper and its alloys, beyond general assertions of their important cultural significance. This problem will only be overcome if archaeologists recognise the importance of metals and their related debris as a critical part of the Farming Communities archaeological record. Future archaeometallurgical research in northern Zimbabwe should be complemented with geological information, namely through archaeologically informed geochemical and isotopic surveys of the possible ore sources, which should allow a more systematic insight into the patterns of trade and consumption of metals. Besides artefacts, the analysis of metal production debris from archaeological sites in Zimbabwe should receive the academic attention that it deserves. Although investigations of metal artefacts provide important information, complementary data can be gained with the analysis of production remains. Long-term, systematic archaeometallurgical projects should be carried out in areas associated with ancient copper mining to establish smelting production, such as the north-western part of Zimbabwe, whilst extant museum assemblages continue to be analysed. However, this is not to say that archaeometallurgical research should be constrained to Zimbabwe. In the second millennium AD, the Zimbabwe plateau was part of successive world systems connected with Islamic and Christian cultures, and also linked by long distance trade of metals to far away areas within the African continent. Thus, only integrated approaches will allow a sound understanding of the cultural and technological dimensions of pre-colonial African metals. Journal of African Archaeology Vol. 7 (1), 2009 Small Size, High Value Downloaded by University Arizona - Library on September 28 2010 Acknowledgements An earlier version of this work was submitted in partial fulfilment of the requirements of an MSc dissertation in Technology and Analysis of Archaeological Materials at the Institute of Archaeology, University College London (Thondhlana 2007). Financial support was made available from the European Union, through a fellowship under the Marie Curie Early Stage Research Training Programme (contract MEST-CT-2004-514509) to one of the authors (TPT). We are indebted to the late Professor Peter Ucko for his unreserved support of African indigenous archaeology, and to Professors Thilo Rehren and Gilbert Pwiti for their precious advice. Previous drafts of this paper were read and commented upon by Dr Shadreck Chirikure, Dr Simon Hall, Dr Robert Soper, Rob Burrett and Paul Hubbard and we would like to thank them for their important suggestions. We would also like to thank the National Museums and Monuments of Zimbabwe (NMMZ) which gave us temporary export permits and also allowed us to carry out invasive sampling on some of their collections. The technical assistance provided by Kevin Reeves, Philip Connolly and Simon Groom at the UCL Institute of Archaeology is also gratefully acknowledged. We are also grateful to Professors E.W. Herbert and D. Killick and the editors of this journal who suggested valuable changes to our earlier draft. However, the errors and omissions in this paper remain our sole responsibility. 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