MATERIAL SAFETY DATA SHEET – HYDROGEN PEROXIDE SOLUTION - 10 VOLUME 3% 1 The information provided in this Material Safety Data Sheet has been obtained from sources believed to be reliable. RW Packaging Ltd. provides no warranties, expressed or implied and assumes no responsibility for the accuracy of the data contained herein. 1. IDENTIFICATION Product Name: HYDROGEN PEROXIDE SOLUTION, 10 VOLUME 3% Manufacturer: RW Packaging Ltd. 200 Omand’s Creek Blvd. Winnipeg, Manitoba Canada R2R 1V7 Ph: (204) 786-6873 Emergency Telephone No.: (613) 996-6666 (Canutec) Composition/Purity of 2.5% -3.5% Hydrogen Peroxide Hazardous Ingredients: IUPAC Chemical Name: Hydrogen Peroxide Synonym(s): Albone, perone, hydrogen dioxide, perhydrol, hydroperoxide, peroxide CAS Registry Number: 7722-84-1 PIN-UN/NA Number(s): Not regulated TDG Classification (Class, Division and Packing Group): N/A Chemical Family: Organic peroxide Molecular Formula: H2-O2 Structural Formula: HO-OH MATERIAL SAFETY DATA SHEET – HYDROGEN PEROXIDE SOLUTION - 10 VOLUME 3% 2 WHMIS Classification: D2A, C Warning Properties: Toxic and an oxidizer General Descriptions Appearance, Odour and State: Clear, odorless liquid Odour Threshold: No data Uses and Occurrences: Used as is as a disinfectant for cuts, sores and wounds; to relieve itching from mosquito bites; to treat water; pharmaceuticals. 2. PHYSICAL DATA Boiling Point: 100 °C Molecular Weight: 34.01 Melting Point/Freezing Point: 0°C Specific Gravity (Water=1): 1.01 @ 20°C Solubility in Water: Infinitely soluble pH: 3.5-5 @ 20°C Solubility in Other Liquids: Soluble in alcohols and ethers. Vapour Density (Air-1): no information found Vapour Pressure no information found % Volatiles by volume: 100 @ 21°C Saturation Vapour Concentration: No Data Evaporation Rate (Butyl Acetate=1): No Data Co-efficient of Water/Oil Distribution: No data MATERIAL SAFETY DATA SHEET – HYDROGEN PEROXIDE SOLUTION - 10 VOLUME 3% 3 3. FIRE AND EXPLOSION HAZARDS Fire : Not considered to be a fire hazard. Concentrated hydrogen peroxide (< 30%) is a strong oxidizer, but this dilute product does not present that hazard. Explosion: Not considered to be an explosion hazard. Drying of concentrated hydrogen peroxide on clothing or other combustible materials may cause fire or explosion. Fire Extinguishing Media: Preferably water, but use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. 4. STABILITY AND REACTIVITY Chemical Stability: Stable under ordinary conditions of use and storage. Incompatibility: Heat, reducing agents, organic materials, dirt alkalis, rust, and many metals. Hazardous Decomposition Products: Decomposes to water and oxygen. Hazardous Polymerization: Will not occur. Conditions to Avoid: Light, heat, incompatibles. MATERIAL SAFETY DATA SHEET – HYDROGEN PEROXIDE SOLUTION - 10 VOLUME 3% 4 5. HAZARD IDENTIFICATION Emergency Overview WARNING: MAY BE HARMFUL IF SWALLOWED.CAUSES EYE IRRITATION Potential Health Effects Inhalation: Not expected to be a health hazard under normal conditions. Ingestion: Large oral doses may cause irritation and blistering to the mouth, throat, and abdomen. May also cause abdominal pain, vomiting, and diarrhea. Skin Contact: No adverse effects expected on intact skin. Contact on burn or open skin may cause stinging pain or irritation. Eye Contact: Causes irritation, redness , and pain. Chronic Exposure: No information found. 6. FIRST AID Inhalation: No expected to require first aid measures. Eye Contact: Immediately flush eye with plenty of water for 20 minutes holding the eyelids open. Get medical attention immediately. Skin Contact: Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation develops. Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. MATERIAL SAFETY DATA SHEET – HYDROGEN PEROXIDE SOLUTION - 10 VOLUME 3% 5 7. PREVENTATIVE MEASURES Spill and Leak Procedures: Restrict access to area until after clean up is complete by trained personnel only. Ventilate area and ensure clean up personnel wear adequate protective equipment. Stop or reduce leak if safe to do so. For small spills, flush with plenty of water. For large spills, dike with inert material. Remove liquid with compatible pumps or vacuum equipment. Place in appropriate covered drums. Flush areas with excess water. Disposal: Review Federal and Provincial and local government requirements prior to disposal. May be possible to neutralize with large quantities of water and dispose in the sewer. Although Hydrogen peroxide is used for supplemental oxygen other applications in waste water disposal systems, large quantities put into streams and rivers (over 40 ppm) could adversely affect aquatic fauna. B. Storage and Handling Storage: Store in clean, cool, well ventilated dark area. Protect from freezing. Isolate from incompatible substances. Protect container from physical damage. Containers of this material may be hazardous when empty since they retain product residues ( vapour, liquid).Observe all warnings and precautions listed for the product. C. Personal Protective Equipment Respiratory Protection: Not expected to require personal respirator usage. Respiratory Protection Guidelines: In situations of unknown H2O2 concentrations, use a NIOSH approved SCBA device with full-face piece. Eye/Face Protection: Chemical goggles and face shield. MATERIAL SAFETY DATA SHEET – HYDROGEN PEROXIDE SOLUTION - 10 VOLUME 3% 6 Skin Protection: For normal situations appropriate clothing and impermeable boots and gloves plus a hard hat. In large spills or IDLH (immediately dangerous to life or health) situations, a fully encompassing body suit may be necessary. Resistance of Materials for Protective Clothing: Neoprene, butyl rubber or vinyl gloves. Personal Protection Comments: None 8. REFERENCES - NIOSH Pocket Guide to Chemical Hazards - Canada Centre for Occupational Health and Safety. - Trade names – Database - CHEMINFO – Database - RTECS – Database - Supplier Material Safety Data Sheets - Manufacturing Chemists Association – Material Safety Data Sheets. - American Conference of Governmental Industrial Hygienists Handbook of Threshold Limit Values and Biological Indices. Prepared by RW Packaging Ltd. (204) 786-6873 Updated: February 25, 2014
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