Facts About Plutonium
By Alina Bradford, Live Science Contributor | December 7, 2016 09:30pm ET
Plutonium is a radioactive, silver metal that can be used to create or destroy.
While it was used for destruction soon after it was made, today the element is
used mostly for creating energy throughout the world.
Plutonium was first produced and isolated in 1940 and was used to make the
"Fat Man" atomic bomb that was dropped on Nagasaki at the end of World
War II, just five years after it was first produced, said Amanda Simson, an
assistant professor of chemical engineering at the University of New Haven.
Just the facts
Here are the properties of plutonium, according to the Los Alamos National
Laboratory:
Atomic number: 94
Atomic symbol: Pu
Atomic weight: 244
Melting point: 1,184 F (640 C)
Boiling point: 5,842 F (3,228 C)
Discovery & history
Plutonium was discovered in 1941 by scientists Joseph W. Kennedy, Glenn T.
Seaborg, Edward M. McMillan and Arthur C. Wohl at the University of
California, Berkley. The discovery occurred when the team bombarded
uranium-238 with deuterons that had been accelerated in a cyclotron device,
which created neptunium-238 and two free neutrons. The neptunium-238
then decayed into plutonium-238 through beta decay.
This experiment wasn't shared with the rest of the scientific community until
1946, after World War II. Seaborg submitted a paper on their discovery to the
journal Physical Review in March 1941, but the paper was removed when it
was discovered that an isotope of plutonium, Pu-239, may be used to create
an atomic bomb.
Soon, Seaborg was sent to lead the Plutonium Production Lab, also known as
the Met Lab, at the University of Chicago, according to the Los Alamos
National Laboratory. The purpose of the lab was to create plutonium as part
of the Manhattan Project. The Manhattan Project was a secret venture during
World War II that worked exclusively to develop an atomic bomb.
On August 18, 1942, they had their first big success. They were able to create a
trace quantity of plutonium that was visible to the eye. It equaled only around
1 microgram. From the tiny sample, scientist determined plutonium's atomic
weight.
The Manhattan Project eventually produced enough plutonium for the
"Trinity Test." During the test, the world's first atomic bomb, or the "The
Gadget," was exploded near Socorro, New Mexico, on July 16, 1945, by Los
Alamos Laboratory director Robert Oppenheimer and Army General Leslie
Groves.
Of the test, Oppenheimer said, "We knew the world would not be the same. A
few people laughed, a few people cried. Most people were silent. I
remembered the line from the Hindu scripture, the Bhagavad-Gita. Vishnu is
trying to persuade the Prince that he should do his duty and to impress him
takes on his multi-armed form and says, 'Now I am become Death, the
destroyer of worlds.' I suppose we all thought that, one way or another,"
according to the Royal Society of Chemistry.
The explosion had the energy equivalent of approximately 20,000 tons of
TNT. The first war-use atomic bomb dropped on Hiroshima, Japan, on
August 6, 1945. That atomic bomb, dubbed "Little Boy," had a uranium core,
though. The second bomb, dropped on Nagasaki, Japan, in August 9, 1945,
had a plutonium core. The "Fat Man," as it was called, hastened the end of
World War II.
Properties of plutonium
Freshly prepared plutonium metal has a silvery bright color but takes on a
dull gray, yellow, or olive green tarnish when oxidized in air. The metal
quickly dissolves in concentrated mineral acids. A large piece of plutonium
feels warm to the touch because of the energy given off by alpha decay; larger
pieces can produce enough heat to boil water. At room temperature alphaform plutonium (the most common form) is as hard and brittle as cast iron. It
can be alloyed with other metals to form the room-temperature stabilized
delta form, which is soft and ductile. Unlike most metals, plutonium is not a
good conductor of heat or electricity. It has a low melting point and an
unusually high boiling point.
Plutonium can form alloys and intermediate compounds with most other
metals, and compounds with a variety of other elements. Some alloys have
superconductive abilities and others are used to make nuclear fuel pellets. Its
compounds come in a variety of colors, depending on the oxidation state and
how complex various ligands are. In aqueous solution there are five valance
ionic states.
Plutonium, along with all of the other transuranium elements, is a
radiological hazard and must be handled with specialized equipment and
precautions. Animal studies have found that a few milligrams of plutonium
per kilogram of tissue are lethal.
Sources
Plutonium generally isn't found in nature. Trace elements of plutonium are
found in naturally occurring uranium ores. Here, it is formed in a way similar
to neptunium: by irradiation of natural uranium with neutrons followed by
beta decay.
Primarily, however, plutonium is a byproduct of the nuclear power industry.
Each year, around 20 tons of plutonium is produced, according to the Los
Alamos National Laboratory. Spent nuclear fuel can also be reprocessed to
separate usable plutonium from other elements in the fuel.
Atmospheric weapons testing in the 1950s and 1960s left tons of plutonium in
the Earth's atmosphere that is still there today, according to the World
Nuclear Association.
Uses
For the most part, plutonium isn't used for much. In fact, of the five common
isotopes, only two of plutonium's isotopes, plutonium-238 and plutonium239, are used for anything at all.
Plutonium-238 is used to make electricity for space probes using radioisotope
thermoelectric generators. These generators are switched on when the probes
can't get enough solar power because they have traveled too far away from the
sun. Some probes that use plutonium-238 are Cassini and Galileo.
When concentrated enough, plutonium-239 undergoes a fission chain
reaction. Because of this, it is used in nuclear weapons and some nuclear
reactors.
In fact, one of the biggest uses for plutonium is energy. According to the
World Nuclear Association, over one-third of the energy produced in most
nuclear power plants comes from plutonium. Plutonium is the main fuel in
fast neutron reactors.
Who knew?
For decades, scientists wondered why plutonium didn't act like other metals
in its group. For instance, plutonium is a poor conductor of electricity and it
doesn't stick to magnets. Now researchers have figured out where its "missing
magnetism" has been hiding out and it has to do with the wacky behavior of
the electrons in the element's outer shell. Unlike other metals, which have a
set number of electrons in their outer shells, when in a ground state,
plutonium can have four, five or six electrons there.
This fluctuating number of outer-shell electrons explains why plutonium isn't
magnetic: In order for an atom to interact with magnets the unpaired
electrons in its outer shell must line up in a magnetic field. [Read more about
plutonium's missing magnetism]
Plutonium's most stable isotope, plutonium-244, can last a long time. It has a
half-life of about 82 million years and decays into uranium-240 through
alpha decay, according to the Jefferson Lab.
Plutonium was named after the planet, Pluto. This is because it came after
Uranium, which was named after the planet Uranus, and neptunium, which
was named after the planet Neptune.
Plutonium emits neutrons, beta particles and gamma rays.
Additional resources
U.S. Nuclear Regulatory Commission: Backgrounder on Plutonium
NASA: What is Plutonium-238?
Centers for Disease Control and Prevention: Plutonium Radioisotope
Brief