Video Education Australasia Bringing Learning to Life Program Support Notes Middle - Senior Secondary 30mins Acids and Bases Teacher Notes by Keir Strahan, B.Sc. Dip.Ed. Produced by Video Education Australasia Commissioning Editor Christine Henderson B.Sc. Ph.D. Dip.Ed. Mark McAuliffe Dip.Art (Film & TV) Dip.Ed. B.Ed. Ph.D. Executive Producer © Video Education Australasia Pty. Ltd. Suitable for: Chemistry To order or inquire please contact VEA: Australia 111A, Mitchell Street, Bendigo, Victoria 3550 FREECALL: 1800 034 282 Phone: (03) 5442 2433 Facsimile: (03) 5441 1148 New Zealand PO BOX 4390, Shortland St., Auckland FREECALL: 0800 486 688 Facsimile: 0800 488 668 WARNING E-mail [email protected] Website www.vea.com.au The Copyright proprietor has licensed the motion picture contained on this video cassette for non-theatrical use only and prohibits any other use, copying, reproduction or performance in public, in whole or part. The penalties for unauthorised copying of this program include a $50,000 fine for individuals and a $250,000 fine for institutions. These notes can be freely copied for classroom use only. Acids and Bases For Teachers: Brief Summary of Program Acids and bases are all around us. The program features the following: early theories of Arrenhius and Lowry-Bronsted. Valence structures, exposed protons and proton transfer. Diprotic and triprotic acids linked to structures. Amphiprotic example given by hydrogen sulphate ion. The pH scale and the use of indicators to measure pH. Conjugate pairs and strengths of acids with strong acids giving weak conjugate bases. Standard reactions: acid + metal, acid + oxide, acid + carbonate, acid + hydrogen carbonate. Introduction Acids and bases are an important part of life. From their presence in food, to their use as cleaning agents and electrolytes, this program introduces them in familiar settings. The corrosive properties of acids and bases are demonstrated by the impact that acid rain has on the environment and building structures, and by the caustic properties of alkaline oven cleaners. The chemistry of acids and bases is then examined. The theories of Svante Arrenhius and LowryBronsted lead into an analysis of the structures of a number of common acids. The need for an exposed proton is clearly explained and the mechanism of an acid-base reaction is graphically demonstrated as we see a proton transfer between water and hydrochloric acid. Examples of diprotic and triprotic acids are provided and the amphiprotic nature of the hydrogen sulphate ion is addressed with clear graphics. The pH scale and its relationship to the concentration of dissolved hydronium ions is linked with the use of indicators in analytical chemistry. Indicators are described as weak acids and a number of common indicators are used to show changes in pH. Acid-base conjugate pairs are then considered and the extent that an acid ionises is used to explain the differences observed in the strengths of certain acids. The program concludes with a look at some common acid-base reactions as acids are mixed with metals, oxides, carbonates and hydrogen carbonates. Chemical equations accompany all of the reactions that are demonstrated. Program Timeline 00.30 01.38 06.10 06.48 12.01 12.56 15.57 16.41 19.00 19.43 23.33 24.25 27.27 29.22 29.55 30.20 Introduction Properties and uses Summary What are acids and bases Summary The pH scale Summary Indicators Summary Acids and bases conjugate pairs and strengths Summary Common reactions of acids Summary Conclusion Credits Acids and bases end 2 Acids and Bases For Students: While Viewing the Program 1. Acids and bases are 2 chemical groups. What other types of chemical groups can you name? _______________________________________________________________________________ _______________________________________________________________________________ 2. What does corrosive mean? _______________________________________________________________________________ _______________________________________________________________________________ 3. What common 2 pollutants produced from the burning of fossil fuels lead to acid rain? _______________________________________________________________________________ _______________________________________________________________________________ 4. What effect does acid rain have on trees, buildings and statues? _______________________________________________________________________________ _______________________________________________________________________________ 5. What does the word “neutralise” mean to you? _______________________________________________________________________________ _______________________________________________________________________________ 6. What does it mean when we say that acids and bases neutralise each other? _______________________________________________________________________________ _______________________________________________________________________________ 7. Heartburn is a burning sensation in your chest that is caused by hydrochloric acid from the stomach affecting the oesophagus. Which property of acids and bases is responsible for this burning? _______________________________________________________________________________ _______________________________________________________________________________ 8. Why is vinegar useful as a cleaning product? _______________________________________________________________________________ _______________________________________________________________________________ 9. Explain why indicators are useful in analytical chemistry that involves acids and bases. _______________________________________________________________________________ _______________________________________________________________________________ 3 Acids and Bases 10. What is an electrolyte? Why do acids make good electrolytes when they are dissolved in water? _______________________________________________________________________________ _______________________________________________________________________________ 11. How did Svante Arrenhius explain the fact that acids and bases neutralise each other? _______________________________________________________________________________ _______________________________________________________________________________ 12. What do all acids have in common? _______________________________________________________________________________ _______________________________________________________________________________ 13. How many electrons and protons do hydrogen atoms have? _______________________________________________________________________________ _______________________________________________________________________________ 14. What is the Lowry-Bronsted theory of acids and bases? _______________________________________________________________________________ _______________________________________________________________________________ 15. When sulphuric acid is dissolved in water it ionises. Is this an acid-base reaction? Explain your answer. _______________________________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ 16. Annotate the equation for the reaction between hydronium ions and hydroxide ions in order to show that it is an acid-base reaction. _______________________________________________________________________________ _______________________________________________________________________________ 17. Ethanoic acid has the molecular formula CH3COOH. It contains 4 hydrogen atoms and yet it is monoprotic. Explain why ethanoic acid is monoprotic. _______________________________________________________________________________ _______________________________________________________________________________ 18. What is an amphiprotic substance? Write out the formulas of some amphiprotic substances. _______________________________________________________________________________ _______________________________________________________________________________ 4 Acids and Bases 19. What is pH? _______________________________________________________________________________ _______________________________________________________________________________ 20. What is the pH of solutions with H3O+ concentrations of 10-2, 10-6.5 and 10-11.1? Which of these pH values are acidic and which are basic? Demonstrate that 10-3 is a larger number than 10-8 and hence show that acidic solutions have a higher concentration of ions than basic solutions. _______________________________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ 21. How can you measure the pH of substances? _______________________________________________________________________________ _______________________________________________________________________________ 22. Name 4 common substances and their pH values. Which are acidic and which are basic? _______________________________________________________________________________ _______________________________________________________________________________ 23. What are indicators? _______________________________________________________________________________ _______________________________________________________________________________ 24. How does Universal Indicator differ from other indicators? Why can it be used to measure pH whereas an indicator such as Phenolphthalein cannot? _______________________________________________________________________________ _______________________________________________________________________________ 25. What is a conjugate base? Why is the chloride ion (Cl-) the conjugate base of hydrochloric acid (HCl)? _______________________________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ 26. What is the difference in molecular formula between a conjugate acid and its base? Use an example in your answer. _______________________________________________________________________________ _______________________________________________________________________________ 5 Acids and Bases 27. Explain how measuring the conductivity of an acid in solution can identify it as being a strong or weak acid. _______________________________________________________________________________ _______________________________________________________________________________ 28. Is the chloride ion (Cl-) a strong or weak conjugate base? _______________________________________________________________________________ _______________________________________________________________________________ 29. Vinegar contains ethanoic acid (CH3COOH) which is a weak acid. Is its conjugate base relatively weak or strong? _______________________________________________________________________________ _______________________________________________________________________________ 30. Compose a generalisation for the strengths of conjugates acids and bases compared to the strengths of the acids and bases from which they are derived. _______________________________________________________________________________ _______________________________________________________________________________ 31. Why is the reaction between magnesium (Mg) and hydrochloric acid (HCl) not classed as an acid base reaction? _______________________________________________________________________________ _______________________________________________________________________________ 32. Write a general equation for the reaction between an acid and an oxide. _______________________________________________________________________________ _______________________________________________________________________________ 33. Write a general equation for the reaction between an acid and a carbonate. _______________________________________________________________________________ _______________________________________________________________________________ 34. Write a general equation for the reaction between an acid and a hydrogen carbonate. _______________________________________________________________________________ _______________________________________________________________________________ 6 Acids and Bases Web Site References • Clearly covers the theory of acids and bases http://chemed.chem.purdue.edu/genchem/topicreview/bp/ch11/acidbaseframe.html • Directory with many links to acid-base sites http://search.looksmart.com/p/browse/us1/us317914/us263953/us263958/us330416/us330423/ • Introduction to acids and bases with examples of common acid-base reactions http://www.rjclarkson.demon.co.uk/junior/junior.htm • Introductory unit into acids and bases http://www.visionlearning.com/library/module_viewer.php?mid=58 • Directory with many sites that relate to acids and bases and how they impact on the environment http://www.westfieldnj.com/eis/team6/6science_ch6.htm#Neutralization • A fun game of memory that asks players to match definitions to other terms http://www.glencoe.com/sec/science/Science600/co/617.php?iRef=617 Other Relevant Programs Available from VEA Chemical Equations Our Chemical Environment Series The Super-Charged World of Chemistry Series Applied Chemistry – Science Bank Series The Amazing Mole Please visit our website for many more relevant programs www.vea.com.au VEA – Bringing Learning to Life 7
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