Center for Academic Services & Advising November 9, 2015 Chemistry I CSI Worksheet 9 1. Determine whether each transition in the Hydrogen atom corresponds to absorption or emission of energy a. n = 3 → n = 1 emission: electron is moving to a lower energy level b. n = 2 → n = 4 absorption: electron is moving to a higher energy level c. n = 4 → n = 3 emission: electron is moving to a lower energy level 2. Write the full electron configuration for each element a. C 1s22s22p2 b. P 1s22s22p63s23p3 c. Ar 1s22s22p63s23p6 d. Na 1s22s22p63s1 3. Determine the element corresponding to each electron configuration a. [Ar] 4s23d104p6 Kr b. [Ar] 4s23d2 Ti c. [Kr] 5s24d105p2 Sn d. [Kr]5s2 Sr 4. Determine the number of valence electrons in each element. Which elements do you expect to lose electrons in chemical reactions? Which do you expect to gain electrons? a. Al 3 because in column 3A; will lose 3 electrons to have the same configuration as [Ne] b. Sn 4 because in column 4A; will either lose 4 electrons to have the configuration of [Kr] or two to have the configuration of Cd c. Br 7 because in column 7A; will gain one electron to have the configuration of [Kr] d. Se 6 because in column 6A; will gain two electrons to have the configuration of [Kr] 5. Arrange the following atoms according to decreasing effective nuclear charge experienced by their valence electrons: S, Mg, Al, Si S = [Ne] 3s23p4 Mg = [Ne] 3s2 Al = [Ne] 3s23p1 Si = [Ne] 3s23p2 COLORADO SCHOOL OF MINES Frances I Core Supplemental Instruction Facilitator | Chemistry II Center for Academic Services & Advising All of them have the same number of core electrons to contribute to shielding so nuclear charge will be due to the number of protons S = 16 Mg = 12 Al=13 Si=14 Oder: S>Si>Al>Mg 6. Write the electron configuration for each ion: a. ClCl = [Ne] 3s23p5 Cl-= [Ne] 3s23p6 b. P3P =[Ne]3s23p3 P3- = [Ne] 3s23p6 c. K+ K = [Ar] 4s1 K+= [Ar] d. Mo3+ Mo = [Kr]5s14d5 Mo3+= [Kr] 5s04d3 OR [Kr] 4d3 e. V3+ V = [Ar]4s23d3 V3+= [Ar] 4s03d2 OR [Ar]3d2 7. Arrange the following elements in order of decreasing first ionization energy: Cl, S, Sn, Pb Ionization energy increases moving across the periodic table to the right and increases moving up each column Cl>S>Sn>Pb 8. Choose the element with the more negative (more exothermic) electron affinity from each pair: a. Mg or S S b. K or Cs K c. Si or P Si d. Ga or Br Br 9. Arrange the following elements in order of decreasing metallic character: Sr, N, Si, P, Ga, Al Metallic character decreases moving left to right across the periodic table and decreases moving up a column Sr>Ga>Al>Si>P>N 10. Write a balanced chemical equation for the reaction of chlorine gas with fluorine gas COLORADO SCHOOL OF MINES Frances I Core Supplemental Instruction Facilitator | Chemistry II
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