(www.tiwariacademy.com) (Chapter β 3) (Atoms and Molecules) 3 Marks each Question 1: John placed 10 moles of sulphur molecules (S8) and 5 moles of glucose (C6H12O6) in the two different pans of a physical balance. Find which pan of the balance would be heavier, support your answer with calculations. (Atomic mass: O = 16 u, C = 12 u, H = 1 u, S = 32 u) [CBSE 2014] Answer 1: Molecular mass of sulphur molecules (S8) = 32 × 8 = 256 gm Molecular mass of glucose (C6H12O6) =(6 × 12) +( 1 × 12) +( 6 × 16) = 72 + 12 + 96=180 Weight of 10 moles of S8 =10 × 256 = 2560 Weight of 5 moles of glucose = 5 × 180 = 900 Therefore, 10 moles of sulphur would weigh more. www.tiwariacademy.com A Free web support in education (www.tiwariacademy.com) (Chapter β 3) (Atoms and Molecules) Question 2: (a) What is Avogadro constant? (b) Calculate the number of particles present in 56 gm of N2 molecule. [CBSE 2012] Answer 2: (a) The number of atoms or molecules in 12 gm of carbon-12 ( in a mole of a substance) is called as Avogadro constant (6.022 × 1023 ) (b) Number of molecules(N) = πΊππ£ππ πππ π ×π΄π£ππππππβ² ππ’ππππ πππππ πππ π Molar mass of 1 mole of N2 = 14 × 2 =28 N= 56 ×6.022 × 1023 28 N = 12.044 × 1023 Hence there are 12.044 × 1023 particles present in 56 gm of N2 Question 3: Calculate the number of moles present in (a) 60 g of calcium. (b) 3.011 × 1023 number of oxygen atoms. [Given that Ca = 40 u; Avogadro number, NA = 6.022 × 1023 per mole] [CBSE 2012] Answer 3: (a) Number of moles of Ca = (b) Number of moles = πΊππ£ππ πππ π ππ πΆπππππ’π πππππ πππ π ππ πΆπππππ’π πΊππ£ππ ππ’ππππ ππ ππππππ’πππ 6.022×1023 = = 60 40 = 1.5 moles 3.011×1023 6.022×1023 www.tiwariacademy.com A Free web support in education = 0.5mol (www.tiwariacademy.com) (Chapter β 3) (Atoms and Molecules) Question 4: (a) The average atomic mass of a sample of an element X is 35.5u. What are the percentages of isotopes 17X37 and 17X35 in the sample ? (b) Write any two applications of isotopes. [CBSE 2012] Answer 4: (a) Let the percentage of 37 17π is p Percentage of 35 17π = (100 β p) Average atomic weight = 35.5 Therefore 35.5 = 37π + 35(100 β π) 100 3550 = 37p + 3500 β 35p 3550 β 3500 = 37p - 35p 2p = 50 β p = 25% 35 Therefore, sample of 37 17π is 25% and 17π will be 100 β 25 = 75% (b) Cesium 137 β Used to treat cancerous tumors. Calcium 47 β It is an important aid for biomedical researchers studying the cellular functions. www.tiwariacademy.com A Free web support in education (www.tiwariacademy.com) (Chapter β 3) (Atoms and Molecules) Question 5: Nitu presented a silver lamp to her mother on her birthday. The lamp contained 3. 011 × 1023 atoms of silver in it. What is the mass of silver lamp and the cost of it if 1 gm silver costs βΉ 60. Atomic mass of Ag = 108 u, N0 = 6.022 × 1023 per mole. [CBSE 2012] Answer 5: Atomic mass of silver (Ag) = 108 u Since mass of 6.022 × 1023 atoms of silver (Ag) = 108 u Hence mass of 3.011 × 1023 atoms of silver (Ag) = 108×3.011×1023 6.022×1023 = 54 gm Cost of 1 gm silver = 60 Therefore, cost of silver lamp = 60 × 54 = βΉ 3240 Question 6: Give an account of the βmole conceptβ. [CBSE 2011] Answer 6: Mole is a unit to express amount of any chemical compound that contains atoms/molecules/ions equal to atoms present in 12 gram of carbon-12 isotope. This number of atoms is fixed and is equal to 6.022 × 1023 (Avagadroβs number). Thus a mole expresses a collection of 6.022 × 1023 atoms, molecules, ions, etc. For e.g., 1 mole of oxygen atom refers to 6.022 × 1023 atoms of oxygen. www.tiwariacademy.com A Free web support in education (www.tiwariacademy.com) (Chapter β 3) (Atoms and Molecules) Question 7: Calculate the ratio by number of atoms for Magnesium sulphide. [Atomic mass of Mg => 24, S => 32] [CBSE 2011] Answer 7: Atomic mass of Mg = 24 Atomic mass of S = 32 Ratio of Mg and S in Magnesium sulphide = 24:32 = 3:4 Mass ratio / Atomic mass of Magnesium (Mg) = Mass ratio / Atomic mass of Sulphur (S) = 4 32 = 3 24 1 8 = 1 8 1 1 Hence, ratio of atoms in Magnesium sulphide (MgS) = : or 1 : 1. 8 8 www.tiwariacademy.com A Free web support in education
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