3/4/2010 Define solute and solvent. Solute and Solvent 6a Simple solutions are homogenous mixtures of two substances. Solutions Solute is the dissolved substance. Solvent is the majority of the solution. Chemistry Standard 6 Examples: Dissolving 6b Saltwater Soda salt = solute water = solvent sugar, coloring, CO2 = solutes water = solvent How do solutes dissolve in solvents? What is equilibrium? Because the molecules of a solvent and solute are in constant random motion, they have kinetic energy, the energy of motion. This energy causes diffusion of the solute into the solvent. Once the solute molecules are evenly spread throughout the solvent, they are said to be at equilibrium. 4 Describe the process by which salts dissolve in water. Not all molecules dissolve equally in a solvent. The amount that dissolves is called the equilibrium concentration. When salts dissolve in water, the anions and cations are separated and surrounded by polar water molecules. These form “hydration spheres” It depends on how attractive solute and solvent are themselves and each other. 1 3/4/2010 Factors Affecting Dissolution 6c In a liquid solvent, the solubility of gases and solids is dependent on temperature. Solids are usually more soluble as you increase temperature Example: Sugar in iced tea vs. Sugar in hot tea Gases are less soluble as you increase temperature Example: warm water contains less oxygen and can actually kill marine life. 7 How are the solubilities of solids and gases affected by: - temperature? - pressure? Solubility is also affected by pressure The solubility of a gas in a liquid is “directly proportional” to the pressure of that gas above the solution. In other words, if you increase the pressure of a gas above a solution, you increase its solubility. Example: When a soda can is pressurized, the CO2 is dissolved in the soda. Open the can and release the pressure and the CO2 bubbles out since it’s suddenly less soluble. Units of Concentration 6d The concentration of a solution can be measured several ways. Grams per liter (g/L) represents the mass of solute divided by the volume of the solution. Molarity (M) (or mol/L) indicates the number of moles of solute per liter of solution. Percent composition (%) is the ratio of one part solute to one hundred parts solvent. To find - mass _ solute x100 = %composition total _ mass Parts per million (ppm) indicates the number of molecules of solute for every million molecules of solution. To find - mass _ solute x1,000,000 = parts _ per _ million total _ mass 2
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