Name
bp °C/mm (mp)
MW
D420
nD20
NICKEL
Atomic number
Crystal form
28
Ni
Oxidation states
Face-centered cubic
Atomic weight
0, 1, 2, 3
Electrical resistivity (20˚C)
58.6934
Electronegativity, Pauling
6.97 μΩ·cm
CAS number
1.8
Enthalpy of melting
7440-02-0
Specific heat (25˚C)
17.15 kJ/mol
Boiling point
0.106 cal/g K
Enthalpy of vaporization
2,732˚C
Thermal conductivity (25˚)
377.5 kJ/mol
Melting point
90.9 W/(m K)
Ionization potential
(spectral)
1,453˚C
7.635 eV (l)
18.168 eV (ll)
Specific gravity (20˚C)
8.902
0.257 V (+2)
(aqueous)
COMPOUNDS
CXNI010
O
+2
H 3C C O 2 Ni
NICKEL(II) ACETATE, tetrahydrate
C4H6NiO4·4H 2 O
Slightly soluble: methanol
176.80/248.80
(>110)
TOXICITY: oral rat, LD50: 410 mg/kg
Color: green
1.744
HYDROLYTIC SENSITIVITY: 0: forms stable aqueous solutions
[6018-89-9]
TSCA
HMIS: 3-1-0-X
50g ¥7,000
2kg ¥34,500
NICKEL ACETYLACETONATE - see AKN580 NICKEL II 2,4-PENTANEDIONATE
AKN572
C4H 9
S
N
S
Ni
C
N
C
S
S
C4H9
C4H9
C4H9
（既）2-1247
NICKEL DI-n-BUTYLDITHIOCARBAMATE
C18H36N2NiS4
Soluble: toluene, CHCl3, warm acetone
Absorption max: 280, 375 nm
Stabilizer for polyolefins (0.1-1.0%)
467.43
(86)
Flashpoint: 260°C (500°F)
TOXICITY: oral rat, LD50: >5,000 mg/kg
Color: green
1.26
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[13927-77-0]
TSCA
EC 237-696-2
AKN575
CH3
S
N
S
Ni
C
N
C
S
S
CH3
CH3
CH3
HMIS: 2-1-0-X
25g ¥12,500
100g ¥30,500
（既）2-1833
NICKEL DIMETHYLDITHIOCARBAMATE
C6H12N2NiS4
18-20% Ni
299.12
(>290)
1.77
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[15521-65-0]
EC 239-560-8
HMIS: 3-1-0-X
10g ¥11,000
INNI023
C6H 5
1,3-BIS(DIPHENYLPHOSPHINO)PROPANE542.05
NICKEL(ll) CHLORIDE
C27H26Cl2NiP2
Color: red
Catalyst for the reaction of Grignards with enol ethers forming olefins
olefins.1
1. Wenkert, E. et al. J. Am. Chem. Soc. 1979, 101 , 2246.
F&F: Vol. 6, p 50; Vol. 15, p. 122.
C6H 5
P
Ni
Cl
Cl
P
C6H 5
C6H 5
(210-220)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[15629-92-2]
O
-
O ) 2 Ni
(HC
+2
5g ¥23,000
HMIS: 3-1-0-X
CXNI045
（既）2-671
NICKEL FORMATE, dihydrate
C2H2NiO4·2H 2 O
Dehydrates: 130-140°C; decomposes: 180-200°C.
184.77/202.77
2.15
HYDROLYTIC SENSITIVITY: 0: forms stable aqueous solutions
[3349-06-2]
TSCA
EC 222-101-0
HMIS: 3-0-0-X
25g ¥8,300
AKN578
CF3
C
O
HC
CF3
C
O
Ni
2
NICKEL(II) HEXAFLUORO-2,4-PENTANEDIONATE,
hydrate
C10H2F12NiO4·xH 2 O
Color: green
472.82
(213)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[14949-69-0]
EC 239-028-5
HMIS: 3-1-0-X
5g ¥15,800
25g ¥49,500
アヅマックス株式会社
TEL 03-5543-1630
FAX 03-5543-0312
[email protected]
Name
CH3
C
O
C
Ni
O 2
HC
CH3
bp °C/mm (mp)
MW
AKN580
D420
nD20
1.455
1.57-1.64
（既）2-2181
COMMERCIAL
NICKEL(II) 2,4-PENTANEDIONATE
256.91
(208 dec)
C10H14NiO4
Metal content: 22.5-23.6% Ni
TOXICITY: ipr mus, LD50: 125 mg/kg
Color: green - turns turquoise on absorption of 3 moles H2O
Water removed by azeotropic distillation with toluene
Solubility, ethanol: 27 g/l
Trimeric compound
Solubility, methoxyethoxyethanol: 70 g/l
ΔHsub: 16.5 kcal/mole
Solubility, toluene: 85 g/l
Vapor pressure, 145˚: 0.01 mm
Solubility, water: 11.0 g/l
UV max: 265-298 nm
NMR shift reagent
Catalyzes conjugate addition of alkynyl aluminums to enones.1
Catalyzes coupling of Grignard reagents to give biaryls.2
Catalyzes Grignard additions to silyl enol ethers forming alkenes.3
Thermochromic effect in non-coordinating solvents at 200°C.4
UV stabilizer for polyphenylene sulfide.5
Catalyzes coupling of dialkylzincs with alkyl iodides.6
Intermediate for Ni nanoparticles by reduction with NaBH4.7
Forms Ni3C nanocrystals by thermolysis in oleylamine.8
1. Hansen, R. T. et al. J. Am. Chem. Soc . 1978, 100 , 2244.
2. Clough, R. L. J. Org. Chem . 1976, 41 , 2252.
3. Hayashi, T. et al. Tetrahedron Lett. 1980, 3915.
4. Cotton, F. et al. J. Am. Chem. Soc. 1961, 83 , 2818.
5. Stahlke, K. Chem. Abstr. 114, 144761u; Eur. Patent Application 326,888, 1989.
6. Giovannini, G. R. et al. J. Org. Chem. 1999, 64 , 3544.
7. Green, M. et al. J. Chem. Soc., Chem. Commun . 2001, 1912.
8. Goto, Y. et al. Chem. Mater. 2008, 20 , 4156.
HYDROLYTIC SENSITIVITY: 0: forms stable aqueous solutions
[3264-82-2]
TSCA
EC 221-875-7
HMIS: 3-1-0-X
25g ¥9,500
100g ¥20,500
AKN584
(CH 3 ) 3 C
C
O
HC
(CH 3 ) 3 C
C
NICKEL(II) 2,2,6,6-TETRAMETHYL-3-5-HEPTANEDIONATE
O
Ni
NICKEL TMHD
2
C22H38NiO4
F&F: Vol. 17, p 40.
425.23
90-110 / 0.1 sub
(223-5)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[41749-92-2]
HMIS: 2-1-0-X
5g ¥36,000
CXNI083
O
CF3 S O
Ni++
O
NICKEL(ll) TRIFLUOROMETHANESULFONATE
C2F6NiO6S2
Hygroscopic
Color: pale green
356.83
HYDROLYTIC SENSITIVITY: 6: forms irreversible hydrate
2
[60871-84-3]
HMIS: 3-1-1-X
5g ¥25,500
AKN586
CF3
C
O
NiII
HC
CH 3
C
O
2
NICKEL(ll) 1,1,1-TRIFLUORO-2,4-PENTANEDIONATE,
dihydrate
C10H8F6NiO4·2H 2 O
Color: green
364.87/400.90
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[14324-83-5]
HMIS: 3-1-0-X
5g ¥36,000
アヅマックス株式会社
TEL 03-5543-1630
FAX 03-5543-0312
[email protected]
10kg inquire