Biomass is a key resource in a future sustainable energy supply. However, many types of biomass are not easy to convert into useful energy in terms of power and heating. There is a constant need for development of more efficient, reliable and cost-effective technological solutions for biomass-based energy plants. New biomass technologies A major challenge of biomass energy plants is fouling and corrosion of the gas cooler. Dall Energy provides a new method to cool and clean gases and recover the heat from the cooled gases, which overcomes the problems of fouling and corrosion. Dall Energy integrates a simple cooling technology “Evaporative Cooling” into biomass energy plants. Evapo- rative cooling is used within heavy industry: cement and steel, where it is necessary to cool and clean the gas before it is led to the stack. Dall Energy integrates air moisturizing into biomass energy plants. Several advantages are hereby achieved, e.g. an increase in efficiency of 10-15%. Patents are pending. A full-scale demonstration project in Denmark is being prepared. Dall Energy Dall Energy develops and implements innovative solutions for biomassbased energy plants. Dall Energy’s activities include combustion plants for heat production and gasification plants for heat and power production. Dall Energy is a specialist company with comprehensive theoretical and practical expertise. Dall Energy cooperates with universities, research institutes and industrial partners. Evaporative cooling Air moisturizing In an evaporative cooler, fine droplets of water are sprayed into the hot gas. Due to the high evaporation energy of water (2.2 MJ/kg), the gas is cooled fast to 150-250°C. In an air moisturizer, the air for combustion or for gasification is preheated and moisturized. Air moisturizers result in several advantages: An increase in thermal efficiency of 10-15% and lower combustion/gasification temperature, which means less slagging and less NOx. Strategic partners: Combustion plants In standard biomass combustion plants, the flue gas is cooled from about 800°C to about 150°C in a “shell and tube” heat exchanger where the flue gas flows inside the tubes and water on the outside of the tubes. When the biomass contains chlorine, potassium or other contaminants, such heat exchangers suffer from corrosion and fouling. The lifetime of such heat exchangers is often short, and the maintenance costs are often high. Quench Standard biomass combustion plant with condensation. Simple cooling Dall Energy offers a new simple and reliable solution to cool flue gases in biomass-based district heating plants. In a Dall Energy biomass combustion plant, the flue gases are cooled in an evaporative cooler. The cooling is done by injection of water droplets into the hot gas. As water has a high evaporation energy, the gases are cooled effectively, while the water evaporates. Due to the water injection, the flue gas now has a high content of water vapours: The water dew point has been increased to about 80°C. Heat recovery After the evaporative cooler, the energy of the flue gas is recovered in a condensation unit. Such condensation unit may be a scrubber unit or a shell and tube heat exchanger. Similar condensation units are known in energy plants, but Dall Energy units are unique: •Due to the high moisture content and the high water dew point in the flue gas, the amount of energy produced in the condensation unit is much higher (up to 5 times) compared to traditional condensation units; Quench Dall Energy combustion plant. •Due to the high water dew point, the condensation unit can produce district heating water at much higher temperatures than normal condensation units: – In scrubber units up to 90°C – In shell and tube units above 100°C •Due to the air moisturizing system, the flue gas is cooled to about 35°C resulting in very little fume and a very high energy efficiency of the plant. Standard Dall Energy Efficiency (LHV): wood / waste 105 % 115% Efficiency (LHV): straw / pellets / coal 90% 105% Corrosion boiler Yes No Fouling boiler Yes No Water system Complex Simple NOx reduction No Yes Slagging in furnace Yes Less Hundested Heating Plant. A 10MW demonstration plant is being prepared. Gasification plants Flue gas to stack Flue gas cooling Hot product gas As the gasifier operates at about 800°C, the alkali metals and chlorine are in gas phase. When the gas is cooled after the gasifier, the alkali metals and chlorine form salts. These salts are sticky, and they build up and clog in traditional heat exchangers. District heating Bag filter Air Gas engine ~ 200°C Ash Condensate District heating Standard gasification plant. Flue gas to stack Flue gas cooling Hot product gas Air District heating or industrial steam District heating Gasification Bag filter Fuel Cold gas cooling Gasifier 800°C Evaporative cooler Agricultural residues are characterized by being cheap and plentiful in many regions. Hence there is a strong interest in having reliable systems that can utilise agricultural residues as fuel. However, these fuels often have a high content of ashes with alkali metals (e.g. potassium) and chlorine, which cause technical problems in the gas cooler. District heating or industrial steam Air Dall Energy provides simple and reliable gas cooling and cleaning technologies for gasification plants. Agricultural residues Cold gas cooling Gasification Hot gas cooling Fuel Water or air heating 800°C Gasifier Biomass gasification may become a key technology in the future energy market. Electricity, biofuels and heat can be produced with high efficiencies by use of biomass gasification. Several different biomass gasification technologies are under development, aiming at different applications and markets. For many applications, such as gas turbines, gas engines, synthesis processes as well as fuel cells, it is important that the produced gas is cooled and cleaned. Air Gas engine ~ 200°C Ash + salts Condensate District heating Dall Energy gasification plant. Simple cooling Gas cleaning Dall Energy offers a new simple and reliable solution to cooling product gas in biomass gasifiers. In a Dall Energy solution, the product gas is cooled by use of evaporative cooling. The cooling is done by injection of water droplets into the hot gas. As water has high evaporation energy, the gases are cooled effectively, while the water evaporates. The cooled gas can be cleaned with traditional gas cleaning technologies, e.g. bag filters. Typical grouping of biomass gasifiers with their advantages and disadvantages Technology Advantage Disadvantage Fluid bed • Reliable • Can be upscaled • Fuel flexible • Medium-high tar levels • Salt condensation if agricultural residues are used Updraft • Reliable • High cold gas efficiency • Can operate on moist fuel • Limited upscale potential • Limited to wood fuels • High tar level Entrained flow • Large scale • Extensive fuel preparation • Poor cold gas efficiency Down draft • Low tar content • Simple gas cleaning • Limited upscale potential • Limited to wood fuels Heat recovery After the gas cleaning unit, the energy of the product gas can be recovered in a condensation unit such as a scrubber system or a shell and tube heat exchanger. Dall Energy develops design tools for innovative solutions of biomass energy plants. The design tools include mass and energy balance programmes for complete plants and design tools for key components. The design tools are programmed in commercial software. Dall Energy software includes: •Mass and energy balance programme for combustion plants •Mass and energy balance programme for gasification plants •Layout of scrubbers for heat recovery •Layout of shell and tube heat exchanger in condensing mode. Screen of energy-mass balance programme for biomass combustion plant with evaporative cooling and heat recovery in scrubber system. Dall Energy • Telephone: +45 2987 2222 • [email protected] • www.dallenergy.com © Dall Energy February 2008 Photos: Biopress & Tao Lytzen Diagrams: COWI Layout: Marusa Design Software
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