MODULE 2 7 WORKSHEET IONISATION ENERGY Syllabus reference 8.3.2 1 Define ionisation energy. Ionisation energy is the energy required to remove an electron from the outer-most energy level of a gaseous atom. 2 Consider the following information on ionisation energies. PERIOD SYMBOL ATOMIC NUMBER GROUP IONISATION ENERGY (kJ/mol) 2 Li 3 1 519 Be 4 2 900 B 5 3 799 C 6 4 1090 N 7 5 1400 O 8 6 1310 F 9 7 1680 Ne 10 8 2080 Na 11 1 494 Mg 12 2 736 Al 13 3 577 Si 14 4 786 P 15 5 1060 S 16 6 1000 Cl 17 7 1260 Ar 18 8 1520 3 Copyright © 2008 McGraw-Hill Australia CONQUERINGCHEMISTRY PRELIM MODULE 2 WS 7 a Use the data in the table above to plot, on the same axes, a graph of ionisation energy versus group number for each of Periods 2 and 3. ���� �������� ���� ���� ���� ���� ���� �������� �������������������������� ���� ���� ���� ���� ���� ���� ��� ��� ��� ��� ��� ��� ��� b � � � � � � ������������ � � Use the graphs from part a to describe the trend in ionisation energy as you move from left to right along a period. In moving from left to right across the Periodic Table first ionisation energy generally increases. c Compare the ionisation energies of Li and Na, C and Si, and F and Cl. What does this suggest regarding trends from top to bottom? Moving from top to bottom of the Periodic Table first ionisation energy decreases. Copyright © 2008 McGraw-Hill Australia CONQUERINGCHEMISTRY PRELIM MODULE 2 WS 7 3 Using the graph in question 2a and the metal activity series from your textbook, circle (on the graph) the two most active metals and put squares around the next most active metals. a What relationship is there between activity and ionisation energy? The lower the ionisation energy the more active the metal. b Does the data below support or refute the generalisation you made in part a? Why? SYMBOL ATOMIC NUMBER IONISATION ENERGY (kJ/mol) Ca 20 596 Fe 26 766 Au 79 891 Yes. Ca is more active than Fe which is more active than Au and the order from lowest to highest ionisaton energy is also Ca, Fe, Au. 4 Scientists discovered a new metal X with an ionisation energy of 650 kJ/mol. Using the data in the questions above, where in the activity series could this metal be placed? Explain your reasoning. On the basis of ionisation energy this metal would be placed between Mg and Al because the ionisation energy of Mg is 736 and that of Al is 577. Copyright © 2008 McGraw-Hill Australia CONQUERINGCHEMISTRY PRELIM MODULE 2 WS 7
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