Thinking (Electro) Negatively CLASS SET! Chemists wanted a way to measure the relative attraction for the pair of electrons shared between two atoms. In 1932 Linus Pauling created the scale for electronegativity given above. The scale indicates how strongly an atom attracts shared electrons. An atom with a large electronegativity attracts shared electrons very strongly. Part One: Electronegativity Examine the table above and answer the following questions: 1. What happens to the electronegativity values across each period from left to right? 2. What happens to the electronegativity values up each group from bottom to top? 3. If you had a bond between a metal atom and a nonmetal atom, which of the two is more electronegative? Explain your thinking. 4. Where are the atoms with the greatest electronegativity values located? Are they metals or nonmetals? 5. Where are the atoms with the lowest electronegativity values located? Are they metals or nonmetals? 6. Why do you think the noble gases have electronegativity values of zero? 7. Circle the atom in each pair below which will attract shared electrons more strongly: a. C or Cl b. Rb or Br c. Ag or S d. As or Na 8. If the difference in electronegativity is greater than 2.1, then the bond is considered ionic. Use the electronegativity table above to create 3 (legit, neutral) compounds with ionic bonds. 9. If the difference in electronegativity is between 0.50 and 2.1, then the bond is polar covalent. What does it mean to be polar covalent? 10. Use the electronegativity table above to create 3 (legit, neutral) examples of compounds with polar covalent bonds. Thinking (Electro) Negatively CLASS SET! 11. If the difference in electronegativity is between 0 and 0.49, then the bond is nonpolar covalent. What does it mean to be nonpolar covalent? 12. Use the electronegativity table above to create 3 (legit, neutral) examples of compounds with nonpolar covalent bonds. 13. Metal atoms tend to form cations with positive charges. Is this consistent with the electronegativity of metal atoms? Why or why not? 14. Do nonmetal atoms tend to form cations with positive charges or anions with negative charges? Explain your thinking. 15. Sulfur forms both ZnS and SF2. Is sulfur the most electronegative element in both compounds? Why or why not? Part Two: Putting it all together Complete the following chart: Molecule Total # valence e- in molecule CCl4 32 H2O SiH2O SiO2 NH3 HCF3 Lewis Dot Structure Structural Formula Shape of molecule Bond angle Electronega tivity differences for each bond Tetrahe dral 109. 5o Cl-C = 0.5 Draw polarity arrows for each bond Is the molecule polar or nonpolar ? Will it dissolve in water? Can we smell it? Nonpol ar No No
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