Journal of Geophysical Research: Atmospheres RESEARCH ARTICLE 10.1002/jgrd.50863 Correspondence to: C. Serio, [email protected] Diurnal variation in Sahara desert sand emissivity during the dry season from IASI observations Guido Masiello1 , Carmine Serio1 , Sara Venafra1 , Italia DeFeis2 , and Eva E. Borbas3 1 School of Engineering and CNISM, Potenza Research Unit, University of Basilicata, Potenza, Italy, 2 IAC-CNR, Naples, Italy, 3 Cooperative Institute for Meteorological Satellite Studies, University of Wisconsin–Madison, Madison, Wisconsin, USA Citation: Masiello, G., C. Serio, S. Venafra, I. DeFeis, and E. E. Borbas (2014), Diurnal variation in Sahara desert sand emissivity during the dry season from IASI observations, J. Geophys. Res. Atmos., 119, 1626–1638, doi:10.1002/jgrd.50863. Received 17 MAY 2013 Accepted 22 SEP 2013 Accepted article online 30 SEP 2013 Published online 7 FEB 2014 Abstract The problem of diurnal variation in surface emissivity over the Sahara Desert during non-raining days is studied and assessed with observations from the Infrared Atmospheric Sounding Interferometer (IASI). The analysis has been performed over a Sahara Desert dune target area during July 2010. Spinning Enhanced Visible and Infrared Imager observations from the European geostationary platform Meteosat-9 (Meteorological Satellite 9) have been also used to characterize the target area. Although the amplitude of this daily cycle has been shown to be very small, we argue that suitable nighttime meteorological conditions and the strong contrast of the reststrahlen absorption bands of quartz (8–14 μm) can amplify its effect over the surface spectral emissivity. The retrieval of atmospheric parameters show that, at nighttime, an atmospheric temperature inversion occurs close to the surface yielding a thin boundary layer which acts like a lid, keeping normal convective overturning of the atmosphere from penetrating through the inversion. This mechanism traps water vapor close to the land and drives the direct adsorption of water vapor at the surface during the night. The diurnal variation in emissivity at 8.7 μm has been found to be as large as 0.03 with high values at night and low values during the day. At 10.8 μm and 12 μm, the variation has the same sign as that at 8.7 μm, but with a smaller amplitude, 0.019 and 0.014, respectively. The impact of these diurnal variations on the retrieval of surface temperature and atmospheric parameters has been analyzed. 1. Introduction Diurnal variations in desert sand emissivity during the dry season have been brought to the public’s attention recently by Li et al. [2012] who performed an analysis with SEVIRI (Spinning Enhanced Visible and Infrared Imager) observations from the European geostationary platform Meteosat (Meteorological Satellite). A recent analysis [Masiello et al., 2013b] performed by some of the authors of this paper with SEVIRI data confirms this effect and also shows that the time variation of emissivity closely follows the daily cycle for temperature. Diurnal variation in surface emissivity is very likely to occur in the natural environment because emissivity (𝜀) is influenced by soil water content (𝜃 ), which even in nonrainfall seasons, can change due to dew condensation at night, for example. However, the emissivity variation we are investigating occurs in desert areas, during non-raining days when the surface temperature does not necessarily drop below the dew point temperature at night. There are a series of basic studies, which can help to explain the phenomenon of diurnal emissivity variations during non-raining days in the dry season and in environmental conditions that do not favor the occurrence of dew formation on a bare sand dune. Agam and Berliner [2004, 2006] brought evidence of a new mechanism of direct water vapor adsorption on land surface. They also showed that the resulting soil moisture variations (with the soil moisture expressed by weight as the ratio of the mass of water present to the dry weight of the soil sample, units of kg kg−1 ) follow the daily cycle [Agam and Berliner, 2004] and the uppermost soil layer (0–1 cm) can change its water content from below ≈ 0.009 kg kg−1 (around midday) to above ≈ 0.02 kg kg−1 before sunrise. Mira et al. [2007a, 2007b] showed that the thermal infrared emissivity of rich-quartz sand strongly depends on soil moisture content. For low values of soil water content (around 0.02 kg kg−1 ), the incremental ratio, Δ𝜀∕Δ𝜃 , at wave numbers of reststrahlen absorption, is very large: Δ𝜀 ≈ 0.05 per Δ𝜃 = 0.01 kg kg−1 [Mira et al., 2007a, 2007b]. MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. 1626 Journal of Geophysical Research: Atmospheres 10.1002/jgrd.50863 The present study is devoted to complement the analysis by Li et al. [2012] and to provide further evidence that the mechanisms outlined in Agam and Berliner [2004, 2006] and Mira et al. [2007a, 2007b] are those responsible for the satellite-based emissivity diurnal variations observed in arid regions. Toward this objective we have analyzed IASI (Infrared Atmospheric Sounding Interferometer) spectra recorded over a Sahara desert area during the dry season (July 2010). Both descending (daytime) and ascending (nighttime) orbits have been considered, and the surface emissivity spectrum has been retrieved simultaneously with skin temperature and atmospheric parameters, namely temperature, water vapor, and ozone profiles, from IASI radiances. Space colocated day and night IASI observations have been used to assess diurnal emissivity variations. A quantitative analysis of the impact of these variations on the retrieval of surface temperature and atmospheric parameters is also carried out. We stress that the effect of soil moisture over thermal infrared emissivity has been assessed both with laboratory measurements and satellite observations [e.g., Ogawa et al., 2006; Mira et al., 2010; Hulley et al., 2010]. However, the present study focuses on the phenomenon of diurnal variation in emissivity of desert sand in situations in which soil moisture does not change because of rain or dew condensation. Diurnal variation in emissivity has also been evidenced with IASI observations by Zhou et al. [2011], who performed a retrieval of emissivity on a global scale. However, no attempt was made to assess the driving mechanism of these variations for desert regions. IASI was developed in France by the Centre National d’Etudes Spatiales (CNES) and is flying on board the Metop-A (Meteorological Operational Satellite) platform, the first of three satellites of the European Organization for the Exploitation of Meteorological Satellite (EUMETSAT) European Polar System (EPS). IASI has been primarily put in orbit for a meteorological mission; hence, its main objective is to provide suitable information on temperature and water vapor profiles. The instrument has a spectral coverage extending from 645 to 2760 cm−1 , which with a sampling interval Δ𝜎 = 0.25 cm−1 gives 8461 data points or channels for each single spectrum. Data samples are taken at intervals of 25 km along and across track, each sample having a minimum diameter of about 12 km. With a swath width on Earth’s surface of about 2000 km, global coverage is achieved in 12 h, during which the instrument records about 650,000 spectra. Further details on IASI and its mission objectives can be found in Hilton et al. [2012]. Regarding the assessment of the origin and mechanism of diurnal variation in emissivity, the complementary role of IASI stands out in its atmospheric sounding capability, which provides information about the thermodynamical state of the atmosphere together with surface parameters. The retrieval of surface and atmospheric parameters from IASI spectral radiances is carried out with a package that we call 𝜑-IASI, the methodological aspects and validation of which have been described in many papers [Amato et al., 1995, 1999; Lubrano et al., 2000; Masiello et al., 2003; Masiello and Serio, 2004; Grieco et al., 2007; Amato et al., 2009; Masiello et al., 2009; Grieco et al., 2010; Masiello et al., 2011, 2012a, 2012b]. The reader is referred to these papers for further details. For our analysis, it was important to identify a target area with surface features characterized as much as possible by sand rich in quartz and without vegetation. In addition, it was important to identify a series of IASI observations over a relatively long sequence of clear sky days in order to perform the analysis in non-raining meteorological conditions. To this end, together with IASI (level 1C) observations, we have also used high rate level 1.5 image data from SEVIRI on board Meteosat-9. SEVIRI channel emissivity maps over the North-West Sahara [Masiello et al., 2013b] helped to identify a target area characterized by sand dunes, whereas time sequences of SEVIRI radiances were used to identify long periods of clear skies. The present study is organized as follows. Section 2 shows the data used in the analysis, whereas section 3 describes the methodology. Section 4 is devoted to the results. Conclusions are summarized in section 5. 2. Data The selected study area is located over the Sahara Desert, Ouargla Province, Algeria (see Figure 1). The area extends from 4◦ to 8◦ of East longitude and 29◦ to 33◦ North latitude, at an average altitude of about 200 m. Sand dunes prevail with a low vegetative cover. IASI data have been acquired for the month of July 2010, that is, in the middle of the dry season. Observed spectra correspond to the descending (day) orbits and ascending (night) orbits. The IASI scan pattern of footprints for a typical day (ascending and descending MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. 1627 Journal of Geophysical Research: Atmospheres a) 10.1002/jgrd.50863 b) Figure 1. (a) Sahara target area (Ouargla Province, Algeria) showing the IASI footprints for a select few daytime (white circles) and nighttime orbits (black circles); (b) Example of day-night IASI footprints which overlap by more than 40%. orbits) is shown in Figure 1. Normally, we have approximately 400 spectra per day, of which half are in the morning (around 9 to 10 UTC) and the remaining half in the evening (around 20 to 21 UTC). The spectra were qualified as clear sky using the stand alone IASI cloud detection scheme developed by Serio et al. [2000]; Masiello et al. [2002, 2003, 2004] and Grieco et al. [2007]. A select few day-night spectra are shown in Figure 2 for the IASI band 1. The daytime IASI spectrum shows the characteristic peak at 8.7 μm (1149.40 cm−1 ), which corresponds to the center of the reststrahlen doublet of quartz. The nighttime spectrum clearly shows H2 O lines in emission in the atmospheric window around 1100 cm−1 (9 μm), which signals a temperature inversion at the surface. It has to be stressed here that ascending/descending IASI footprints (see also Figure 1a) are not perfectly overlapped. Therefore, the surface seen in the morning orbit could be different from that seen during the night. To limit as much as possible any bias due to spatial collocation, we have considered day-night footprints with an overlap greater than 40% (see, e.g., Figure 1b). IASI band 1 spectral radiance (r.u.) Another source of possible emissivity variation is the zenith angle. According to García-Santos et al. [2012], desert sand emissivity has an angular behavior, which becomes important for zenith angles > 40◦ . For this reason we have considered IASI pairs with a field of view angle lower than 40◦ . Based on the two selection rules above, the number of day-night 0.2 Day Spectrum; (32.89° N, 5.94° E); FOV angle: 13.88° couples available for each day of the 0.18 Night Spectrum; (31.86° N, 6.48° E); FOV angle: 20.12° month are shown in Figure 3. 0.16 Reststrahlen peak at 8.7 μ m 0.14 0.12 0.1 0.08 0.06 0.04 0.02 H O lines in emission 2 0 700 800 900 1000 1100 1200 wave number (cm−1) Figure 2. Example of select few day-night IASI spectra over the target area (Ouargla Province, Algeria). Note 1 r.u. (radiance units) corresponds to 1 W m−2 sr−1 (cm−1 )−1 . MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. Meteosat 9 high rate SEVIRI level 1.5 image data in the infrared for the same target area and time period were also extensively used to characterize the surface emissivity [Masiello et al., 2013b]. The SEVIRI instrument has eight infrared channels with peaks at 13.4 (746.30), 12.0 (833.33), 10.8 (925.90), 9.7 (1030.9), 8.7 (1149.40), 7.3 (1369.9), 6.2 (1612.9), and 3.9 (2564.10) μm (cm−1 ), respectively. The time resolution of the data is 15 min, whereas each pixel has a size of 3×3 km2 . Particularly interesting for the present analysis is the SEVIRI channel at 8.7 μm (1149.40 cm−1 ). In fact, this channel is 1628 Journal of Geophysical Research: Atmospheres located just in the quartz doublet peak of the reststrahlen band, which has a very high contrast within the atmospheric window. Using SEVIRI observations for July 2010 [Masiello et al., 2013b], it was possible to check that the selected study area shows emissivity features common to desert sand rich of quartz. 30 25 Number of IASI pairs 10.1002/jgrd.50863 20 15 In addition, SEVIRI data (colocated with IASI footprints) have been also used to identify clear sky through a direct inspection of the time sequence at SEVIRI 5 window channels, such as that at 12 μm (833.33 cm−1 ). An example is shown in 0 0 5 10 15 20 25 30 Figure 4, where the temporal evolution Day of the month (July 2010) of SEVIRI radiances at 12 μm is plotted Figure 3. Number of pairs of day-night IASI spectra considered to for the month of July. The figure correassess the diurnal emissivity variation. sponds to SEVIRI pixels at 30.66◦ North latitude and 5.56◦ East longitude. The radiance sequence follows exactly the daily cycle. Deviations (even small) from the smooth signal expected for clear sky allow us to detect the presence of clouds. From this plot we see that the first 10 days of the month were characterized as clear sky, whereas clouds were present at the end of the month (around 25 July). 10 3. Methods IASI spectra have been inverted for emissivity, skin temperature, and atmospheric parameters using the 𝜑-IASI package. As mentioned in section 1, the details of the package have been described at length in a series of papers. Here we limit ourselves to describe the methodology we use for emissivity, which is a relatively new aspect of the scheme. We use the optimal estimation [Rodgers, 2000] with the emissivity spectrum represented with a truncated Fourier transform series [Masiello and Serio, 2013a]. Emissivity Fourier coefficients, skin temperature (Ts ), and atmospheric parameters, temperature (T ), water vapor mixing ratio (w), and ozone mixing ratio (o) profiles, are simultaneously retrieved. Month of July 2010, SEVIRI pixel at 30.66° N., 5.56° E SEVIRI radiance at 12 µm (r.u. units) 0.18 0.16 0.14 0.12 0.1 0.08 0.06 Heavy Cloudiness Light Cloudiness 0.04 0 5 10 15 20 25 30 Time (day of the month) Figure 4. Sequence of SEVIRI radiance at 12μm for the month of July 2010. The continuity expected for clear sky helps to identify the presence of cloudiness. Note, 1 r.u. (radiance units) corresponds to 1 W m−2 sr−1 (cm−1 )−1 . MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. For the forward model, we use 𝜎 -IASI [Amato et al., 2002], which can handle the radiance term reflected from the surface either with a specular or Lambertian model. For the analysis shown in this paper, we use the Lambertian model. Within the inverse scheme, an important issue is the background vector and covariance matrix for emissivity. For the purpose of developing a suitable background for emissivity, we have used the University of Wisconsin (UW) Baseline Fit (BF) Emissivity database (UW/BFEMIS database, e.g., http://cimss.ssec.wisc. edu/iremis/ [Seemann et al., 2008]). The UW/BFEMIS database is derived from the monthly mean operational Aqua/MODIS (Moderate Resolution Imaging Spectroradiometer) products (called MYD11C3) using a conceptual model called the 1629 Journal of Geophysical Research: Atmospheres July 2010, location 32.85 N Lat, 7.61 E Lon. 1 0.95 Emissivity 0.9 0.85 0.8 0.75 0.7 IASI emissivity spectrum Hinge points from UW/BFEMIS 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 wave number (cm−1) 10.1002/jgrd.50863 Baseline Fit method developed from laboratory measurements of surface emissivity. This method is applied to fill in the spectral gaps between the six emissivity wavelengths available in MYD11C3 products. The UW/BFEMIS database is available from the year 2003 to 2012 globally with 0.05◦ spatial resolution at 10 wavelengths (3.6, 4.3, 5.0, 5.8, 7.6, 8.3, 9.3, 10.8, 12.1, and 14.3) μm. Those wavelengths were chosen as hinge points to capture as much of the shape of the higher resolution emissivity spectra as possible between 3.6 and 14.3 μm. The available band emissivities cannot be straightly interpolated to the IASI spectral bands, because this would be too crude an approximation. This problem has been addressed in Borbas and Ruston [2010] where an Empirical Orthogonal Function (EOF) regression was applied between the UW/BFEMIS database and the first five eigenvectors at high spectral resolution of a representative set of laboratory measurements of surface emissivity. In this study a similar algorithm has been developed to interpolate a low spectral resolution emissivity spectrum to the IASI wave number range. As in Borbas and Ruston [2010], the interpolation is based on the EOF decomposition of a suitable training data set of high spectral resolution emissivity spectra from laboratory measurements. For the present study, we used a total of 134 emissivity spectra from the ASTER (Advanced Spaceborne Thermal Emission Reflection Radiometer) Spectral Library version 2.0 [Baldridge et al., 2009] and the MODIS UCSB (Moderate Resolution Imaging Spectrometer, University of California, Santa Barbara) Emissivity Library (http://www. icess.ucsb.edu/modis/EMIS/html/em.html). An example of the interpolation from UW/BFEMIS to IASI is presented in Figure 5. Figure 5. IASI emissivity spectra derived from the UW/BFEMIS database for a case corresponding to a site located within the Ouargla district. The interpolation from the low spectral resolution emissivities to the IASI emissivity spectrum is based on the EOF decomposition of a suitable training data set of high spectral resolution emissivity spectra from laboratory measurements (see text for more details). Derived from the UW/BFEMIS database, these IASI spectral resolution emissivity spectra have been used to build up an appropriate a priori or background (mean and covariance) for the optimal estimation retrieval. For the emissivity-covariance matrix, we only considered the diagonal elements (variances). As noted, in our retrieval procedure, the emissivity spectrum is represented through decomposition in a truncated Fourier cosine series. The truncation point can depend on the surface type. For desert sand, we need to resolve the reststrahlen absorption band at 8.7 μm. For this reason, we have used 400 Fourier coefficients, which correspond to render the emissivity spectrum with a spectral resolution of ≈ 5 cm−1 . Comparison with laboratory measurements shows that this spectral resolution is enough to resolve the spectral structures present within desert sand emissivity [Masiello and Serio, 2013a]. Further details on how we handle the retrieval of surface emissivity can be found in Masiello and Serio [2013a]. Here we limit to show a retrieval example from one IASI spectrum recorded over desert sand. The example (see Figure 6) is shown here also to exemplify the precision of the retrieval. The precision is computed as the square root of the diagonal of the a posteriori covariance matrix. An additional important aspect of the methodology is that we can retrieve the emissivity spectrum over the entire IASI spectral coverage, even though we only used a limited number of IASI channels (see Figure 6). At wave numbers not used for the mathematical inversion of IASI radiances, the retrieved emissivity spectrum is just an interpolation of the Fourier cosine series. It is also important to stress that as the IASI spectrum is mostly sensitive to surface emission in atmospheric window spectral regions, the emissivity retrieval is most significant in those regions. MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. 1630 Journal of Geophysical Research: Atmospheres a) Emissivity 1 Emissivity retrieval ± 1 σ error bar 0.8 0.6 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 IASI spectrum (r.u.) wave number (cm−1) 0.15 b) IASI spectrum Channels used for retrieval 0.1 0.05 0 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 wave number (cm−1) Figure 6. (a) Example of one IASI surface emissivity spectrum retrieval over desert sand. The emissivity was simultaneously retrieved with surface temperature, temperature, water vapor, and ozone atmospheric profiles, using (b) the channels shown. Note 1 r.u. (radiance units) corresponds to 1 W m−2 sr−1 (cm−1 )−1 . 10.1002/jgrd.50863 As described earlier, we use the optimal estimation [Rodgers, 2000] to retrieve the state vector. Within the context of optimal estimation theory we can also address the issue of the sensitivity of the retrieval to the variation by a model parameter, which, e.g., is not included in the state vector. The general problem of sensitivity to a given interfering parameter can be handled by considering the derivative of the retrieved vector, 𝐯̂ with respect to the perturbation introduced by the interfering parameter, e.g., spectral emissivity. According to Carissimo et al. [2005], this derivative can be written as ( )−1 T −1 𝜕 𝐯̂ = 𝐒−1 + 𝐊T 𝐒−1 𝐊 𝐊 𝐒e 𝐊X (1) a e 𝜕𝐗 where 1. 𝐯̂ is the retrieved state vector, 2. 𝐗 denotes the generic interfering parameter-vector, 3. 𝐒a is the state vector background matrix, 4. 𝐒e is the observational covariance matrix, (e.g., IASI radiometric noise), 5. 𝐊 is the Jacobian matrix of the state vector, 6. 𝐊X is the Jacobian matrix of the emissivity vector. The sensitivity of the state vector, Δ𝐯̂ to a given perturbation, Δ𝐗 is obtained as Δ𝐯̂ = 𝜕 𝐯̂ Δ𝐗 𝜕𝐗 (2) As already mentioned, the way we handle the various Jacobian terms and covariance matrix has been detailed at a length in previous papers. In particular, the reader interested in the details of 𝐒a , which we use in our retrieval scheme, is referred to Masiello et al. [2012a]. If we identify Δ𝐗 with the diurnal variation in emissivity, the methodology above can be used to assess the impact over the estimated state vector of this variation in case the emissivity is not retrieved and its value is taken, e.g., from a suitable atlas, such as the UW/BFEMIS database. Finally, we recall that the soil moisture (𝜃 ) is defined according to its gravimetric method of measurement, 𝜃= wtw − wtd wtd (3) where wtw is the mass of wet soil and wtd that of the dry soil. 4. Results The IASI spectra corresponding to day-night pairs identified in Figure 3 have been inverted for the simultaneous retrieval of 𝜀, Ts , T , w, and o, according to the methodology outlined in section 3. The number of IASI channels considered for the retrieval are those shown in Figure 6. To make a proper comparison, e.g., with the results shown in Li et al. [2012] and also to capture salient characteristics in the diurnal emissivity variation, the IASI emissivity retrieval has been transformed to the SEVIRI channel emissivity at 12, 10.8, and 8.7 μm, by convolving the IASI spectrum emissivity with the SEVIRI instrument response at 12, 10.8, and 8.7 μm, respectively. The results for the days for which we had available MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. 1631 Journal of Geophysical Research: Atmospheres pairs to allow computation are shown in Figure 7. Averaging the results over the whole month, we found an average diurnal emissivity variation of 0.029 at 8.7 μm, 0.019 at 10.8 μm, and 0.014 at 12 μm. 0.08 12 μm 10.8 μm 8.7 μm Diurnal Emissivity Variation 0.07 10.1002/jgrd.50863 0.06 0.05 0.04 0.03 0.02 0.01 0 −0.01 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 Day of the Month (July 2010) Figure 7. Diurnal variation in emissivity at 12, 10.8, and 8.7 μm for the month July 2010. For each day, the diurnal variation has been averaged over the number of pairs shown in Figure 3). From Figure 7, we see that the largest diurnal variations are seen around periods with heavy cloudiness (compare with Figure 4). If we focus on the most stable, non-raining period, that is, the first 10 days of the month, we see that the diurnal variation is confined below 0.04 at 8.7 μm and, normally, well below 0.02 at 10.8 and 12.8 μm. According to Li et al. [2012], we also see that the diurnal variation is larger at 8.7 μm than at 10.8 μm, which, in turn, is larger than that at 12 μm. Details of the diurnal variation in spectral emissivity for 6 and 20 July, which correspond to two clear sky days with the larger number of couples of IASI day-night spectra and in the middle of two long periods of clear skies are shown in Figures 8 (left) and 8 (middle), respectively. A direct computation of the dew point temperature, derived from the IASI retrieval, shows that the diurnal variation we see in Figure 8 cannot be due to the formation of dew, because the dew point temperature is found well below the surface temperature. An example is shown in Figure 9 for 20 July 2010. A similar behavior was also found by Li et al. [2012]. As a consequence, on the assumption that the observed diurnal emissivity variation seen in Figures 8 (left) and 8 (middle) is due to soil moisture, according to Agam and Berliner [2004, 2006], the only mechanism responsible for the change is that of direct water vapor adsorption at the surface. To support this conclusion, we have analyzed the thermodynamical state of the atmosphere close to the surface. For 6 and 20 July 2010, this analysis is shown again in Figures 8 (left) and 8 (middle). The daytime retrieval does not show any inversion close to the surface and has a normal shape that favors evaporation. Conversely, the nighttime temperature profiles show an evident inversion, which traps water vapor close to the surface. This temperature inversion is consistent with the mechanism for H2 O adsorption and drives the day-night emissivity variation. In the same figures, the water vapor profile is also shown. It is possible to see that the day-night variation of H2 O is very low. For 6 and 20 July, the diurnal variation in water vapor column amount (day-night) is of 0.23 cm and 0.16 cm, respectively. This very small variation leads us to conclude that the atmosphere was very stable, and the presence of moisture by large scale atmospheric circulation was likely absent. To further support the above conclusion, Figure 8 (right) also shows the results for 26 July 2010. On this day, the diurnal variation was very low (below 0.005 at 8.7 μm) and the emissivity retrieval at ≈9 UTC was almost identical to that at ≈20 UTC. However, for this day, the nighttime temperature profiles do not show any evident inversion in the boundary layer (see again Figure 9, right). This result confirms that the mechanism which causes the diurnal emissivity variation is governed by a boundary layer temperature inversion. Also, a strong diurnal temperature difference seems to be important for the emissivity variation. This difference was ≈12 K for 26 July, whereas for 6 and 20 July, this was 19 K and 20 K, respectively. The temperature profiles shown in Figure 8 have been averaged over the number of soundings available for the given days. This averaging operation tends to smooth the inversion in the lower troposphere. However, the inversion is very well seen in each single retrieval and takes place very close to the surface. This is exemplified for one single temperature retrieval in Figure 10a, which also compares the IASI retrieved temperature with the time-space colocated ECMWF analysis. The ECMWF analysis at the canonical hours of 00, 06, 12, 18, 24 UTC were used for the time interpolation. It is seen that the ECMWF model greatly MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. 1632 Journal of Geophysical Research: Atmospheres 10.1002/jgrd.50863 Day: 06 July 2010 Day Night 0.9 0.8 a) 0.7 700 800 Pressure (hPa) 0 900 1000 wave number (cm−1) 0 Day Night 200 400 600 1200 Day Night 400 600 800 800 c) b) 1000 0 1100 200 Pressure (hPa) Emissivity 1 5 10 15 H2O mixing ratio (g/kg) 1000 200 250 300 Temperature (K) Emissivity Day: 20 July 2010 Day Night 0.9 0.8 0.7 a) 700 800 900 1000 wave number (cm−1) 200 400 600 Day Night 200 800 400 600 800 b) 1000 0 1200 0 Day Night Pressure (hPa) Pressure (hPa) 0 1100 c) 5 10 15 H O mixing ratio (g/kg) 1000 200 250 300 Temperature (K) 2 Emissivity Day: 26 July 2010 Day Night 0.9 0.8 0.7 a) 700 800 900 1000 wave number (cm−1) 200 400 600 800 Day Night 200 400 600 800 c) b) 1000 0 1200 0 Day Night Pressure (hPa) Pressure (hPa) 0 1100 5 10 H O mixing ratio (g/kg) 1000 15 200 2 250 300 Temperature (K) Figure 8. (a) Night and day time IASI emissivity spectra, (b) IASI H2 O retrieval, and (c) temperature retrieval for 3 days of July 2010: (top) 6 July, (middle) 20 July, and (bottom) 26 July. The retrievals have been averaged over the number of IASI pairs shown in Figure 3. MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. 1633 Journal of Geophysical Research: Atmospheres smoothes the temperature day-night dynamic in the lower troposphere, which, conversely, appears much more pronounced in the IASI retrieval. 20 July 2010: Daytime Temperature (K) 60 a) 40 10.1002/jgrd.50863 Dew Point Temperature Surface Temperature From Figure 10, we see that an inversion occurs in between 975 and 925 hPa, 0 which corresponds to a boundary layer 0 5 10 15 20 25 30 altitude of ≈ 500 m. It could be questionIASI sounding number 20 July 2010: Nighttime able whether or not IASI has this high 60 vertical spatial resolution close to the b) Dew Point Temperature Surface Temperature surface. To demonstrate that in fact IASI 40 does have this high spatial vertical resolution, Figures 10b and 10c show the 20 averaging kernels for the two IASI temperature retrievals shown in Figure 10a. 0 0 5 10 15 20 25 30 The very highly resolved averaging kerIASI sounding number nels close to the surface, as already Figure 9. (a) Daytime and (b) Nighttime IASI dew point and surface mentioned, are a result of the desert temperature for 20 July 2010. The retrieval was obtained at each single sand emissivity, which yields a strong IASI footprint available on that day. contrast throughout most of the IASI bands 1 and 3. What is important to capture in Figures 10b and 10c is the fact that the averaging kernels peak almost exactly at the corresponding layer pressure. This behavior shows that the retrieval is spatially resolved in the vertical at those layers in the lower troposphere. Temperature (K) 20 The results we have shown have been obtained over a target area, whose surface consists of bare sand dunes. In these conditions, the emissivity is largely determined by a mixture of two components: soil water content and sand. According to Hillel [1998], the process responsible for water vapor adsorption by soils is a reversible physical adsorption, which allows us to deal with moist soil as if it were mainly a mixture of water and sand. Chemical processes do not play an important role in this adsorption mechanism [Hillel, 1998]. In this respect, if these two components are additively combined, according to their abundance in the mixture, we obtain a composite emissivity, 𝜀(𝜎) given by 𝜀(𝜎) = (1 − 𝜃)𝜀q (𝜎) + 𝜃𝜀w (𝜎) (4) where 𝜀q (𝜎) is the emissivity of sand and 𝜀w (𝜎) that of water. Nighttime a) Temperature (K) Daytime 700 700 740 760 780 800 820 840 860 880 900 920 940 960 980 1000 −0.1 P=979.2 hPa P=966.2 hPa P=952.7 hPa P=939.3 hPa P=928.9 hPa P=919 hPa P=906.5 hPa 720 740 Atmospheric Pressure (hPa) P=979.2 hPa P=966.2 hPa P=952.7 hPa P=939.3 hPa P=928.9 hPa P=919 hPa P=906.5 hPa 720 Atmospheric Pressure (hPa) Atmopsheric Pressure (hPa) 06−July−2010, 31.76° N, 7.85° E 500 Nighttime IASI, FOV angle 1.43°, UTC 20:35 525 Nighttime ECMWF 550 Daytime ECMWF 575 Daytime IASI, FOV angle 1.37°, UTC 09:18 600 625 650 Retrieved Surface Temperature 675 Day: 324.5 K 700 Night: 307.4 K 725 750 775 800 825 850 875 900 925 950 975 1000 260 265 270 275 280 285 290 295 300 305 310 315 320 325 330 760 780 800 820 840 860 880 900 920 940 960 b) 980 0 0.1 0.2 0.3 Averaging Kernels for Temp. 1000 −0.1 c) 0 0.1 0.2 0.3 Averaging Kernels for Temp. Figure 10. a) Example of day-night IASI retrieval for temperature in the lower troposphere for a single IASI footprint. The figure also shows a comparison with the colocated ECMWF analysis. (b) Nighttime and (c) daytime show the temperature averaging kernels, corresponding to the retrieval shown in Figure 10a. The averaging kernels are shown for the lowermost seven tropospheric layers. MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. 1634 Journal of Geophysical Research: Atmospheres Under a variation 𝛿𝜃 of soil moisture, a variation 𝛿𝜀(𝜎) is given by 06 July 2010 30 Day Night ( ) 𝛿𝜀(𝜎) = 𝛿𝜃 𝜀w (𝜎) − 𝜀q (𝜎) 25 Field of View angle (degrees) 10.1002/jgrd.50863 (5) Since 𝜀w ≈ 1 in the whole infrared range, the difference 𝜀w (𝜎) − 𝜀q (𝜎) has a very large amplitude (contrast) at the rest15 strahlen doublet of quartz, where 𝜀q (𝜎) can be as low as 0.6 [Baldridge et al., 2009]. 10 This is why we see that the effect of diurnal variation is larger at 8.7 μm than at 5 10.8 and 12.0 μm. In addition, the above model states that a reverse sign in the 0 diurnal variation is possible in spectral 0 5 10 15 20 25 30 regions where the difference 𝜀w (𝜎) − 𝜀q (𝜎) IASI sounding number changes its signs. For the type of surface Figure 11. Field of view angle of the 28 day-night IASI pairs for 6 July we have analyzed, we expect that, within 2010. the atmospheric window, water has the larger emissivity. Therefore, the sign of the diurnal variation (nighttime-daytime) should normally be positive at window channels such as 8.7, 10.8, and 12 μm. However, especially at 12 μm, we may have land features with emissivities larger than that of water and a reverse sign could be possible. This reverse sign has been observed by Li et al. [2012], who examined a much larger area than that analyzed in this paper. 20 According to Agam and Berliner [2004, 2006], diurnal variations in the uppermost 1 cm soil layer moisture due to the direct H2 O adsorption have amplitudes of approximately 2%. This variation might be not enough to explain the diurnal variation we have observed in the atmospheric window. However, thermal infrared measurements from satellite are sensitive to the top few micrometers. Thus, a 2% amplitude below the surface could not be representative of what is occurring in the topmost layer, where the effect could be larger, and therefore explains the magnitude of diurnal variation we see at 8.7 μm. It is also fair to say that a non-Lambertian behavior has been evidenced in quartz powder [Wald and Salisbury, 1992], which at large angles (≥ 70◦ ) has the effect of decreasing the emissivity. A similar behavior has been evidenced in a recent paper by García-Santos et al. [2012], who also claimed that a non-Lambertian behavior begins to be evident at zenith angle larger than 40◦ . 1 Emissivity a) 0.9 0.8 0.7 IASI−day UW/BFEMIS 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 wave number (cm−1) 1 Emissivity b) 0.9 IASI−night UW/BFEMIS 0.8 0.7 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 wave number (cm−1) Figure 12. Day and night average emissivity computed on the basis of the 28 pairs of IASI soundings for 6 July 2010. (a) Daytime average emissivity; (b) nighttime average emissivity. The figure also shows the average emissivity obtained by the UW/BFEMIS database. MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. However, as already discussed, to limit possible angular dependence of the sand emissivity, the IASI day-night couples we have analyzed in this paper refer to zenith angles below 40◦ . In addition, the relative zenith angle, that is, the day-night difference of the field of view angle does not exceed 10◦ for any single day-night pair analyzed in this paper. In other words, the two IASI spectra of any single pair are observed with almost the same field of view angle. This is exemplified for 6 July 2010 in Figure 11. 4.1. Sensitivity of Skin Temperature and Atmospheric Parameters Retrieval to Diurnal Emissivity Variation How significant are these diurnal variations and what impact do they have on the retrieval of skin temperature, Ts and 1635 Journal of Geophysical Research: Atmospheres atmospheric parameters, temperature, water vapor, and ozone, (T , w, and o)? 0 a) Pressure (hPa) Number of Events 10 5 0 −3 −2.5 −2 −1.5 −1 −0.5 b) 500 1000 −4 −2 0 2 ΔTs 4 6 8 10 ΔT (K) Pressure (hPa) Pressure (hPa) 0 c) 500 1000 −2 −1 0 Δw (g/kg) 1 2 d) 10 10 0 2 −1 0 1 10.1002/jgrd.50863 These issues have been addressed by applying the sensitivity analysis illustrated in section 3 to the retrieval obtained for 6 July 2010. This day is in the middle of a non-raining period with an average diurnal variation in emissivity at 8.7 μm of 0.04. We have 28 day-night IASI soundings for 6 July 2010, the day and night average emissivity for which is shown in Figure 12. For each single daytime sounding, we have computed Δ𝐯̂ corresponding to the perturbation, 2 Δo (ppmv) Figure 13. IASI Retrieval sensitivity to the diurnal emissivity variation. The figure shows the impact on the retrieval by imposing for the daytime retrievals the nighttime emissivity instead of that correct for daytime; (a) histogram of ΔTs ; (b) average difference, ΔT ; (c) average difference, Δw; and (d) average difference, Δo. Δ𝐗 ≡ Δ𝜺 = 𝜺day − 𝜺night (6) In this way, we mimic the effect of using the nighttime emissivity to invert daytime IASI soundings. The results have been averaged over the 28 daytime IASI soundings and are shown in Figure 13. For the case of Ts , we find that this parameter would be negatively biased, because we use an emissivity, which is larger than the (supposedly) correct one, obtained within the simultaneous retrieval (section 4). The average negative bias for the surface temperature is equal to −1.5 K. For the atmospheric parameters we also see a consistent bias, which means that the diurnal variation has a large impact over the retrieval of these parameters. The bias for temperature has a peak value of 8 K in the lower troposphere, whereas for water vapor we observe a difference of ±1 g/kg. For ozone we also observe a consistent bias of 1 ppmv. A second example is obtained by considering a variation with respect to the emissivity obtained by the UW/BFEMIS database. Derived from MODIS day-night products, the UW/BFEMIS database emissivity assumes a constant emissivity between day and night in the retrieval. Thus, it does not represent an average of diurnal variations, but it is simply one emissivity per day and, therefore, the present sensitivity exercise is also important to check the quality of satellite products, where emissivity is assumed to be diurnally invariant. In performing the sensitivity exercise, the UW/BFEMIS emissivity is imposed on the retrieval and the difference is considered for the case in which emissivity is itself retrieved along with Ts , T , w, and o. This latter retrieval exercise is that we have just shown in section 4. For the 28 day-night IASI soundings, the average UW/BFEMIS emissivity is compared to the retrieved emissivity in Figure 12. In the case of the daytime IASI soundings, the emissivity perturbation is computed according to Δ𝜺 = 𝜺day − 𝜺UW/BFEMIS (7) In the same way for the nighttime soundings, we have Δ𝜺 = 𝜺night − 𝜺UW/BFEMIS (8) The results of the sensitivity analysis are summarized in Figure 14. For the case of skin temperature, we have that the assumption of imposing on the retrieval the UW/BFEMIS emissivity instead of simultaneously retrieving it with the other parameters, would result in a downward bias in Ts during the day and, the reverse, an upward bias in Ts would result at night. However, on average, the degree of this bias is confined to within ±1 K (−0.40 K in the daytime and +0.68 K at nighttime). The impact on atmospheric parameters appears to be much larger. The temperature can be affected by ±5 K in the lower troposphere, the water vapor mixing ratio by ±2 g/kg and ozone by up to 2 ppmv in the stratosphere. MASIELLO ET AL. ©2013. American Geophysical Union. All Rights Reserved. 1636 Journal of Geophysical Research: Atmospheres Night Day 10 5 −2 −1 0 1 Pressure (hPa) Number of Events a) 0 5. Conclusions 0 15 b) Night Day 500 1000 −6 −4 −2 2 ΔTs 0 2 4 6 8 ΔT (K) Night Day 500 1000 −6 Pressure (hPa) Pressure (hPa) 0 c) 10.1002/jgrd.50863 d) Night Day 0 10 2 10 We have addressed the issue of diurnal variation in the emissivity spectrum of desert sand with a series of day-night IASI soundings recorded over the Sahara Desert during July 2010. In our analysis, great care has been taken to ensure that (a) the target area included only bare sand dunes, (b) there was a long sequence of clear sky with no rain, and (c) the IASI angle of views were below 40◦ to minimize other possible sources of emissivity variation. In agreement with Li et al. [2012], our analysis does find evidence of diurnal variations in the emissivity specFigure 14. IASI Retrieval sensitivity to the diurnal emissivity variatrum. Nighttime emissivity is found to tion. The figure shows the impact on the retrieval by imposing the UW/BFEMIS emissivity instead of that correct for daytime/nightime; (a) be systematically larger than that histogram of ΔTs ; (b) average difference, ΔT ; (c) average difference, Δw; retrieved during the daytime, which and (d) average difference, Δo. leads us to conclude that the soil moisture undergoes a daily cycle with a dip around midday and a peak at night. −4 −2 0 2 Δw (g/kg) 4 6 −2 −1 0 1 2 Δo (ppmv) This conclusion is consistent with previous results by Agam and Berliner [2004, 2006], who showed that H2 O can be directly adsorbed at the surface without the formation of dew. During the dry season, the amplitude of the soil moisture cycle is normally 1–2%. These values refer to the top few centimeters of soil moisture, while thermal infrared measurements represent the top few micrometers. Accounting also for nonlinear volume scattering effects and further experimental evidence [Mira et al., 2007a, 2007b] about the effect of soil moisture on rich-quartz sand, we conclude that this amplitude is enough to yield diurnal variations in emissivity at 8.7 μm as large as 0.04. The question of how common this phenomenon is can be raised. Direct adsorption of water vapor has been shown for arid and semiarid regions [Agam and Berliner, 2006]. However, the phenomenon depends on the thermal and hydraulic properties of the surface and these properties can vary significantly for different soil types. Normally, the presence of clay improves the adsorption mechanism [Agam and Berliner, 2006]. If we limit to stable, dry meteorological conditions, the transport of water vapor is driven by moisture and temperature gradients. Thus, a temperature inversion close to the surface is important to transport moisture toward the surface, as well, it is necessary that relative humidity of the soils pores is lower than the relative humidity of the air. As far as the transport of atmospheric water vapor toward the surface is concerned, IASI retrieval of the thermodynamic state of the atmosphere has shown that at nighttime an atmospheric temperature inversion occurs close to surface and creates a thin boundary layer which acts like a lid, trapping water vapor close to land and supposedly driving the direct adsorption of H2 O at the surface during the night. Acknowledgments IASI has been developed and built under the responsibility of the Centre National d’Etudes Spatiales (CNES, France). It is flown onboard the Metop satellites as part of the EUMETSAT Polar System. The IASI L1 data are received through the EUMETCast near real time data distribution service. Work partially supported through EUMETSAT contract EUM/CO/11/4600000996/PDW. We wish to thank Dr Zhenglong Li of SSEC, University of Wisconsin, for a critical reading of the manuscript and for the valid comments he provided to us. MASIELLO ET AL. The results we have found lead us to conclude that the common belief that the desert sand emissivity is stable during the year is not correct and that diurnal variations have to be properly taken into account for a correct retrieval of surface and atmospheric parameters. In this respect, our findings specifically point out the importance of using physically based algorithms to retrieve surface temperature and emissivity. 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