Lesson Plan Outline for Science Saturdays Title of Lesson: Waste to Energy Target Grades: 11th and 12th grade; most appropriate for AP Biology or AP Chemistry Time Required: 90 minutes Materials Needed: candle, glass, lighter, list of amounts of wastewater produced by each state (in millions of gallons per day), calculators, dimensional analysis worksheet, access to internet and GoogleDocs Background Information Needed by Teachers Fuel cells Types of energy and energy conversion Cellular Respiration including ATP production Oxidation/Reeducation reactions Electrogen bacteria Dimensional analysis and conversions Greenhouse effect Use of GoogleDocs to make spreadsheets Needed by Students Relationship of greenhouse gases to climate change Basics of cellular respiration; more in depth knowledge will make this lesson easier Basics of redox reactions Use of calculator to do math involving exponents Lesson Objectives Students will be able to describe how bacteria can use cellular respiration to produce energy that can be harvested by a fuel cell. Students will be able to use dimensional analysis to calculate the MWh/day that can be produced by a certain amount of wastewater (MGD). Students will be able to analyze data using a chart generated by GoogleDocs. Instructional Process Hook Student Actions Enter, read prompt, and begin brainstorming a list of alternative energy options. Teacher Actions Display a prepared prompt asking students to develop a list of alternative energy options. Share alternative energies with class. Add to class list to develop as inclusive a list as possible. After a few minutes of brainstorming, have students share answers. Develop a large class list of all alternative energy options. Think about similarities between these sources. Share them with the class. Participate in class discussion. Discuss similarities of these alternative energies. Focus on the fact that they are renewable. Transition into new material discussion of microbial fuel cells, which is likely not on the brainstorming list. Introduction of New Material Student Actions Listen attentively. Take notes. Ask questions as necessary. Connect to prior knowledge by recognizing that bacteria can produce electrons during cellular respiration. Teacher Actions Describe the general structure of a fuel cell. Introduce microbial fuel cells, which use bacteria as a catalyst. Describe the general method by which bacteria break down sugar to release electrons which can be used to generate electricity. This is bio-electricity. Ask students to recall a process by which bacteria could generate electrons. View the demo. Answer questions asked by teacher. Light a candle. Talk to students about combustion and the fuel and oxygen needed. Place a glass over the candle to limit the amount of oxygen that the candle has. Describe cellular respiration as the “burning” of carbs, requiring oxygen. Answer teacher questions about cellular respiration. Offer elaboration on other students’ answers. Review cellular respiration; focus on electron transport and ATP synthase. Stress the movement of electrons. Allow the class to lead this review, if you have already taught cellular respiration. Explain that unlike the burning candle, some organisms can use molecules other than oxygen for cellular respiration, but there will be less energy produced. The electrogen bacteria in the fuel cells are anaerobic. Explain that the electrogen bacteria can pass their electrons from cellular respiration through an electron transport chain and to a biological nanowire that can be used to harvest electricity. This is how a microbial fuel cell works. After being used to generate electricity, the electrons are finally accepted by oxygen on the cathode side of the microbial fuel cell to create water, like in human cellular respiration. Practice Student Actions Listen attentively. Ask questions to clarify. Recall prior knowledge about dimensional analysis (if applicable). Teacher Actions Now that students understand how a fuel cell works, they can calculate the potential energy production from a microbial fuel cell using wastewater. Show/review dimensional analysis with students. Be sure students understand that they must cancel unit on top and bottom to obtain the desired end units. Show students a sample calculation using dimensional analysis. Beginning with wastewater in MGD, use a calculator, equalities, and dimensional analysis to determine the number of MWh/day that can be produced in the assigned state using microbial fuel cells which break down organic matter in wastewater. Pass out dimensional analysis worksheets and give each student a slip of paper with one state’s wastewater production in millions of gallons/day. **NOTE: numbers on info sheet are in millions of gallons/day, but the dimensional analysis worksheet begins with gallons/day, so students will need to be sure to account for that.** Rotate, checking on student progress. Enter data into computer as instructed. View instructor created graph OR create down graphs, depending on goals of instructor. Closing Student Actions Answer questions in writing or through class discussion as directed by instructor. Analyze and think critically about the graph produced. Recall knowledge of cellular respiration and relate it to MFCs. Instruct students to input data into an excel spreadsheet or googledocs for display. If desired, students could generate their own graphs by hand or using a program for additional mathematics practice. If this is not the goal of the lesson, displaying a class graph for discussion will allow the students to accomplish the lesson objectives. Teacher Actions Provide analysis questions for students to interpret the graph. Examples: 1. Which state could produce the most energy from wastewater? Why do you think this state has more wastewater than others? 2. Given that 24MWh/day could power 750 homes, how many homes could be powered by microbial fuel cells using the wastewater in all of TN? The US? 3. Do you feel that microbial fuel cells are a viable alternative energy source? Justify your response using information you have learned today. Provide content review questions to ensure student understanding of cellular respiration and the connection between it and the electricity production by electrogen bacteria. Example: 1. Describe how the electrons that are transferred from the anode to the cathode in a microbial fuel cell are generated by bacteria. Where did these electrons originate? 2. Why do living things produce these electrons? In other words, what important process do these electrons naturally power? Assessment/Follow-up Student knowledge of dimensional analysis can be assessed by having them calculate the MWh/day from a different state’s wastewater (WGD). Knowledge of cellular respiration driving MFCs can be assessed using an essay or multiple choice exam. Key Vocabulary Bio-electricity Anode Cellular Respiration Anaerobic Fuel Cell Cathode ATP Synthase Electrogen bacteria Microbial fuel cell Catalyst Aerobic Wastewater Safety and Cleanup Required This lesson has no special safety or cleanup concerns. Alignment with TN Science and Math Standards Algebra I CLE 3102.1.5 Recognize and use mathematical ideas and processes that arise in different settings, with an emphasis on formulating a problem in mathematical terms, interpreting the solutions, mathematical ideas, and communication of solution strategies. CLE 3102.1.7 Use technologies appropriately to develop understanding of abstract mathematical ideas, to facilitate problem solving, and to produce accurate and reliable models. CLE 3102.5.1 Describe and interpret quantitative information. Algebra II CLE 3103.1.2 Apply and adapt a variety of appropriate strategies to problem solving, including testing cases, estimation, and then checking induced errors and the reasonableness of the solution. CLE 3103.1.4 Move flexibly between multiple representations (contextual, physical, written, verbal, iconic/pictorial, graphical, tabular, and symbolic), to solve problems, to model mathematical ideas, and to communicate solution strategies CLE 3103.1.5 Recognize and use mathematical ideas and processes that arise in different settings, with an emphasis on formulating a problem in mathematical terms, interpreting the solutions, mathematical ideas, and communication of solution strategies. CLE 3103.1.7 Use technologies appropriately to develop understanding of abstract mathematical ideas, to facilitate problem solving, and to produce accurate and reliable models. CLE 3103.2.3 Use appropriate technology (including graphing calculators and computer spreadsheets) to solve problems, recognize patterns and collect and analyze data. CLE 3103.2.4 Understand the capabilities and limitations of technology when performing operations, graphing, and solving equations involving complex numbers. CLE 3103.5.1 Describe, interpret, and apply quantitative data. Biology CLE 3210.Inq.3 Use appropriate tools and technology to collect precise and accurate data. CLE 3210.Inq.4 Apply qualitative and quantitative measures to analyze data and draw conclusions that are free of bias. CLE 3210.Inq.6 Communicate and defend scientific findings. CLE 3210.3.2 Distinguish between aerobic and anaerobic respiration. Chemistry CLE 3221.Inq.3 Use appropriate tools and technology to collect precise and accurate data. CLE 3221.Inq.4 Apply qualitative and quantitative measures to analyze data and draw conclusions that are free of bias. CLE 3221.Inq.6 Communicate and defend scientific findings. CLE 3221.3.3 Explore the mathematics of chemical formulas and equations. Alignment with AP College Board Enduring Understandings AP Biology EU 2A: Growth, reproduction and maintaining the organization of living systems require energy and matter. EU 2B: Growth, reproduction and homeostasis require that cells create and maintain internal environments that are different from their external environments. EU 2D: Growth and homeostasis of a biological system are influenced by changes in the system’s environment. AP Chemistry EU 3A: Chemical changes are represented by a balanced chemical reaction that identifies the ratios with which reactants react and products form. EU 3C: Chemical and physical transformations may be observed in several ways and typically involve a change in energy. EU 4C: Many reactions proceed via a series of elementary reactions EU 4D: Reaction rates may be increased by the presence of a catalyst. EU 5B: Energy is neither created nor destroyed but only transformed from one form to another Resources STATE AL AZ AK CA CO CT DE DC FL GA HI ID IL IN IA KS KY # waste treatment plants 286 121 362 570 235 91 18 1 359 306 22 168 675 418 763 628 243 MGD 629.2 266.2 796.4 1254 517 200.2 39.6 2.2 789.8 673.2 48.4 369.6 1485 919.6 1678.6 1381.6 534.6 MWh/day 340 144 431 678 280 108 21 1 427 364 26 200 803 498 908 747 289 LA MN MD MA MI MN MS MO MT NE NV NH NJ NM NY NC OH OK OR PA SC SD TN TX UT VT VA WA WV WI WY 166 136 167 124 391 139 315 746 114 468 48 88 156 27 582 330 723 490 215 830 165 25 244 1326 106 73 228 92 257 591 97 365.2 299.2 367.4 272.8 860.2 305.8 693 1641.2 250.8 1029.6 105.6 193.6 343.2 59.4 1280.4 726 1590.6 1078 473 1826 363 55 536.8 2917.2 233.2 160.6 501.6 202.4 565.4 1300.2 213.4 198 162 199 148 465 165 375 888 136 557 57 105 186 32 693 393 861 583 256 988 196 30 290 1578 126 87 271 110 306 703 115 Purpose: You will use dimensional analysis to determine the amount of energy in MWh/day (Megawatt hours/day) produced by a particular amount of waste water in MGD (million gallons per day). Instructions • Start with a known value and your desired end value units. • Fill in the chart with “equalities” from the list to the right that cause your units to cancel. A unit on the bottom can cancel out the same unit on top. • Continue to cancel units using equalities until you are only left with your desired end value units on the top and bottom. • Multiply numbers across the top and bottom to get your end value in the correct units. Equalities 1 day = 24 hours 3.785L = 1 gal 1 hour = 3600 sec 0.2g organic matter = 1 L 1 mole organic matter = 30g organic matter 4 moles e- = 1 mole organic matter Beginning value End Value = gal moles e- day Reduce your number from above to moles e-/ 1 second by dividing the numerator by the denominator. sec ___________moles e1 sec *This conversion factor will cancel all units, leaving you with MWh/day. x 0.46313* = ___________MWh 1 day Instructions for Creating Map Display of Data in GoogleDocs 1. Sign into Google Account. Click on “drive.” 2. Click “create” and then “spreadsheet.” 3. In cell 1A, type State as a column title. In cell 1B, type Power (MWh/day) as a column title. 4. Type (or have students type) the state abbreviations in column A. 5. Type (or have students type) the calculated amount of power generated by wastewater in each state in column B. 6. Click “insert” and “chart.” 7. Next to “recommended charts” click “more.” 8. Click “map” and then choose the map that displays large circles. 9. Look at the tabs at the top of the Chart Editor box. Click “Customize.” 10. Select “United States” for the region. Change the colors as you’d like. Click “Insert.” 11. Click the chart that has been inserted into your spreadsheet. A small arrow will appear in the upper right hand corner. Click it. Click “move to own sheet.” 12. You can now switch back and forth between the spreadsheet and your graph using the tabs at the bottom of the webpage. The circles on your map will change as data is entered into the spreadsheet.
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