Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 13 HOMEWORK 13-1 (pp. 395–397) VOCABULARY Define. 1. heterogeneous mixture _______________________________________________________________ __________________________________________________________________________________ 2. homogeneous mixture _______________________________________________________________ __________________________________________________________________________________ 3. components ________________________________________________________________________ __________________________________________________________________________________ 4. soluble ____________________________________________________________________________ __________________________________________________________________________________ GRAPHIC ORGANIZER Make a tree diagram to show the possible solute-solvent combinations in solutions. STANDARDIZED TEST PREP Circle the letter of the best answer. 1. Which describes the solvent in any solution? a. the substance being dissolved b. the dissolving medium c. a liquid d. a solid 2. Which describes the dissolved substance in a solution? a. a solid b. a gas c. the solute d. the solvent Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 13 HOMEWORK 13-2 (pp. 397–400) VOCABULARY Select the term in Column B that is most closely related to each term in Column A. Column A Column B 1. suspension _____ a. sugar solution 2. colloid _____ b. salt solution 3. electrolyte _____ c. sol 4. nonelectrolyte _____ d. gas e. muddy water GRAPHIC ORGANIZER Make a list of colloids found in your home. Then make a table showing the class and phase of each. STANDARDIZED TEST PREP Circle the letter of the best answer. 1. Which describes a colloid in which a liquid is dispersed in gas? a. smoke b. smog c. foam d. fog 2. In which would the Tyndall effect be used to distinguish one from the other? a. a solution and a suspension b. a solution and a colloid c. a colloid and a solution d. a colloid and a compound Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 13 HOMEWORK 13-3 (pp. 401–404) VOCABULARY If the statement is true, write true. If the statement is false, replace the underlined term with the term that makes the statement true. 1. A solution that contains the maximum amount of solute is a(n) unsaturated solution. ____________ 2. A supersaturated solution contains less solute than a saturated solution under the same conditions. ____________ 3. A(n) dynamic equilibrium exists between dissolution and crystallization of a substance dissolved in water. ____________ 4. The speed with which sugar dissolves in tea depends on the temperature of the tea. ____________ 5. Collisions between solvent molecules and solute are more frequent at lower than higher temperatures. ____________ EXPERIMENT A photographer adds 300 g of hypo to 100 g of water in a beaker and heats it to 45°C. A few crystals remain at the bottom of the beaker. She adds more hypo and raises the temperature to 80°C to be sure all the hypo is dissolved. She lets the solution cool and leaves it undisturbed. She then adds a tiny crystal of hypo. A large amount of hypo crystallizes immediately. Chemists would say that the solution is supersaturated. 1. What is a supersaturated solution? _____________________________________________________ _________________________________________________________________________________ 2. How could the photographer get the crystals back into solution? _____________________________ _________________________________________________________________________________ STANDARDIZED TEST PREP Circle the letter of the best answer. 1. What must be specified for the solubility of a gas but not for a solid? a. pressure b. temperature c. formula d. atomic mass 2. Which describes solution equilibrium? a. Dissolution is faster than crystallization. b. Dissolution is slower than crystallization. c. Dissolution and crystallization occur at equal rates. d. Dissolution and crystallization occur at different rates. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 13 HOMEWORK 13-4 (pp. 404–407) VOCABULARY Write yes or no. 1. Is gasoline more soluble in water than in benzene? ____________ 2. In the solution process, is water the solvent referred to by the term hydration? ____________ 3. Are ionic compounds usually soluble in nonpolar solvents? ____________ 4. Does the solubility of gases in water increase with temperature? ____________ 5. Does a change in pressure of gases change their solubility in water? ____________ GRAPHIC ORGANIZER Use the data in Table 13-4 on page 404 to answer each question. 1. At what temperature do 238 g of C12H22O11 dissolve in water? ________________________________ 2. At 60°C, how many grams of AgNO3 dissolve in water? ____________________________________ 3. Which two compounds decrease in stability with increased temperature? _______________________ __________________________________________________________________________________ 4. Which compound is insoluble in water at 100°C? __________________________________________ 5. Write your own question and answer, using the data in the table. _____________________________ __________________________________________________________________________________ __________________________________________________________________________________ __________________________________________________________________________________ STANDARDIZED TEST PREP Circle the letter of the best answer. 1. Which describes liquid solutes and solvents that are not soluble in each other? a. hydrogen bond b. hydrated c. miscible d. immiscible 2. Which statement is true? a. Hydrated copper(II) sulfate has no water trapped in it. b. CaSO4 is an anhydrous compound. c. Carbon tetrachloride (CCl4) is a polar solvent. d. London forces are strong between nonpolar compounds. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 13 HOMEWORK 13-5 (pp. 407–411) VOCABULARY Fill in the blank with the correct term. 1. A solute particle surrounded by solvent molecules is ______________________. 2. The solubility of gases in water decreases as the temperature of the water ______________________. 3. The rapid escape of gas from a liquid in which it is dissolved is ______________________. 4. The heat energy absorbed or released when a specific amount of solute dissolves in a solvent is the ______________________. 5. The solubility of a gas in a liquid is directly proportional to the partial pressure of that gas on the surface of the liquid according to ______________________. EXPERIMENT A scientist added 100 mL of water at the same temperature to two beakers, labeled A and B. Next he placed a thermometer in each beaker. He added 10 g of NaOH to beaker A. As the NaOH dissolved, the temperature in the beaker increased. He added 10 g of NaNO3 to beaker B. As the NaNO3 dissolved, the temperature of the beaker decreased. 1. Is the process in beaker A exothermic or endothermic? ________________________________ 2. Is the process in beaker B exothermic or endothermic? ____________________________________ 3. What is the scientist studying in this experiment? _______________________________ 4. Is the heat of solution positive or negative when heat is released? _____________________________ STANDARDIZED TEST PREP Circle the letter of the best answer. 1. To which class of chemicals does artificial blood, C8F17Br, belong? a. oxygents b. perfluorocarbons c. HIV d. hemoglobins 2. Which statement is true of all compounds? a. They increase in solubility with an increase in temperature. b. They decrease in solubility with a decrease in temperature. c. They increase in solubility with a decrease in temperature. d. Each has its own specific solubility in relation to temperature. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 13 HOMEWORK 13-6 (pp. 412–415) VOCABULARY Define. 1. concentration _______________________________________________________________________ __________________________________________________________________________________ 2. dilute _____________________________________________________________________________ __________________________________________________________________________________ 3. concentrated _______________________________________________________________________ __________________________________________________________________________________ 4. molarity ___________________________________________________________________________ __________________________________________________________________________________ EXPERIMENT José and Al want to prepare a liter of a molar solution of fructose. They have a liter graduated cylinder, a balance, a stirring rod, and a container of fructose (C6H12O6). They determine the gram molecular mass of fructose as 192 (C = 6 x 12 = 72; H = 12 x 1 = 12; O = 6 x 18 = 108). They measure 192 g of fructose on the balance. Next they place the 192 g of fructose in the graduated cylinder. Then they add water to the half-liter mark and stir the solution. 1. What is the molarity of the solution? Explain. _____________________________________________ __________________________________________________________________________________ __________________________________________________________________________________ 2. How can they make their solution into a 1 M solution? ____________________________________ __________________________________________________________________________________ __________________________________________________________________________________ STANDARDIZED TEST PREP Circle the letter of the best answer. 1. Which is not used to prepare 1 L of a 1 M solution of NaCl? a. 1 mol of NaCl b. 1 L of NaCl solution c. 1 L flask d. 1 L of water 2. Which is used to prepare 2 L of a 0.5 M solution of sucrose? a. 1 mol of sucrose b. 0.5 g of sucrose c. 1 L of water d. 0.5 L of water Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Lesson Print Name ______________________________________ Date ____________ Class _______________________ Modern Chemistry • CHAPTER 13 HOMEWORK 13-7 (pp. 416–418) VOCABULARY Write true or false. 1. A molal solution contains 1 mol of solution per 1000 g of solvent. ____________ 2. Molality is the concentration of a solution in moles of solute per kilogram of solvent. ____________ 3. A molal and a molar solution of NaCl are the same.____________ 4. A molal and a molar solution of sucrose are the same. ____________ 5. In a molal solution, a specific amount of solvent is always used. ____________ GRAPHIC ORGANIZER Make a step-by-step chart or list to show how you would use 80 g of sodium hydroxide (NaOH) to prepare a 1 m solution. 1. __________________________________________________________________________________ __________________________________________________________________________________ 2. __________________________________________________________________________________ __________________________________________________________________________________ 3. __________________________________________________________________________________ __________________________________________________________________________________ 4. __________________________________________________________________________________ __________________________________________________________________________________ 5. __________________________________________________________________________________ __________________________________________________________________________________ 6. __________________________________________________________________________________ __________________________________________________________________________________ STANDARDIZED TEST PREP Circle the letter of the best answer. 1. Which statement is true? a. To find molality, you must know the mass of solvent. b. To find molality, you must know the volume of solvent. c. Any molal solution must have exactly 1 mol of solute. d. Any molal solution must have exactly 1 kg of solvent. 2. Which statement is true? a. Any molal solution is concentrated. b. Any molal solution is dilute. c. A molal solution is designated M. d. A molal solution is designated m. Modern Chemistry Copyright © by Holt, Rinehart and Winston. All rights reserved. Menu Print Name Date Class CHAPTER 13 REVIEW Solutions MIXED REVIEW SHORT ANSWER Answer the following questions in the space provided. 1. Solid CaCl2 does not conduct electricity, but it is considered to be an electrolyte. Explain. 2. Explain the following statements at the molecular level: a. Generally a polar liquid and a nonpolar liquid are immiscible. b. Carbonated soft drinks taste flat when they are warmed. 3. An unknown compound is observed to mix with toluene, C6H5CH3, but not with water. a. Is the unknown compound ionic, polar covalent, or nonpolar covalent? b. Suppose the unknown compound is also a liquid. Will it be able to dissolve table salt? Explain your answer. MODERN CHEMISTRY HRW material copyrighted under notice appearing earlier in this work. CHAPTER 13 MIXED REVIEW 115 Menu Print Name Date Class MIXED REVIEW continued PROBLEMS provided. Write the answer on the line to the left. Show all your work in the space 4. Consider 500. mL of a 0.30 M CuSO4 solution. a. How many moles of solute are present in this solution? b. How many grams of solute were used to prepare this solution? 5. a. If a solution is electrically neutral, can all of its ions have the same charge? Explain your answer. b. The concentration of the OH ions in pure water is known to be 1.0 107 M. How many OH ions are present in each milliliter of pure water? 6. 90. g of CaBr2 are dissolved in 900. g of water. a. What volume does the 900. g of water occupy if its density is 1.00 g/mL? b. What is the molality of this solution? 116 CHAPTER 13 MIXED REVIEW MODERN CHEMISTRY HRW material copyrighted under notice appearing earlier in this work.
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