!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*
2>$0&./%0/>,**
6)&$.')7%*<$$-$-*
• "#$%&'$()!*#+%$!,%-!.#)!#)/(01&!&2%*1,-)3!
• 4(-(!-(5$%!
• 67%)&1,%,!.#)!3#')!(,,1/0%+!)#$%8!,-'+%0-!98!:8!;8!#)!<=!
>?21,!@(&A%-!1,!.#)!,-'+%0-!<B!
?#$.#'$4*
?21,!%7%)&1,%!1,!+%,1/0%+!-#!2%$@!3#'!'0+%),-(0+!,-)'&-')%!(0+!5#0+10/!10!23+)#&()5#0,=!C-!($,#!
10-)#+'&%,!3#'!-#!3#')!*#$%&'$()!*#+%$!A1-8!(,!D%$$!(,!,@%&-)#,&#@1&!+(-(!.#)!-2%!*#+%$,!-2(-!3#'!
5'1$+=!E#'!D1$$!5'1$+!(@@)#71*(-%$3!-%0!*#+%$,!(,!3#'!&#*@$%-%!-21,!(&-1F1-3=!6(&2!#.!3#')!$(5!/)#'@!
@()-0%),!D1$$!($,#!5'1$+!(!)%$(-%+!,%-!#.!9G!*#+%$,=!H.-%)!3#'!2(F%!.101,2%+!3#')!*#+%$!5'1$+10/!(0+!
+(-(!(0($3,1,!3#')!/)#'@!D1$$!*%%-!-#!+1,&',,!($$!3#')!)%,'$-,=!C.!3#'!/%-!,-'&A!($#0/!-2%!D(3!3#'!&(0!
(,A!3#')!@()-0%),!D2(-!*#+%$,!-2%3!()%!5'1$+10/!(0+!D2(-!-2%3!()%!-210A10/=!E#'!#)!3#')!/)#'@!&(0!
($,#!(,A!3#')!10,-)'&-#)!.#)!/'1+(0&%=!!!
I0%!#.!-2%!)%,#')&%,!3#'!D1$$!',%!10!-21,!$(5#)(-#)3!1,!-2%!&()5#0J9;!>KJ9;B!L'&$%()!"(/0%-1&!
M%,#0(0&%!>L"MB!,@%&-)(!#.!F()1#',!&#*@#'0+,=!N',-!(,!+#&-#),!(0+!@23,1&($!-2%)(@1,-,!',%!
"(/0%-1&!M%,#0(0&%!C*(/10/!-#!+1(/0#,%!*%+1&($!&#0+1-1#0,8!#)/(01&!&2%*1,-,!&(0!',%!-2%!)%$(-%+!
L"M!@)#&%,,!-#!+%+'&%!-2%!5#0+10/!@(--%)0,!#.!(-#*,!10!#)/(01&!*#$%&'$%,=!L"M!%7@%)1*%0-,!
,-'+3!0'&$%1!#.!,@%&1.1&!%$%*%0-,!10!&#*@#'0+,=!?2%!1,#-#@%,!(0+!%$%*%0-,!*#,-!',%.'$!-#!#)/(01&!
&2%*1,-,!()%!23+)#/%0!>D1-2!(!*(,,!#.!9B!(0+!&()5#0!>D1-2!(!*(,,!#.!9;B=!?2%!+%-(1$,!#.!#5-(1010/!
L"M!,@%&-)(!()%!0#-!(@@)#@)1(-%!.#)!#0%!#.!3#')!.1),-!%7@%)1%0&%,!10!#)/(01&!&2%*1,-)38!5'-!-2%!
)%,'$-,!#.!&()5#0J9;!L"M!&(0!5%!F%)3!@#D%).'$!-#!2%$@!3#'!'0+%),-(0+!-2%!,-)'&-')%,!#.!#)/(01&!
&#*@#'0+,=!4#0O-!D#))3!-2(-!3#'!D#0O-!/%-!%0#'/2!#.!-21,!.'08!$(-%)!10!-21,!&#'),%!3#'!D1$$!($,#!
$%()0!2#D!-#!10-%)@)%-!-2%!10.#)*(-1#0!.)#*!23+)#/%0!>@)#-#0B!L"M=!!
P%,1+%,!-2%!0'*5%)!#.!#5,%)F%+!(5,#)@-1#0,!10!(!KJ9;!L"M8!-2%!@#,1-1#0!#0!-2%!QJ(71,!D2%)%!-2%!
(5,#)@-1#0!#&&'),!1,!1*@#)-(0-=!?21,!F($'%!1,!&($$%+!-2%!&2%*1&($!,21.-=!E#'!D1$$!-(5'$(-%!-2%!F($'%!#.!
-2%!&2%*1&($!,21.-,!#5,%)F%+!.#)!23+)#&()5#0,!-2)#'/2#'-!-21,!(&-1F1-3!(0+!$##A!.#)!@(--%)0,=!P#-2!
-2%!0'*5%)!#.!(5,#)@-1#0,!10!-2%!KJ9;!L"M!(0+!-2%1)!&2%*1&($!,21.-!1,!',%.'$!-#!#)/(01&!&2%*1,-,!10!
-2%1)!'0+%),-(0+10/!#.!-2%!,-)'&-')%!#.!#)/(01&!&#*@#'0+,=!!!
!
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
!"#$%&'#'()*$(+,-.#/,(0(
!"#$%&'#()*+(
!"#$%&'($)%'%"*+$,*"*'$,'-."'+%$/0&"&'&1-1'*.""-2'
:*)C D3'7-*)*>7)%&'0*E/-$7*/A*>$"&)"$F*8G+:HC*!A*>$"&)"$*'%*&,>$-*/"&/*)*>)($*'&*E'(5&*1$*.$>.$%$"&$-*)%****
*
*
*
*
*
:*1C I./E*,/3.*0/"%&.30&$-*E/-$7F*45)&*'%*&5$*)>>./@'E)&$*+J8J+*/.*&5$*+J8J8*1/"-*)"(7$%K*
LM*NO°*
DM*PO°*
8M*:OP°*
QM*:HO°*
?M*:RO°*
:*0C S5)&*'%*&5$*5,1.'-'T)&'/"*/A*&5$*0).1/"*)&/E%*'"*>$"&)"$K**D.'$A7,*$@>7)'"*5/4*,/3*)..'#$*)&*,/3.*
)"%4$.C*
:*-C S'&5/3&*1.$)U'"(*)",*1/"-%F*45)&*E/&'/"V%W*'%X).$*)77/4$-*&5)&*E),*05)"($*&5$*>/%'&'/"*/A*)",*/A*
&5$*)&/E%*'"*>$"&)"$K***
30,-4'05'($)'.$6&'$,"'#1%7$,'1-$8'0,'$,"'.1,&9'&"*#%07"'-."'8$-0$,'$7*"%/"&'05'($)'-)%,'-."'$-."%'
#1%7$,'1-$8':0-.'($)%'$-."%'.1,&'1*'05'($)':"%"'-)%,0,;'$,'1':1-"%'51)#"-2<'
:*$C +/4*E)",*7'"$%*V)1%/.>&'/"%W*).$*%$$"*&5$*89:;*<6=*/A*>$"&)"$K*
*
:*AC !A*&5$*"3E1$.*/A*)1%/.>&'/"%*/1%$.#$-*'"*&5$*89:;*<6=*/A*>$"&)"$*).$*"/&*$Y3)7*&/*&5$*"3E1$.*/A*
0).1/"*)&/E%*'"*>$"&)"$F*45,*"/&K***
30,-4'=17"6'$,"'#1%7$,'1-$8'>'?9-."'*"#$,&'#1%7$,'1-$8'>@9'"-#'1,&'-.",'60*-'-."'1-$8*'"1#.'#1%7$,'
AB>?'-.%$);.'B>C<'0*'#$,,"#-"&'-$2'D.1-'&$'($)',$-0#"'17$)-'-."*"'#$,,"#-0$,*E'
:*(C S5)&*>./>$.&,*'%*)>>).$"&*A./E*&5$*E/-$7*/A*>$"&)"$*&5)&*)7%/*>.$-'0&%*&5$*"3E1$.*/A*89:;*
)1%/.>&'/"%*/1%$.#$-*A/.*>$"&)"$K*
:*5C S5)&*'%*&5$*89:;*<6=*05$E'0)7*%5'A&*VZ9)@'%*#)73$W*/A*&5$*89:;*)1%/.>&'/"%*/A*>$"&)"$K*
?@$.0'%$%*A/.*2&3-$"&*B*
:*
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
!"#$%&'#()*,(
H*)C D3'7-*&5$*A/77/4'"(*&4/*%&.30&3.$%*
F-%)#-)%"'GH@2?' '
'
'
'
'
F-%)#-)%"'GH@2?'
'
*
H*1C S5)&*'%*&5$*.$7)&'/"%5'>*1$&4$$"*&5$%$*&4/*%&.30&3.$%K*
B$,*0&"%'-."*"'I)"*-0$,*'-$'."6+'($)'&"#0&"4'J%"'*-%)#-)%"*'GH@2?'1,&'GH@2@'-."'0&",-0#16'8$6"#)6"9'
K)*-'+%"*",-"&'$%'&%1:,'&055"%",-6(E'J%"'-."*"'*-%)#-)%"*'0*$8"%*E'AL055"%",-'#$8+$),&*':0-.'-."'
*18"'8$6"#)61%'5$%8)612<'M5'-."*"'*-%)#-)%"*'1%"'0*$8"%*':.1-'-(+"'$5'0*$8"%*'1%"'-."(E'
H*0C +/4*E)",*)1%/.>&'/"%*).$*%$$"*'"*&5$*89:;*<6=*/A*%&.30&3.$*B9HC:K*
*
H*-C +/4*E)",*)1%/.>&'/"%*).$*%$$"*'"*&5$*89:;*<6=*/A*%&.30&3.$*B9HCHK*
*
H*$C D)%$-*/"*&5$*89:;*<6=*/A*%&.30&3.$%*B9HCH*)"-*B9HC;F*45)&*'%*&5$*$#'-$"0$*&5)&*B9HCH*)"-*B9HC;*).$*
&5$*%)E$*/.*-'AA$.$"&*0/E>/3"-%K**?@>7)'"*,/3.*)"%4$.C*
H*AC ['%&*&5$*05$E'0)7*%5'A&%*VZ9)@'%*#)73$%W*/A*$)05*/A*&5$*)1%/.>&'/"%*'"*0/E>/3"-%*B9HCH*)"-*B9HC;C*
?@$.0'%$%*A/.*2&3-$"&*B*
H*
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
!"#$%&'#()*-(
;*)C D3'7-*&5$*A/77/4'"(*8G+:H*%&.30&3.$%*
F-%)#-)%"'GHN2?* *
*
*
*
*
F-%)#-)%"'GHN2@*
*
*
;*1C S5)&*'%*&5$*.$7)&'/"%5'>*1$&4$$"*&5$%$*&4/*%&.30&3.$%K*
B$,*0&"%'-."*"'I)"*-0$,*'-$'."6+'($)'&"#0&"4'J%"'*-%)#-)%"*'GHN2?'1,&'GHN2@'-."'0&",-0#16'8$6"#)6"9'
K)*-'+%"*",-"&'$%'&%1:,'&055"%",-6(E'J%"'-."*"'*-%)#-)%"*'0*$8"%*E'M5'-."*"'*-%)#-)%"*'1%"'0*$8"%*'
:.1-'-(+"'$5'0*$8"%*'1%"'-."(E'
;*0C +/4*E)",*)1%/.>&'/"%*).$*%$$"*'"*&5$*89:;*<6=*/A*%&.30&3.$*B9;C:K*
*
;*-C +/4*E)",*)1%/.>&'/"%*).$*%$$"*'"*&5$*89:;*<6=*/A*%&.30&3.$*B9;CHK*
*
*
;*$C D)%$-*/"*&5$*89:;*<6=*/A*%&.30&3.$%*B9;C:*)"-*B9;CHF*45)&*'%*&5$*$#'-$"0$*&5)&*B9;C:*)"-*B9;CH*).$*
&5$*%)E$*/.*-'AA$.$"&*0/E>/3"-%K*?@>7)'"*,/3.*)"%4$.C*
;*AC ['%&*&5$*05$E'0)7*%5'A&%*VZ9)@'%*#)73$%W*/A*$)05*/A*&5$*)1%/.>&'/"%*'"*0/E>/3"-%*B9;C:*)"-*B9;CHC*
?@$.0'%$%*A/.*2&3-$"&*B*
;*
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
!"#$%&'#()*)((
B*)C D3'7-*$&5$"$*8H+BC*D$*%3.$*&/*05$0U*&5)&*,/3*5)#$*0/"%&.30&$-*&5$*-/317$*1/"-*0/..$0&7,\*
*
*
*
*
*
*
B*1C S5)&*'%*&5$*)>>./@'E)&$*+J8J+*/.*+J8J8*1/"-*)"(7$K*
LM*NO°*
DM*PO°*
8M*:OP°*
QM*:HO°*
?M*:RO°*
B*0C S5)&*'%*&5$*5,1.'-'T)&'/"*/A*&5$*0).1/"*)&/E%*'"*$&5$"$K*D.'$A7,*$@>7)'"*5/4*,/3*)..'#$-*)&*,/3.*
)"%4$.C*
B*-C +/4*-/$%*&5$*8J8*-/317$*1/"-*'"*$&5$"$*0/E>).$*&/*&5$*8J8*%'"(7$*1/"-*'"*$&5)"$K**
B*$C +/4*E)",*)1%/.>&'/"%*).$*/1%$.#$-*'"*&5$*89:;*<6=*/A*$&5$"$K*
*
B*AC ?@>7)'"*&5$*"3E1$.*/A*)1%/.>&'/"%*/1%$.#$-C**V2$$*5'"&*'"*?@$.0'%$*B9:F*Y3$%&'/"*:ACW*
B*(C S5)&*'%*&5$*05$E'0)7*%5'A&*VZ*)@'%*#)73$W*/A*&5$*/1%$.#$-*)1%/.>&'/"*/A*$&5$"$K*
!"#$%&'#()*.(
G*)C D3'7-*&5$*A/77/4'"(*8B+R*%&.30&3.$%*
F-%)#-)%"'GHC2?* *
*
*
?@$.0'%$%*A/.*2&3-$"&*B*
*
*
*
*
*
F-%)#-)%"'GHC2@'
*
B*
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
G*1C S5)&*'%*&5$*.$7)&'/"%5'>*1$&4$$"*&5$%$*&4/*%&.30&3.$%K*
O$'."6+'($)'1,*:"%'-.0*9'05'-."'-:$'*-%)#-)%"*'A1,&'+.(*0#16'8$&"6*'$5'-."'*-%)#-)%"*<'#1,'7"'
0,-"%#$,/"%-"&'A:0-.$)-'7%"1P0,;'7$,&*<'-."('#$)6&'7"'0&",-0#16'8$6"#)6"*'K)*-'+%"*",-"&'$%'&%1:,'
&055"%",-6(2''O$'16*$'."6+'($)'0,'($)%'&"#0*0$,'6$$P'1-'-."'BH?N'QR!'*+"#-%1'$5'B$8+$),&*'GHC2?'1,&'
GHC2@'+%"*",-"&'7"6$:2'
G*0C +/4*E)",*)1%/.>&'/"%*).$*/1%$.#$-*'"*&5$*89:;*<6=*/A*%&.30&3.$*B9GC:K*
*
G*-C S5)&*).$*&5$*/1%$.#$-*05$E'0)7*%5'A&%*V@9)@'%*#)73$W*A/.*&5$%$*)1%/.>&'/"%K**
G*$C +/4*E)",*)1%/.>&'/"%*).$*/1%$.#$-*'"*&5$*89:;*<6=*/A*%&.30&3.$*B9GCHK*
*
G*AC S5)&*).$*&5$*/1%$.#$-*05$E'0)7*%5'A&%*V@9)@'%*#)73$W*A/.*&5$%$*)1%/.>&'/"%K*
G*(C ?@>7)'"*&5$*"3E1$.*/A*)1%/.>&'/"%*/1%$.#$-*)"-*&5$*"3E1$.*/A*0).1/"*)&/E%*'"*&5$*E/7$037).*
A/.E37)*/A*1/&5*%&.30&3.$%*B9GC:*)"-*B9GCHC*V2$$*5'"&*'"*?@$.0'%$*B9:F*Y3$%&'/"*:ACW*
G*5C S5)&*-/$%*&5$*89:;*<6=*-)&)*A/.*%&.30&3.$%*B9GC:*)"-*B9GCH*&$77*,/3*)1/3&*%&.30&3.$%*B9GC:*)"-**
B9GCH*1$'"(*'-$"&'0)7*/.*-'AA$.$"&*0/E>/3"-%K*
?@$.0'%$%*A/.*2&3-$"&*B*
G*
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
!"#$%&'#()*/(
N*)C D3'7-*$&5,"$F*45'05*'%*)7%/*U"/4"*)%*)0$&,7$"$F*8H+HC**VD$*%3.$*&/*05$0U*&5)&*,/3*5)#$*0/"%&.30&$-*
&5$*&.'>7$*1/"-*0/..$0&7,\W*
*
*
*
*
*
*
N*1C S5)&*).$*&5$*+J8J8*1/"-%*)"(7$%*'"*$&5,"$K*
LM*NO°*
DM*PO°*
8M*:OP°*
QM*:HO°*
?M*:RO°*
N*0C S5)&*'%*&5$*5,1.'-'T)&'/"*/A*&5$*0).1/"*)&/E%*'"*$&5,"$K**D.'$A7,*$@>7)'"*5/4*,/3*)..'#$-*)&*,/3.*
)"%4$.C*
N*-C +/4*E)",*)1%/>.&'/"%*).$*/1%$.#$-*'"*&5$*89:;*<6=*/A*$&5,"$K*
*
N*$C S5)&*'%X).$*&5$*05$E'0)7*%5'A&*V@9)@'%*#)73$W*/A*&5$*/1%$.#$-*89:;*<6=*)1%/.>&'/"V%W*/A*$&5,"$K***
!"#$%&'#()*0((
]*)C D3'7-*1$"T$"$F*8N+NC*
*
*
*
*
*
]*1C S5)&*'%*E/%&*%&.'U'"(*)1/3&*&5$*>/%'&'/"*/A*)77*&5$*)&/E%*'"*&5$*1$"T$"$*E/7$037$K***
]*0C S5)&*).$*&5$*+J8J8*/.*8J8J8*1/"-*)"(7$%*'"*1$"T$"$K*
LM*NO°*
DM*PO°*
8M*:OP°*
QM*:HO°*
?M*:RO°*
]*-C S5)&*'%*&5$*5,1.'-'T)&'/"*/A*&5$*0).1/"*)&/E%*'"*1$"T$"$K*D.'$A7,*$@>7)'"*5/4*,/3*)..'#$-*)&*,/3.*
)"%4$.C*
?@$.0'%$%*A/.*2&3-$"&*B*
N*
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
]*$C +/4*E)",*)1%/.>&'/"%*).$*/1%$.#$-*'"*&5$*89:;*<6=*/A*1$"T$"$K*S5)&*-/$%*&5'%*'E>7,*)1/3&*&5$*
0).1/"*)&/E%*)"-*0).1/"J0).1/"*1/"-%*'"*1$"T$"$K*
*
]*AC S5)&*'%*&5$*05$E'0)7*%5'A&*V@*)@'%*#)73$W*/A*&5$*/1%$.#$-*)1%/.>&'/"%*'"*1$"T$"$K*
!"#$%&'#()*1(
R*)C D3'7-*0,07/5$@)"$F*8N+:HC*
*
*
R*1C L.$*)77*/A*&5$*)&/E%*'"*/"$*>7)"$*'"*0,07/5$@)"$*)%*'"*1$"T$"$K***
R*0C ^5$*>30U$.$-*0/"A/.E)&'/"*)1/#$*'%*0)77$-*&5$*05)'.*0/"A/.E)&'/"C*^5./3(5*&4'%&'"(*)"-*&3."'"(*
V4'&5/3&*1.$)U'"(*1/"-%W*A/.E*,/3.*E/-$7*/A*0,07/5$@)"$*'"&/*/"$*/A*&5$%$*%5)>$%K*S5,*-/*,/3*
&5'"U*0,07/5$@)"$*)-/>&%*&5'%*%5)>$K*
R*-C ^5$*5,-./($"%*&5)&*%&'0U*%&.)'(5&*3>*/.*-/4"*).$*0)77$-*_)@')7F`*&5/%$*&5)&*)"(7$*/AA*&/*&5$*%'-$%*).$*
_$Y3)&/.')7C`*?)05*0).1/"*)&/E*'"*&5$*05)'.*0/"A/.E)&'/"*/A*0,07/5$@)"$*5)%*/"$*)@')7*)"-*/"$*
$Y3)&/.')7*5,-./($"C*a%'"(*&5$*05)'.*0/"A/.E)&'/"*/A*0,07/5$@)"$*%5/4"*'"*%&$>*])F*-.)4*0'.07$%*
)./3"-*)77*)@')7*5,-./($"%*)"-*%Y3).$%*)./3"-*)77*$Y3)&/.')7*5,-./($"%C*+/4*E)",*)@')7*5,-./($"%*
).$*'"*0,07/5$@)"$K*+/4*E)",*$Y3)&/.')7*5,-./($"%*).$*'"*0,07/5$@)"$K*
R*$C +/4*E)",*)1%/.>&'/"%*/003.*'"*&5$*89:;*<6=*/A*0,07/5$@)"$K**S5)&*'%*&5$*05$E'0)7*%5'A&*V@*)@'%*
#)73$W*/A*&5$*)1%/.>&'/"%*/A*0,07/5$@)"$K*
?@$.0'%$%*A/.*2&3-$"&*B*
]*
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
*
!"#$%&'#()*2(
P*)C D3'7-*#0*H:FH9-'E$&5,70,07/5$@)"$C**
*
*
Q$-"'-.1-'-."'-:$'*-%)#-)%"*'*.$:,'#1,'7"'0,-"%#$,/"%-"&'7('*08+6('7",&0,;'$%'-:0*-0,;'-."'BSB'
7$,&*'$5'-."'%0,;2''O.0*'8$-0$,'166$:*'1T016'8"-.(6';%$)+*'-$'7"#$8"'"I)1-$%016'1,&'/0#"'/"%*12'
P*1C +/4*E)",*)1%/.>&'/"%*).$*'"*&5$*89:;*<6=*/A*#0*H:FH9-'E$&5,70,07/5$@)"$K*
*
P*0C ?@>7)'"*&5$*"3E1$.*/A*)1%/.>&'/"%*/1%$.#$-C*
P*-C S5)&*).$*&5$*05$E'0)7*%5'A&%*V@9)@'%*#)73$W*/A*&5$*/1%$.#$-*)1%/.>&'/"%K*
P*$C S5)&*-/$%*&5$*05$E'0)7*%5'A&*V@9)@'%*#)73$W*'"-'0)&$*)1/3&*&5$*5,1.'-'T)&'/"*/A*&5$*0).1/"*)&/E%*/A*
#0*9:FH9-'E$&5,70,07/5$@)"$K*
?@$.0'%$%*A/.*2&3-$"&*B*
R*
!"#$%&'()&'"(*+,-./0).1/"*2&.30&3.$*4'&5*6/7$037).*6/-$7%*)"-*89:;*<6=*2>$0&./%0/>,*
3&'%4''&56(74#'8&56'(
J,*:"%'-."'I)"*-0$,*'7"6$:9'&0*#)**0,;'-."8':0-.'($)%';%$)+2'B$,-0,)"'$,'1,$-."%'*.""-'05',""&"&2'
:C S5)&*07)'E%*0)"*,/3*E)U$*)1/3&*&5$*5,1.'-'T)&'/"*/A*0).1/"*)&/E%F*&5$*"3E1$.*)"-*&,>$*/A*1/"-%*
&/*&5/%$*0).1/"*)&/E%F*)"-*&5$*($/E$&.'0*)..)"($E$"&*/A*)&/E%*)./3"-*&5/%$*0).1/"*)&/E%K*
HC S5)&*07)'E%*0)"*,/3*E)U$*)1/3&*&5$*5,1.'-'T)&'/"*/A*)*0).1/"*)&/E*)"-*&5$*89:;*05$E'0)7*%5'A&*/A*
&5$*0).1/"*)&/EK***
;C S5)&*>./>$.&,*/A*)"*/.()"'0*0/E>/3"-*0)3%$%*&5$*"3E1$.*/A*89:;*)1%/.>&'/"%*&/*1$*7$%%*&5)"*&5$*
"3E1$.*/A*0).1/"*)&/E%*'"*&5$*E/7$037).*A/.E37)K*
BC +/4*0)"*&5$*89:;*<6=*%>$0&.)*/A*&4/*0/E>/3"-%*1$*3%$-*&/*&$77*'A*&5$*0/E>/3"-%*).$*'%/E$.%*/.*
&5$*%)E$*0/E>/3"-*b3%&*-.)4"*-'AA$.$"&7,K*
GC S'&5*,/3.*(./3>*E$E1$.%F*-.)4*45)&*,/3*>.$-'0&*A/.*&5$*89:;*<6=*/A*:FH9-'E$&5,70,07/>$"&$"$C*
V2$$*%&.30&3.$*1$7/4CW*c/3.*<6=*-.)4'"(*"$$-%*&/*%5/4*&5$*"3E1$.*/A*)1%/.>&'/"%*)"-*
)>>./@'E)&$*05$E'0)7*%5'A&*VZ9)@'%*>/%'&'/"W*,/3*>.$-'0&C**
*
NC Q.)4*)"/&5$.*'%/E$.*/A*8]+:HC*Q.)4*&5$*89:;*<6=*%>$0&.3E*,/3*>.$-'0&*A/.*&5'%*'%/E$.C*[)1$7*&5'%*
%>$0&.3E*_!%/E$.*/A*:FH9-'E$&5,70,07/>$"&$"$C`****
*
?@$.0'%$%*A/.*2&3-$"&*B*
P*
cis -1,4dimethylcyclohexane
C6H12
cyclohexane
C6H6
benzene
C2H2
ethyne
C4H8
Structure 4-5.2
C4H8
Structure 4-5.1
C2H4
ethene
C5H12
Structure 4-3.2
C5H12
Structure 4-3.1
C5H12
Structure 4-2.2
C5H12
Structure 4-2.1
C5H12
pentane
compounds
!"#$%&"'(')*"*'+*,-%'
4-9
4-8
4-7
4-6
4-5
4-5
4-4
4-3
4-3
4-2
4-2
4-1
exercise
!
1b
Bond
angles
Number of C-13
absorptions
1c
Hybridization on
carbon
4c
1e
2c
2d
3c
3d
4e
Relationship between
two compounds
(include evidence for
your answer)
2e
3e
5h
Chemical shifts
(x-axis value) of
C-13 absorptions
1h
2f
2f
3f
3f
4g
5d
6e
4b
5c
6c
5f
6d
7f
5e
6b
7d
8e
7e
8e
9d
7c
9b
Comments on
compound or C-13
absorptions