The International System of Units: A shift to fundamental constants Alan Steele NCSLI 2011 Facebook Metrology Outline • A bit about the SI and the Convention of the Metre – Base Units in the International System – Thinking about the metric system – The General Conference on Weights and Measures • Proposed p Changes g to the SI – Fundamental constants – New definitions for kg, A, K, mol – New wording for s, m, cd • The time line for change – it’s not this year! International System of Units • SI units must be: – stable, invariant, self-consistent – independent of other parameters – transferable at the lowest uncertainty – realizable at the lowest uncertaintyy SI & Fundamental Constants • SI units must be: – stable, invariant, self-consistent – independent of other parameters, – transferable at the lowest uncertainty – realizable at the lowest uncertainty • Fundamental constants are: – stable, invariant, self-consistent – independent of other parameters, parameters – universally transferable – determinations are sometimes limited by SI units SI : Proposed Change In essence essence, the change involves exactly fixing the values of 7 constants that set the scale of the units themselves: c – speed of light Δν – ground state hyperfine splitting frequency of 133Cs h – Planck constant E = hυ e – the elementary charge charge on an electron k – Boltzmann constant E = kT NA – Avogadro constant number of entities in a mole Kcd – luminous efficacy of 540 × 1012 Hz radiation Think about Speed • With definitions for units of length (metre) and time interval (second), we can derive a unit for speed: v = d / t (in metre per second) Speed Of Light • With a definition for the unit of time interval (second) and a fixed value for a fundamental constant such as the speed of light (metre / second), we can define the unit of length (metre): d=c*s • Th The metre t is i the th length l th off the th path th travelled t ll d b by lilight ht iin vacuum during a time interval of 1/299 792 458 of a second. second Not Quite the Speed Of Light • If we used a different fixed value for the fundamental constant we would alter the size of the unit of length: d' = c' * s • The newMetre is the length of the path travelled by light in vacuum during a time interval of 1/300 000 000 off a second. d It is i slightly li htl shorter h t than th the th SI metre t but b t the new speed of light is easier to remember! Visit the BIPM Website... ...get the SI Brochure ...and read about the “New SI” Metre Convention (1875) • The International Bureau shall operate under the exclusive direction and supervision of an International Committee for Weights and Measures, itself placed under the authority of a General Conference on Weights and Measures, consisting of the delegates of all the contracting Governments Governments. General Conference • The mission of the CGPM is to discuss and instigate measures necessary for the propagation and improvement of the metric system as well as to approve new fundamental metrological determinations that might have been made in the interval between its meetings • Votes at a General Conference are made by Member States, each State has the right to one vote. Convocation of CGPM • The General Conference on Weights and Measures is convoked for its 24th meeting for Monday 17 October 2011 in Paris. • Much of this talk is drawn from the Convocation published to guide the meeting, circulated as a part of the invitation to each of the Member States • This includes background information and DRAFT Resolutions on the various agenda items The Original SI (~1880) kg m N J W s K Four base units, all independent and all based on artefacts g – international p prototype yp kg m – quadrant of the earth s – rotation of the earth K – fixed points of water The SI Today Δν kg c Kcd μ s 0 K cd mol m NA N A u m(12C)/12 J C V F Ω W The Electrical “SI”, As Used • Since 1990 the Josephson and Quantum Hall effects have been used to realize the volt and the ohm SI Did NOT Change in 1990 • Adopting conventional values for RK-90 K 90 and KJ-90 J 90 improved electrical metrology • Fixing the values of h and e at that time was not possible since our knowledge was insufficient and we would have broken the equivalence principle between mechanical and electrical force • Electrical metrology is routinely outside the SI and the proposed change fixes this CGPM Draft Resolution A • takes note of the intention of the International Committee for Weights and Measures to propose a revision to the SI as follows: • the International System of Units, Units the SI, SI will be the system of units in which: – the ground state hyperfine splitting frequency of the caesium 133 atom Δν(133Cs)hfs hf is exactly 9 192 631 770 hertz – the speed of light in vacuum c is exactly 299 792 458 metre per second, – the Planck constant h is exactly 6.626 06X × 10-34 joule second, – the elementary charge e is exactly 1.602 17X × 10-19 coulomb, – the Boltzmann constant k is exactly 1.380 6X × 10-23 joule per kelvin, – the Avogadro constant NA is exactly 6.022 14X × 1023 reciprocal mole, – the luminous efficacyy Kcd of monochromatic radiation of frequency q y 540 × 1012 Hz is exactly 683 lumen per watt, Base Units: kg • the kilogram will continue to be the unit of mass • its magnitude will be set by fixing the numerical value of the Planck constant to be equal to exactly 6.626 06X × 10-34 when it is expressed in the SI unit m2 kg s-11, which is equal to J s Base Units: A • the ampere will continue to be the unit of electric current • its magnitude will be set by fixing the numerical value of the elementary charge to be equal to exactly 19 when it is expressed in the SI unit 1.602 17X × 10-19 A s, which is equal to C, Base Units: K • the kelvin will continue to be the unit of thermodynamic temperature • its magnitude will be set by fixing the numerical value of the Boltzmann constant to be equal to exactly 23 when it is expressed in the SI unit 1.380 6X × 10-23 m2 kg s-2 K-1, which is equal to J K-1, Base Units: mol • the mole will continue to be the unit of amount of substance of a specified elementary entity • its magnitude will be set by fixing the numerical value of the Avogadro constant to be exactly equal to 23 when it is expressed in the SI unit 6.022 14X × 10-23 mol-1. New Wording for Old Units • Although there is no immediate intention to change the definitions for the second, metre or candela the intention is to re-write them using the new language to enhance the understandability of the new System Base Units: s • the second is the unit of time • its magnitude is set by fixing the numerical value of the ground state hyperfine splitting frequency of the caesium 133 atom, at rest and at a temperature of 0 K, to be equal to exactly 9 192 631 770 when it is expressed in the SI unit s-1, which is equal to Hz Base Units: m • the metre is the unit of length • its magnitude is set by fixing the numerical value of the speed of light in vacuum to be equal to exactly 299 792 458 when it is expressed in the SI unit m s-1 Base Units: cd • the candela is the unit of luminous intensity in a given direction • its magnitude is set by fixing the numerical value of the luminous efficacy of monochromatic radiation of frequency 540 × 1012 Hz to be equal to exactly 683 when it is expressed in the SI unit m-2 kg-1 s3 cd sr, or cd sr W-1, which is equal to lm W-1 The Proposed Change NA c Δν h e k Kcd mol m s V Ω K cd dalton ~m((12C)/12 A F u W Mu kg 1u ~ m(12C)/12 No longer Exact an experimentally derived quantity μ ε 0 No llonger exact, N t a derived quantity 0 No longer exact, d i d quantity tit a derived Nothing Is Free... • To ensure a seamless transition for the four base units involved in the proposal, we will use the best experimental values of the fundamental constants to make the change • The best experimental uncertainties of the four fundamental constants involved in the proposed change don’t don t just disappear forever when we fix their values Consequence for kilogram • The mass of the international prototype of the kilogram m(K) will be exactly 1 kg but with a relative uncertainty equal to that of the recommended value of h just before redefinition and that subsequently its value will be determined experimentally Consequence for Ampere • The magnetic constant (permeability of vacuum) μ0 will be exactly 4π × 10-7 H m-1 but with a relative uncertainty equal to that of the recommended value of the fine-structure constant α and that subsequently its value will be determined experimentally Consequence for Kelvin • The thermodynamic triple point of water TTPW will be exactly 273.16 K but with a relative uncertainty equal to that of the recommended value of k just before redefinition and that subsequently its value will be determined experimentally Consequence for mole • The molar mass of carbon 12 M(12C) will be exactly 0.012 kg mol-1 but with a relative uncertainty equal to that of the recommended value of NA just before redefinition and that subsequently its value will be determined experimentally. The Proposed Change NA c Δν h e k Kcd mol m s V Ω K cd dalton ~m((12C)/12 A F u W Mu kg 1u ~ m(12C)/12 No longer Exact an experimentally derived quantity μ ε 0 No llonger exact, N t a derived quantity 0 No longer exact, d i d quantity tit a derived When Will This Happen? k e Δν NA c Kcd • When we’re sure we’re ready! h
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