Each element has different number of protons. Nuclear Energy and radiation Atom ingredients: Proton (positive charge) – charge = 1.6 x 10-19 Coulombs mass = 1.66 x 10-27 kg. Neutron (no charge) – no charge mass = 1.66 x 10-27 kg. Electron (negative charge) – charge = -1.6 x 10-19 Coulombs mass = 9.10 x 10-31 kg. "I am become Death, the destroyer of worlds.“ –J. R. Oppenheimer (quoting Bhagavad Gita) Phys 1010, Day 14: Questions? Nuclear Weapons 16.1 Nuclear Power 16.2 Reminders: HW Today Review next Tues Exam Next Thursday 7:30 PM Oxygen has 8 protons, 8 neutrons: hydrogen 1p deuterium 1 p, 1n helium 2 p, 2 n Uranium 238 92 p, 146 n Oxygen has 8 protons, 8 neutrons Consider a nuclei with 7 protons, 7 neutrons (nitrogen atom)… what if we want to add another proton to make oxygen (8 protons): Consider a nuclei with 7 protons, 7 neutrons… what if we want to add another proton to make oxygen: What will we need to do to get proton stuck to nucleus: b. the closer it gets, the harder you have to push, will take lots of work ... Lots of energy What will we need to do to get proton stuck to nucleus: a. just give it a little push so it will hit nucleus dead on and it will drift towards nucleus and stick. b. the closer it gets, the harder you have to push, will take lots of work c. you’ll need to push really hard at first and then less as you get closer d. you’ll have to push the proton towards the nucleus with a fixed amount of force (constant force). Like charges repel: 7 positives One positive Big repelling force Bigger repelling force Force on proton given by Coulomb’s law (k = Coulomb’s constant): In general: Force = k x charge of object #1 x charge of object #2 (distance between objects)2 F = k x charge of nucleus in coulombs x charge of proton in coulombs (distancenucleus-proton)2 The smaller the distance the larger the force! What if threw proton so starts out going towards nitrogen nucleus with a lot of speed (lots of kinetic energy)? Starts with lots of kinetic energy Repelling force from nucleus slows down proton Proton’s kinetic energy converted into electrostatic potential energy, as it gets closer to nucleus Potential energy curves- represent energy to bring particles r, separation distance together. Gravity energy analogy. Potential energy Kinetic energy r, separation distance Potential energy curvesrepresent energy to bring particles together. separation distance, r Potential energy = k x charge of 7 proton nucl. x charge of single proton Potential energy at separation distance of r Kinetic energy Gravity energy analogy. separation distance, r if at center, want to roll down hill/fly apart … lots of electrostatic potential energy 5 (separation distance) Charge of 1 proton = 1.6 x 10-19 Coulombs; Charge of 7 protons=11.2 x 10-19 C So at 10-15 m away (~ radius of nucleus), Potential energy = 8.99 x 109 N m2/C2 x 11.2 x 10-19 C x 1.6 x 10-19 C (10-15 m) = 1.61 x 10-12 Joules = 10 million electron Volts. (1 electron volt = energy gained 1 chemical reacction. So this is 10 millions times bigger/atom) 1 potential energy curve for bringing electron in to proton Potential energy curve (Energy vs. separation distance) for bringing electron in to proton a. This curve would be flat, not going up or down b. look like bringing a proton into a proton except upside down so going down instead of up. c. would look same as proton on proton b. look like proton on proton except upside down so going down. r r Lots of EPE when separated Electron and proton get pulled together, curve tells us that must add energy to separate electron and proton. electron wants to roll into center as close as possible. 7 How can a bunch of repulsive positively charged protons stick together? Like hopper toy- really strong nuclear force between protons and neutrons overwhelms electrical force if really close together. Electrical force is like gravity, pushes over distance. like nuclear force, only strong when very close (protons and neutrons only feel this if they can hold hands). like double sticky tape… only works if in close contact. Neutrons help with this force (more neutrons further up the table suction cup or springNuclear force- Why like this? That is the way nature is! Stabilizing effect of neutrons in the nucleus … why do you need them? Add neutrons They don’t repel anyone. They still have the Strong force The bind protons and neutrons They let the protons stay a bit further apart without adding + charge Like putting a bunch of neutral people between that can hold hands but don’t cause anyone to run away… MORE STABLE SITUATION… (more or less) What about a neutron? No electrostatic repulsion! 8 Stabilizing effect of neutrons in the nucleus … why do you need them? Protons Repel from electrostatic force (all distances) Protons also attract some from Strong force (very short distances <nuclear radius) Quickly the Strong force can’t win over the size of the nucleus Like putting a bunch of people who find each other repulsive in same room. They can only keep from falling apart if they can clasp hands… The crowd quickly becomes an UNSTABLE SITUATION Potential energy curve for proton approaching nucleus Energy scale gigantic compared to chemical energy. Why? Simple coulomb’s law. electrostatic repulsion separation distance, r attractive nuclear combination--real nucleus separation distance, r F= k (charge of #1)(charge of #2) r2 Chemistry- forces between electrons and protons on distance scale of atomic size (> 10-10 m). Nuclear forces- forces between protons on distance scale 10-100,000 times smaller. 10,000 times closer means forces have to be 100,000,000 times bigger to hold nucleus together (have to beat 1/r2). Lots more potential energy stored!!! 2 Gets deeper until iron (26 P, 30 N) less deep if bigger. Atomic nuclei beryllium harder to push together, but bigger drop when do. helium Nuclear decay- one kind of nucleus changes into another. alpha decay, (beta decay), induced fission A. alpha decay- alpha particle = 2p and 2n. They escape together. Most radioactivity is this type (e.g. radon). “tunnel” out. If alpha particle, finds itself outside, lots of PE, zooms away PEKE Not real tunnel it doesn’t lose energy. Quantum physics says Tiny objects are spread out Very small fraction of time appear outsidewhen happens-- run for it!! 2protons-2neutrons stuck together. (chained together prisoners escaping!) Really stable: Have to add a whole bunch of energy to break up! Really big nucleus, >100 P, >100 N, like Uranium or plutonium 2P-2N 14 B. Radioactive decay-fission tunneling difficulty = width x depth of tunnel Neutron Induced fission- key to atomic bombs •two smaller nuclei Neutron E nucleus1 hard- takes long time, billions of years! 3 2 medium How much energy released? a. 1 most, 2 second, 3 least b. 2 most, 1, 3 least c. 3 most, 2, 1 least d. 3 most, 1, 2 least easy!, happens in millionths of a second! •few extra free neutrons •LOTS OF ENERGY!! “parent” nucleus “daughter” nuclei •(+sometimes other bad stuff) “daughter” nuclei – come out in excited nuclear energy state …. Give off gamma rays as drop to lower energy. energy is difference from bottom of crater to outside. 3 is most, 2 second, 1 is least Jumps down in energy … Gives off gamma ray… VERY HIGH ENERGY PHOTON 16 B. Radioactive decay-fission Neutron Induced fission- key to atomic bombs Neutron Induced fission- key to atomic bombs N “parent” nucleus •two smaller nuclei Neutron “daughter” nuclei •few extra free neutrons “parent” nucleus “daughter” nuclei •LOTS OF ENERGY!! •two smaller nuclei •LOTS OF ENERGY!! •It is a messy process with lots of •few extra free neutrons N •(+sometimes other bad stuff) Found in strange results from Enrico Fermi’s lab Otto Hahn saw similar results and called to his former student for help Lise Meitner came to his aide and explained what was happening. Uranium 235 92 p, 143 n Neutron absorbed Excites U235 nucleus up above potential barrier Splits into two smaller nuclei… which zoom apart due to electrostatic repulsion! (there is even more energy from other sources) 3 Fission Nuclear explosion “atomic bomb” neutron induced fission Fermi first did it, it was very hard to figure out how this could be. If don’t get swallowed the 3 free neutrons can go induce more fission. Ur 235 2nd generation 3rd generation BOOM! 1st generation Chain reaction: neutrons making fission that makes more neutrons, that makes more fission that makes more neutrons, that makes more fission that makes more neutrons, that makes more fission that makes more Uranium 235 or plutonium 100 generations per microsecond! 2 x 2 x 2 .…x2 fissions each with LOTS of energy. that makes more neutrons, that makes more fission that neutrons, that makes more fission makes more neutrons, that makes more This is very similar to a conventional explosion Recipe for fission bomb. Methane + 2 Oxygen mainly stable combining will release energy (heat) Heat+CH4+2 O2 they combine immediately releasing more heat 100 generations per microsecond! 2 x 2 x 2 .…x2 reactions with a lot of energy each. Each one is a millionth of a fission reaction. 3rd generation 1. Find neutron induced fissionable material that produces bunch of extra free neutrons when fissions. 2. Sift it well to remove all the other material that will harmlessly swallow up the extra neutrons. (THE HARDEST STEP.) 3. Assemble “supercritical mass”, really fast!. Need enough stuff that the neutrons run into other nuclei rather than just harmlessly leaving sample. If your mass tends to melt with a small fizzle you are not assembling fast enough to be supercritical. Put together faster. 1st generation 2nd generation BOOM! 4. Let sit for 1 millionth of a second- will bake itself! 22 Fusion bomb (simple picture) chemical explosive hydrogen isotopes tritium,deuterium Plutonium “trigger” chemical explosive Plutonium reaches supercritical, explodes. (fission bomb) Shaped plutonium and assembled bombs at Rocky Flats. 4 Al Bartlett CU professor 1950-2013 Energy: 1 fission of Uranium 235 releases: ~10-11 Joules of energy 1 fusion event of 2 hydrogen atoms: ~10-13 Joules of energy Burning 1 molecule of TNT releases: ~10-18 Joules of energy Was a CU professor from 1950-2013 Had a lot of interesting ideas about population, sustainability, fuel use, etc Photographed atomic explosions at Los Alamos with nano second resolution 19441945 In the first plutonium bomb a 6.1 kg sphere of plutonium was used and the explosion produced the energy equivalent of 22 ktons of TNT = 8.8 x 1013 J 88,000,000,000,000 J How does 6.1 kg relate to 22 ktons? (the 22 k tons is 10 million times more massive) Dropping 1 quart of water 4 inches ~ 1J of energy Useful exercise… compare this volume of TNT, H2, and U235 The hardest part of getting a nuclear bomb is the material “Front End” - obtain 235U (HEU=at least 80%) by the same methods used to make Low Enriched Uranium (LEU), 3-4%. Have to use tiny mass difference very hard Would have to drop that quart of water from 1 billion kilometers (our model of gravity fails first). Gas centrifuge (use inertial difference between masses). Bohr told his American colleagues that a bomb couldn't be made without turning the entire country into a giant factory. When he saw Los Alamos he said, “I told you so.” 5 The hardest part of getting a nuclear bomb is the material “Back End” -obtain 239Pu from Spent Nuclear Fuel: chemistry 238U loves neutrons: grabs them and converts to 239Pu (another process called beta decay) 239Pu is very much like 235U Chemical separation of Pu is much easier. Fusion bomb or “hydrogen bomb” Basic process like in sun. Stick small nuclei together. Deuterium on Tritium Deuterium on Deuterium Which will release more energy during fusion? a. Deuterium combining with deuterium b. Deuterium combining with tritium Answer is b. Incoming deuterium particle has comparatively more potential energy! Fusion bomb or “hydrogen bomb” Basic process like in sun. Stick small nuclei together. activation energy of 100 million degrees push together energy required Stick hydrogen isotopes together to make helium. + energy released if push over the hump = helium Plutonium reaches supercritical, explodes. Simple if can push hard enough- just use sun or fission bomb. More energy per atom than fission. Can use LOTS of hydrogen. End up with GIGANTIC bombs 1000 times bigger than first fission bombs Tritium etc. nuclei pushed together and combine to form helium. Fission bomb- chain reaction, hideous amounts of energy comes off as heat and high energy particles (electrons, neutrons, x-rays, gamma rays) “Radiation”. Heats up air that blows things down. In atomic bomb, roughly 20% of Pl or Ur decays by induced fission This means that after explosion there are a. about 20% fewer atomic nuclei than before with correspondingly fewer total neutrons and protons, b. 20% fewer at. nucl. but about same total neut. and protons. c. about same total neutrons and protons and more atomic nuclei, d. almost no atomic nuclei left, just whole bunch of isolated Neut.s and prot.s., e. almost nothing of Ur or Pl left, all went into energy. ans. c. Makes and spreads around lots of weird radioactive “daughter” nuclei (iodine etc.) that can be absorbed by people and plants and decay slowly giving off damaging radiation. Lots of free neutrons directly from explosion can also induce radioactivity in some other nuclei. 6 U235 and U238 atoms are placed into a container, which are likely to result in a chain reaction (resulting in explosion) when a free neutron triggers fission of one of the U235: Lots of uranium in the ground… why not just blow up or heat up until it melts? U235 and U238 It did once (at least once). Now #5 #1 a. b. c. d. e. #2 #2 only #1, #2, and #5 #2 and #4 #2, #3, and #4 #2, #4, and #5. #3 #4 Lots of uranium in the ground… why not just blow up or heat up until it melts? Correct answer is c. (#2 and #4) Analysis: #1 is too sparse .. most neutrons will leave box before hitting another U235. #2 is good.. Pure U235, densely packed, large package #3 has too many U238’s… more U238’s than 235’s. Free neutrons more likely to be absorbed by 238’s than to hit and fission another 235. #4 is OK … More U235’s than 238’s, still densely packed, large package #5 is too small of package … neutrons likely to escape package before hitting another U235. 4 BY ago U235 is less stable than U238. So 1.8 billion years ago natural Uranium ore had about 3% U235. This is how much we enrich Uranium for a reactor Why didn’t it happen earlier? Uranium too diffuse. For 2 BY after earth’s formation the Uranium remained diffuse. Then life released Oxygen. Oxygen reacted with the Uranium making it mobile and in Gabon it concentrated. There was water present which acted to slow down neutrons that were too fast. There were no other elements that soaked up the neutrons and…? It didn’t explode. Instead it slowly burned for millions of years. Alpha particles: helium nuclei Radioactive materials and “radiation” Daughters often have too few neutrons to stick together, so radioactive, divide more. Other bad/energetic stuff that comes out. Neutrons electrons (“beta particles”) photons (“gamma rays”) helium nuclei (“alpha particles”) - most of radiation is this type - common is Radon (comes from natural decay process of U 238), only really bad because Radon is a gas .. Gets into lungs, if decays there bad for cell. In air: Travels ~2 cm ionizing air molecules and slowing down … eventually turns into He atom with electrons If decays in lung, hits cell and busts up DNA and other molecules: ++ Why radiation bad? Jocell Usually doesn’t get far -- because it hits things Beta particles: energetic electrons … behavior similar to alpha particles, but smaller and higher energy 41 Sources of Gamma Radiation 42 gamma rays: high-energy photons - So high energy can pass through things (walls, your body) without being absorbed, but if absorbed really bad! •two smaller nuclei Neutron •few extra free neutrons •LOTS OF ENERGY!! “parent” nucleus “daughter” nuclei In air: Can travel long distances until absorbed In body, if absorbed by DNA or other molecule in cell … damages cell… can lead to cancer. •(+sometimes other bad stuff) “daughter” nuclei – come out in excited nuclear energy state …. Give off gamma rays as drop to lower energy. Jumps down in energy … Gives off gamma ray… VERY HIGH ENERGY PHOTON 43 + + Most likely If pass through without interacting with anything in cell then no damage. 44 7 An odd world… + + Also break DNA cancer a) a hand, b pocket, g eat b) b hand, g pocket, a eat c) g hand, a pocket, b eat d) b hand, a pocket, g eat e) a hand, g pocket, b eat But also can cure cancerConcentrate radiation on cancer cells to kill them. 45 Results of radiation You find yourself in some diabolical plot where you are given an alpha (a) source, beta (b) source, and gamma (g) source. You must eat one, put one in your pocket and hold one in your hand. You … ~4,000 counts/min = .002 Rem/hr dose in rem = dose in rad x RBE factor (relative biological effectiveness) RBE = 1 for g , 1.6 for b, and 20 for a. a - very bad, but easy to stop -- your skin / clothes stop it b - quite bad, hard to stop -- pass into your body -- keep far away g- bad, but really hard to stop--- rarely rarely gets absorbed Me--- I pick (d)--46 How much energy do we use? on what? A rad is the amount of radiation which deposits 0.01 J of energy into 1 kg of absorbing material. domestic Renew + nuclear. foreign + primarily due to atmospheric testing of nuclear weapons by US and USSR in the 50’s and early 60’s, prior to the nuclear test-ban treaty which forbid above-ground testing. How do you get “power” out of Uranium. How do you get “power” out of Uranium. The same way to get useful power from carbon based fuels The same way to get useful power from carbon based fuels Carbon things can explode Nuclei can explode Or you can burn them slowly Or you can burn them slowly 8 U.S. Oil Curves What about US oil? '03 DOE-EIA 2.1E9 bbl/yr 51 What does this mean? 52 What is inevitable? Of course this is an estimate (and perhaps worst case); what is best case? 53 57 “Paying Attention Quiz” 1. A chain reaction as it occurs in atomic bombs is a. the chemical reaction used to form the metal used in making chains. b. a series of chemical reactions where each one triggers the next. c. the sequence of one nucleus splitting up and causing another to split up followed by another etc. d. the set of steps required to assemble an atomic bomb. 1. c, 2.c 1 2 2. To the left are energy profiles for various atoms. Which decays most rapidly and which never decays? 3 4 a. 3 most rapid, 4 never b. 1 most rapid, 2 never c. 2 most rapid, 1 never d. 4 most rapid, 3 never e. 4 most rapid, 1 never 59 9
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