A.P. CHEMISTRY SCHEDULE: Chapter 17 and End of Year Review/Final; Term III - 2014 Tues. DATE 3-11 ACTIVITIES Chapter 1-3 in Purple Review Book due (Sorry! No group time.) Determine new groups; assign chapter review guides (see back) Start LECTURE, Chapter 17.1 pg. 790-800 (through intro voltaic cells) Wed. 3-12 Expt. #27 – An Intro. to Oxidation-Reduction Check your data w/ instructor prior to leaving lab! Lab Check-out Thurs. 3-13 Collect Expt. #27; Quiz Lecture – Rest of 17.1 pg. 790-800 (Review/continuation voltaic cells) Fri. 3-14 PROBLEM SET 17.1 DUE (~30 minutes group work); QUIZ PROBLEMS, Even Numbers 26-36 (omit 30), 44-48 (#32 do 26 part only) pg. 830-838 Start Lecture 17.2; pg. 800-803 Mon. 3-17 Finish Lecture 17.2, pg. 800-803 Revised Expt. #28 – Electrochemical Cells Chapters 4-6 in Purple Review book due (~20 min group) Tues. 3-18 Collect Expt. #28 @ start of class (No group time) PROBLEM SET 17.2 DUE (~30 minutes group time); QUIZ (will also have review from PS 17.1) Even #’s 16abd,30,38,40,42,50,56,60,66,96,102 pg. 830-838 Note: These are meant to be done WITHOUT your calculators! PS 17.2 Short version = omit 16,66 Wed. 3-19 Lecture 17.3, pg. 803-808 Cont. Expt. #28 – Electrochemical Cells (Part IV); (Collect lab @ end block) Ch. 7-8 in purple book due Thurs. 3-20 LECTURE, Ch 17.3, pg. 808-814 (batteries); 814-820 (electrolysis); 821-826 (commercial electrolysis) & Predicting Reactions PROBLEM SET 17.3 – complete: Even #’s 52,54,58,62, 70ab,72 (this will not be graded today) Fri. 3-21 PROBLEM SET 17.3 DUE (~ 20 min group time)-no extra time!; QUIZ(takes 30-45 min) PROBLEMS, Also complete Even #’s 80-84, 92 E.C. 112a, 114 pg. 830-838 Mon. 3-24 Ch. 9 in purple book due Review for Chapter 17 – work on ChemStudy Test in pairs Redox predicting Reactions WS due (skipped from before)- optional Predicting Reactions Test #2 (focus on redox) Mon. 3-24 TEST – CH. 17 Tues. 3-25 A. P. TEST (need 9 extra minutes) - Free Response Section (90 minutes – 50 min w/calc; 40 min no calc) E.C. Due Complete 2009 FRQ; Grade it in red pen and keep track of your score for each question. Turn in FRQ graded, 2009 exam and 2009 grading rubric Mon. 3-25 Get back tests, Review for A.P. Test; Predicting Reactions Test #3 GO OVER Free Response Section & Lab Check out Wed. 3-26 A. P. TEST (need 4 extra minutes) – Multiple Choice Section (90 minutes - no or equations sheet ) E.C. Due Complete 1984 Multiple Choice Test (In Review binder); Grade it in red pen. Do item analysis and count how many wrong of each topic area (there is a sheet that has the topic for each question) NOTE: Students were allowed to use their calculators on the 1984 exam. Return textbook, partial solutions manual, purple review book. If you would like a copy to study for the exam you will be re-issued a different copy. Return review binder only if you are not going to use it to study. GO OVER Multiple Choice Section ** Return all A.P. study materials to me by the day of the exam (there will be a cart there)! ** Ch. 17 Essential Questions: • How can you predict and write net ionic reactions for the following reaction types: oxidation/reduction? • How can you explain galvanic and electrolytic cells? • How can you relate free energy change to equilibrium constants and electrode potentials? AP Chemistry Review Assignment - DUE _________________ (the day before the Ch. 17 test) Your task is to: 1) Make a review sheet (one page front and back maximum) for the entire class • It must be typed and organized in a logical manner 2) Present the main ideas to the class using your sheet as a guide ~5 min. Be sure to include: a. All the BIG concepts for your chapter. If you're not sure if something is "BIG" ask me. b. Any important/useful diagrams. • I can have figures from your book photocopied for you if you write me a list of the page #'s you need copied (and if you want me to shrink/enlarge the image by a certain %) by Thurs 2-28 c. Some worked out example problems (if important to your chapter). (Don’t include ex. problems without answers.) d. A list of common misconceptions/mistakes people may make. POINTS WILL BE DEDUCTED FOR SLOPPY/INCOMPLETE (not thorough) WORK. ** Please submit your review sheet single-sided. Thanks! Chapters 1 -2 Intro stuff:: classification of matter, moles, sig fig's, history of chemistry (names & experiments), naming compounds, Chapters 3-4 Stoichiometry: mole stuff, limiting reactants etc. &Chemical Reactions Chapter 5 Gases Chapter 6 Thermochemistry Chapter 7 Atomic Structure & Periodicity Chapter 8 Bonding: General Concepts (Lewis dots, molecular geometry, etc.) Chapter 9 Covalent Bonding: Orbitals Chapter 10 Liquids & Solids (Intermolecular forces, phase diagrams) Chapter 11 Properties of Solutions (solutions, solubility, Colligative properties) Chapter 12 Chemical Kinetics (Rates) Chapter 13 Chemical Equilibrium Chapter 14 Acids & Bases (acid/base properties, Calculation pH of strong/weak acid solutions) Chapter 15 Applications of Aqueous Equilibria (Buffers, titration curves, indicators, Ksp) Chapter 16 Spontaneity, Entropy, and Free Energy Chapter 17 Electrochemistry Ch. 17 Unit Objectives Problem Set 17.1 – Introduction to Electrochemistry – terms, voltaic cells, cell potential 1) Students will have be able to explain the terms: oxidation, reduction, oxidizing agent, reducing agent. 2) Student will be able to balance redox reactions by the half-reaction method. 3) Given two metals (and metal soltions) tudent will be able to draw a voltaic cell and label the following: cathode, anode, direction of electron flow, direction of ion flow in solution and in salt bridge. 4) Students will be able to draw the shorthand notation for a voltaic cell. 5) Students will be able to calculate the cell potential for a voltaic cell and predict what reactions are spontaneous. 6) Students will be able to organize a list of substances into columns showing strength as oxidizing and reducing agents (knowing some qualify in only one category, while others qualify in both). Problem Set 17.2 – Cell potential, electrical work, and free energy; LeChatelier & Nernst 1) Students will be able to calculate the work possible given a volaic cell (by first calculating the cell potential). 2) Students will know how charge relates to number of electrons (using Faraday’s constant). 3) Students will be able to predict qualitatively what happens to cell potential when concentrations of ions are changed (LeChatelier). 4) Students will be able to predict quantitatively what happens to cell potential when concentrations of ions are changed (Nernst). Problem Set 17.3 – Electrolytic cells, predicting electrolytic reactions; batteries 1) Students will be able to describe the difference between a voltaic and an electrolytic cell. 2) Students will be able to calculate how much metal can be plated when a specific current flows for a specified amount of time. 3) Students will be able to predict what reactions happen at the anode and cathod of an electrolytic cell. 4) Students will have a basic understanding of how a variety of batteries work.
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