Car & Home Care 3 segments Home Care Surface Care Furniture and wood polishes Floor polish Metal/stainless steel polish Shoe & Leather care Glass cleaners Carpet cleaning products Tile grout sealers Antistatic solutions Car Care Surface Care Wash and Rinse Aid Exterior Car polish Windscreen & glass cleaners Tire/Rim Care Interior Trim/Dashboard Leather renovators Home Care Laundry Care Laundry detergents additives Fabric softeners additives Dry cleaning Car Care Consumer requirements Speed / Ease of Use Shine / Colour Enhancement Water Repellancy Cleaning ability What is a Polish ? Polish = a temporary coating that enhances and protects the substrate to which it is applied Enhances by cleaning and increasing gloss/color Protects by depositing a barrier film that repels water and also gives a degree of dirt repellency Why are silicones used in Car Care? Ease of application - Lubricant Polish cleaning ability - increase surface wettability Ease of polishing - lubricant, less effort to polish Gloss / Shine Increase Colour Intensity (depth of gloss) Surface Protection - Durability & Detergent Resistance Water Repellency – Long lasting Streakability - reduces “streaking” of polish Surface Smoothness/slip - less easy for dirt to adhere Characteristics of Silicones CHARACTERISTIC BENEFIT Low surface tension Spreads on most surfaces Strong Si-O & Si-C bonds UV, oxidative, thermal & chemical stability High R.I:(1.375 -1.403) Gloss Low intermolecular forces (high chain flexibility) Lubricity & high permeability, low surface friction Methyl groups Water repellency Low Glass Transition Liquids at high molecular weight Silicones for the Car Care industry Silicone Emulsions & Silicone Oils - BRB Sempure 35, Sempure 60 & 66 - BRB Sempure HV 6500 & BRB Sempure 1997 - BRB Silicone Oils 50, 350, 1000, 12.500, 60.000 cSt Aminofunctional Silicones - BRB Sempure 3733, BRB Sempure 135 Paintable Silicones - BRB Sempure 5332, BRB Alkyl Aryl Fluid Volatile Silicones - BRB CM 40, CM 50, Silicone oil 0,65 cst Silicone Glycols - BRB 526, 6373, 356 Silicone emulsions : benefits Ease of Application – Streak resistance Improved Cleaning - Low surface tension, increases surface wetting. Allows more intimate contact between the abrasives/solvents and surface Polishing - Lubrication properties makes this much easier Depth of Gloss / Color Water repellency - Forms a lower surface tension film that promotes water beading Slip - Gives a smooth/lower friction surface Silicone emulsions & oils: range Sempure 35 & 60/66 35 or 60% non-ionic emulsion of mid viscosity PDMS for general purpose polish formulations Sempure HV 6500 60% non-ionic emulsion of high & low viscosity PDMS blend for premium polish formulations Optimized balance between ease of application, spreading, gloss & durability Sempure 1997 55% non-ionic emulsion of high viscosity PDMS for superior shine and long durability Silicone oils 50, 350, 1.000, 12.500, 60.000 cSt For customers who want to emulsify by themselves and fine tune their own emulsions Formulation of Silicone oils Formulation properties Oil soluble, not water soluble Medium viscosity: easier application & emulsification Higher viscosity: better protection & conditioning Defoaming properties Can be formulated into Solvent in water emulsions, normally use 50-1000 cSt PDMS Water in solvent - can include high visc fluids Polish formulations - use a combination of high/medium viscosity fluids to optimize benefits 3 : 1 : 1 350 1000 60.000 ease of use / optimise gloss / durability Properties optimization by formulating silicone oils TYPE GLOSS PDMS (50cs) PDMS (350cs) PDMS (1000cs) PDMS (12.500cs) PDMS (60.000cs) ## #### ##### ## # DURABILITY PROTECTION some # ## ### #### EASY TO APPLY ##### #### ### ## # WETTING SPREADING #### ### ## # - Aminofunctional Fluids for durability Polar amine groups effectively anchors the product to substrate -> physical attraction to negatively charged surfaces Reactive grades crosslink to form a polymer film with high detergent resistance and effective protection, How is durability achieved The amino functionality ensures a firm anchoring of the polish to the paintwork NH2 NH2 NH2 + + + Paint -----------------------------------------Reactive groups crosslink Aminofunctional Fluids: range BRB Sempure 3733 40% cationic emulsion of amino silicone for extended durability and slip BRB Sempure 135 NEW 35% non-ionic micro-emulsion for car care shampoo and windscreen washes formulations (water repellency, gloss, durability, antifog) Gloss Silicone oil 1000 Polish Durability BRB Sempure 3733 or BRB Sempure 135 Ease of Use Silicone oil 350 Paintable Silicones The Silicones listed below are all capable of being over-painted Required for special polishes before car body repair work or customizing BRB Sempure 5332 Paintable 50% non-ionic emulsion of alkyl aryl silicone BRB Alkyl Aryl Fluid For customers who want to emulsify by themselves Also volatile Fluids are over-paintable: BRB CM 40 BRB CM 50 BRB Silicone oil 0.65 cst Volatile Fluids Applications Replace solvent as carriers in polish formulations (for “solventless” solvent formulations) Good spreading and easy to rub out Cleaners-lift and remove dirt, low surface tension increases surface wettability, provides more contact between abrasives & surface Typical Properties / Benefits Oil, alcohol solubility Volatile Non-greasy Good spreadability/wetting Leaves no residue Colorless/odorless Safe for most common surfaces Product range BRB CM 50 (cyclic) BRB CM 40 (cyclic) Silicone oil 0,65 cst (linear) depending on required rate of evaporation Silicone Glycols Applications Designed for formulating stable water in silicone emulsions or emulsions in which volatile silicones make up the oil phase. Emulsions based on silicone glycols are less greasy than typical water in oil products. Typical Properties / Benefits Foam booster / foam quality Water/alcohol dispersible Spreading, wetting agents - Low surface tension - Improve cleaning of oils & greases Antifogging Lubricity Emulsification, dispersing agents Product range BRB 526 BRB 6373 BRB 356 (trisiloxane - superspreader) Silicones for Car Care Application selector guide Water based Silicone oils Solvent based Wash and Rinse Aid Exterior car polish/ conditioner o Silicone emulsions Aminofunctional silicones (oils/emulsions) Alkyl Aryl silicones Volatile silicones Silicone glycols Tire/ Rim Care Interior Trim/ Dashboard Leather o o o o o o o o o o o o o Glass Care o o o o o o o o Silicones for Car Care Performance characteristics Shine Durability Ease of use Wetting Silicone oils 50 – 1000 cSt 10.000 – 60.000 cSt ▲ ▲ ▲ ▲ ▲ Silicone emulsions Sempure 35, 60 & 66 Sempure HV 6500 Sempure 1997 ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ Aminofunctional silicones Sempure 3733 Sempure 135 BRB 864 / 869 ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ Alkyl Aryl silicones BRB Alkyl Aryl Fluid & Sempure 5332 ▲ ▲ ▲ ▲ Volatile silicones Silicone oil 0,65 cSt, CM40, CM50 ▲ ▲ Silicone glycols BRB 526 / 356 / 6373 ▲ ▲ Customer support Formulation support We can provide examples of formulations using our silicones Sales of ready-to-use products Allows the customers to test the market before formulating by themselves Introduction of new ingredients Customer support Ready-to-use products with silicones : BRB PTFE Clean & Shine Polish for 2nd hand cars (abrasive) BRB New Car Polish Polish for new cars (mild) BRB Glass Water Repellant Windscreen polish BRB Cockpit Shine Dashboard polish Ready-to-use products w/o silicones : BRB Truck Clean – car shampoo Screen wash Concentrate and Ready Mix Home Care segments Surface Care Furniture and wood polishes Floor polish Metal/stainless steel polish Shoe & Leather care Glass cleaners Carpet cleaning products Tile grout sealers Antistatic solutions Home - Surface Care applications Furniture and wood polish Shine ingredients in liquid o/w furniture care emulsions providing full surface conditioning & protection Floor polish additives Active ingredients in o/w emulsions or solvent-based floor care formulations providing a durable non-slip but easy-to-polish protective film Shoe & leather care High gloss, lubrication for sponges. Useful spreading, leveling & wetting of shoe polishes Metal & Glass cleaners (+ mirrors & Shower cabinet sprays) Offers transient shine, anti-streak by slow drying and anti-fogging Carpet cleaners Defoamers are widely used in ‘foam-cleaning’ machines – Rugdoctor Plant care Aids gloss enhancement in leaf-shine products Silicones for Surface Care Silicone Oils Solvent-based formulations basis or for emulsion production Silicone Emulsions Gloss & water repellent additive for water-based polish Volatile Silicones Replace organic solvent as carriers in polish formulations Silicone Glycols Foam boosters and wetting agents in floor & surface cleaners Amino-functional Silicones Provide durability & detergent resistance to surface care products Silicone resins Provide enhanced film forming & water-repellency Silicone antifoams Foam control in floor polish and carpet cleaners Inhibits foam development in formulations, aids bottle filling BRB surface care product range Silicone oils & Silicone emulsions BRB Silicone Oils 50, 350, 1000, 12.500, 60.000 cSt BRB Sempure 35, Sempure 60 BRB Sempure 1997 BRB Sempure HV 6500 Volatile Silicones BRB CM 40, CM 50, Silicone oil 0,65 cst Silicone Glycols BRB 526, 6373, BRB 356 NEW Aminofunctional Emulsions BRB Sempure 3733, Sempure 230 NEW Silicone resins BRB TMS Silicone antifoams BRB Snapsil RE 10, 20 BRB Snapsil 100 New Polyether modified Trisiloxane • BRB 356 - properties • Superspreading surfactant based on trisiloxane ethoxylate • Outstanding surface tension reduction • Water soluble • Benefits • Improves spray coverage • Excellent penetration, antifogging and sheeting properties • Reduces surface tension already at very low level (0,1%) New for hard surface cleaners • BRB Sempure 230 - properties • 30% active, micro-emulsion of silicone quaternium polymer • Specifically developed for cleaning formulations • Offers shine and protection to ceramics, glass and painted surfaces • Benefits • • • • • Hydrophobising film former Reduces formation of streaks and scale on tiles and glass Increases the durability of water based polishes Easy to formulate into aqueous blends Typical use : 0,5% as received Silicone Antifoams • BRB Snapsil RE 10, 20 • Alkali resistant, silicone based antifoam emulsions • Specifically developed for technical applications and to be used in a broad pH • Good high temperature performance • Excellent knockdown as well as defoaming performance • RE 10 : 15 % active content • RE 20 : 30 % active content • BRB Snapsil 100 • Highly effective, silicone based antifoam compound which has been developed specifically for non-aqueous system • Outstanding reliability and versatility • Excellent knockdown Surface care: product selector Product Shoe / Leather Care Furniture Polish Silicone oils 50 to 60,000 cSt X X Silicone emulsions Sempure 35 & 60 Sempure HV 6500 & Sempure 1997 X X Volatile silicones Silicone oil 0,65 cSt, CM40, CM50 X Silicone glycols BRB 356, 526, 6373 X X Aminofunctional silicones Sempure 3733 Sempure 230 BRB 864 / 869 X X Silicone resins BRB TMS X X Antifoams BRB Snapsil RE 10, 20, Snapsil 100 Cleaners X X Home Care segments Laundry Care Laundry detergents additives Fabric softeners additives Dry cleaning Laundry Care applications Laundry detergents Silicone antifoams prevent and knock down foam that occurs during consumer use & during manufacture For liquid, powder, tablet detergents Fabric softeners Silicones emulsions incorporated into fabric softeners & ironing aids Enhanced softness, improves iron-glide and better water absorbency Dry cleaning Alternative to perchlorethylene Silicone route is nontoxic, nonhazardous waste Gentler on garments and does not cause colour loss Usually requires spotting agents Requires a license from GreenEarth Cleaning Silicones for Laundry Care Silicone antifoams Foam control in liquid detergents & fabric conditioners Antifoam systems for powder detergents (post-addition or spray on) Silicone Glycols Wetting agent, ease of ironing benefit in liquid laundry tablets Silicone Emulsions Softness, anti-wrinkle, ease of ironing and water absorbency for fabric softeners Volatile Silicones Dry cleaning solvent Laundry Care product range Silicone antifoams BRB Snapsil RE 10, RE 20 BRB Snapsil 100 BRB Snapsil 20LD NEW Silicone Glycols BRB 526 Silicone Emulsions BRB Sempure 35, 60 BRB Sempure 3733 BRB Sempure 270 Under development Volatile Silicones BRB CM 50 New Antifoam for Laundry Care • BRB Snapsil 20LD • 20% active, highly effective white emulsion • Ideal for opaque liquid detergents New Silicones for Laundry Care • BRB Sempure 270 - properties 70% active, micro-emulsion of Quat Polyether terpolymer Specifically developed for fabric treatment Recommended for use in rinse-cycle laundry products. Compatible in aqueous dispersion with organic softeners (e.g. esterquats). • Typical formulation contains 2.5% BRB Sempure 270 and 15% organics. • Post-addition with moderate agitation • • • • • Benefits • Deposits onto fabric from the rinse cycle • Enhance softness (silicones have a silky feel attenuating the ‘greasier’ organics) • Promotes ease ironing • Improve water absorbency Laundry care: product selector Product Liquid laundry detergent BRB Snapsil RE 10, 20 X BRB Snapsil 100 X BRB Snapsil 20LD X BRB 526 Liquid laundry tablets Powder laundry detergents Fabric softeners X X BRB Sempure 35 & 60 X BRB Sempure 3733 & 270 X BRB CM 50 Dry Cleaning X Ambition Flexibility Innovation
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