Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 1. IDENTIFICATION Product Name Ammonium Bifluoride Other Names Ammonium Acid Fluoride; Ammonium Difluoride; AMMONIUM FLUORIDE, ((NH4)(HF2)); Ammonium Hydrogen Fluoride Uses In manufacture of magnesium and magnesium alloys; in brightening of aluminium; for purifying and cleansing various parts of beer-dispensing apparatus, tubes, etc., sterilizing dairy and other food equipment. In glass and porcelain industries; as mordant for aluminium; as a `sour' in laundering cloth. In the laboratory production of hydrogen fluoride. Chemical Family No Data Available Chemical Formula (NH4)HF2 Chemical Name Ammonium Bifluoride Product Description No Data Available Contact Details of the Supplier of this Safety Data Sheet Organisation Location Telephone Redox Pty Ltd 2 Swettenham Road Minto NSW 2566 Australia +61-2-97333000 Redox Pty Ltd 11 Mayo Road Wiri Auckland 2104 New Zealand +64-9-2506222 Redox Inc. 2132A E. Dominguez Street Carson CA 90810 USA +1-424-675-3200 Redox Chemicals Sdn Bhd Level 2, No. 8, Jalan Sapir 33/7 Seksyen 33, Shah Alam Premier Industrial Park 40400 Shah Alam Sengalor, Malaysia +60-3-5614-2111 Emergency Contact Details For emergencies only; DO NOT contact these companies for general product advice. Organisation Location Telephone Poisons Information Centre Westmead NSW 1800-251525 131126 Chemcall Australia 1800-127406 +64-4-9179888 Chemcall Malaysia +64-4-9179888 Chemcall New Zealand 0800-243622 +64-4-9179888 National Poisons Centre New Zealand 0800-764766 CHEMTREC USA & Canada 1-800-424-9300 CN723420 +1-703-527-3887 2. HAZARD IDENTIFICATION Poisons Schedule (Aust) 7 Globally Harmonised System Redox Pty Ltd Corporate Office Sydney Locked Bag 15 Minto NSW 2566 Australia 2 Swettenham Road Minto NSW 2566 Australia All Deliveries: 4 Holmes Road Minto NSW 2566 Australia Form 21047, Revision 3, Page 1 of 10, 14-Jun-2017 02:24:52 Phone Fax E-mail Web ABN +61 2 9733 3000 +61 2 9733 3111 [email protected] www.redox.com 92 000 762 345 Australia Adelaide Brisbane Melbourne Perth Sydney New Zealand Auckland Christchurch Hawke’s Bay Malaysia Kuala Lumpur USA Los Angeles Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 Hazard Classification Hazardous according to the criteria of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS) Hazard Categories Acute Toxicity (Oral) - Category 3 Skin Corrosion/Irritation - Category 1B Serious Eye Damage/Irritation - Category 1 Pictograms Signal Word Danger Hazard Statements H301 Toxic if swallowed. H314 Causes severe skin burns and eye damage. P260 Do not breathe dusts or mists. P264 Wash exposed skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/eye protection/face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P330 Rinse mouth. P501 Dispose of contents/container in accordance with local / regional / national / international regulations. Precautionary Statements Prevention Response Disposal National Transport Commission (Australia) Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) Dangerous Goods Classification Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) Environmental Protection Authority (New Zealand) Hazardous Substances and New Organisms Amendment Act 2015 HSNO Classifications Health Hazards Environmental Hazards 6.1C Substances that are acutely toxic- Toxic 8.2C Substances that are corrosive to dermal tissue UN PGIII 8.3A Substances that are corrosive to ocular tissue 9.3B Substances that are ecotoxic to terrestrial vertebrates 3. COMPOSITION/INFORMATION ON INGREDIENTS Form 21047, Revision 3, Page 2 of 10, 14-Jun-2017 02:24:52 Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 Ingredients Chemical Entity Formula CAS Number Proportion Ammonium Bifluoride (NH4)HF2 1341-49-7 >98 % 4. FIRST AID MEASURES Description of necessary measures according to routes of exposure Swallowed For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (headdown position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay. Eye Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. Skin Avoid further contact. Immediately remove contaminated clothing, including footwear. Flush skin under running water for 15 minutes. Avoiding contamination of the hands, massage calcium gluconate gel into affected areas, pay particular attention to creases in skin. Contact the Poisons Information Centre. Continue gel application for at least 15 minutes after burning sensation ceases. If pain recurs, repeat application of calcium gluconate gel or apply every 20 minutes. If no gel is available, continue washing for at least 15 minutes, using soap if available. If patient is conscious, give six calcium gluconate or calcium carbonate tablets in water by mouth. Transport to hospital, or doctor, urgently. Inhaled If dust is inhaled, remove from contaminated area. Encourage patient to blow nose to ensure clear breathing passages. Ask patient to rinse mouth with water but to not drink water. Seek immediate medical attention. For massive exposures : If dusts, vapours, aerosols, fumes or combustion products are inhaled, remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. If victim is conscious, give six calcium gluconate or calcium carbonate tablets in water by mouth. Transport to hospital, or doctor, urgently. Advice to Doctor For acute or short term repeated exposures to fluorides: Fluoride absorption from gastro-intestinal tract may be retarded by calcium salts, milk or antacids. Fluoride particulates or fume may be absorbed through the respiratory tract with 20-30% deposited at alveolar level. Peak serum levels are reached 30 mins. post-exposure; 50% appears in the urine within 24 hours. For acute poisoning (endotracheal intubation if inadequate tidal volume), monitor breathing and evaluate/monitor blood pressure and pulse frequently since shock may supervene with little warning. Monitor ECG immediately; watch for arrhythmias and evidence of Q-T prolongation or T-wave changes. Maintain monitor. Treat shock vigorously with isotonic saline (in 5% glucose) to restore blood volume and enhance renal excretion. Where evidence of hypocalcaemic or normocalcaemic tetany exists, calcium gluconate (10 ml of a 10% solution) is injected to avoid tachycardia. For acute or short term repeated exposures to strong acids: Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially. Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling. Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise. Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in specific tissues. INGESTION: Immediate dilution (milk or water) within 30 minutes post ingestion is recommended. DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury. Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult. Charcoal has no place in acid management. Some authors suggest the use of lavage within 1 hour of ingestion. SKIN: Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping. Deep second-degree burns may benefit from topical silver sulfadiazine. EYE: Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT use neutralising agents or any other additives. Several litres of saline are required. Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears may be indicated dependent on the severity of the injury. Steroid eye drops should only be administered with the approval of a consulting ophthalmologist). Medical Conditions Aggravated by Exposure No information available on medical conditions aggravated by exposure to this product. Form 21047, Revision 3, Page 3 of 10, 14-Jun-2017 02:24:52 Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 5. FIRE FIGHTING MEASURES General Measures If safe to do so, move undamaged containers from fire area. Do NOT move cargo if cargo has been exposed to heat. Dam fire control water for later disposal. Avoid generating dust. Flammability Conditions Product is a non-flammable solid. Extinguishing Media In case of fire, use Water spray or fog, Foam, Dry chemical powder, BCF (where regulations permit), Carbon dioxide. Fire and Explosion Hazard Product is a combustible solid. Hazardous Products of Combustion Decomposition may produce toxic fumes of:, hydrogen fluoride , nitrogen oxides (NOx) Special Fire Fighting Instructions Clear fire area of all non-emergency personnel. Stay upwind. Keep out of low areas. Eliminate ignition sources. Move fire exposed containers from fire area if it can be done without risk. Do NOT allow fire fighting water to reach waterways, drains or sewers. Store fire fighting water for treatment. Personal Protective Equipment Fire fighters should wear a positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots and gloves) or chemical splash suit. Please note: Structural fire fighters uniform will provide limited protection. Flash Point No Data Available Lower Explosion Limit No Data Available Upper Explosion Limit No Data Available Auto Ignition Temperature No Data Available Hazchem Code 2X 6. ACCIDENTAL RELEASE MEASURES General Response Procedure Avoid accidents, clean up immediately. Increase ventilation. Avoid walking through spilled product as it is slippery when spilt. Isolate the danger area. Use clean, non-sparking tools and equipment. Shut off all possible sources of ignition. Clean Up Procedures Minor spills : Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Use dry clean up procedures and avoid generating dust. Place in a suitable, labelled container for waste disposal. Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. Check regularly for spills and leaks. Major spills : Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Consider evacuation (or protect in place). Stop leak if safe to do so. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Neutralise/decontaminate residue (see Section 13 for specific agent). Collect solid residues and seal in labelled drums for disposal. Wash area and prevent runoff into drains. After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using. If contamination of drains or waterways occurs, advise emergency services Containment Stop leak if safe to do so. Environmental Precautionary Measures Do not allow product to reach drains, sewers or waterways. If product does enter a waterway, advise the Environmental Protection Authority or your local Waste Authority. Evacuation Criteria Evacuate all unnecessary personnel. Personal Precautionary Measures Personnel involved in the clean up should wear full protective clothing as listed in section 8. 7. HANDLING AND STORAGE Handling Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and recommended procedures. Wash thoroughly after handling. Take precautionary measures against static discharges by bonding and grounding equipment. Avoid contact with eyes, skin and clothing. Do not inhale product vapours. Avoid prolonged or repeated exposure. Operations should be carried out in an efficient fume hood or equivalent system. Remove contaminated clothing and wash before reuse. Discard contaminated shoes. Keep away from combustible material. Chemicals should be used only by those trained in handling potentially hazardous materials. Storage Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such as damage or leaks. Protect against physical damage. Store away from incompatible materials as Form 21047, Revision 3, Page 4 of 10, 14-Jun-2017 02:24:52 Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 listed in section 10. Keep away from acids. Keep away from strong bases. This product has a UN classification of 1727 and a Dangerous Goods Class 8 (corrosive) according to The Australian Code for the Transport of Dangerous Goods by Road and Rail. Container Container type/packaging must comply with all applicable local legislation. Store in original packaging as approved by manufacturer. Drums and jerricans must be of the non-removable head type. Where a can is to be used as an inner package, the can must have a screwed enclosure. DO NOT use aluminium or galvanised containers. DO NOT use unlined steel containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION General No exposure standard has been established for this product by the Australian Safety and Compensation Council (ASCC). However, the exposure standard for dust not otherwise specified is 10mg/m3 (for inspirable dust) and 3mg/m3 (for respirable dust). No exposure standard has been established for this product by the Australian Safety and Compensation Council (ASCC). However, the exposure standard for dust not otherwise specified is 10mg/m3 (for inspirable dust) and 3mg/m3 (for respirable dust). Exposure Limits No Data Available Biological Limits No information available on biological limit values for this product. Engineering Measures A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Adequate ventilation should be provided so that exposure limits are not exceeded. Personal Protection Equipment RESPIRATOR: Always use a approved respirator when necessary (AS1715/1716). EYES: Wear appropriate protective eyeglasses or chemical safety goggles (AS1336/1337). HANDS: Wear appropriate protective gloves to prevent skin exposure (AS2161). CLOTHING: Long-sleeved protective clothing and safety footwear (AS3765/2210). Work Hygienic Practices No Data Available 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Solid Appearance Rhombohedral crystal Odour Pungent odour Colour White pH <1 28% solution Vapour Pressure 1hPa torr (@ 20 °C) Relative Vapour Density No Data Available Boiling Point 239.5 Deg C @ 760 mmHg Melting Point 125 °C Freezing Point 125 °C Solubility 630 g/L 20°C Specific Gravity 1.50 Flash Point No Data Available Auto Ignition Temp No Data Available Evaporation Rate No Data Available Bulk Density No Data Available Corrosion Rate No Data Available Decomposition Temperature No Data Available Density No Data Available Specific Heat No Data Available Molecular Weight 57.04 Net Propellant Weight No Data Available Form 21047, Revision 3, Page 5 of 10, 14-Jun-2017 02:24:52 Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 Octanol Water Coefficient No Data Available Particle Size No Data Available Partition Coefficient No Data Available Saturated Vapour Concentration No Data Available Vapour Temperature No Data Available Viscosity No Data Available Volatile Percent No Data Available VOC Volume No Data Available Additional Characteristics No Data Available Potential for Dust Explosion No Data Available Fast or Intensely Burning Characteristics No Data Available Flame Propagation or Burning Rate of Solid Materials No Data Available Non-Flammables That Could No Data Available Contribute Unusual Hazards to a Fire Properties That May Initiate or Contribute to Fire Intensity No Data Available Reactions That Release Gases or Vapours No Data Available Release of Invisible Flammable Vapours and Gases No Data Available 10. STABILITY AND REACTIVITY General Information Corrosive Solid. Chemical Stability Product is stable under normal conditions of use, storage and temperature. Conditions to Avoid Incompatible materials, moisture, temperatures above 300°C. Materials to Avoid Reacts with water forming a weak solution of hydrofluoric acid reacts violently with bases releasing ammonia gas attacks glass, cement and most metals in the presence of moisture upon contact with moisture and meal may release flammable hydrogen gas which may collect in confined spaces -a void aluminium, nickel or steel containers when heated to decomposition emits toxic and corrosive fumes of ammonia, hydrogen fluoride and nitric oxides. Hazardous Decomposition Products Decomposition may produce toxic fumes of:, hydrogen fluoride , nitrogen oxides (NOx) Hazardous Polymerisation Hazardous polymerisation will not occur. 11. TOXICOLOGICAL INFORMATION General Information No Data Available EyeIrritant Causes eye burns. Ingestion Poison by ingestion. Causes gastrointestinal tract burns. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause headache. May cause nausea and vomiting. Chronic ingestion may cause chronic fluoride poisoning (fluorosis) characterized by weight loss, weakness, anemia, brittle bones, and stiff joints. May cause digestive tract disturbances. Inhalation May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Chronic inhalation and may cause chronic fluoride poisoning (fluorosis) characterized by weight loss, weakness, anemia, brittle bones, and stiff joints. May cause digestive tract disturbances. SkinIrritant Causes skin burns. Contact with liquid is corrosive and causes severe burns and ulceration. Carcinogen Category No Data Available Form 21047, Revision 3, Page 6 of 10, 14-Jun-2017 02:24:52 Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 12. ECOLOGICAL INFORMATION Ecotoxicity Fish toxicity: LC0 zebra-fish: 137 mg/L/96 h Bacteria toxicity: EC50 activated sludge: 2394 mg/L Persistence/Degradability No information available on persistence/degradability for this product. Mobility No information available on mobility for this product. Environmental Fate Do NOT let product reach waterways, drains and sewers. Bioaccumulation Potential No information available on bioaccumulation for this product. Environmental Impact No Data Available 13. DISPOSAL CONSIDERATIONS General Information Dispose of in accordance with all local, state and federal regulations. All empty packaging should be disposed of in accordance with Local, State, and Federal Regulations or recycled/reconditioned at an approved facility. Special Precautions for Land Fill Contact a specialist disposal company or the local waste regulator for advice. Incinerate at an approved site following all local regulations. This material may be suitable for approved landfill. 14. TRANSPORT INFORMATION Land Transport (Australia) ADG Proper Shipping Name AMMONIUM HYDROGENDIFLUORIDE, SOLID Class 8 Corrosive Substances Subsidiary Risk(s) No Data Available EPG 37 Toxic And/Or Corrosive Substances Non-Combustible UN Number 1727 Hazchem 2X Pack Group II Special Provision No Data Available Land Transport (Malaysia) ADR Code Proper Shipping Name AMMONIUM HYDROGENDIFLUORIDE, SOLID Class 8 Corrosive Substances Subsidiary Risk(s) No Data Available EPG 37 Toxic And/Or Corrosive Substances Non-Combustible UN Number 1727 Hazchem 2X Pack Group II Special Provision No Data Available Land Transport (New Zealand) NZS5433 Proper Shipping Name Form 21047, Revision 3, Page 7 of 10, 14-Jun-2017 02:24:52 AMMONIUM HYDROGENDIFLUORIDE, SOLID Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 Class 8 Corrosive Substances Subsidiary Risk(s) No Data Available EPG 37 Toxic And/Or Corrosive Substances Non-Combustible UN Number 1727 Hazchem 2X Pack Group II Special Provision No Data Available Land Transport (United States of America) US DOT Proper Shipping Name AMMONIUM HYDROGENDIFLUORIDE, SOLID Class 8 Corrosive Substances Subsidiary Risk(s) No Data Available ERG 154 Substances - Toxic and/or Corrosive (Non-Combustible) UN Number 1727 Hazchem No Data Available Pack Group II Special Provision No Data Available Sea Transport IMDG Proper Shipping Name AMMONIUM HYDROGENDIFLUORIDE, SOLID Class 8 Corrosive Substances Subsidiary Risk(s) No Data Available UN Number 1727 Hazchem No Data Available Pack Group II Special Provision No Data Available EMS FA,SB Marine Pollutant No Air Transport IATA Proper Shipping Name AMMONIUM HYDROGENDIFLUORIDE, SOLID Class 8 Corrosive Substances Subsidiary Risk(s) No Data Available UN Number 1727 Hazchem No Data Available Pack Group II Special Provision No Data Available National Transport Commission (Australia) Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) Dangerous Goods Classification 15. REGULATORY INFORMATION Form 21047, Revision 3, Page 8 of 10, 14-Jun-2017 02:24:52 Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 General Information No Data Available Poisons Schedule (Aust) 7 Environmental Protection Authority (New Zealand) Hazardous Substances and New Organisms Amendment Act 2015 Approval Code HSR003970 National/Regional Inventories Australia (AICS) Listed Canada (DSL) Not Determined Canada (NDSL) Not Determined China (IECSC) Not Determined Europe (EINECS) Not Determined Europe (REACh) Not Determined Japan (ENCS/METI) Not Determined Korea (KECI) Not Determined Malaysia (EHS Register) Not Determined New Zealand (NZIoC) Listed Philippines (PICCS) Not Determined Switzerland (Giftliste 1) Not Determined Switzerland (Inventory of Notified Substances) Not Determined Taiwan (NCSR) Not Determined USA (TSCA) Not Determined 16. OTHER INFORMATION Related Product Codes AMBIFL1000, AMBIFL1001, AMBIFL1002, AMBIFL1003, AMBIFL1004, AMBIFL1005, AMBIFL1006, AMBIFL1007, AMBIFL1008, AMBIFL1009, AMBIFL1010, AMBIFL1011, AMBIFL1012, AMBIFL1013, AMBIFL1014, AMBIFL1100, AMBIFL1200, AMBIFL1300, AMBIFL2000, AMBIFL2001, AMBIFL2002, AMBIFL2500, AMBIFL2600, AMBIFL3000, AMBIFL4000, AMBIFL5000, AMBIFL5800, AMBIFL5801, AMBIFL5802, AMBIFL5803, AMBIFL5804, AMBIFL5805, AMBIFL5806, AMBIFL5807, AMBIFL5808, AMBIFL5809, AMBIFL5810, AMBIFL5811, AMBIFL5812, AMBIFL6000, AMBIFL1800, AMBIFL1801, AMBIFL1802, AMBIFL3500 Revision 3 Revision Date 11 Feb 2014 Key/Legend < Less Than > Greater Than AICS Australian Inventory of Chemical Substances atm Atmosphere CAS Chemical Abstracts Service (Registry Number) cm² Square Centimetres CO2 Carbon Dioxide COD Chemical Oxygen Demand Form 21047, Revision 3, Page 9 of 10, 14-Jun-2017 02:24:52 Safety Data Sheet Ammonium Bifluoride Revision 3, Date 11 Feb 2014 deg C (°C) Degrees Celcius EPA (New Zealand) Environmental Protection Authority of New Zealand deg F (°F) Degrees Farenheit g Grams g/cm³ Grams per Cubic Centimetre g/l Grams per Litre HSNO Hazardous Substance and New Organism IDLH Immediately Dangerous to Life and Health immiscible Liquids are insoluable in each other. inHg Inch of Mercury inH2O Inch of Water K Kelvin kg Kilogram kg/m³ Kilograms per Cubic Metre lb Pound LC50 LC stands for lethal concentration. LC50 is the concentration of a material in air which causes the death of 50% (one half) of a group of test animals. The material is inhaled over a set period of time, usually 1 or 4 hours. LD50 LD stands for Lethal Dose. LD50 is the amount of a material, given all at once, which causes the death of 50% (one half) of a group of test animals. ltr or L Litre m³ Cubic Metre mbar Millibar mg Milligram mg/24H Milligrams per 24 Hours mg/kg Milligrams per Kilogram mg/m³ Milligrams per Cubic Metre Misc or Miscible Liquids form one homogeneous liquid phase regardless of the amount of either component present. mm Millimetre mmH2O Millimetres of Water mPa.s Millipascals per Second N/A Not Applicable NIOSH National Institute for Occupational Safety and Health NOHSC National Occupational Heath and Safety Commission OECD Organisation for Economic Co-operation and Development Oz Ounce PEL Permissible Exposure Limit Pa Pascal ppb Parts per Billion ppm Parts per Million ppm/2h Parts per Million per 2 Hours ppm/6h Parts per Million per 6 Hours psi Pounds per Square Inch R Rankine RCP Reciprocal Calculation Procedure STEL Short Term Exposure Limit TLV Threshold Limit Value tne Tonne TWA Time Weighted Average ug/24H Micrograms per 24 Hours UN United Nations wt Weight Form 21047, Revision 3, Page 10 of 10, 14-Jun-2017 02:24:52
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